Physical Sciences and Mathematics Commons^™

Laser Initiated Chain Reactions: The Kinetics Of The Chlorine/Cyclohexane/Oxygen Chain System, Robert Alan Forlines

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The combination of laser photolysis with infrared chemiluminescence detection has proven an effective technique for determining the propagation rate coefficients of halogen + RH chain reactions. This thesis will extend the technique to cyclic alkanes by determining the propagation rate coefficients of the Cl₂/ cyclohexane chain system as well as the rate coefficient for the primary chain termination mechanism, R + O₂ → RO₂. The following reaction scheme is supported by the kinetic analysis: Cl₂ → 2Cl Laser Photolysis Cl + RH → HCl(v) + R First Propagation Step (k₁) R + …

Synthetic Approach To Epibatidine From 1-(Phenylsulfonyl)Pyrrole, Brandon G. Vanness

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The goal of this research was to synthesize the natural product epibatidine, a non-opiate analgesic and nicotinic acetylcholine agonist isolated from Epipedobates tricolor. A synthetic pathway utilizing a Diels-Alder cycloaddition of a 3-pyridyl substituted pyrrole and tosylacetylene was conceived based upon the original mass spectral fragmentation pathway of epibatidine determined by Daly. Although this pathway had been previously attempted using 1-(triisopropyl)-3-[5-(2-chloropyridyl)]pyrrole in the key Diels-Alder step, the lack of cycloadduct suggested that a pyrrole with a more electron withdrawing protecting group was required for this step. Therefore, synthesis of 1-(phenylsulfonyl)-3-[5-(2-chloropyridyl)]pyrrole via a palladium catalyzed cross-coupling reaction of 1-(phenylsulfonyl)-3-pyrroline and …

Evidence Of A Pre-Mount Simon, Half-Graben In Greene County, Ohio By Reprocessing A Wright State University Seismic Line, John Sink

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The reprocessing of the WSU2002 seismic line indicates the presence of a Precambrian half-graben. Also observed through this reprocessing is the possible presence of Paleozoic structures. Although Paleozoic features have been interpreted, variations in glacial drift thickness evidenced by glacial drift maps also may have contributed to a lower quality of stacked section in comparison to other seismic lines. WSU2002 was originally processed by Lauren Geophysical. The Lauren processing resulted in an image that was of much lower quality than corresponding seismic lines. The Lauren Geophysical processed section revealed many horizontal Paleozoic reflections, with no prominent reflectors beneath the Paleozoic. …

Summaritive Digest For Large Document Repositories With Application To E-Rulemaking, Lijun Chen

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Large document repositories need to be organized and summarized to make them more accessible and understandable. Such needs exist in many applications, including web search, e-rulemaking (electronic rulemaking) and document archiving. Even though much has been done in the areas of document clustering and summarization, there are still many new challenges and issues that need to be addressed as the repositories become larger, more prevalent and dynamic. In this dissertation, we investigate more informative ways to organize and summarize large document repositories, especially e-rulemaking feedback repositories (ERFRs), so that the large repositories can be managed and digested more efficiently and …

Tailoring Branching For Poly (Arylene Ether)S Via Reactivity Ratio Controlled Polymerizations, Amanda Ike

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The ability to control physical and mechanical properties of polymer systems has become an important aspect of polymer science. In order to tailor the branching in polymer systems, an understanding into the reactivity of the electrophilic sites in the monomer is important. Kinetic methods have been explored in order to determine the reactivity of monomers in preparing poly(arylene ether)s and to predict the degree of branching that will occur in a polymer of this kind. The reactivity of AB2 sulfones and phosphine oxides was explored, along with the reactivity of ABB'B'' sulfones. NMR spectroscopy was used as a probe into …

Porosity And Permeability Of Bimodal Sediment Mixtures Using Natural Sediment, Peter M. Phillips

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Porosity and permeability are parameters that affect the flow of ground water in the subsurface and have significant implications on the modeling of fate and transport of contaminants. However, little has been done to quantitatively examine the effect on porosity and permeability of packing in bimodal mixtures of natural sediment. This study compares measurements of porosity and permeability on model bimodal sediment mixtures with predictions from petrophysical models. The main goal is to evaluate how well these petrophysical models predict porosity and permeability in bimodal mixtures of natural sediment. The effect of the volume fraction of fines on porosity and …

Polarization Reversal In Potassium Titanyl Phosphate, William D. Mitchell

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Polarization reversal in both hydrothermal and flux grown potassium titanyl phosphate was studied using square pulses at room temperature from 1600 V/mm to 5000 V/mm. Maximum switching current and inverse switching time data is compared to the ferroelectric polarization reversal model developed by Fatuzzo and Merz in the last century. Room temperature calculation of spontaneous polarization is reported and compared to that of potassium titanyl phosphate in the literature.

An Analog Evolvable Hardware Device For Active Control, Saranyan A. Vigraham

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The field of Evolvable Hardware (EH) has recently gained a lot of interest due to the novel methodology it offers for designing electrical circuits and machines. EH techniques involve configuring a reconfigurable hardware platform with the aid of learning engines such as evolutionary algorithms. The EH devices normally act as closed loop controllers with the capability of learning necessary control laws adaptively. Current EH practices have several shortcomings, which have restricted their use as reliable controllers. This dissertation will present an improved EH device based on behavioral reconfigurability that addresses the current open challenges in the field of analog Evolvable …

Xml Integrated Environment For Service-Oriented Data Management, Marwan Younes Maarouf

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The proliferation of XML as a family of related standards including a markup language (XML), formatting semantics (XSL style sheets), a linking syntax (XLINK), and appropriate data schema standards have emerged as a de facto standard for encoding and sharing data between various applications. XML is designed to be simple, easily parsed and self-describing. XML is based on and support the idea of separation of concerns: information content is separated from information rendering, and relationships between data elements are provided via simple nesting and references. As the XML content grows, the ability to handle schemaless XML documents becomes more critical …

The Electroanalytical Performance Of Sonogel Carbon Titanium (Iv) Oxide Electrodes Versus Conducting Polymer Electrodes In The Electrochemical Detection Of Biological Molecules, Jelynn A. Stinson

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The electrochemical performance of a newly developed sonogel carbon titanium (IV) oxide (SGC/TiO2 ) electrode against poly(3-methylthiophene) (P3MT) and poly(2,2'-bithiophene) (PBTP) modified electrodes in the electrochemical detection of biological molecules is reported. The stability of the Titanium (IV) Oxide coating on the sonogel carbon electrode was shown to be greater than the P3MT coating on the conventional size glassy carbon electrode. After 10 consecutive scans, there was a 21% loss of the initial signal at the P3MT modified electrode and a 5% loss of the initial signal at the SGC/TiO2 electrode. The influence of NAD+ on NADH response was tested. …

Hydrophobically Modified Polyethyleneimines And Ethoxylated Polyethyleneimines, Michael Joseph Simons

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The modification of the commercially available polymers polyethyleneimines and ethoxylated polyethyleneimines took place with approximately a 3-10% alkylbromide modification followed by, in the case of the polyethyleneimines, a 2-hydroxypropyl modification, using propylene oxide, on the order of 65-70%. The objective was to increase the hydrophobicity of the polymer while keeping the cloud point above 60°C. Another approach taken was to form hydrophobic ethers from ethoxylated polyethyleneimine. We also added a 2-hydroxy ethyl group to a hexylated polyethyleneimine avoiding the use of ethylene oxide or drying EPI.

Comparative Investigation Of Dosimetric Tools In Imrt, Aaron Nicholas Garcia

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Verification of the isodose distribution delivered to the planned tumor volume is required for quality assurance in the clinic. Verification in this context means ensuring that the actual dose delivered to a volume matches the dose that a computerized planning system intended that volume to receive. The computerized planning is performed by a Computerized Medical Systems (CMS) Intensity Modulated Radiation Therapy (IMRT) plan. Two methods of measuring the delivered dose are film dosimetry and diode dosimetry. This project will compare the relative isodose distribution profiles of film dosimetry and MapCheck (Sun Nuclear Corporation, a diode-based dosimetry system) to the relative …

Simple Descriptors For Modeling The Solubility Of Gases, Alcohols, And Halogenated Hydrocarbons In Water, Sule Sidigu

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The Statmost, QSARIS, Excel, and SAS programs were used to model the solubility of gases, alcohols, and halogenated hydrocarbons in water using simple physical and topological descriptors. The alcohols were well-modeled using measures of the number of carbons, terminal methyls, and steric hindrance about the hydroxyl group. Molecular mass, boiling point, and critical volume or critical pressure were the best descriptors for the halogenated hydrocarbons. Critical pressure was the most applicable single descriptor for the gases. Molecular mass and boiling point also yielded good results for the gases and halogenated hydrocarbons when regressed together.

Gpu-Assisted Rendering Of Large Tree-Shaped Data Sets, Pallavi Ramachandra Mangalvedkar

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Due to their complexity, medical data sets can easily comprise of several gigabytes in size. For example, geometric representations of a coronary arterial tree spanning vessels from the large proximal coronary arteries down to the capillary level consist of 6 gigabytes or more of geometry data, depending on the accuracy of the geometric representation. Visualization of such large data sets using the CPU alone can be inefficient and time consuming since they require special out-of-core techniques due to the size of the data set. The usage of the GPU can help render such data sets faster compared to CPU-based implementations …

Formation Of A Sydno[3,4- A]Indolone And Reactions Thereof, Ryan Christopher Vikan

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In the present work, a synthetic route to the formation of a sydno[3,4- a]indolone was explored in the hope of attaining the first example of a fused-ring sydnone with an sp2-hybridized bridge. Formation of this product and exploration of its chemical behavior was anticipated to be of particular interest to the formation of NO-releasing prodrugs. A direct synthetic pathway to yield the target sydnoindolone starting from 3-(2-methoxycarbonylphenyl)sydnone and reaction with a base was proposed and explored. Attempted formation and isolation of the target sydnoindolone proved impossible under a variety of different conditions, undoubtedly due to the instability of this …

Biogeochemical Processes And Seasonal Effects In Flow-Through Mesocosm Reactors Simulating Constructed Wetlands, Sarah J. Tritschler

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Due to their distinctive environments, constructed wetlands are utilized to remediate groundwater that has been contaminated with chlorinated ethenes (i.e. perchloroethene) and other such contaminants. This research focuses on vertical flow mesocosm reactors housed in a greenhouse at Wright State University, which simulate a constructed wetland on Wright-Patterson Air Force Base. These reactors were studied to investigate the effects of vegetation and seasonal changes on the redox parameters present. Water samples were collected from six different reactors from late September/early October 2006 until August 2007. The reactors were sampled three days in a row and this sampling was done once …

A Hybrid Approach To Retrieving Web Documents And Semantic Web Data, Trivikram Immaneni

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The Semantic Web has been evolving into a property-linked web of RDF data, conceptually divorced from (but physically housed in) the World Wide Web of hyperlinked documents. Data Retrieval techniques are typically used to retrieve data from the Semantic Web while Information Retrieval techniques are used to retrieve documents from the Hypertext Web. Conceptually unifying the two webs enables the exploitation of their interconnections resulting in benefits to both data and document retrieval. Towards this end, we present the Unified Web model that integrates the two webs and formalizes the structure and the semantics of their interconnections. We present a …

Implicit Online Learning With Kernels, Li Cheng, S. V. N. Vishwanathan, Dale Schuurmans, Shaojun Wang, Terry Caelli

Kno.e.sis Publications

We present two new algorithms for online learning in reproducing kernel Hilbert spaces. Our first algorithm, ILK (implicit online learning with kernels), employs a new, implicit update technique that can be applied to a wide variety of convex loss functions. We then introduce a bounded memory version, SILK (sparse ILK), that maintains a compact representation of the predictor without compromising solution quality, even in non-stationary environments. We prove loss bounds and analyze the convergence rate of both. Experimental evidence shows that our proposed algorithms outperform current methods on synthetic and real data.

Regression Cubes With Lossless Compression And Aggregation, Yixin Chen, Guozhu Dong, Jiawei Han, Jian Pei, Benjamin W. Wah, Jianyong Wang

Kno.e.sis Publications

As OLAP engines are widely used to support multidimensional data analysis, it is desirable to support in data cubes advanced statistical measures, such as regression and filtering, in addition to the traditional simple measures such as count and average. Such new measures will allow users to model, smooth, and predict the trends and patterns of data. Existing algorithms for simple distributive and algebraic measures are inadequate for efficient computation of statistical measures in a multidimensional space. In this paper, we propose a fundamentally new class of measures, compressible measures, in order to support efficient computation of the statistical models. For …

Active Semantic Electronic Medical Record, Amit P. Sheth, Sangeeta Agrawal, Jonathan Lathem, Nicole Oldham, H. Wingate, K. Gallagher

Kno.e.sis Publications

The healthcare industry is rapidly advancing towards the widespread use of electronic medical records systems to manage the increasingly large amount of patient data and reduce medical errors. In addition to patient data there is a large amount of data describing procedures, treatments, diagnoses, drugs, insurance plans, coverage, formularies and the relationships between these data sets. While practices have benefited from the use of EMRs, infusing these essential programs with rich domain knowledge and rules can greatly enhance their performance and ability to support clinical decisions. Active Semantic Electronic Medical Record (ASEMR) application discussed here uses Semantic Web technologies to …

{Ontology: Resource} X {Matching : Mapping} X {Schema : Instance} :: Components Of The Same Challenge, Amit P. Sheth

Kno.e.sis Publications

Ontologies enable us to elevate syntactic and structural processing in an information system/Web to an information system/Web powered with semantic processing. Experience has shown that monolithic and tightly coupled approaches seldom succeed, and majority of information systems and applications will need to deal with plurality of ontologies in a loosely coupled environment (i.e., independently evolving ontologies and inter-ontology relationships, existence of different contexts for different users/applications etc.) Development of such loosely-coupled multi-ontology environments entails development of techniques for ontology mapping/alignment, multi-ontology query processing, and much more.

How To Reason With Owl In A Logic Programming System, Markus Krotzsch, Pascal Hitzler, Denny Vrandecic, Michael Sintek

Computer Science and Engineering Faculty Publications

Logic programming has always been a major ontology modeling paradigm, and is frequently being used in large research projects and industrial applications, e.g., by means of the F-Logic reasoning engine OntoBroker or the TRIPLE query, inference, and transformation language and system. At the same time, the Web Ontology Language OWL has been recommended by the W3C for modeling ontologies for the Web. Naturally, it is desirable to investigate the interoperability between both paradigms. In this paper, we do so by studying an expressive fragment of OWL DL for which reasoning can be reduced to the evaluation of Horn logic programs. …

On The Complexity Of Horn Description Logics, Markus Krotzsch, Sebastian Rudolph, Pascal Hitzler

Computer Science and Engineering Faculty Publications

Horn-SHIQ has been identified as a fragment of the description logic SHIQ for which inferencing is in PT_IME with respect to the size of the ABox. This enables reasoning with larger ABoxes in situations where the TBox is static, and represents one approach towards tractable description logic reasoning. In this paper, we show that reasoning in Horn-SHIQ, in spite of its low datacomplexity, is E_xpT_IME-hard with respect to the overall size of the knowledge base. While this result is not unexpected, the proof is not a mere modification of existing reductions since …

Magnetopolaron Effect On Shallow Donors In Gan, A. Wysmolek, R. Stepniewski, M. Potemski, B. Chwalisz-Pietka, K. Pakula, J. M. Baranowski, David C. Look, S. S. Park, S. K. Lee

Physics Faculty Publications

Resonant interaction between longitudinal-optic (LO) phonons and electrons bound on shallow donors in GaN is studied using magnetoluminescence of neutral-donor bound excitons (D⁰X). The experiments were performed on high-quality freestanding GaN material and heteroepitaxial GaN layers grown on sapphire. In addition to the principal recombination channel of D⁰X, in which donors are left in their ground states, two-electron satellites (TES) involving different excited donor excitations, as well as replicas of the principal D⁰X transition due to LO phonons, were observed for the oxygen and silicon donors. In order to separate transitions involving ground and …

A Framework For Schema-Driven Relationship Discovery From Unstructured Text, Cartic Ramakrishnan, Krzysztof Kochut, Amit P. Sheth

Kno.e.sis Publications

We address the issue of extracting implicit and explicit relationships between entities in biomedical text. We argue that entities seldom occur in text in their simple form and that relationships in text relate the modified, complex forms of entities with each other. We present a rule-based method for (1) extraction of such complex entities and (2) relationships between them and (3) the conversion of such relationships into RDF. Furthermore, we present results that clearly demonstrate the utility of the generated RDF in discovering knowledge from text corpora by means of locating paths composed of the extracted relationships.

Analysis Of Large Scale Image Data Using Out-Of-Core Techniques, Chandrashekara H. Raju, Thomas Wischgoll

Computer Science and Engineering Faculty Publications

No abstract provided.

Ceg 210: Pc Networking I, Chris P. Fickert

Computer Science & Engineering Syllabi

An introduction to PC networking hardware, software, concepts, and technologies. Focus is on LAN administration, hardware, and software configuration.

Course Goals

At the end of the quarter the student will be able to:

• design and configure a client/server network
• create and manage network objects
• plan and implement directory services and the network file systems
• plan and implement network security
• design and write network login scripts
• manage and solve problems related to a client/server network

Ceg 434/634: Concurrent Software Design, Natsuhiko Futamura

Computer Science & Engineering Syllabi

This course provides an introduction to concurrent program design in the UNIX environment. Classical problems of synchronization, concurrency , and their solutions are examined through the course projects and through readings on operating system design text book.

Ceg 333: Introduction To Unix, Thomas Wischgoll

Computer Science & Engineering Syllabi

By the end of this quarter, you should be able to:

• Describe the basic methodology of UNIX filters, including pipes and redirection of stdin/stdout

• Program simple UNIX utilities at the command-line and shell-script level • Discuss the advantages and disadvantages of common user interfaces {such as UNIX vs. PC/Windows)

• Discuss the philosophy of UNIX development and the open source movement

• Work comfortably in the UNIX environment

• Edit and manage files and user-level security for UNIX development

• Use standard UNIX development tools for C or C++

Ceg 221: Advanced C Programming For Engineers, Robert Helt

Computer Science & Engineering Syllabi

This course introduces advanced constructs, algorithms, and data structures in the C programming language. Emphasis is on problem solving and techniques useful to engineers. Topics include functions, array, pointers, structures as well as sorting algorithms, linked lists, complex numbers, stacks, queues, hash tables, and binary trees. 4 credit hours. Prerequisite: CEG220 (Introduction to C Programming for Engineers).