Physical Sciences and Mathematics Commons^™

Interactions Of Vanadium Compounds With Reducing Equivalents: Evidence Of Free Radical Involvement And Possible Mechanisms Of Toxicity, Randal J. Keller

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Vanadium compounds have been reported to cause numerous toxicological effects including NAD(P)H oxidation and lipid peroxidation. The purpose of this thesis is to determine the active form of vanadium in causing these effects, and to determine any possible free radical involvement in these processes. Vanadium-stimulated oxidation of NADH was studied spectrophotometrically and by electron spin resonance spectroscopy. In 25 mM sodium phosphate buffer at pH 7. 4, vanadyl, (V(IV)), is slightly more effective in stimulating NADH oxidation than was vanadate (V(V)). Addition of a superoxide generating system, xanthine/xanthine oxidase, results in a marked increase in NADH oxidation by vanadyl, and …

1-Acyldihydropyridones As Synthetic Intermediates, Michael Andrew Foley

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The most efficient and stereoselective total synthesis of (+/-)- lausbine II to date has been achieved. The key steps in this are the copper-mediated conjugate addition reaction of the Grignard reagent of 1-bromo-4-chlorobutane to a dihydropyridone and a stereoselective reduction of a quinolizidinone.

Methodology has been developed for the convenient synthesis of 1-acyl-2-substituted-1,2,5,6-tetrahydropyridines. This was accomplished by adding novel alkylzinc iodides to the 1-acyliminium ion derived from N-phenoxycarbonyl-4-methoxy-1,2,3,4-tetrahydropyridine.

A Comparison Of Rank And Bootstrap Procedures For Completely Randomized Designs With Jittering, Feng-Ling Lee

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper discusses results of a computer simulation to investigate the effect of jittering to simulate measurement error. In addition, the classical F ratio, the bootstrap F and the F for ranked data are compared. Empirical powers and p-values suggest the bootstrap is a good and robust procedure and the rank procedure seems to be too liberal when compared to the classical F ratio.

Petrology Of Pliocene (?) Basalts Of Curlew Valley (Box Elder Co.), Utah, Steven Brent Kerr

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Basalt outcrops in Curlew Valley consist of several flow remnants and eruptive centers situated along the valley margins. Basalt is also found in association with salic rocks that erupted in the central portion of the valley. The basalts are of probable Pliocene age and were erupted during a period of active extensional tectonics. Since their emplacement, the basalts have been extensively eroded and downfaulted. The present morphology reflects the erosional and depositional processes of prehistoric Lake Bonneville.

Twelve samples were analyzed chemically for major oxides, trace elements, and rare-earth elements. The basalts form a hypersthene normative series ranging from olivine …

Hydrogeology And Hydrochemistry Of Springs In Mantua Valley And Vicinity, North-Central Utah, Karen C. Rice

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Chemical and tritium analyses of groundwater, precipitation and discharge records, fracture orientations, lineaments, and structural, stratigraphic, and topographic relationships have been used to describe the groundwater systems of Mantua Valley, north-central Utah. Groundwater flows through fractured Paleozoic quartzites and carbonate rocks and discharges from eleven perennial springs in Mantua Valley. Permeability in quartzites is the result of intense faulting and jointing. Groundwater in carbonate aquifers flows through fractures and/or fractures modified by solution and discharges as relatively large springs (up to 227 liters per second). Neogene normal faulting, rather than extensive karst processes, has produced valleys which are closed or …

Nonparametric Confidence Intervals For The Reliability Of Real Systems Calculated From Component Data, Jean Spooner

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A methodology which calculates a point estimate and confidence intervals for system reliability directly from component failure data is proposed and evaluated. This is a nonparametric approach which does not require the component time to failures to follow a known reliability distribution.

The proposed methods have similar accuracy to the traditional parametric approaches, can be used when the distribution of component reliability is unknown or there is a limited amount of sample component data, are simpler to compute, and use less computer resources. Depuy et al. (1982) studied several parametric approaches to calculating confidence intervals on system reliability. The test …

Surficial Geology Of The Smithfield Quadrangle, Cache County, Utah, Michael V. Lowe

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Smithfield 7.5' quadrangle is located about 13.8 kilometers (8.6 miles) south of the Utah-Idaho State Line and occupies the central portion of the eastern side of Cache Valley, Utah. The mapped area contains more than 55 square miles. The Bear River Range on the eastern side of the quadrangle contains stratigraphic units ranging from Precambrian to Quaternary age. Cache Valley contains deposits of Tertiary and Quaternary age. Quaternary units in the Smithfield quadrangle are subdivided into thirty-two map units based on age and genesis. Five ages of Quaternary units are identified, and these units are assigned to one of …

Variational Principles Of Fluid Mechanics And Electromagnetism: Imposition And Neglect Of The Lin Constraint, Ross Roundy Allen Jr.

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Variational principles in classical fluid mechanics and electromagnetism have sprinkled the literature since the eighteenth century. Even so, no adequate variational principle in the Eulerian description of matter was had until 1968 when an Eulerian variational principle was introduced which reproduces Euler's equation of fluid dynamics. Although it successfully produces the appropriate equation of motion for a perfect fluid, the variational principle requires imposition of a constraint which was not fully understood at the time the variational principle was introduced. That constraint is the Lin constraint. The Lin constraint has subsequently been utilized by a number of authors who have …

Synthetic Studies Toward B-Alkylthiolanthionines, Hwa-Ok Kim

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Synthetic routes toward a B-alkylthiolanthionine derivative, as found in the quinomycin depsipeptide antibiotics, have been studied through a sequence involving as the key intermediates and steps (a) (S) - Z-[(benzyloxycarbonyl)amino]-3,3-dimethoxy-l-propanol (2), prepared from N-benzyloxycarbonyl-L-serine in 3 or 4 steps, (b) N-benzyloxycarbonyl- 0 - tetrahydropyranyl-B,B-(ethylsulfinylethylthio)-alaninol (4a), converted from 2, and (c) attempted Lewis acid catalyzed replacement of alkylsulfinyl function by thiol moiety of cysteine, which gave undesired products. Stability of protecting groups used in this study, which are N,0-isopropylidenyl and tetrahydropyranyl functions in N-protected-L-serinol 20 or 26, under acidic conditions was found to play an important role in determining the optical …

Spatial And Temporal Landslide Distribution And Hazard Evaluation Analyzed By Photogeologic Mapping And Relative-Dating Techniques, Salt River Range, Wyoming, John B. Rice Jr.

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The distribution of landslide type and age was analyzed to determine the causes and timing of landsliding, and to assess landslide hazards in the study area. 1173 landslides and zones of landsliding were mapped on 1:15,840 scale air photos and designated by their style of movement and age. Slides were assigned to one of four age classes based on their degree of morphologic modification visible on air photos. Relative dating (RD) methods previously applied to glacial deposits were used to refine and calibrate the age classification.

Eleven RD para meters were measured on 21 rockslide and 19 glacial deposits. Cluster …

A Test For Determining An Appropriate Model For Accelerated Life Data, Yuan-Who Chen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this thesis was to evaluate a method for testing the appropriateness of accelerated life model. This method is based upon a polynomial approximation. The parameters are estimated and used for testing the appropriateness of the model.

An example illustrates the polynomial method. Real data are applied for this method. Comparison with another method demonstrates that the polynomial method is much simpler and has comparable accuracy.

Least-Change Secant Updates Of Non-Square Matrices, Samih Kassem Bourji

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

In many problems involving the solution of a system of nonlinear equations, it is necessary to keep an approximation to the Jacobian matrix which is updated at each iteration. Computational experience indicates that the best updates are those that minimize some reasonable measure of the change to the current Jacobian approximation subject to the new approximation obeying a secant condition and perhaps some other approximation properties such as symmetry.

All of the updates obtained thus far deal with updating an approximation to an nxn Jacobian matrix. In this thesis we consider extending most of the popular updates to the non-square …

Petrology Of The Middle Cambrian Langston And Ute Formations In Southeastern Idaho, Daniel T. Rogers

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Middle Cambrian Langston and Ute formations were studied in the northern portion of the Bear River Range and the south-central part of the Portneuf Range in southeastern Idaho.

The rocks of the Langston and Ute formations were divided into 17 different rock types. The 17 rock types were formed within four recognizable lithofacies: I) Shoal - or Coastal-Peritidal Carbonate Complex; 2) Agitated Shoal; 3) Inner Marine Shelf; and 4) Outer Marine Shelf. Clastic sediments belonging to the Spence Shale Member of the Langston Formation (outer marine shelf) were deposited over the carbonate complex. A transgressive sequence marks the base …

Disturbed Alpine Ecosystems: Seedling Establishment Of Early And Late Seral Dominant Species, Jeanne C. Chambers

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This study examined the effects of seedbed and seedling environment on establishment of early and late seral dominant alpine species. Species studied included late seral dominant forbs (Geum rossii, Artemisia scopulorum, and Polemonium viscosum), early seral dominant forbs (Potentilla diversifolia and Sibbaldia procumbens), a late seral dominant grass (Festuca idahoensis), and early seral dominant grasses (Calamagrostis purpurascens and Deschampsia cespitosa). Germination responses of each species to wet vs. dry cold stratification and light vs. dark conditions were investigated. No statistical differences were observed in the seed germination of early and late …

Shamat: A Matrix Manipulation Program, Shahriyar Dadkhah

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This report is both a users guide and a programmers manual for running and modifying the program SHAMAT, an interactive matrix calculator. The program is written in Turbo Pascal version 3.0 for MS-DOS computers. This software enables the user to type in matrix equations for solving statistical problems such as multiple regression, analysis of variance, etc. All matrix operations necessary for linear models analysis are included in this program. Since each operation uses a separate subroutine, program enhancement, modification and updating is demonstrated to be easy.

Boron Composition Of Alfalfa In Utah As Related To Soils And Irrigation Waters, Robert N. Radtke Jr.

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Eighteen field plots at 15 locations were selected throughout the state to evaluate the status of the boron content in irrigation waters, soils, and alfalfa (Medicago sativa) plant tissue under irrigated conditions.

No boron deficiency symptoms were observed in any of the alfalfa plants at any of these locations, nor were any of the plant tissue boron levels inadequate. Only two locations were found in which the alfalfa plants exibited toxicity symptoms. These locations were along the Indian and Antelope Creeks in Duchesne County which contain high boron levels in the water. All the alfalfa and soil tested …

Diagenesis And Water Chemistry Of The Woodbine Group In The East Texas Basin, Helmuth Victor Wuerch

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Petrographic and SEM study of flu vial-deltaic sections of the Woodbine Group in the East Texas Basin indicates that authigenic mineral suites are controlled, in part, by the presence of organic-rich matrix.

During early, precompaction diagenesis, organic matter supplied the metabolic fuel required by sulfate-reducing bacteria to reduce sulfate in depositional waters ultimately to pyrite. With burial the sulfate supply was ultimately exhausted, and bicarbonate activity thereafter controlled the precipitation of siderite and Fe-calcite.

Matrix material supplied the components and reaction sites for the most import ant porosity-occluding reaction: kaolinite --> Fe,M g chlorite. Matrix physically inhibited the growth of …

Sedimentological And Foraminiferal Characterization Of A Holocene Island Slope (130-240m), North Jamaica, Craig V. Nelson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Recent carbonate sediments from (133-236m) on the northern Jamaican island slope are significantly different from shallower reef zones (l-70m) in grain constituents, textural parameters, and foraminiferal assemblages. The island slope sediment is dominated by coral fragments, calcareous algae, Halimeda plates, and foraminiferal tests. The sediment is characteristically poorly-sorted, nearly-symmetrically skewed, and mesokurtic, with a mean grain size in the fine sand range. Mineralogically, the sediment is predominantly aragonite (66%) and high-Mg calcite (22%), with some calcite (8%), and minor amounts of clays and other insoluble minerals (4%).

Q-mode cluster analyses of sediment constituents, textural parameters, and foraminiferal species and larger …

Structural Geology Of The Central Part Of Clarkston Mountain, Malad Range, Utah, Douglas A. Green

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The central part of Clarkston Mountain is located in northcentral Utah in the southern part of the Malad Range. It is northwest of Clarkston, Utah. The mapped area measures 2.5 mi. in the north-south direction and 6.5 mi. in the east-west direction. It is within the Basin and Range Province.

The Ute Formation of Middle Cambrian age is the oldest exposed stratigraphic unit. Other Cambrian units, in ascending order, are: Blacksmith Formation, Bloomington Formation, Nounan Formation, and St. Charles Formation. These units consist predominantly of limestone, dolostone, and shale. Units of Ordovician age include the Garden City Formation and the …

Petrology Of The Late Proterozoic(?) - Early Cambrian Arumbera Sandstone And The Late Proterozoic Quandong Conglomerate, East-Central Amadeus Basin, Central Australia, Johnnie O. Phillips

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Throughout the James Ranges and Gardiner Range the Arumbera Sandstone forms prominent strike ridges with distinctive dark reddish slopes and pale red to orange-white cliffs. Because of their lithologic and stratigraphic similarities, the names Eninta and ''Quandong" for these units should be suppressed in favor of the name of Arumbera Sandstone, which has precedence. The stratigraphic and lithologic differences observed between the Quandong Conglomerate in the type locality and the Arumbera Sandstone in the study area suggest that these units are not equivalent. Similarites with the Areyonga Formation suggest the Quandong Conglomerate could be part of the Areyonga Formation.

Lithofacies …

Direct Simulation From A Model Specification Language, Richard Pimentel

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this thesis was to develop a program that would accept, as input, a finite set of algebraic equations and simple if-then conditional expressions that model a natural system, and then produce a continuous computer simulation with graphics and tabular output. The equations and conditionals can be in any order and key elements can be missing. The program can be used to run existing models or as a development tool to produce immediate prototypic computer simulations through synergistic man-machine interactions.

The theoretical aspects of automatic program generation were discussed, as well as the architectural design of the system. …

On The Generalizations Of Gershgorin's Theorem, Sang-Gu Lee

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper deals with generalization fo Gershgorin's theorem. This theorem is investigated and generalized in terms of contour integrals, directed graphs, convex analysis, and clock matrices.

These results are shown to apply to some specified matrices such as stable and stochastic matrices and some examples will show the relationship of eigenvalue inclusion regions among them.

The Surficial Geology And Neotectonics Of Hansel Valley, Box Elder County, Utah, Robert M. Robison

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Hansel Valley, located at the north end of the Great Salt Lake in Box Elder County, Utah, has exposures of the lacustrine sediments of the Little Valley, Bonneville, and Gilbert lake cycles. A 1:50,000 scale map was constructed of the surface geology. Although no trenches were dug for this study, about 240m of logs were compiled in an arroyo in lake bottom sediments. Sediments from at least three lake cycles were found in this gully: 1) compact bottom deposits from the Little Valley cycle; 2) bottom sediments from an intermediate cycle (the Hansel Valley cycle); and 3) beach gravel and …

The Effects Of Recreation Specialization And Motivations On The Environmental Setting Preferences Of Backcountry Hikers, Randy J. Virden

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This study explored how recreation specialization and different types of motivations were related to environmental settings preferred by backcountry hikers. A questionnaire was developed that measured the level of hiking specialization, desired psychological outcomes, and preferred environmental setting attributes. Questionnaires were mailed to 619 backcountry hikers from three Intermountain West hiking areas; a response rate of 68 percent was attained.

Results of the study revealed significant associations between the level of hiking specialization and the psychological states desired by backcountry hikers. In general, increased hiking specialization served to increase the importance of specific psychological outcomes such as autonomy, exercise, achievement …

(E,2e) Spectroscopic Investigations Of The Spectral Momentum Densities Of Thin Carbon Films, John Robert Dennison

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

An (e,2e) electron scattering spectrometer has been constructed and used for the first time to investigate the spectral momentum density of the valence bands of a solid target. This technique provides fundamental information about the electronic structure of both crystalline and amorphous solids. The three fundamental quantities, the band structure, electron density of states, and electron momentum distribution can be simultaneously derived from the measured (e,2e) cross section.

A review of single electron and (e,2e) scattering theory is given with an emphasis on scattering from solids. The effects of multiple scattering are discussed and a method of deconvoluting those effects …

Parameters Controlling Sediment Composition Of Modern And Pleistocene Jamaican Reefs, Stephen K. Boss

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Recent carbonate sediments from Jamaican north coast fringing reefs display variation in constituent composition, texture, and mineralogy related to their location on the reef. Samples were collected along lines which traversed the back reef and fore reef (0.5m to 70m).

The sediment is dominated by highly comminuted coral fragments, plates of the calcareous green alga, Halimeda, coralline algae, and the encrusting Foraminifera, Homotrema rubrum, with lesser amounts of other taxonomic groups (Foraminifera; molluscs; echinoderms). Relative abundances of these biotic components vary between sites. Q-mode cluster analysis indicates that constituent composition can be used to delineate the different reef …

Structural Geology Of Eastern Part Of Dairy Ridge Quadrangle And Western Part Of Meachum Ridge Quadrangle, Utah, Val A. Kienast

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A detailed geologic investigation was made of the eastern part of the Dairy Ridge Quadrangle and the western part of the Meachum Ridge Quadrangle, Utah. The area is located in north-central Utah in Rich County. It lies between lat. 41°22'30" N. and lat. 41°28'50" N. and between long. 111°21'40" W. and long. 111°25'15" W. The area measures 13.8 km in the north-south direction and 5.5 km in the east-west direction. It is on the eastern side of the Wasatch Range about 20 km west-southwest of Randolph, Utah.

Stratigraphic units of Precambrian to Cambrian age crop out in the western part …

Sequential Thrusting Beneath The Willard Thrust Fault, Wasatch Mountains, Ogden, Utah, Tad William Schirmer

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The downstructure of viewing geologic maps, balanced and cross sections, and hanging-wall-sequence diagrams are applied to produce the first comprehensive synthesis of the structure below the willard thrust sheet.

Development of the duplex beneath the Willard thrust may be explained with a "piggyback" thrust model where younger thrust slices form below and fold an older, overlying thrust sheet. Progressive failure of the footwall ramp of the Willard thrust sheet extended the sole thrust eastward and produced a duplex consisting of thrust slices (horses) which adhered to the overriding thrust sheet where it ramped from a lower sole thrust to an …

Petrology And Mineralogy Of Tertiary(?) Volcanic Rocks Of Snowville Area, Utah, And Tertiary-Quaternary(?) Volcanic Rocks Of Table Mountain And Holbrook Areas, Idaho, Yunshuen Wang

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Basalt flows occur in the Snowville area of north-central Utah and the Table Mountain and Holbrook areas of south-central Idaho. All basalt flows are aphanitic in groundmass, and contain olivine, plagioclase, augite, and opaque oxides. They can be distinguished by texture. Snowville basalt has predominantly subophitic to intergranular textures. Table Mountain basalt is fine grained, with stumpy groundmass plagioclase and equant ilmenite crystals. Holbrook basalt has pilotaxitic to intergranular textures, with the presence of plagioclase phenocrysts and characteristic exsolution lamellae in Fe-Ti oxides. The olivine grains in Holbrook area are intensely oxidized to Fe-Ti oxides.

Snowville basalt contains olivine phenocrysts …

Structural Geology Of The Northern Part Of Elkhorn Mountain, Bannock Range, Idaho, Stephen R. Crook

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Northern Elkhorn Mountain was unmapped previous to this investigation. The mapped area is located north of Malad City, Idaho, in the Bannock Range. It is within the Basin and Range Province. The mapped area measures 5.4 mi. in the north-south direction and 8.9 mi. in the east-west direction.

The oldest exposed stratigraphic unit, within the mapped area, consists of orthoquartzite and is of Early Cambrian age. Cambrian formations of the mapped area, in ascending order, are as follows: Camelback Mountain Quartzite, Gibson Jack Formation, Elkhead Formation, Bloomington Formation, Nounan Formation, and St. Charles Formation. Units of Ordovician age are the …