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Articles 1051 - 1080 of 1524
Full-Text Articles in Physical Sciences and Mathematics
Enhanced Sodium-Ion Battery Performance By Structural Phase Transition From Two-Dimensional Hexagonal-Sns2 To Orthorhombic-Sns, Tengfei Zhou, Wei Kong Pang, Chaofeng Zhang, Jianping Yang, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Enhanced Sodium-Ion Battery Performance By Structural Phase Transition From Two-Dimensional Hexagonal-Sns2 To Orthorhombic-Sns, Tengfei Zhou, Wei Kong Pang, Chaofeng Zhang, Jianping Yang, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Australian Institute for Innovative Materials - Papers
Structural phase transitions can be used to alter the properties of a material without adding any additional elements and are therefore of significant technological value. It was found that the hexagonal-SnS2 phase can be transformed into the orthorhombic-SnS phase after an annealing step in an argon atmosphere, and the thus transformed SnS shows enhanced sodium-ion storage performance over that of the SnS2, which is attributed to its structural advantages. Here, we provide the first report on a SnS@graphene architecture for application as a sodium-ion battery anode, which is built from two-dimensional SnS and graphene nanosheets as complementary building blocks. The …
Potential Advantage Of Multiple Alkali Metal Doped Knbo3 Single Crystals, Hideo Kimura, Hongyang Zhao, Rumi Tanahashi, Lei Guo, Tingting Jia, Qiwen Yao, Zhenxiang Cheng
Potential Advantage Of Multiple Alkali Metal Doped Knbo3 Single Crystals, Hideo Kimura, Hongyang Zhao, Rumi Tanahashi, Lei Guo, Tingting Jia, Qiwen Yao, Zhenxiang Cheng
Australian Institute for Innovative Materials - Papers
Potassium niobate crystal KNbO3 (KN) is a well-known crystal for lead free piezoelectric or nonlinear optical applications. The KN crystal has been studied in both single crystal form and in thin film form which has resulted in many review articles being published. In order to exceed the KN crystal, it is important to study KN phase forming and doping effects on the K site. This article summarizes the authors' study towards a multiple alkali metal doped KN crystal and related single crystals briefly from the viewpoint of crystal growth.
Direct Evidence Of Ni Magnetic Moment In Tbni2mn-X-Ray Magnetic Circular Dichroism, D H. Yu, Meng-Jie Huang, Jianli Wang, Hui-Chia Su, Hong-Ji Lin, Chien-Te Chen, S J. Campbell
Direct Evidence Of Ni Magnetic Moment In Tbni2mn-X-Ray Magnetic Circular Dichroism, D H. Yu, Meng-Jie Huang, Jianli Wang, Hui-Chia Su, Hong-Ji Lin, Chien-Te Chen, S J. Campbell
Australian Institute for Innovative Materials - Papers
We have investigated the individual magnetic moments of Ni, Mn and Tb atoms in the intermetallic compound TbNi2Mn in the Laves phase (magnetic phase transition temperature TC ∼131 K) by X-ray magnetic circular dichroism (XMCD) studies at 300 K, 80 K and 20 K. Analyses of the experimental results reveal that Ni atoms at 20 K in an applied magnetic field of 1 T carry an intrinsic magnetic moment of spin and orbital magnetic moment contributions 0.53±0.01 μB and 0.05±0.01 μB, respectively. These moment values are similar to those of the maximum saturated moment of Ni element. A very small …
Graphene Oxide Dispersions: Tuning Rheology To Enable Fabrication, Sina Naficy, Rouhollah Jalili, Seyed Hamed Aboutalebi, Robert A. Gorkin Iii, Konstantin Konstantinov, Peter C. Innis, Geoffrey M. Spinks, Philippe Poulin, Gordon G. Wallace
Graphene Oxide Dispersions: Tuning Rheology To Enable Fabrication, Sina Naficy, Rouhollah Jalili, Seyed Hamed Aboutalebi, Robert A. Gorkin Iii, Konstantin Konstantinov, Peter C. Innis, Geoffrey M. Spinks, Philippe Poulin, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Here, we show that graphene oxide (GO) dispersions exhibit unique viscoelastic properties, making them a new class of soft materials. The fundamental insights accrued here provide the basis for the development of fabrication protocols for these two-dimensional soft materials, in a diverse array of processing techniques.
A Novel Carbon Nanotube Modified Scaffold As An Efficient Biocathode Material For Improved Microbial Electrosynthesis, Ludovic Jourdin, Stefano Freguia, Bogdan C. Donose, Jun Chen, Gordon G. Wallace, Jurg Keller, Victoria Flexer
A Novel Carbon Nanotube Modified Scaffold As An Efficient Biocathode Material For Improved Microbial Electrosynthesis, Ludovic Jourdin, Stefano Freguia, Bogdan C. Donose, Jun Chen, Gordon G. Wallace, Jurg Keller, Victoria Flexer
Australian Institute for Innovative Materials - Papers
We report on a novel biocompatible, highly conductive three-dimensional cathode manufactured by direct growth of flexible multiwalled carbon nanotubes on reticulated vitreous carbon (NanoWeb-RVC) for the improvement of microbial bioelectrosynthesis (MES). NanoWeb-RVC allows for an enhanced bacterial attachment and biofilm development within its hierarchical porous structure. 1.7 and 2.6 fold higher current density and acetate bioproduction rate normalized to total surface area were reached on NanoWeb-RVC versus a carbon plate control for the microbial reduction of carbon dioxide by mixed cultures. This is the first study showing better intrinsic efficiency as biocathode material of a three-dimensional electrode versus a flat …
Platinum Dendritic Nanoparticles With Magnetic Behavior, Wenxian Li, Ziqi Sun, Dongliang Tian, Ivan P. Nevirkovets, S X. Dou
Platinum Dendritic Nanoparticles With Magnetic Behavior, Wenxian Li, Ziqi Sun, Dongliang Tian, Ivan P. Nevirkovets, S X. Dou
Australian Institute for Innovative Materials - Papers
Magnetic nanoparticles have attracted increasing attention for biomedical applications in magnetic resonance imaging, high frequency magnetic field hyperthermia therapies, and magnetic-field-gradient-targeted drug delivery. In this study, three-dimensional (3D) platinum nanostructures with large surface area that features magnetic behavior have been demonstrated. The well-developed 3D nanodendrites consist of plentiful interconnected nano-arms ∼4 nm in size. The magnetic behavior of the 3D dendritic Pt nanoparticles is contributed by the localization of surface electrons due to strongly bonded oxygen/Pluronic F127 and the local magnetic moment induced by oxygen vacancies on the neighboring Pt and O atoms. The magnetization of the nanoparticles exhibits a …
90° Magnetic Coupling In A Nife/Femn/Biased Nife Multilayer Spin Valve Component Investigated By Polarized Neutron Reflectometry, S J. Callori, J Bertinshaw, David L. Cortie, J W. Cai, A P. Le Brun, T Zhu, Frank Klose
90° Magnetic Coupling In A Nife/Femn/Biased Nife Multilayer Spin Valve Component Investigated By Polarized Neutron Reflectometry, S J. Callori, J Bertinshaw, David L. Cortie, J W. Cai, A P. Le Brun, T Zhu, Frank Klose
Australian Institute for Innovative Materials - Papers
We have observed 90° magnetic coupling in a NiFe/FeMn/biased NiFe multilayer system using polarized neutron reflectometry. Magnetometry results show magnetic switching for both the biased and free NiFe layers, the latter of which reverses at low applied fields. As these measurements are only capable of providing information about the total magnetization within a sample, polarized neutron reflectometry was used to investigate the reversal behavior of the NiFe layers individually. Both the non-spin-flip and spin-flip neutron reflectometry signals were tracked around the free NiFe layer hysteresis loop and were used to detail the evolution of the magnetization during reversal. At low …
Magnetic Properties And Magnetocaloric Effect In Layered Ndmn 1.9v0.1si2, M F. Md Din, Jianli Wang, R Zeng, Shane Kennedy, S J. Campbell, S X. Dou
Magnetic Properties And Magnetocaloric Effect In Layered Ndmn 1.9v0.1si2, M F. Md Din, Jianli Wang, R Zeng, Shane Kennedy, S J. Campbell, S X. Dou
Australian Institute for Innovative Materials - Papers
The structural and magnetic properties of the compounds NdMn2-xVxSi2 have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9V0.1Si2 are been indicate at TC ~ 24 K and TN ~ 376 K respectively. The giant magnetocaloric effect (GMCE) around TC is found in layered NdMn1.9V0.1Si2 associated with first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc]. This behaviorhas been confirmed as contribution of the magnetostructural coupling by using neutron powder diffraction. The magnetic entropy …
Enhancement Of Transition Temperature In Fexse0.5te0.5 Film Via Iron Vacancies, J C. Zhuang, Wai K. Yeoh, Xiangyuan Cui, Jung Ho Kim, Dongqi Shi, Z X. Shi, S P. Ringer, Xiaolin Wang, S X. Dou
Enhancement Of Transition Temperature In Fexse0.5te0.5 Film Via Iron Vacancies, J C. Zhuang, Wai K. Yeoh, Xiangyuan Cui, Jung Ho Kim, Dongqi Shi, Z X. Shi, S P. Ringer, Xiaolin Wang, S X. Dou
Australian Institute for Innovative Materials - Papers
The effects of iron deficiency in Fe x Se0.5Te0.5 thin films (0.8 ≤ x ≤ 1) on superconductivity and electronic properties have been studied. A significant enhancement of the superconducting transition temperature (TC ) up to 21 K was observed in the most Fe deficient film (x = 0.8). Based on the observed and simulated structural variation results, there is a high possibility that Fe vacancies can be formed in the Fe x Se0.5Te0.5 films. The enhancement of TC shows a strong relationship with the lattice strain effect induced by Fe vacancies. Importantly, the presence of Fe vacancies alters the …
Photocatalytic Degradation Of Methyl Orange By Ceo2 And Fe-Doped Ceo2 Films Under Visible Light Irradiation, D Channei, B Inceesungvorn, N Wetchakun, S Ukritnukun, Andrew Nattestad, Jun Chen, S Phanichphant
Photocatalytic Degradation Of Methyl Orange By Ceo2 And Fe-Doped Ceo2 Films Under Visible Light Irradiation, D Channei, B Inceesungvorn, N Wetchakun, S Ukritnukun, Andrew Nattestad, Jun Chen, S Phanichphant
Australian Institute for Innovative Materials - Papers
Undoped CeO2 and 0.50-5.00 mol% Fe-doped CeO2 nanoparticles were prepared by a homogeneous precipitation combined with homogeneous/impreganation method, and applied as photocatalyst films prepared by a doctor blade technique. The superior photocatalytic performances of the Fe-doped CeO2 films, compared with undoped CeO2 films, was ascribed mainly to a decrease in band gap energy and an increase in specific surface area of the material. The presence of Fe3+ as found from XPS analysis, may act as electron acceptor and/or hole donor, facilitating longer lived charge carrier separation in Fe-doped CeO2 films as confirmed by photoluminescence spectroscopy. The 1.50 mol% Fe-doped CeO2 …
Performance Enhancement Of Single-Walled Nanotube-Microwave Exfoliated Graphene Oxide Composite Electrodes Using A Stacked Electrode Configuration, Dennis Antiohos, Mark S. Romano, Joselito M. Razal, Stephen Beirne, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Jun Chen
Performance Enhancement Of Single-Walled Nanotube-Microwave Exfoliated Graphene Oxide Composite Electrodes Using A Stacked Electrode Configuration, Dennis Antiohos, Mark S. Romano, Joselito M. Razal, Stephen Beirne, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Jun Chen
Australian Institute for Innovative Materials - Papers
We report the development of a stacked electrode supercapacitor cell using stainless steel meshes as the current collectors and optimised single walled nanotubes (SWNT)-microwave exfoliated graphene oxide (mw rGO) composites as the electrode material. The introduction of mw rGO into a SWNT matrix creates an intertwined porous structure that enhances the electroactive surface area and capacitive performance due to the 3-D hierarchical structure that is formed. The composite structure was optimised by varying the weight ratio of the SWNTs and mw rGO. The best performing ratio was the 90% SWNT-10% mw rGO electrode which achieved a specific capacitance of 306 …
Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder
Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder
Australian Institute for Innovative Materials - Papers
A long-standing technological challenge to the widespread application of thermoelectric generators is obtaining high-performance thermoelectric materials from abundant elements. Intensive study on PbTe alloys has resulted in a high figure of merit for the single-phase ternary PbTe-PbSe system through band structure engineering, and the low thermal conductivity achieved due to nanostructuring leads to high thermoelectric performance for ternary PbTe-PbS compounds. Recently, the single-phase p-type quaternary PbTe-PbSe-PbS alloys have been shown to provide thermoelectric performance superior to the binary and ternary lead chalcogenides. This occurs via tuning of the band structure and from an extraordinary low thermal conductivity resulting from high-contrast …
A Comparative Study Of Magnetic Behaviors In Tbni2, Tbmn2 And Tbni2mn, Jianli Wang, M F. Md Din, Shane Kennedy, F Hong, Stewart J. Campbell, A J. Studer, G H. Wu, Zhenxiang Cheng, S X. Dou
A Comparative Study Of Magnetic Behaviors In Tbni2, Tbmn2 And Tbni2mn, Jianli Wang, M F. Md Din, Shane Kennedy, F Hong, Stewart J. Campbell, A J. Studer, G H. Wu, Zhenxiang Cheng, S X. Dou
Australian Institute for Innovative Materials - Papers
All TbNi2, TbMn2, and TbNi2Mn compounds exhibit the cubic Laves phase with AB2-type structure in spite of the fact that the ratio of the Tb to transition-metal components in TbNi2Mn is 1:3. Rietveld refinement indicates that in TbNi2Mn the Mn atoms are distributed on both the A (8a) and B (16d) sites. The values of the lattice constants were measured to be a = 14.348 Å (space group F-43 m), 7.618 Å, and 7.158 Å (space group Fd-3 m) for TbNi2, TbMn2, and TbNi2Mn, respectively. The magnetic transition temperatures TC were found to be TC = 38 K and TC …
High Performance Pure Sulfur Honeycomb-Like Architectures Synthesized By A Cooperative Self-Assembly Strategy For Lithium Sulfur Batteries, Xin Liang, Mohammad Kaiser, Konstantin Konstantinov, Richard Tandiono, Zhaoxiang Prof Zhaoxiang Wang, Hua-Kun Liu, S X. Dou, Jiazhao Wang
High Performance Pure Sulfur Honeycomb-Like Architectures Synthesized By A Cooperative Self-Assembly Strategy For Lithium Sulfur Batteries, Xin Liang, Mohammad Kaiser, Konstantin Konstantinov, Richard Tandiono, Zhaoxiang Prof Zhaoxiang Wang, Hua-Kun Liu, S X. Dou, Jiazhao Wang
Australian Institute for Innovative Materials - Papers
Honeycomb-like pure sulfur architectures were synthesized by a cooperative self-assembly strategy, in which a soft template is used to form the porous structure. Their electrochemical performance is significantly improved comparing with the commercial sulfur powder and the as-prepared sulfur without honeycomb morphology. There has been no report on using a soft template to prepare honeycomb-like sulfur particles.
Printed Ionic-Covalent Entanglement Hydrogels From Carrageenan And An Epoxy Amine, Shannon Bakarich, Paul Balding, Robert Gorkin Iii, Geoffrey M. Spinks, Marc In Het Panhuis
Printed Ionic-Covalent Entanglement Hydrogels From Carrageenan And An Epoxy Amine, Shannon Bakarich, Paul Balding, Robert Gorkin Iii, Geoffrey M. Spinks, Marc In Het Panhuis
Australian Institute for Innovative Materials - Papers
Carrageenan/epoxy amine ionic-covalent entanglement hydrogels were fabricated on a 3D printer. The thermal gel transition behaviour of the biopolymer kappa-carrageenan was exploited to fix the shape of the patterned ink until a covalent polymer network formed by epoxy amine addition chemistry. The printed hydrogels display a work of extension value of 1.4 ± 0.3 MJ m-3.
Tuning Three-Dimensional Tio2 Nanotube Electrode To Achieve High Utilization Of Ti Substrate For Lithium Storage, Zhijia Zhang, Qing-Yi Zeng, Shulei Chou, Xinjun Li, Huijun Li, Kiyoshi Ozawa, Hua-Kun Liu, Jiazhao Wang
Tuning Three-Dimensional Tio2 Nanotube Electrode To Achieve High Utilization Of Ti Substrate For Lithium Storage, Zhijia Zhang, Qing-Yi Zeng, Shulei Chou, Xinjun Li, Huijun Li, Kiyoshi Ozawa, Hua-Kun Liu, Jiazhao Wang
Australian Institute for Innovative Materials - Papers
Three-dimensional (3D) TiO2 nanotube arrays grown on Ti mesh were prepared via the anodization process. The diameters of the Ti and TiO 2/Ti wires and the length of the TiO2 nanotubes have linear relationships with the anodization processing time. When the anodization processing time is 600 min, the TiO2/Ti mesh anode materials showed good capacity retention and high specific area capacity, without the need for a current collector or binder, due to their high surface area, high substrate utilization, and large active material loading rate per unit area. At the current density of 50 μA cm-2, TiO2/Ti mesh with 600 …
Highly Conductive Carbon Nanotube-Graphene Hybrid Yarn, Javad Foroughi, Geoffrey M. Spinks, Dennis Antiohos, Azadehsadat Mirabedini, Sanjeev Gambhir, Gordon G. Wallace, Shaban Reza Ghorbani, Germanas Peleckis, Mikhail Kozlov, Marcio Lima, Ray Baughman
Highly Conductive Carbon Nanotube-Graphene Hybrid Yarn, Javad Foroughi, Geoffrey M. Spinks, Dennis Antiohos, Azadehsadat Mirabedini, Sanjeev Gambhir, Gordon G. Wallace, Shaban Reza Ghorbani, Germanas Peleckis, Mikhail Kozlov, Marcio Lima, Ray Baughman
Australian Institute for Innovative Materials - Papers
An efficient procedure for the fabrication of highly conductive carbon nanotube/graphene hybrid yarns has been developed. To start, arrays of vertically aligned multi-walled carbon nanotubes (MWNT) are converted into indefinitely long MWNT sheets by drawing. Graphene flakes are then deposited onto the MWNT sheets by electrospinning to form a composite structure that is transformed into yarn filaments by twisting. The process is scalable for yarn fabrication on an industrial scale. Prepared materials are characterized by electron microscopy, electrical, mechanical, and electrochemical measurements. It is found that the electrical conductivity of the composite MWNT-graphene yarns is over 900 S/cm. This value …
Cuo Single Crystal With Exposed {001} Facets-A Highly Efficient Material For Gas Sensing And Li-Ion Battery Applications, Dawei Su, Xiuqiang Xie, S X. Dou, Guoxiu Wang
Cuo Single Crystal With Exposed {001} Facets-A Highly Efficient Material For Gas Sensing And Li-Ion Battery Applications, Dawei Su, Xiuqiang Xie, S X. Dou, Guoxiu Wang
Australian Institute for Innovative Materials - Papers
Single crystal copper oxide nanoplatelets with a high percentage of {001} facets were synthesized by a facile hydrothermal approach. The as-prepared materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, and high resolution transmission microscopy. Via density functional theory calculations, it was found that the {001} facets are active crystal planes. When the single crystal CuO nanoplatelets were applied as an anode material in Li-ion batteries, they demonstrated outstanding electrochemical performance with high lithium storage capacity, satisfactory cyclability, and excellent high rate capacity. When used as a sensing material in gas sensors, they exhibited …
Edge-Enriched Graphene Quantum Dots For Enhanced Photo-Luminescence And Supercapacitance, Mahbub Hassan, Enamul Haque, Kakarla Raghava Reddy, Andrew I. Minett, Jun Chen, Vincent G. Gomes
Edge-Enriched Graphene Quantum Dots For Enhanced Photo-Luminescence And Supercapacitance, Mahbub Hassan, Enamul Haque, Kakarla Raghava Reddy, Andrew I. Minett, Jun Chen, Vincent G. Gomes
Australian Institute for Innovative Materials - Papers
Graphene quantum dots (GQDs) with their edge-bound nanometer-size present distinctive properties owing to quantum confinement and edge effects. We report a facile ultrasonic approach with chemical activation using KOH to prepare activated GQDs or aGQDs enriched with both free and bound edges. Compared to GQDs, the aGQDs we synthesized had enhanced BET surface area by a factor of about six, the photoluminescence intensity by about four and half times and electro-capacitance by a factor of about two. Unlike their non-activated counterparts, the aGQDs having enhanced edge states emit enhanced intense blue luminescence and exhibit electrochemical double layer capacitance greater than …
Design Considerations In Mgb2-Based Superconducting Coils For Use In Saturated-Core Fault Current Limiters, Jonathan Knott, Philip A. Commins, Jeffrey Moscrop, S X. Dou
Design Considerations In Mgb2-Based Superconducting Coils For Use In Saturated-Core Fault Current Limiters, Jonathan Knott, Philip A. Commins, Jeffrey Moscrop, S X. Dou
Australian Institute for Innovative Materials - Papers
Saturated-core fault current limiters (FCLs) are devices that have many applications and potential for use within power networks. At a commercial scale, these devices require high H-field magnets to saturate the steel core, which can typically only be achieved through the use of superconducting coils. Here, we present several challenges that arise in the application of superconducting coils in FCLs and discuss how to address these issues through a case study MgB2-based coil. It is found that significant ac magnetic fields, Lorentz forces, and Joule heating in components occur during normal and fault operations; however, these issues can be mitigated …
3-Dimensional (3d) Fabricated Polymer Based Drug Delivery Systems, Simon Moulton, Gordon G. Wallace
3-Dimensional (3d) Fabricated Polymer Based Drug Delivery Systems, Simon Moulton, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Drug delivery from 3-dimensional (3D) structures is a rapidly growing area of research. It is essential to achieve structures wherein drug stability is ensured, the drug loading capacity is appropriate and the desired controlled release profile can be attained. Attention must also be paid to the development of appropriate fabrication machinery that allows 3D drug delivery systems (DDS) to be produced in a simple, reliable and reproducible manner. The range of fabrication methods currently being used to form 3D DDSs include electrospinning (solution and melt), wet-spinning and printing (3-dimensional). The use of these techniques enables production of DDSs from the …
Complementary Terahertz Absorption And Inelastic Neutron Study Of The Dynamic Anisotropy Contribution To Zone-Center Spin Waves In A Canted Antiferromagnet Ndfeo3, Evan Constable, David L. Cortie, Josip Horvat, Roger A. Lewis, Zhenxiang Cheng, Guochu Deng, Shixun Cao, Shujuan Yuan, Guohong Ma
Complementary Terahertz Absorption And Inelastic Neutron Study Of The Dynamic Anisotropy Contribution To Zone-Center Spin Waves In A Canted Antiferromagnet Ndfeo3, Evan Constable, David L. Cortie, Josip Horvat, Roger A. Lewis, Zhenxiang Cheng, Guochu Deng, Shixun Cao, Shujuan Yuan, Guohong Ma
Australian Institute for Innovative Materials - Papers
We employ a combination of pulsed- and continuous-wave polarized terahertz spectroscopy techniques to probe temperature-dependent spin waves in the antiferromagnet NdFeO3. Our optical data span 1.6-467 K and reveal a conspicuous spin reorientation between 110 and 170 K, during which the lower-energy mode softens completely. Complementary inelastic neutron scattering reveals that the frequencies of the optically excited spin waves are consistent with a temperature-variable spin gap in the low-energy spin-wave dispersion of NdFeO3. The result links the temperature dependence of the spin waves to a dynamic in-plane anisotropy. The magnetic anisotropy is calculated based on the results of the optical …
Influence Of Capping On The Atomistic Arrangement In Palladium Nanoparticles At Room Temperature, Gaston Corthey, Jimena A. Olmos-Asar, Gilberto Casillas, Marcelo M. Mariscal, Sergio Mejia-Rosales, Julio C. Azcarate, Eduardo Larios, Miguel Jose-Yacaman, Roberto Salvarezza, M Fonticelli
Influence Of Capping On The Atomistic Arrangement In Palladium Nanoparticles At Room Temperature, Gaston Corthey, Jimena A. Olmos-Asar, Gilberto Casillas, Marcelo M. Mariscal, Sergio Mejia-Rosales, Julio C. Azcarate, Eduardo Larios, Miguel Jose-Yacaman, Roberto Salvarezza, M Fonticelli
Australian Institute for Innovative Materials - Papers
The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S-Pd bond in the sulfide layer that surrounds the nanoparticles.
Mesoporous Hexagonal Co3o4 For High Performance Lithium Ion Batteries, Dawei Su, Xiuqiang Xie, Paul Munroe, S X. Dou, Guoxiu Wang
Mesoporous Hexagonal Co3o4 For High Performance Lithium Ion Batteries, Dawei Su, Xiuqiang Xie, Paul Munroe, S X. Dou, Guoxiu Wang
Australian Institute for Innovative Materials - Papers
Mesoporous Co3O4 nanoplates were successfully prepared by the conversion of hexagonal beta-Co(OH)(2) nanoplates. TEM, HRTEM and N-2 sorption analysis confirmed the facet crystal structure and inner mesoporous architecture. When applied as anode materials for lithium storage in lithium ion batteries, mesoporous Co3O4 nanocrystals delivered a high specific capacity. At 10 degrees C current rate, as-prepared mesoporous Co3O4 nanoplates delivered a specific capacity of 1203 mAh/g at first cycle and after 200 cycles it can still maintain a satisfied value (330 mAh/g). Fromex-situ TEM, SAED and FESEM observation, it was found that mesoporous Co3O4 nanoplates were reduced to Li2O and Co …
Highly Oriented Lifepo4 Thin Film Electrodes Via Chemical Solution Deposition, Qi Li, Shulei Chou, Jiazhao Wang, Dongqi Shi, Hua-Kun Liu
Highly Oriented Lifepo4 Thin Film Electrodes Via Chemical Solution Deposition, Qi Li, Shulei Chou, Jiazhao Wang, Dongqi Shi, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
Highly oriented LiFePO4 thin-film electrodes were fabricated via chemical solution deposition combined with spin coating. The effects of the precursor concentrations and types of substrates on microstructures and electrochemical performances were studied. Single-phase LiFePO4 with orientations perpendicular to the (211)/(020) and (311) planes prepared using stainless steel as substrate presents the capacity of 4.9 μAh•cm-2 and the apparent activation energy of 59.2 kJ•mol-1, indicating its great potential to be used as cathode material for lithium thin film batteries.
A New Strategy For Integrating Abundant Oxygen Functional Groups Into Carbon Felt Electrode For Vanadium Redox Flow Batteries, Ki Jae Kim, Seung-Wook Lee, Taeeun Yim, Jae-Geun Kim, Jang Wook Choi, Jung Ho Kim, Min-Sik Park, Young-Jun Kim
A New Strategy For Integrating Abundant Oxygen Functional Groups Into Carbon Felt Electrode For Vanadium Redox Flow Batteries, Ki Jae Kim, Seung-Wook Lee, Taeeun Yim, Jae-Geun Kim, Jang Wook Choi, Jung Ho Kim, Min-Sik Park, Young-Jun Kim
Australian Institute for Innovative Materials - Papers
The effects of surface treatment combining corona discharge and hydrogen peroxide (H2O2) on the electrochemical performance of carbon felt electrodes for vanadium redox flow batteries (VRFBs) have been thoroughly investigated. A high concentration of oxygen functional groups has been successfully introduced onto the surface of the carbon felt electrodes by a specially designed surface treatment, which is mainly responsible for improving the energy efficiency of VRFBs. In addition, the wettability of the carbon felt electrodes also can be significantly improved. The energy efficiency of the VRFB cell employing the surface modified carbon felt electrodes is improved by 7% at high …
Tio2 Coated Three-Dimensional Hierarchically Ordered Porous Sulfur Electrode For The Lithium/Sulfur Rechargeable Batteries, Hongqiang Wang, Sha Li, Dan Li, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Tio2 Coated Three-Dimensional Hierarchically Ordered Porous Sulfur Electrode For The Lithium/Sulfur Rechargeable Batteries, Hongqiang Wang, Sha Li, Dan Li, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Australian Institute for Innovative Materials - Papers
A three-dimensional (3D) hierarchically ordered mesoporous carbon-sulfur composite slice coated with a thin TiO2 layer has been synthesized by a low-cost process and investigated as a cathode for the lithium-sulfur batteries. The TiO2 coated carbon sulfur composite thin slice works as a binder-free cathode without any current collectors for lithium-sulfur batteries. The hierarchical architecture provides a 3D conductive network for electron transfer, open channels for ion diffusion and strong confinement of soluble polysulfides. Meanwhile, TiO2 (titanium dioxide) coating layer could further effectively prevent the dissolution of polysulfides and also improve the strength of the entire electrode, thereby enhancing the electrochemical …
Tuning The Band Gap In Silicene By Oxidation, Yi Du, Jincheng Zhuang, Hongsheng Liu, Xun Xu, Stefan Eilers, Kehui Wu, Peng Cheng, Jijun Zhao, Xiaodong Pi, Khay Wai See, Germanas Peleckis, Xiaolin Wang, S X. Dou
Tuning The Band Gap In Silicene By Oxidation, Yi Du, Jincheng Zhuang, Hongsheng Liu, Xun Xu, Stefan Eilers, Kehui Wu, Peng Cheng, Jijun Zhao, Xiaodong Pi, Khay Wai See, Germanas Peleckis, Xiaolin Wang, S X. Dou
Australian Institute for Innovative Materials - Papers
Silicene monolayers grown on Ag(111) surfaces demonstrate a band gap that is tunable by oxygen adatoms from semimetallic to semiconducting type. With the use of low-temperature scanning tunneling microscopy, we find that the adsorption configurations and amounts of oxygen adatoms on the silicene surface are critical for band gap engineering, which is dominated by different buckled structures in √13 x √13, 4 x 4, and 2√3 x 2√3 silicene layers. The Si-O-Si bonds are the most energy-favored species formed on √13 x √13, 4 x 4, and 2√3 x 2√3 structures under oxidation, which is verified by in situ Raman …
A Novel Codoping Approach For Enhancing The Performance Of Polypyrrole Cathode In A Bioelectric Battery, Yang Yang, Caiyun Wang, Chunming Zhang, Dan Wang, Dannong He, Gordon G. Wallace
A Novel Codoping Approach For Enhancing The Performance Of Polypyrrole Cathode In A Bioelectric Battery, Yang Yang, Caiyun Wang, Chunming Zhang, Dan Wang, Dannong He, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
A conducting polymer (CP) based bioelectric battery provides a promising alternative to commercial lithium batteries to drive biomedical devices. However, the low power density limits practical application. Here, we synthesize a polypyrrole (PPy)/anthraquinone sulfonate (AQS)/reduced graphene oxide (r-GO) composite via a facile electrochemical route, and use this as a novel cathode material for bioelectric batteries. The presence of r-GO significantly enhanced the electrochemical properties of PPy and led to greatly improved cell performance compared to that of PPy/AQS. The resultant PPy/AQS/r-GO composite delivered a maximum power density of 6240.5 mW m(-2), 14.2 times higher than that of PPy/p-toluenesulfonate (pTS) as …
Study On Vanadium Substitution To Iron In Li2fep 2o7 As Cathode Material For Lithium-Ion Batteries, Jiantie Xu, Shulei Chou, Qinfen Gu, M F. Md Din, Hua-Kun Liu, S X. Dou
Study On Vanadium Substitution To Iron In Li2fep 2o7 As Cathode Material For Lithium-Ion Batteries, Jiantie Xu, Shulei Chou, Qinfen Gu, M F. Md Din, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
A series of Li2Fe1-3x/2VxP 2O7 (x = 0, 0.025, 0.05, 0.075, and 0.1) cathode materials for LIBs were prepared by the sol-gel method. Structural characterization of Li2Fe1-3x/2VxP2O7 (x = 0, 0.025, 0.05, 0.075, and 0.1) samples was conducted by synchrotron X-ray diffraction. The morphology and oxidation states of Fe2+ and V 3+ in the Li2Fe1-3x/2VxP 2O7 samples were confirmed by scanning electron microscopy and magnetic susceptibility measurements, respectively. The electrochemical measurements indicated that Li2Fe1-3x/2VxP 2O7 (x = 0.025) delivered the higher reversible capacity of 79.9 mAh g-1 at 1 C in the voltage range of 2.0 - 4.5 V with …