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Full-Text Articles in Physical Sciences and Mathematics

From Science Fiction To Reality: The Dawn Of The Biofabricator, Gordon G. Wallace Jan 2015

From Science Fiction To Reality: The Dawn Of The Biofabricator, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

[extract] Science is catching up to science fiction. Last year a paralysed man walked again after cell treatment bridged a gap in his spinal cord. Dozens of people have had bionic eyes implanted, and it may also be possible to augment them to see into the infra-red or ultra-violet. Amputees can control bionic limb implant with thoughts alone.


Delocalized Surface State In Epitaxial Si(111) Film With Spontaneous √3 X √3 Superstructure, Jian Chen, Yi Du, Zhi Li, Wenbin Li, Baojie Feng, Jinlan Qiu, Peng Cheng, S X. Dou, Lan Chen, Ke-Hui Wu Jan 2015

Delocalized Surface State In Epitaxial Si(111) Film With Spontaneous √3 X √3 Superstructure, Jian Chen, Yi Du, Zhi Li, Wenbin Li, Baojie Feng, Jinlan Qiu, Peng Cheng, S X. Dou, Lan Chen, Ke-Hui Wu

Australian Institute for Innovative Materials - Papers

The " multilayer silicene" films were grown on Ag(111), with increasing thickness above 30 monolayers (ML). Scanning tunneling microscopy (STM) observations suggest that the " multilayer silicene" is indeed a bulk-like Si(111) film with a (√ 3 x √ 3)R30° honeycomb superstructure on surface. The possibility for formation of Si(111)(√ 3 x √ 3)R30°-Ag reconstruction on the surface can be distinctively ruled out by peeling off the surface layer with the STM tip. On this surface, delocalized surface state as well as linear energy-momentum dispersion was observed from quasiparticle interference patterns. Our results indicate that a bulklike silicon film with …


Synthesis Of Different Cuo Nanostructures By A New Catalytic Template Method As Anode Materials For Lithium-Ion Batteries, Xiaohang Ma, Shuang Zeng, Bangkun Zou, Xin Liang, Jia-Ying Liao, Chunhua Chen Jan 2015

Synthesis Of Different Cuo Nanostructures By A New Catalytic Template Method As Anode Materials For Lithium-Ion Batteries, Xiaohang Ma, Shuang Zeng, Bangkun Zou, Xin Liang, Jia-Ying Liao, Chunhua Chen

Australian Institute for Innovative Materials - Papers

CuO powders composed of different rod-like clusters or dandelion-like nanospheres are prepared by a low-temperature thermal decomposition process of Cu(OH)2 precursors, which are obtained via a catalytic template method. A tentative mechanism is proposed to explain the formation and transformation of different Cu(OH)2 nanostructures. X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, field-emission scanning electron microscopy, transmission electron microscopy, infrared spectra analysis, Brunauer-Emmett-Teller measurements, and galvanostatic cell cycling are employed to characterize the structures and electrochemical performance of these CuO samples. The results show that these CuO samples obtained after 500 °C calcination have a stable cycling performance with a reversible …


N-Doped Pierced Graphene Microparticles As A Highly Active Electrocatalyst For Li-Air Batteries, Tao Yuan, Weimin Zhang, Wen-Ting Li, Chuantao Song, Yu-Shi He, Joselito M. Razal, Zi-Feng Ma, Jun Chen Jan 2015

N-Doped Pierced Graphene Microparticles As A Highly Active Electrocatalyst For Li-Air Batteries, Tao Yuan, Weimin Zhang, Wen-Ting Li, Chuantao Song, Yu-Shi He, Joselito M. Razal, Zi-Feng Ma, Jun Chen

Australian Institute for Innovative Materials - Papers

In this work we report a novel scalable strategy to prepare a lithium-air battery electrode from 3D N-doped pierced graphene microparticles (N-PGM) with highly active performance. This approach has combined the merits of spray drying technology and the hard template method. The pierced structured graphene microparticles were characterized physically and electrochemically. An x-ray photoelectron spectrometer and Raman spectra have revealed that the novel structure possesses a higher N-doping level than conventional graphene without the pierced structure. A much higher BET surface area was also achieved for the N-PGM than the conventional N-doped graphene microparticles (N-GM). Cyclic voltammetry indicated that the …


Effects Of Cu Substitution For Sn On The Electrochemical Performance Of La0.7mg0.3al0.3mn0.4sn0.5−Xcuxni3.8 (X = 0-0.5) Alloys For Ni-Mh Batteries, Julio Cesar Serafim Casini, Zaiping Guo, Hua-Kun Liu, Rubens Nunes Faria, Hidetoshi Takiishi Jan 2015

Effects Of Cu Substitution For Sn On The Electrochemical Performance Of La0.7mg0.3al0.3mn0.4sn0.5−Xcuxni3.8 (X = 0-0.5) Alloys For Ni-Mh Batteries, Julio Cesar Serafim Casini, Zaiping Guo, Hua-Kun Liu, Rubens Nunes Faria, Hidetoshi Takiishi

Australian Institute for Innovative Materials - Papers

The effects of substitution of Cu for Sn on the electrochemical discharge capacity performance of La0.7Mg0.3Al0.3Mn0.4Sn0.5−xCuxNi3.8 (x = 0.0, 0.1, 0.2, 0.3, and 0.5) negative electrode alloys were investigated. Results indicate that increasing Cu content enhanced electrochemical behavior by increasing the maximum discharge capacity from 239.8 mA·h/g (x = 0) to 305.2 mA·h/g (x = 0.5), the discharge capacity retention at the 100th cycle from 78.0% (x = 0) to 81.8% (x = 0.5), and the high rate dischargeability (HRD) from 25.7% (x = 0) to 80.6% (x = 0.5).


Pre-Differentiation Of Human Neural Stem Cells Into Gabaergic Neurons Prior To Transplant Results In Greater Repopulation Of The Damaged Brain And Accelerates Functional Recovery After Transient Ischemic Stroke, Hima C. S Abeysinghe, Laita Bokhari, Anita F. Quigley, Mahesh A. Choolani, Jerry Chan, Gregory J. Dusting, Jeremy M. Crook, Nao R. Kobayashi, Carli Roulston Jan 2015

Pre-Differentiation Of Human Neural Stem Cells Into Gabaergic Neurons Prior To Transplant Results In Greater Repopulation Of The Damaged Brain And Accelerates Functional Recovery After Transient Ischemic Stroke, Hima C. S Abeysinghe, Laita Bokhari, Anita F. Quigley, Mahesh A. Choolani, Jerry Chan, Gregory J. Dusting, Jeremy M. Crook, Nao R. Kobayashi, Carli Roulston

Australian Institute for Innovative Materials - Papers

2015 Abeysinghe et al. Introduction: Despite attempts to prevent brain injury during the hyperacute phase of stroke, most sufferers end up with significant neuronal loss and functional deficits. The use of cell-based therapies to recover the injured brain offers new hope. In the current study, we employed human neural stem cells (hNSCs) isolated from subventricular zone (SVZ), and directed their differentiation into GABAergic neurons followed by transplantation to ischemic brain. Methods: Pre-differentiated GABAergic neurons, undifferentiated SVZ-hNSCs or media alone were stereotaxically transplanted into the rat brain (n=7/group) 7 days after endothelin-1 induced stroke. Neurological outcome was assessed by neurological deficit …


Enhanced Electron Lifetimes In Dye-Sensitized Solar Cells Using A Di-Chromophoric Porphyrin: The Utility Of Inter-Molecular Forces, Long Zhao, Pawel W. Wagner, Holly Van Der Salm, Keith C. Gordon, Shogo Mori, Attila J. Mozer Jan 2015

Enhanced Electron Lifetimes In Dye-Sensitized Solar Cells Using A Di-Chromophoric Porphyrin: The Utility Of Inter-Molecular Forces, Long Zhao, Pawel W. Wagner, Holly Van Der Salm, Keith C. Gordon, Shogo Mori, Attila J. Mozer

Australian Institute for Innovative Materials - Papers

Electron lifetimes in dye-sensitized solar cells employing a porphyrin dye, an organic dye, a 1:1 mixture of the two dyes and a di-chromophoric dye design consisting of the two dyes using a non-conjugated linker were measured, suggesting that the dispersion force of the organic dyes has a significant detrimental effect on the electron lifetime and that the di-chromophoric design can be utilized to control the effect of the dispersion force.


Harvesting Temperature Fluctuations As Electrical Energy Using Torsional And Tensile Polymer Muscles, Shi Hyeong Kim, Marcio Dias Lima, Mikhail E. Kozlov, Carter S. Haines, Geoffrey M. Spinks, Shazed Aziz, Changsoon Choi, Hyeon Jun Sim, Xuemin Wang, Hongbing Lu, Dong Qian, John D. W Madden, Ray H. Baughman, Seon Jeong Kim Jan 2015

Harvesting Temperature Fluctuations As Electrical Energy Using Torsional And Tensile Polymer Muscles, Shi Hyeong Kim, Marcio Dias Lima, Mikhail E. Kozlov, Carter S. Haines, Geoffrey M. Spinks, Shazed Aziz, Changsoon Choi, Hyeon Jun Sim, Xuemin Wang, Hongbing Lu, Dong Qian, John D. W Madden, Ray H. Baughman, Seon Jeong Kim

Australian Institute for Innovative Materials - Papers

Diverse means have been deployed for harvesting electrical energy from mechanical actuation produced by low-grade waste heat, but cycle rate, energy-per-cycle, device size and weight, or cost have limited applications. We report the electromagnetic harvesting of thermal energy as electrical energy using thermally powered torsional and tensile artificial muscles made from inexpensive polymer fibers used for fishing line and sewing thread. We show that a coiled 27 μm-diameter nylon muscle fiber can be driven by 16.7 °C air temperature fluctuations to spin a magnetic rotor to a peak torsional rotation speed of 70 000 rpm for over 300 000 heating-cooling …


Harvesting Temperature Fluctuations As Electrical Energy Using Torsional And Tensile Polymer Muscles, Shi Hyeong Kim, Marcio Dias Lima, Mikhail E. Kozlov, Carter S. Haines, Geoffrey M. Spinks, Shazed Aziz, Changsoon Choi, Hyeon Jun Sim, Xuemin Wang, Hongbing Lu, Dong Qian, John D. W Madden, Ray H. Baughman, Seon Jeong Kim Jan 2015

Harvesting Temperature Fluctuations As Electrical Energy Using Torsional And Tensile Polymer Muscles, Shi Hyeong Kim, Marcio Dias Lima, Mikhail E. Kozlov, Carter S. Haines, Geoffrey M. Spinks, Shazed Aziz, Changsoon Choi, Hyeon Jun Sim, Xuemin Wang, Hongbing Lu, Dong Qian, John D. W Madden, Ray H. Baughman, Seon Jeong Kim

Australian Institute for Innovative Materials - Papers

Diverse means have been deployed for harvesting electrical energy from mechanical actuation produced by low-grade waste heat, but cycle rate, energy-per-cycle, device size and weight, or cost have limited applications. We report the electromagnetic harvesting of thermal energy as electrical energy using thermally powered torsional and tensile artificial muscles made from inexpensive polymer fibers used for fishing line and sewing thread. We show that a coiled 27 μm-diameter nylon muscle fiber can be driven by 16.7 °C air temperature fluctuations to spin a magnetic rotor to a peak torsional rotation speed of 70 000 rpm for over 300 000 heating-cooling …


A Comparison Of Chemical And Electrochemical Synthesis Of Pedot: Dextran Sulphate For Bio-Application, Leo Stevens, David G. Harman, Kerry J. Gilmore, Marc In Het Panhuis, Gordon G. Wallace Jan 2015

A Comparison Of Chemical And Electrochemical Synthesis Of Pedot: Dextran Sulphate For Bio-Application, Leo Stevens, David G. Harman, Kerry J. Gilmore, Marc In Het Panhuis, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Poly(3,4-ethylenedioxythiophene) (PEDOT) is an organic conducting polymer that has been the focus of significant research over the last decade, in both energy and biological applications. Most commonly, PEDOT is doped by the artificial polymer polystyrene sulfonate due to the excellent electrical characteristics yielded by this pairing. The biopolymer dextran sulphate (DS) has been recently reported as a promising alternative to PEDOT: PSS for biological application, having electrical properties rivaling PEDOT: PSS, complimented by the potential bioactivity of the polysaccharide. In this work we compared chemical and electrochemical polymerisations of PEDOT: DS in terms of their impact on the electrical, morphological …


Towards Understanding The Lithium Transport Mechanism In Garnet-Type Solid Electrolytes: Li+ Ions Exchanges And Their Mobility At Octahedral/Tetrahedral Sites, Da-Wei Wang, Guiming Zhong, Wei Kong Pang, Zaiping Guo, Yixiao Li, Matthew J. Mcdonald, Riqiang Fu, Jin-Xiao Mi, Yong Yang Jan 2015

Towards Understanding The Lithium Transport Mechanism In Garnet-Type Solid Electrolytes: Li+ Ions Exchanges And Their Mobility At Octahedral/Tetrahedral Sites, Da-Wei Wang, Guiming Zhong, Wei Kong Pang, Zaiping Guo, Yixiao Li, Matthew J. Mcdonald, Riqiang Fu, Jin-Xiao Mi, Yong Yang

Australian Institute for Innovative Materials - Papers

The cubic garnet-type solid electrolyte Li7La3Zr2O12 with aliovalent doping exhibits a high ionic conductivity, reaching up to ∼10−3 S/cm at room temperature. Fully understanding the Li+ transport mechanism including Li+ mobility at different sites is a key topic in this field, and Li7−2x−3yAlyLa3Zr2−xWxO12 (0 ≤ x ≤ 1) are selected as target electrolytes. X-ray and neutron diffraction as well as ac impedance results show that a low amount of aliovalent substitution of Zr with W does not obviously affect the crystal structure and the activation energy of Li+ ion jumping, but it does noticeably vary the distribution of Li+ ions, …


Towards The Knittability Of Graphene Oxide Fibres, Shayan Seyedin, Mark S. Romano, Andrew I. Minett, Joselito M. Razal Jan 2015

Towards The Knittability Of Graphene Oxide Fibres, Shayan Seyedin, Mark S. Romano, Andrew I. Minett, Joselito M. Razal

Australian Institute for Innovative Materials - Papers

Recent developments in graphene oxide fibre (GO) processing include exciting demonstrations of hand woven textile structures. However, it is uncertain whether the fibres produced can meet the processing requirements of conventional textile manufacturing. This work reports for the first time the production of highly flexible and tough GO fibres that can be knitted using textile machinery. The GO fibres are made by using a dry-jet wet-spinning method, which allows drawing of the spinning solution (the GO dispersion) in several stages of the fibre spinning process. The coagulation composition and spinning conditions are evaluated in detail, which led to the production …


Ultrafast Spin Polarization In A Multiferroic Manganite Bife0.5mn0.5o3 Thin Film, Zeyu Zhang, Zuanming Jin, Xian Lin, Zhenxiang Cheng, H Y. Zhao, Hideo Kimura, Guohong Ma Jan 2015

Ultrafast Spin Polarization In A Multiferroic Manganite Bife0.5mn0.5o3 Thin Film, Zeyu Zhang, Zuanming Jin, Xian Lin, Zhenxiang Cheng, H Y. Zhao, Hideo Kimura, Guohong Ma

Australian Institute for Innovative Materials - Papers

In this work, we present observations of ultrafast carrier dynamics and spin polarization in a multiferroic manganite BiFe0.5Mn0.5O3 film excited by linearly and circularly polarized femtosecond pulses, respectively. The d-band charge transfer transition is reasonably assigned to Γ3 → Γ5. The transient reflectivity decay on a time scale as fast as only 0.3 ps is consistent with the picture of ultrafast electron-phonon coupling. The ultrafast switching of polarization ellipticity (< 150 fs) originates from a transient coherent spin polarization by optical orientation. The ultrafast spin polarization switching is assigned to the Raman coherence process.


Can The Wet - State Conductivity Of Hydrogels Be Improved By Incorporation Of Spherical Conducting Nanoparticles?, Katharina Schirmer, Cody Wright, Holly Warren, Brianna C. Thompson, Anita F. Quigley, Robert M. I Kapsa, Gordon G. Wallace Jan 2015

Can The Wet - State Conductivity Of Hydrogels Be Improved By Incorporation Of Spherical Conducting Nanoparticles?, Katharina Schirmer, Cody Wright, Holly Warren, Brianna C. Thompson, Anita F. Quigley, Robert M. I Kapsa, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

In nerve and muscle regeneration applications, the incorporation of conducting elements into biocompatible materials has gained interest over the last few years, as it has been shown that electrical stimulation of some regenerating cells has a positive effect on their development. A variety of different materials, ranging from graphene to conducting polymers, have been incorporated into hydrogels and increased conductivities have been reported. However, the majority of conductivity measurements are performed in a dry state, even though material blends are designed for applications in a wet state, in vivo environment. The focus of this work is to use polypyrrole nanoparticles …


Pauli-Limited Effect In The Magnetic Phase Diagram Of Fesexte1−X Thin Films, Jincheng Zhuang, Zhen Li, Xun Xu, Li Wang, Wai Kong Yeoh, X Z. Xing, Zhixiang Shi, Xiaolin Wang, Yi Du, S X. Dou Jan 2015

Pauli-Limited Effect In The Magnetic Phase Diagram Of Fesexte1−X Thin Films, Jincheng Zhuang, Zhen Li, Xun Xu, Li Wang, Wai Kong Yeoh, X Z. Xing, Zhixiang Shi, Xiaolin Wang, Yi Du, S X. Dou

Australian Institute for Innovative Materials - Papers

We present a detailed investigation on the doping dependence of the upper critical fieldHc2(T) of FeSexTe1−xthin films (0.18 ≤ x ≤ 0.90) by measuring the electrical resistivity as a function of magnetic field. The Hc2(T) curves exhibit a downturn behavior with decreasing temperature in all the samples, owing to the Pauli-limited effect (spin paramagnetic effect). The Pauli-limited effect on the upper critical field can be monotonically modulated by variation of the Se/Te composition. Our results show that Te-doping induced disorder and excess Fe atoms give rise to enhancement of the Pauli-limited effect.


Improvement In Structure And Superconductivity Of Bulk Fese0.5te0.5 Superconductors By Optimizing Sintering Temperature, Ning Chen, Yongchang Liu, Zongqing Ma, Liming Yu, Huijun Li Jan 2015

Improvement In Structure And Superconductivity Of Bulk Fese0.5te0.5 Superconductors By Optimizing Sintering Temperature, Ning Chen, Yongchang Liu, Zongqing Ma, Liming Yu, Huijun Li

Australian Institute for Innovative Materials - Papers

Sintering temperature plays a vital role in the evolution of phase structure and microstructure in polycrystalline FeSe0.5Te0.5 bulks fabricated by the two-step sintering method, and thus significantly influences their superconducting properties. Elevated sintering temperature (600-700°C) at second step facilitates the substitution of Te into the superconducting phase, which leads to the increased lattice distortion and thus contributes to the enhancement of superconductivity (the value of Tc reaches 15.6K). At the same time, the accelerated growth of the superconducting grains and the improved homogeneity motivated by elevated sintering temperature serve as the main reason for the sharp superconducting transition.


High Acetic Acid Production Rate Obtained By Microbial Electrosynthesis From Carbon Dioxide, Ludovic Jourdin, Timothy Grieger, Juliette Monetti, Victoria Flexer, Stefano Freguia, Yang Lu, Jun Chen, Mark S. Romano, Gordon G. Wallace, Jurg Keller Jan 2015

High Acetic Acid Production Rate Obtained By Microbial Electrosynthesis From Carbon Dioxide, Ludovic Jourdin, Timothy Grieger, Juliette Monetti, Victoria Flexer, Stefano Freguia, Yang Lu, Jun Chen, Mark S. Romano, Gordon G. Wallace, Jurg Keller

Australian Institute for Innovative Materials - Papers

High product specificity and production rate are regarded as key success parameters for large-scale applicability of a (bio)chemical reaction technology. Here, we report a significant performance enhancement in acetate formation from CO2, reaching comparable productivity levels as in industrial fermentation processes (volumetric production rate and product yield). A biocathode current density of -102 ± 1 A m-2 and an acetic acid production rate of 685 ± 30 (g m-2 day-1) have been achieved in this study. High recoveries of 94 ± 2% of the CO2 supplied as the sole carbon source and 100 ± 4% of electrons into the final …


Uniform Yolk-Shell Iron Sulfide-Carbon Nanospheres For Superior Sodium-Iron Sulfide Batteries, Yunxiao Wang, Jianping Yang, Shulei Chou, Hua-Kun Liu, Weixian Zhang, Dongyuan Zhao, S X. Dou Jan 2015

Uniform Yolk-Shell Iron Sulfide-Carbon Nanospheres For Superior Sodium-Iron Sulfide Batteries, Yunxiao Wang, Jianping Yang, Shulei Chou, Hua-Kun Liu, Weixian Zhang, Dongyuan Zhao, S X. Dou

Australian Institute for Innovative Materials - Papers

Sodium-metal sulfide battery holds great promise for sustainable and cost-effective applications. Nevertheless, achieving high capacity and cycling stability remains a great challenge. Here, uniform yolk-shell iron sulfide-carbon nanospheres have been synthesized as cathode materials for the emerging sodium sulfide battery to achieve remarkable capacity of ∼545 mA h g-1 over 100 cycles at 0.2 C (100 mA g-1), delivering ultrahigh energy density of ∼438 Wh kg-1. The proven conversion reaction between sodium and iron sulfide results in high capacity but severe volume changes. Nanostructural design, including of nanosized iron sulfide yolks (∼170 nm) with porous carbon shells (∼30 nm) and …


Development And Characterization Of Novel Hybrid Hydrogel Fibers, Azadeh Mirabedini, Javad Foroughi, Anthony C. Romeo, Gordon G. Wallace Jan 2015

Development And Characterization Of Novel Hybrid Hydrogel Fibers, Azadeh Mirabedini, Javad Foroughi, Anthony C. Romeo, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Biopolymeric continuous core-sheath fibres, with an inner core of chitosan and alginate as the sheath, were fabricated for the first time without using a template. Hereby, the necessary conditions to achieve chitosan-alginate core-sheath fibre via a wet-spinning process are presented. SEM micrographs show the cylinder-shaped monofilament structure of the chitosan core surrounded by the alginate sheath. The coaxial fibres exhibit a 260% increase in ultimate stress and more than 300% enhancement in the Young's modulus compared to the alginate counterpart. Release profiles from the coaxial fibre were determined using a model component. The obtained results suggest that the fibres are …


Effects Of Nanostructure On Clean Energy: Big Solutions Gained From Small Features, Jinyan Xiong, Chao Han, Zhen Li, S X. Dou Jan 2015

Effects Of Nanostructure On Clean Energy: Big Solutions Gained From Small Features, Jinyan Xiong, Chao Han, Zhen Li, S X. Dou

Australian Institute for Innovative Materials - Papers

The increasing energy consumption and environmental concerns have driven the development of cost-effective, high-efficiency clean energy. Advanced functional nanomaterials and relevant nanotechnologies are playing a crucial role and showing promise in resolving some energy issues. In this view, we focus on recent advances of functional nanomaterials in clean energy applications, including solar energy conversion, water splitting, photodegradation, electrochemical energy conversion and storage, and thermoelectric conversion, which have attracted considerable interests in the regime of clean energy.


Tuning The Conductance Of H2o@C60 By Position Of The Encapsulated H2o, Chengbo Zhu, Xiaolin Wang Jan 2015

Tuning The Conductance Of H2o@C60 By Position Of The Encapsulated H2o, Chengbo Zhu, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

The change of conductance of single-molecule junction in response to various external stimuli is the fundamental mechanism for the single-molecule electronic devices with multiple functionalities. We propose the concept that the conductance of molecular systems can be tuned from inside. The conductance is varied in C60 with encapsulated H2O, H2O@C60. The transport properties of the H2O@ C60-based nanostructure sandwiched between electrodes are studied using first-principles calculations combined with the non-equilibrium Green's function formalism. Our results show that the conductance of the H2O@C60 is sensitive to the position of the H2O and its dipole direction inside the cage with changes in …


Edge-Hydroxylated Boron Nitride Nanosheets As An Effective Additive To Improve The Thermal Response Of Hydrogels, Feng Xiao, Sina Naficy, Gilberto Casillas, Majharu Haque Khan, Tomas Katkus, Lei Jiang, Hua-Kun Liu, Huijun Li, Zhenguo Huang Jan 2015

Edge-Hydroxylated Boron Nitride Nanosheets As An Effective Additive To Improve The Thermal Response Of Hydrogels, Feng Xiao, Sina Naficy, Gilberto Casillas, Majharu Haque Khan, Tomas Katkus, Lei Jiang, Hua-Kun Liu, Huijun Li, Zhenguo Huang

Australian Institute for Innovative Materials - Papers

Upon flowing hot steam over hexagonal boron nitride (h-BN) bulk powder, efficient exfoliation and hydroxylation of BN occur simultaneously. Through effective hydrogen bonding with water and N-isopropylacrylamide, edge-hydroxylated BN nanosheets dramatically improve the dimensional change and dye release of this temperature-sensitive hydrogel and thereby enhance its efficacy in bionic, soft robotic, and drug-delivery applications.


Growth Of Mos2@C Nanobowls As A Lithium-Ion Battery Anode Material, Chunyu Cui, Xiu Li, Zhe Hu, Jiantie Xu, Hua-Kun Liu, Jianmin Ma Jan 2015

Growth Of Mos2@C Nanobowls As A Lithium-Ion Battery Anode Material, Chunyu Cui, Xiu Li, Zhe Hu, Jiantie Xu, Hua-Kun Liu, Jianmin Ma

Australian Institute for Innovative Materials - Papers

Layered MoS2 has attracted much attention as a promising anode material for lithium ion batteries. The intrinsically poor electrical/ionic conductivity, volume expansion and pulverization, stress accumulation and unstable solid-electrolyte interface formation within MoS2 electrodes during the lithiation-delithiation process significantly result in their fast capacity fading, poor rate capability and cycle life. To address these critical issues, a novel nanobowl structure for MoS2 with a carbon coating (MoS2@C-400, 500, 600) is successfully fabricated by a facile solvothermal method, followed by a post-annealing process. The fabricated MoS2@C-600 and MoS2@C-500 exhibited high reversible capacities of 1164.4 and 1076.4 mA h g-1 at 0.2C, …


A Simple And Versatile Method For Microencapsulation Of Anti-Epileptic Drugs For Focal Therapy Of Epilepsy, Yu Chen, Zhilian Yue, Simon E. Moulton, Patricia Y. Hayes, Mark J. Cook, Gordon G. Wallace Jan 2015

A Simple And Versatile Method For Microencapsulation Of Anti-Epileptic Drugs For Focal Therapy Of Epilepsy, Yu Chen, Zhilian Yue, Simon E. Moulton, Patricia Y. Hayes, Mark J. Cook, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Nearly 30% of epilepsy cases cannot be adequately controlled with current medical treatments. The reasons for this are still not well understood, but there is a significant body of evidence pointing to the blood-brain barrier. Resective surgery can provide an alternative method of epilepsy control; however this treatment option is not suitable for most epilepsy sufferers. Local drug delivery through micro-injection to or implantation into the brain provides an innovative approach to bypass the blood-brain barrier for epilepsy treatment. In order to develop effective local delivery systems for anti-epilepsy drug (AED), we have prepared a variety of core-shell microcapsules via …


Improving Fault Ride-Through Capability Of Dfig Based Wind Generators By Using Bridge-Type Superconducting Fault Current Limiter, Mehrdad Tarafdar Hagh, Kashem M. Muttaqi, Danny Sutanto, Md Shahriar Hossain, Ahmed M. Haidar Jan 2015

Improving Fault Ride-Through Capability Of Dfig Based Wind Generators By Using Bridge-Type Superconducting Fault Current Limiter, Mehrdad Tarafdar Hagh, Kashem M. Muttaqi, Danny Sutanto, Md Shahriar Hossain, Ahmed M. Haidar

Australian Institute for Innovative Materials - Papers

This paper proposes series connection of a diode bridge-type superconducting fault current limiter (SFCL) with rotor side converter (RSC) of a double fed induction generator (DFIG) based wind turbine. The proposed SFCL improves the fault ride through (FRT) capability of DFIG and prevents the RSC from damaging fault currents. Because of using superconductor DC coil, there is not any power loss during fault or normal operation of system. The proposed SFCL does not have any considerable affect in wind turbine's operation during normal condition. It is not necessary to use any measurement and control systems, too. The SFCL returns to …


In Situ Anchoring Uniform Mno2 Nanosheets On Three-Dimensional Macroporous Graphene Thin-Films For Supercapacitor Electrodes, Yong Zhao, Yuena Meng, Haiping Wu, Yue Wang, Zhixiang Wei, Xiaojun Li, Peng Jiang Jan 2015

In Situ Anchoring Uniform Mno2 Nanosheets On Three-Dimensional Macroporous Graphene Thin-Films For Supercapacitor Electrodes, Yong Zhao, Yuena Meng, Haiping Wu, Yue Wang, Zhixiang Wei, Xiaojun Li, Peng Jiang

Australian Institute for Innovative Materials - Papers

We present a facile and efficient fabrication of 3D macroporous rGO/MnO2 nanosheet thin-films for supercapacitor electrodes. An amorphous-carbon-modified rGO thin-film is firstly prepared through a simple glucose and CaCO3 particle mediated template method. Then ultrathin MnO2 nanosheets are in situ synthesized on the rGO networks by the rapid and scalable redox reaction between KMnO4 and amorphous carbon. The fabricated three-dimensional porous hybrid thin-film shows a high specific capacitance of 245 F g-1 (based on the total mass of the film) at a scan rate of 2 mV s-1, a good rate capability of 143 F g-1 at 300 mV s-1, …


Integration Of Mno@Graphene With Graphene Networks Towards Li-Ion Battery Anodes, Wei Guo, Xiu Li, Dickon Ng, Jianmin Ma Jan 2015

Integration Of Mno@Graphene With Graphene Networks Towards Li-Ion Battery Anodes, Wei Guo, Xiu Li, Dickon Ng, Jianmin Ma

Australian Institute for Innovative Materials - Papers

In this work, we have directly integrated MnO@graphene with graphene networks through the thermal decomposition of a Mn-oleate complex in an Ar atmosphere at high temperatures. By introducing dual protective graphene shells and networks, the as-synthesized MnO/graphene composites exhibited superior cycling performance.


Increased Upconversion Performance For Thin Film Solar Cells: A Trimolecular Composition, Yuen Yap Cheng, Andrew Nattestad, Tim F. Schulze, Rowan W. Macqueen, Burkhard Fückel, Klaus Lips, Gordon G. Wallace, Tony Khoury, Maxwell J. Crossley, Timothy W. Schmidt Jan 2015

Increased Upconversion Performance For Thin Film Solar Cells: A Trimolecular Composition, Yuen Yap Cheng, Andrew Nattestad, Tim F. Schulze, Rowan W. Macqueen, Burkhard Fückel, Klaus Lips, Gordon G. Wallace, Tony Khoury, Maxwell J. Crossley, Timothy W. Schmidt

Australian Institute for Innovative Materials - Papers

Photochemical upconversion based on triplet-triplet annihilation (TTA-UC) is employed to enhance the short-circuit currents generated by two varieties of thin-film solar cells, a hydrogenated amorphous silicon (a-Si:H) solar cell and a dye-sensitized solar cell (DSC). TTA-UC is exploited to harvest transmitted sub-bandgap photons, combine their energies and re-radiate upconverted photons back towards the solar cells. In the present study we employ a dual-emitter TTA-UC system which allows for significantly improved UC quantum yields as compared to the previously used single-emitter TTA systems. In doing so we achieve record photo-current enhancement values for both the a-Si:H device and the DSC, surpassing …


Nanocomposite Hydrogels: Fracture Toughness And Energy Dissipation Mechanisms, Andrea Klein, Philip G. Whitten, Katharina Resch, Gerald Pinter Jan 2015

Nanocomposite Hydrogels: Fracture Toughness And Energy Dissipation Mechanisms, Andrea Klein, Philip G. Whitten, Katharina Resch, Gerald Pinter

Australian Institute for Innovative Materials - Papers

In this study, fracture toughness of nanocomposite hydrogels is quantified, and active mechanisms for dissipation of energy of nanocomposite hydrogels are ascertained. Poly(N,N-dimethylacrylamide) nanocomposite hydrogels are prepared by in situ free radical polymerization with the incorporation of Laponite, a hectorite synthetic clay. Transmission electron microscopy proves exfoliation of clay platelets that serve as multifunctional crosslinkers in the created physical network. Extraordinary high fracture energies of up to 6800 J m-2 are determined by the pure shear test approach, which shows that these soft and stretchable hydrogels are insensitive to notches. In contrast to single- and double-network hydrogels, dynamic mechanic analysis …


Porous Agpd-Pd Composite Nanotubes As Highly Efficient Electrocatalysts For Lithium-Oxygen Batteries, Wenbin Luo, Xuanwen Gao, Shulei Chou, Jiazhao Wang, Hua-Kun Liu Jan 2015

Porous Agpd-Pd Composite Nanotubes As Highly Efficient Electrocatalysts For Lithium-Oxygen Batteries, Wenbin Luo, Xuanwen Gao, Shulei Chou, Jiazhao Wang, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Porous AgPd-Pd composite nanotubes (NTs) are used as an efficient bifunctional catalyst for the oxygen reduction and evolution reactions in lithium-oxygen batteries. The porous NT structure can facilitate rapid O2 and electrolyte diffusion through the NTs and provide abundant catalytic sites, forming a continuous conductive network throughout the entire energy conversion process, with excellent cycling performance.