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Articles 1201 - 1230 of 1524
Full-Text Articles in Physical Sciences and Mathematics
Scalable One-Step Wet-Spinning Of Graphene Fibers And Yarns From Liquid Crystalline Dispersions Of Graphene Oxide: Towards Multifunctional Textiles, Rouhollah Jalili, Seyed Hamed Aboutalebi, Dorna Esrafilzadeh, Roderick L. Shepherd, Jun Chen, Sima Aminorroaya-Yamini, Konstantin Konstantinov, Andrew I. Minett, Joselito M. Razal, Gordon G. Wallace
Scalable One-Step Wet-Spinning Of Graphene Fibers And Yarns From Liquid Crystalline Dispersions Of Graphene Oxide: Towards Multifunctional Textiles, Rouhollah Jalili, Seyed Hamed Aboutalebi, Dorna Esrafilzadeh, Roderick L. Shepherd, Jun Chen, Sima Aminorroaya-Yamini, Konstantin Konstantinov, Andrew I. Minett, Joselito M. Razal, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Key points in the formation of liquid crystalline (LC) dispersions of graphene oxide (GO) and their processability via wet-spinning to produce long lengths of micrometer-dimensional fibers and yarns are addressed. Based on rheological and polarized optical microscopy investigations, a rational relation between GO sheet size and polydispersity, concentration, liquid crystallinity, and spinnability is proposed, leading to an understanding of lyotropic LC behavior and fiber spinnability. The knowledge gained from the straightforward formulation of LC GO "inks" in a range of processable concentrations enables the spinning of continuous conducting, strong, and robust fibers at concentrations as low as 0.075 wt%, eliminating …
Simply Mixed Commercial Red Phosphorus And Carbon Nanotube Composite With Exceptionally Reversible Sodium-Ion Storage, Wei-Jie Li, Shulei Chou, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou
Simply Mixed Commercial Red Phosphorus And Carbon Nanotube Composite With Exceptionally Reversible Sodium-Ion Storage, Wei-Jie Li, Shulei Chou, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Recently, sodium ion batteries (SIBs) have been given intense attention because they are the most promising alternative to lithium ion batteries for application in renewable power stations and smart grid, owing to their low cost, their abundant natural resources, and the similar chemistry of sodium and lithium. Elemental phosphorus (P) is the most promising anode materials for SIBs with the highest theoretical capacity of 2596 mA h g-1, but the commercially available red phosphorus cannot react with Na reversibly. Here, we report that simply hand-grinding commercial microsized red phosphorus and carbon nanotubes (CNTs) can deliver a reversible capacity of 1675 …
Hollow Structured Li3vo4 Wrapped With Graphene Nanosheets In Situ Prepared By One-Pot Template-Free Method As An Anode For Lithium-Ion Batteries, Yi Shi, Jia-Zhao Wang, Shulei Chou, David Wexler, Hui-Jun Li, Kiyoshi Ozawa, Hua-Kun Liu, Yu-Ping Wu
Hollow Structured Li3vo4 Wrapped With Graphene Nanosheets In Situ Prepared By One-Pot Template-Free Method As An Anode For Lithium-Ion Batteries, Yi Shi, Jia-Zhao Wang, Shulei Chou, David Wexler, Hui-Jun Li, Kiyoshi Ozawa, Hua-Kun Liu, Yu-Ping Wu
Australian Institute for Innovative Materials - Papers
To explore good anode materials of high safety, high reversible capacity, good cycling, and excellent rate capability, a Li3VO4 microbox with wall thickness of 40 nm was prepared by a one-pot and template-free in situ hydrothermal method. In addition, its composite with graphene nanosheets of about six layers of graphene was achieved. Both of them, especially the Li3VO4/graphene nanosheets composite, show superior electrochemical performance to the formerly reported vanadium-based anode materials. The composite shows a reversible capacity of 223 mAh g−1 even at 20C (1C = 400 mAh g−1). After 500 cycles at 10C there is no evident capacity fading.
Cell Attachment And Proliferation On High Conductivity Pedot-Glycol Composites Produced By Vapour Phase Polymerisation, Elise M. Stewart, Manrico Fabretto, Mischa Mueller, Paul J. Molino, Hans J. Griesser, Robert D. Short, Gordon G. Wallace
Cell Attachment And Proliferation On High Conductivity Pedot-Glycol Composites Produced By Vapour Phase Polymerisation, Elise M. Stewart, Manrico Fabretto, Mischa Mueller, Paul J. Molino, Hans J. Griesser, Robert D. Short, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
High conductivity poly(3,4-ethylene dioxythiophene) (PEDOT) was synthesised using vacuum vapour phase polymerization (VVPP). The process produces PEDOT composites which incorporate glycol within the polymer. To assess biocompatibility, a suite of analytical techniques were utilised in an effort to characterise the level of glycol present and its impact on cell attachment and proliferation. A small decrease in fibroblast cell attachment and proliferation was observed with increasing glycol content within the PEDOT composite. Keratinocyte cell attachment and proliferation by comparison showed an increase. As such, the results herein indicate that cell attachment and proliferation depends on the individual cell lines used and …
Magnetic Field Induced Discontinuous Spin Reorientation In Erfeo3 Single Crystal, Hui Shen, Zhenxiang Cheng, Fang Hong, Jiayue Xu, Shujuan Yuan, Shixun Cao, Xiaolin Wang
Magnetic Field Induced Discontinuous Spin Reorientation In Erfeo3 Single Crystal, Hui Shen, Zhenxiang Cheng, Fang Hong, Jiayue Xu, Shujuan Yuan, Shixun Cao, Xiaolin Wang
Australian Institute for Innovative Materials - Papers
The spin reorientation of ErFeO3 that spontaneously occurs at low temperature has been previously determined to be a process involving the continuous rotation of Fe3þ spins. In this work, the dynamic process of spin reorientation in ErFeO3 single crystal has been investigated by AC susceptibility measurements at various frequencies and static magnetic fields. Interestingly, two completely discontinuous steps are induced by a relatively large static magnetic field due to the variation in the magnetic anisotropy during this process. It provides deeper insights into the intriguing magnetic exchange interactions which dominate the sophisticated magnetic phase transitions in the orthoferrite systems.
Collective Librations Of Water Molecules In The Crystal Lattice Of Rubidium Bromide: Experiment And Simulation, L M. Lepodise, J Horvat, Roger A. Lewis
Collective Librations Of Water Molecules In The Crystal Lattice Of Rubidium Bromide: Experiment And Simulation, L M. Lepodise, J Horvat, Roger A. Lewis
Australian Institute for Innovative Materials - Papers
Terahertz spectroscopy of RbBr reveals four prominent absorption lines at room temperature and a further 15 lines at 10 K. Via density-functional-theory (DFT) numerical modelling using the PBE0 hybrid GGA functional, all the absorptions are identified as correlated librations of water molecules in the RbBr lattice. Each libration mode is a combination of rocking, wagging and twisting motions of the water molecules. The number of libration lines and numerical modelling show that the C2v symmetry of water in RbBr is broken. Our modelling shows that the distribution of libration amplitudes and phases for different water molecules in the RbBr unit …
Microstructure And Metal-Dielectric Transition Behaviour In A Percolative Al2o3-Fe Composite Via Selective Reduction, Zidong Zhang, Runhua Fan, Zhicheng Shi, Kelan Yan, Zhijia Zhang, Xiaolin Wang, S X. Dou
Microstructure And Metal-Dielectric Transition Behaviour In A Percolative Al2o3-Fe Composite Via Selective Reduction, Zidong Zhang, Runhua Fan, Zhicheng Shi, Kelan Yan, Zhijia Zhang, Xiaolin Wang, S X. Dou
Australian Institute for Innovative Materials - Papers
The electromagnetic (EM) medium plays a key role in many areas, such as communications, stealth technology, etc. Different EM properties are required for different applications. In this paper, we have obtained tunable EM properties in an Al2O3-Fe composite via selective reduction. By adjusting the content of one functional component, the composite shows totally different EM properties, in accordance with the predictions of effective medium theory. Hybrid EM behaviour is obtained near the percolation threshold, which has a close relationship with its microstructure.
Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian
Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian
Australian Institute for Innovative Materials - Papers
Mixed metal oxides have been attracting more and more attention recently because of their advantages and superiorities, which can improve the electrochemical performance of single metal oxides. These advantages include structural stability, good electronic conductivity, and reversible capacity. In this work, uniform yolk-shelled ZnCo2O4 microspheres were synthesized by pyrolysis of ZnCo-glycolate microsphere precursors which were prepared via a simple refluxing route without any precipitant or surfactant. The formation process of the yolk-shelled microsphere structure during the thermal decomposition of ZnCo-glycolate is discussed, which is mainly based on the heterogeneous contraction caused by non-equilibrium heat treatment. The performances of the as-prepared …
Improved Dehydrogenation Properties Of The Combined Mg(Bh4) 2·6nh3-Nnh3bh3 System, Xiaowei Chen, Feng Yuan, Qinfen Gu, Yingbin Tan, Hua-Kun Liu, S X. Dou, Xuebin Yu
Improved Dehydrogenation Properties Of The Combined Mg(Bh4) 2·6nh3-Nnh3bh3 System, Xiaowei Chen, Feng Yuan, Qinfen Gu, Yingbin Tan, Hua-Kun Liu, S X. Dou, Xuebin Yu
Australian Institute for Innovative Materials - Papers
A combined strategy via mixing Mg(BH4)2·6NH3 with ammonia borane (AB) is employed to improve the dehydrogenation properties of Mg(BH4)2·6NH3. The combined system shows a mutual dehydrogenation improvement in terms of dehydrogenation temperature and hydrogen purity compared to the individual components. A further improved hydrogen liberation from the Mg(BH4)2·6NH3–6AB is achieved with the assistance of ZnCl2, which plays a crucial role in stabilizing the NH3 groups and promoting the recombination of NHδ+⋯HBδ−. Specifically, the Mg(BH4)2·6NH3–6AB/ZnCl2 (with a mole ratio of 1:0.5) composite is shown to release over 7 wt.% high-pure hydrogen (>99 mol%) at 95 °C within 10 min, thereby …
Fabrication Of Graphene Electrodes By Electrophoretic Deposition And Their Synergistic Effects With Pedot And Platinum, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Gordon G. Wallace
Fabrication Of Graphene Electrodes By Electrophoretic Deposition And Their Synergistic Effects With Pedot And Platinum, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
This research presents a useful electrophoretic deposition (EPD) technique for electrode fabrication from an aqueous colloidal solution of graphene to produce graphene electrodes by the deposition of graphene on to indium-tin oxide (ITO) coated glass. Resultant graphene electrodes are composited with conducting polymer (PEDOT), and platinum nanoparticles, to investigate their synergistic effects. Firstly, PEDOT is composited with graphene by electropolymerization on to the graphene layer. The graphene/PEDOT electrodes demonstrate an improvement in electrochemical response in tetrabutylammonium perchlorate/ acetonitrile solution. Secondly, graphene electrodes are composited with platinum by EPD of platinum nanoparticles on to the graphene layer. The resultant graphene/platinum electrodes …
Nanoscale Platinum Printing On Insulating Substrates, C D. O'Connell, M J. Higgins, R P. Sullivan, S S. Jamali, S E. Moulton, G G. Wallace
Nanoscale Platinum Printing On Insulating Substrates, C D. O'Connell, M J. Higgins, R P. Sullivan, S S. Jamali, S E. Moulton, G G. Wallace
Australian Institute for Innovative Materials - Papers
The deposition of noble metals on soft and/or flexible substrates is vital for several emerging applications including flexible electronics and the fabrication of soft bionic implants. In this paper, we describe a new strategy for the deposition of platinum electrodes on a range of materials, including insulators and flexible polymers. The strategy is enabled by two principle advances: (1) the introduction of a novel, low temperature strategy for reducing chloroplatinic acid to platinum using nitrogen plasma; (2) the development of a chloroplatinic acid based liquid ink formulation, utilizing ethylene glycol as both ink carrier and reducing agent, for versatile printing …
Wet-Spinning Of Pedot:Pss/Functionalized-Swnts Composite: A Facile Route Toward Production Of Strong And Highly Conducting Multifunctional Fibers, Rouhollah Jalili, Joselito M. Razal, Gordon G. Wallace
Wet-Spinning Of Pedot:Pss/Functionalized-Swnts Composite: A Facile Route Toward Production Of Strong And Highly Conducting Multifunctional Fibers, Rouhollah Jalili, Joselito M. Razal, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
With the aim of fabricating multifunctional fibers with enhanced mechanical properties, electrical conductivity and electrochemical performance, we develop wet-spinning of composite formulation based on functionalized PEG-SWNT and PEDOT:PSS. The method of addition and loading are directly correlated to the quality and the ease of spinnability of the formulation and to the mechanical and electrical properties of the resultant fibers. Both the fiber modulus (Y) and strength (σ) scaled linearly with PEG-SWNT volume fraction (Vf). A remarkable reinforcement rate of dY/dVf = 417 GPa and dσ/dVf = 4 GPa were obtained when PEG-SWNTs at Vf ≤ 0.02. Further increase of PEG-SWNTs …
Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen
Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen
Australian Institute for Innovative Materials - Papers
By controlling the SWNT-rGO electrode composition and thickness to attain the appropriate porosity and tortuosity, the electroactive surface area is maximized while rapid diffusion of the electrolyte through the electrode is maintained. This leads to an increase in exchange current density between the electrode and electrolyte which results in enhanced thermocell performance.
Quantum Dot-Based Nanoprobes For In Vivo Targeted Imaging, Y Zhu, H Hong, Z P. Xu, Z Li, W Cai
Quantum Dot-Based Nanoprobes For In Vivo Targeted Imaging, Y Zhu, H Hong, Z P. Xu, Z Li, W Cai
Australian Institute for Innovative Materials - Papers
Fluorescent semiconductor quantum dots (QDs) have attracted tremendous attention over the last decade. The superior optical properties of QDs over conventional organic dyes make them attractive labels for a wide variety of biomedical applications, whereas their potential toxicity and instability in biological environment have puzzled scientific researchers. Much research effort has been devoted to surface modification and functionalization of QDs to make them versatile probes for biomedical applications, and significant progress has been made over the last several years. This review article aims to describe the current state-of-the-art of the synthesis, modification, bioconjugation, and applications of QDs for in vivo …
Photodegradation In Encapsulated Silole-Based Polymer: Pcbm Solar Cells Investigated Using Transient Absorption Spectroscopy And Charge Extraction Measurements, Tracey M. Clarke, Christoph Lungenschmied, Jeff Peet, Nicolas Drolet, Kenji Sunahara, Akihiro Furube, Attila J. Mozer
Photodegradation In Encapsulated Silole-Based Polymer: Pcbm Solar Cells Investigated Using Transient Absorption Spectroscopy And Charge Extraction Measurements, Tracey M. Clarke, Christoph Lungenschmied, Jeff Peet, Nicolas Drolet, Kenji Sunahara, Akihiro Furube, Attila J. Mozer
Australian Institute for Innovative Materials - Papers
Light induced degradation has been observed in the performance of organic solar cells in the absence of oxygen and a detailed analysis of the effect of this photodegradation on optical and electrical features has been accomplished. This photodegradation study has been performed on encapsulated photovoltaic blend devices comprised of the silole-based donor-acceptor polymer KP115 blended with [6,6]-phenyl C61-butyric acid methyl ester (PCBM). Photodegradation induces an almost 20% decrease in power conversion efficiency, primarily as a result of a reduction in short circuit current, JSC. The initial burn-in phase of the photodegradation has been examined using a combination of transient absorption …
The Ultimate Iron Chef - When 3d Printers Invade The Kitchen, Robert Gorkin Iii, Susan Dodds
The Ultimate Iron Chef - When 3d Printers Invade The Kitchen, Robert Gorkin Iii, Susan Dodds
Australian Institute for Innovative Materials - Papers
Printing food seems more like an idea based in Star Trek rather than in the average home. But recent advances in 3D printing (known formally as additive manufacturing) are driving the concept closer to reality. With everything from printed metal airplane wings to replacement organs on the horizon, could printed food be next? And how will we feel when it's served at the table?
Wet-Spinning Of Multifunctional Graphene Fibers Using Graphene Oxide Liquid Crystals, Rouhollah Jalili, Seyed Hamed Aboutalebi, Dorna Esrafilzadeh, Roderick L. Shepherd, Jun Chen, Sima Aminorroaya-Yamini, Konstantin Konstantinov, Andrew I. Minett, Joselito M. Razal, Gordon G. Wallace
Wet-Spinning Of Multifunctional Graphene Fibers Using Graphene Oxide Liquid Crystals, Rouhollah Jalili, Seyed Hamed Aboutalebi, Dorna Esrafilzadeh, Roderick L. Shepherd, Jun Chen, Sima Aminorroaya-Yamini, Konstantin Konstantinov, Andrew I. Minett, Joselito M. Razal, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
The recent discovery of liquid crystalline (LC) behavior of graphene oxide (GO) dispersions in various organic, and aqueous media brings added control to the assembly of larger structures using the chemical process approach.[1-3] The LC state can be used to direct the ordered assembly of nanocomponents in macroscopic structures via simple methods like wet-spinning.
Combined Wet-Spinning And Electrospinning: Novel And Facile Method To Fabricate Micro-Nano Scale Conducting Fibres, Dorna Esrafilzadeh, Rouhollah Jalili, Kerry J. Gilmore, Joselito M. Razal, Simon L. Moulton, Gordon G. Wallace
Combined Wet-Spinning And Electrospinning: Novel And Facile Method To Fabricate Micro-Nano Scale Conducting Fibres, Dorna Esrafilzadeh, Rouhollah Jalili, Kerry J. Gilmore, Joselito M. Razal, Simon L. Moulton, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
One of the main challenges in tissue engineering is to design and fabricate an appropriate 3D extra cellular matrix (ECM) with capability to tune the in vivo environment in conjugation with additional requirements for cells enhancement. The composition, topology and artichectures of ECM are critical to achieve the desirable functionality of tissue or organ to be regenerated [1].
Precision Wet-Spinning Of Cell-Impregnated Alginate Fibres For Tissue Engineering, Rhys Cornock, Magdalena Kita, Anita Quigley, Gordon G. Wallace, Robert M. I Kapsa
Precision Wet-Spinning Of Cell-Impregnated Alginate Fibres For Tissue Engineering, Rhys Cornock, Magdalena Kita, Anita Quigley, Gordon G. Wallace, Robert M. I Kapsa
Australian Institute for Innovative Materials - Papers
The selective assembly of functionalised fibres produced by wet-spinning into implantable three dimensional contructs presents attractive prospects for the field of medical bionics[1]. In particular, the incorporation of biological factors and large numbers of cells within biocompatible and macroporous fibres is expected to deliver improvements to drug delivery platforms as well as to tissue engineering biotechnology[2, 3].
Living Fibres: 3d Hydrogel Fibres For Tissue Engineering, Anita Quigley, Magdalena Kita, Rhys Cornock, Tharun Mysore, Javad Foroughi, Gordon G. Wallace, Robert M. I Kapsa
Living Fibres: 3d Hydrogel Fibres For Tissue Engineering, Anita Quigley, Magdalena Kita, Rhys Cornock, Tharun Mysore, Javad Foroughi, Gordon G. Wallace, Robert M. I Kapsa
Australian Institute for Innovative Materials - Papers
To use rapid fibre spinning technologies for the creation of 3D constructs for cell delivery, tissue engineering and the study of 3D cellular interactions. This study describes the fabrication of biosynthetic soft gel fibers containing myoblasts and myogenic growth factors and their use for restoration of dystrophin expression in dystrophic mdx mouse muscle.
Evaluation Of Mg Size Dependence On Superconductivity Of Mgb2, B.B Sinha, Seok Hem Jang, K C. Chung, Jung Ho Kim, S X. Dou
Evaluation Of Mg Size Dependence On Superconductivity Of Mgb2, B.B Sinha, Seok Hem Jang, K C. Chung, Jung Ho Kim, S X. Dou
Australian Institute for Innovative Materials - Papers
MgB2 bulk samples are synthesized through solid state reaction route using Mg precursors with different particle size by keeping the boron precursor unchanged. Scanning electron microscopy study of the fractured surface for all the samples depicts quite distinct structure depending on the Mg precursor. Big size of Mg precursor resulted in to largely elongated and deep pores while smaller one gave roughly ellipsoidal and shallow pore structure. Influence of the Mg particle size on the grain to grain connectivity reflected in the critical current density value which was greater for samples with smaller Mg precursor. All the synthesized samples …
In Situ Growth Of Nanoparticles Through Control Of Non-Stoichiometry, Dragos Neagu, George Tsekouras, David N. Miller, Herve Menard, John T. S Irvine
In Situ Growth Of Nanoparticles Through Control Of Non-Stoichiometry, Dragos Neagu, George Tsekouras, David N. Miller, Herve Menard, John T. S Irvine
Australian Institute for Innovative Materials - Papers
Surfaces decorated with uniformly dispersed catalytically active nanoparticles play a key role in many fields, including renewable energy and catalysis. Typically, these structures are prepared by deposition techniques, but alternatively they could be made by growing the nanoparticles in situ directly from the (porous) backbone support. Here we demonstrate that growing nano-size phases from perovskites can be controlled through judicious choice of composition, particularly by tuning deviations from the ideal ABO3 stoichiometry. This non-stoichiometry facilitates a change in equilibrium position to make particle exsolution much more dynamic, enabling the preparation of compositionally diverse nanoparticles (that is, metallic, oxides or …
Atomic And Electronic Structures Of Single-Layer Fese On Srtio3(001): The Role Of Oxygen Deficiency, Junhyeok Bang, Zhi Li, Y Y. Sun, Amit Samanta, Y Y. Zhang, Wenhao Zhang, Lili Wang, Xi Chen, Xu-Cun Ma, Qi-Kun Xue, S B. Zhang
Atomic And Electronic Structures Of Single-Layer Fese On Srtio3(001): The Role Of Oxygen Deficiency, Junhyeok Bang, Zhi Li, Y Y. Sun, Amit Samanta, Y Y. Zhang, Wenhao Zhang, Lili Wang, Xi Chen, Xu-Cun Ma, Qi-Kun Xue, S B. Zhang
Australian Institute for Innovative Materials - Papers
Using first-principles calculation, we propose an interface structure for single triple-layer FeSe on the SrTiO3(001) surface, a high-Tc superconductor found recently. The key component of this structure is the oxygen deficiency on the top layer of the SrTiO3 substrate, as a result of Se etching used in preparing the high-Tc samples. The O vacancies strongly bind the FeSe triple layer to the substrate giving rise to a (2 x 1) reconstruction, as observed by scanning tunneling microscopy. The enhanced binding correlates to the significant increase of Tc observed in experiment. The O vacancies also serve as the source of electron …
Polypyrrole Stretchable Actuators, Wen Zheng, Gursel Alici, Phillip R. Clingan, Bridget Munro, Geoffrey M. Spinks, Julie R. Steele, Gordon G. Wallace
Polypyrrole Stretchable Actuators, Wen Zheng, Gursel Alici, Phillip R. Clingan, Bridget Munro, Geoffrey M. Spinks, Julie R. Steele, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Here, we report a simple way to prepare stretchable polypyrrole (PPy)-based actuator materials that can be operated over a wide dynamic strain range and generate useable actuation displacements and pressures. The stretchable actuators were prepared as a laminated composite of PPy and a gold-coated roughened rubber sheet. By manipulating the corrugated surface of the rubber substrate, the stretchability of PPy was greatly improved. Gold-coated rubbers could be stretched to 30 percent without significant change in electrical resistance. The corrugated PPy/gold/rubber laminates successfully showed - 1 percents of actuation strain even when prestretched to 24 percent. The actuation strains were smaller …
A Study Of Tio2 Binder-Free Paste Prepared For Low Temperature Dye-Sensitized Solar Cells, Jeremy H. Yune, Inna Karatchevtseva, Gerri Triani, Klaudia Wagner, David Officer
A Study Of Tio2 Binder-Free Paste Prepared For Low Temperature Dye-Sensitized Solar Cells, Jeremy H. Yune, Inna Karatchevtseva, Gerri Triani, Klaudia Wagner, David Officer
Australian Institute for Innovative Materials - Papers
A binder-free titania paste was prepared by chemical modification of an acidic TiO2 sol with ammonia. By varying the ammonia concentration, the viscosity of the acidic TiO2 suspension increased, thereby allowing uniform films to be cast. The photoelectrochemical performance of TiO2 electrodes, cast as single layers, was dependent on the thermal treatment cycle. Fourier transform infrared spectroscopy was used to characterize the extent of residual organics and found that acetates from the TiO2 precursor preparation were retained within the electrode structure after thermal treatment at 150 °C. Electrodes of nominal thickness 4 lm produced an energy conversion efficiency as high …
Comparative Displacement Study Of Bilayer Actuators Comprising Of Conducting Polymers, Fabricated From Polypyrrole, Poly(3,4- Ethylenedioxythiophene) Or Poly(3,4-Propylenedioxythiophene), Babita Gaihre, Syed Ashraf, Geoffrey M. Spinks, Peter C. Innis, Gordon G. Wallace
Comparative Displacement Study Of Bilayer Actuators Comprising Of Conducting Polymers, Fabricated From Polypyrrole, Poly(3,4- Ethylenedioxythiophene) Or Poly(3,4-Propylenedioxythiophene), Babita Gaihre, Syed Ashraf, Geoffrey M. Spinks, Peter C. Innis, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
The stress gradient generated due to electrochemical oxidation/reduction of a conducting polymer in a bilayer actuator causes a bending movement. Here we report a comparative study of the displacement of bilayer actuators prepared using different conducting polymers. The effects of conducting polymers obtained from electrochemical or chemical synthesis route: different polymers (polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) PEDOT and poly(3,3-dihexyl-3-4-dihydro-2H-thieno[3,4b][1,4]-dioxepine [PProDOT(Hx) 2]); and different electrolytes (0.1 M lithium trifluromethanesulfonate/propylenecarbonate (LiTFSI/PC) and 1-ethyl-3-methyl imidazolium trifluromethanesulfonate (EMITFSI)) on the displacement amplitude and displacement patterns of these actuators were investigated and compared. The results indicate that the bilayer actuator consisting of an electrochemically synthesized conducting polymer …
Crystallization, Phase Evolution And Ferroelectric Properties Of Sol-Gel-Synthesized Ba(Ti0.8zr0.2)O3- X(Ba0.7ca0.3)Tio3 Thin Films, Zeng-Mei Wang, Kuan Zhao, Xin-Li Guo, Wei Sun, Hua-Long Jiang, Xue-Qin Han, Xu-Tang Tao, Zhen-Xiang Cheng, Hong-Yang Zhao, Hideo Kimura, Guo-Liang Yuan, Jiang Yin, Zhi-Guo Liu
Crystallization, Phase Evolution And Ferroelectric Properties Of Sol-Gel-Synthesized Ba(Ti0.8zr0.2)O3- X(Ba0.7ca0.3)Tio3 Thin Films, Zeng-Mei Wang, Kuan Zhao, Xin-Li Guo, Wei Sun, Hua-Long Jiang, Xue-Qin Han, Xu-Tang Tao, Zhen-Xiang Cheng, Hong-Yang Zhao, Hideo Kimura, Guo-Liang Yuan, Jiang Yin, Zhi-Guo Liu
Australian Institute for Innovative Materials - Papers
A lead-free piezoelectric material with ultra-high properties, Ba(Ti0.8Zr0.2)O3-x(Ba0.7Ca0.3)TiO3(BZT-xBCT) nanocrystals was synthesized via a sol-gel method, and the corresponding thin films were also deposited on Pt/Ti/SiO2/Si substrates by a spin-coating approach. The BZT-xBCT thin film exhibited a high remnant polarization of 22.15 mC cm2 with a large coercive field of 68.06 kV cm1. The resultant gel is calcined at various elevated temperatures and studied with FTIR/XRD/Raman/DSC-TGA/AFM/SEM techniques for gel composition, crystallization, phase transition, thermochemistry and the morphology of the film. Although the room temperature crystal structure of the BZT-xBCT nanocrystals appears to be a standard perovskite structure by conventional X-ray diffraction …
Effect Of Polymer Ligand Structures On Fluorescence Of Gold Clusters Prepared By Photoreduction, Luo Li, Zhen Li, Hui Zhang, Shoucun Zhang, Irfan Majeed, Bien Tan
Effect Of Polymer Ligand Structures On Fluorescence Of Gold Clusters Prepared By Photoreduction, Luo Li, Zhen Li, Hui Zhang, Shoucun Zhang, Irfan Majeed, Bien Tan
Australian Institute for Innovative Materials - Papers
Blue emission fluorescent Au5 clusters with maximum quantum yield of 20.1% were synthesized by a simple photoreduction method using three specially designed tridentate polymer ligands. The evolution of fluorescent Au nanoclusters (Au NCs) under UV irradiation was studied by fluorescence, UV-Vis and X-ray photoelectron spectroscopic techniques, suggesting that the fluorescence of Au NCs is size-dependent and is associated with the presence of Au(i) ions in the Au NCs. The effect of polymer structure on the fluorescent Au NCs has also been discussed. These highly fluorescent Au NCs have potential applications in the fabrication of optoelectronic devices and light emitting materials.
Collaborate Or Commiserate !, Gordon G. Wallace
Collaborate Or Commiserate !, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
The ability to build effective collaborative research activities is no longer a secondary skill for scientists. It is a skill critical to the development of a successful career. Without a demonstrated capacity to deliver on projects that mandate collaboration, a competitive position cannot be sustained. The importance of collaboration in delivering efficient, effective and high impact advances in research and innovation is well documented. See for example the position paper entitled “Australian Science in a Changing World: Innovation requires Global Engagement” published by the Australian Academy of Science in 2011. A scant search of the research literature also shows numerous …
Exact Asymptotic Behavior Of Magnetic Stripe Domain Arrays, Tom H. Johansen, Alexey V. Pan, Yuri M. Galperin
Exact Asymptotic Behavior Of Magnetic Stripe Domain Arrays, Tom H. Johansen, Alexey V. Pan, Yuri M. Galperin
Australian Institute for Innovative Materials - Papers
The classical problem of magnetic stripe domain behavior in films and plates with uniaxial magnetic anisotropy is addressed. Exact analytical results are derived for the stripe domain widths as a function of applied perpendicular field H, in the regime where the domain period becomes large. The stripe period diverges as (H-c - H)(-1/2), where H-c is the critical (infinite period) field, an exact result confirming a previous conjecture. The magnetization approaches saturation as (H-c - H)(1/2), a behavior that compares excellently with experimental data obtained for a 4-mu m thick ferrite garnet film. The exact analytical solution provides a new …