Physical Sciences and Mathematics Commons^™

Investigation Of Topological Phonons In Discrete Mechanical Metamaterials, Kai Qian

Dissertations

The study of topological mechanical metamaterials is a new emerging field that focuses on the topological properties of artificial mechanical structures. Inspired by topological insulators, topological mechanism has attracted intensive attention in condensed matter physics and successfully connected the quantum mechanical descriptions of electrons with the classical descriptions of phonons. It has led to experiments of mechanical metamaterials possessing topological characteristics, such as topologically protected conducting edges or surfaces without back-scattering. This dissertation presents a new experimental approach for mechanically engineering topological metamaterials based on patterning magnetically coupled spinners in order to localize the propagation of vibrations and evaluate different …

Towards Improving The Security Of The Software Supply Chain, Hammad Afzali

Dissertations

A software supply chain comprises a series of steps performed to develop and distribute a software product. History has shown that each of these steps is vulnerable to attacks that can have serious repercussions and can affect many users at once. To address the attacks against the software supply chain, end users must be provided with verifiable guarantees about the individual steps of the chain and with assurances that the steps are securely chained together.

In this dissertation, the security of several individual steps in the software supply chain is enhanced. The first step of the chain, managing the source …

Improving Multi-Threaded Qos In Clouds, Weiwei Jia

Dissertations

Multi-threading and resource sharing are pervasive and critical in clouds and data-centers. In order to ease management, save energy and improve resource utilization, multi-threaded applications from different tenants are often encapsulated in virtual machines (VMs) and consolidated on to the same servers. Unfortunately, despite much effort, it is still extremely challenging to maintain high quality of service (QoS) for multi-threaded applications of different tenants in clouds, and these applications often suffer severe performance degradation, poor scalability, unfair resource allocation, and so on.

The dissertation identifies the causes of the QoS problems and improves the QoS of multi-threaded execution with three …

Mechanisms Of Oscillations And Polyglot Entrainment In Neuronal And Circadian Models, Emel Khan

Dissertations

Entrainment is a type of synchronization in which the period of an endogenous oscillator matches the period of an external forcing signal and a stable phase relationship is maintained between them. Entrainment patterns are described in terms of the number of input oscillations (N) that are phase-locked to a number of output oscillations (M), referred to as N:M patterns. Arnold tongue diagrams are used to depict the regions of N:M entrainment patterns in the input period-amplitude parameter space. Although the entrainment of self-sustained oscillators by periodic forcing are well investigated is a well-studied problem, entrainment of damped oscillators has been …

Assessing The Real-Time Lagrangian Predictability Of The Operational Navy Coastal Ocean Model In The Gulf Of Mexico, Lea Kristen Locke

Dissertations

This study quantitatively assesses the drift predictive skill of Fleet Numerical Meteorology and Oceanography Center’s (FNMOC’s) operational ocean models which are used to support a wide range of military and civilian applications. Overall, the findings of this work support the recommendation of spatial filtering for regional-scale ocean model velocity fields used in deep-water drift applications. In conjunction with filtering, the use of a pure particle drift algorithm is suggested for short-term forecasts and a drift algorithm including a sub-grid scale, random flight, parameterization for predictions requiring extended forecast predictions.

Drift prediction skill is quantified through metrics of in-cloud percentage, distance …

An Integrated Approach For The Assessment And Monitoring Of Land Deformation In The Riyadh City And Its Surroundings For Identifying The Controlling Factors, Abdulaziz Ibrahim Aljammaz

Dissertations

An integrated approach (remote sensing, field, geodesy, geology, and hydrogeology) was conducted to assess and monitor land deformation at Riyadh city and its surroundings. Two settings were investigated. The first, Jinadriyah area (1.5 km²), an urban area located east of Riyadh city, was selected to assess deformation associated with urbanization over desert lands. The second location was Al Kharj area (19,790 km²) to the south of Riyadh city, a reclaimed desert land that was selected to assess the deformation associated with agricultural groundwater extraction from fossil aquifers. My investigations revealed high subsidence rates (up to -30 …

Institutional Changes In Western Michigan University For Incorporation Of Education For Sustainability, Saman Khan

Dissertations

Higher Education institutions (HEIs) have the potential to be significant contributors in the pursuit of a sustainable world through the incorporation of Education for Sustainability (EFS). However, HEIs are entrenched with structures and values that are often resistant to change. The literature reveals that instructors’ beliefs and institutional contexts are the two main factors that impact the implementation of institutional change for sustainability education. Western Michigan University (WMU) has created new required curriculum “WMU Essential Studies” (WES) for undergraduate students and they have targeted sustainability as an essential learning outcome, by integrating and applying it in content courses. Using a …

On Problems In Random Structures, Ryan Cushman

Dissertations

This work addresses two problems in optimizing substructures within larger random structures. In the first, we study the triangle-packing number v(G), which is the maximum size of a set of edge-disjoint triangles in a graph. In particular we study this parameter for the random graph G(n,m). We analyze a random process called the online triangle packing process in order to bound v(G). The lower bound on v(G(n,m)) that this produces allows for the verification of a conjecture of Tuza for G( …

Synthesis And Self-Assembly Of Amphiphilic Block Copolymers For The Fabrication Of Non-Spherical Polymersomes, Tamuka Chidanguro

Dissertations

Polymersomes, also known as polymer vesicles, have gained a lot of interest over the past two decades. These hollow spherical systems are made via the self-assembly of amphiphilic block copolymers and have found use in a range of areas from drug delivery, to cellular models, to nanoreactors. Their hollow nature allows them to carry hydrophilic cargo in their inner compartment and hydrophobic cargo in their membrane. Over the last decade, increasing efforts have focused on controlling the morphology of polymersomes. Research has shown that polymersome morphology plays an important role for instance in drug delivery, where tubular or rod-like vesicles …

The Power Of Sulfur: A Study Of An Isothiocyanate Chiral Derivatizing Agent, Thioamide Based Chiral Solvating Agents, And The Geometry Of Sulfonamides, Emily B. Crull

Dissertations

This three-part dissertation is connected by the thread of utilizing sulfur-based functional groups, hence the power of sulfur. The first project was the development of a pentafluorobenzene based isothiocyanate chiral derivatizing agent (CDA), a class of compounds that differentiate enantiomers through covalent bond formation. This project, which was addressed using a combination of synthetic and computational methods and NMR analysis, gave rise to an CDA that was highly selective for amines and computationally predictable. Branching off of that, the second project demonstrated the use of two thioamide chiral solvating agents (CSAs), which had never been reported as a core functional …

A Component-Wise Approach To Smooth Extension Embedding Methods, Vivian Montiforte

Dissertations

Krylov Subspace Spectral (KSS) Methods have demonstrated to be highly scalable methods for PDEs. However, a current limitation of these methods is the requirement of a rectangular or box-shaped domain. Smooth Extension Embedding Methods (SEEM) use fictitious domain methods to extend a general domain to a simple, rectangular or box-shaped domain. This dissertation describes how these methods can be combined to extend the applicability of KSS methods, while also providing a component-wise approach for solving the systems of equations produced with SEEM.

Data-Driven Approaches To Complex Materials: Applications To Amorphous Solids, Dil Kumar Limbu

Dissertations

While conventional approaches to materials modeling made significant contributions and advanced our understanding of materials properties in the past decades, these approaches often cannot be applied to disordered materials (e.g., glasses) for which accurate total-energy functionals or forces are either not available or it is infeasible to employ due to computational complexities associated with modeling disordered solids in the absence of translational symmetry. In this dissertation, a number of information-driven probabilistic methods were developed for the structural determination of a range of materials including disordered solids to transition metal clusters. The ground-state structures of transition-metal clusters of iron, nickel, and …

Semantic Classification Of Multidialectal Arabic Social Media, Tom Rishel

Dissertations

Arabic is one of the most widely used languages in the world, but due in part to its morphological and syntactic richness, resources for automated processing of Arabic are relatively rare. Arabic takes three primary forms: Classical Arabic as seen in the Qur’an and other classical texts; Modern Standard Arabic (MSA) as seen in newspapers, formal documents, and other written text intended for widespread distribution; and dialectal Arabic as used in common speech and informal communication. Social media posts are often written in informal language and may include non-standard spellings, abbreviations, emoticons, hashtags, and emojis. Dialectal Arabic is commonly used …

Structural Origin Of Thermal, Mechanical Properties And Morphological Behaviors Of Semiconducting Polymers, Song Zhang

Dissertations

The past decades have witnessed a surging exploration of semiconducting polymers for the application of wearable and flexible organic electronic devices. Despite the increased amounts of molecular engineered polymers and their much-improved electrical performances, a systematic study of the structure-thermal/mechanical property-morphology relationship of semiconducting polymers is still less investigated.

To understand the thin-film mechanical properties, a pseudo-free standing tensile tester was self-built and utilized to obtain their real-time stress-strain behaviors through uniaxial stretching on top of the water surface. It also enables the first quantitative measurement of fracture energy on ultrathin polymeric films. Through multiple mechanical testing methods (i.e., strain-rate …

Efficient Denoising Of High Resolution Color Digital Images Utilizing Krylov Subspace Spectral Methods, Eva Lynn Greenman

Dissertations

The solution to a parabolic nonlinear diffusion equation using a Krylov Subspace Spectral method is applied to high resolution color digital images with parallel processing for efficient denoising. The evolution of digital image technology, processing power, and numerical methods must evolve to increase efficiency in order to meet current usage requirements. Much work has been done to perfect the edge detector in Perona-Malik equation variants, while minimizing the effects of artifacts. It is demonstrated that this implementation of a regularized partial differential equation model controls backward diffusion, achieves strong denoising, and minimizes blurring and other ancillary effects. By adaptively tuning …

Microplankton Dynamics In The River-Dominated Mississippi Bight, Adam D. Boyette

Dissertations

The Mississippi Bight (MSB) is a river-dominated continental margin influenced by multiple large river systems, including the Mississippi River, Alabama and Tombigbee rivers via Mobile Bay, and numerous smaller rivers, creeks, and bayous. This is part of a biologically-rich ecosystem that supports the second largest fishery industry by volume in the United States. Despite our understanding of the linkages between primary production with higher trophic levels, there remains limited studies quantifying these trophic interactions in this system. Microplankton (µm) community dynamics and trophic connectivity between primary producers and heterotrophic protists represent a critical nexus influencing overall biological productivity in this …

Design And Modeling Of Bioinspired Polyelectrolytes With Controlled Architectures For Gene Delivery Applications, Kelli Stockmal

Dissertations

This dissertation focuses on the development of a range of bioinspired polyelectrolytes with controlled architectures for gene and drug delivery applications. Glycans are ubiquitous in biological systems, and understanding the role of saccharide stereochemistry, as well as cationic charge, on polymer behavior in aqueous solution and the interactions with nucleic acids can provide insight into how synthetic polyelectrolytes can be used for non-viral gene delivery and other biological applications. The first chapter provides an introductory overview on how cationic polyelectrolytes can be used to aid the delivery of RNA for controlling gene expression in a variety of cell types, how …

Atomic Oxygen Resistant Low Earth Orbit Stable Polymer Matrix Composites Employing Phenylphosphine Oxide Epoxy-Amines, Witold Fuchs

Dissertations

Atomic oxygen (AO) attacks polymer matrix composites (PMC’s) on the surfaces of spacecraft in low earth orbit (LEO) and threatens safe spacecraft operation and service life. Incorporating phenylphosphine oxide (PPO) groups into polymer chains offers a self-regenerating method of protection from AO but remains poorly understood. Herein, epoxies containing PPO groups were synthesized with increasing concentrations of phosphorus [P] from 0 to 8 wt % to investigate their AO resistance. Measurements confirmed the exposure of these materials to AO produces a passivation phosphate (POx) layer on the surface of the sample and the efficacy of the resultant layer was directly …

Water Elites’ Perceptions Of Water Security In The Middle East And North Africa Region, Ghaleb Akari

Dissertations

The Middle East and North African region continues to face significant water security challenges. The purpose of this dissertation is to gain a deeper understanding of water elites’ perceptions of water security in the MENA region. It is not meant to generalize the findings. Instead, the intention for the research is to identify, explain, and analyze by national elites' contrasting perceptions in Jordan, Iraq, Egypt, and Tunisia.

The study examines water elites’ perceptions in four areas: current knowledge level of water security, water resource management, water service delivery, and water-related risk mitigation. These elites’ perceptions of water security will help …

Dolomite Stoichiometry As A Proxy For Fluid Chemistry, Cameron J. Manche

Dissertations

The origin of massive dolomites is a contentious issue in geology. Because modern dolomite is rare, interpretation of ancient dolomites requires the use of proxy resources, most of which provide ambiguous information. High-temperature dolomite synthesis experiments have shown that dolomite stoichiometry, the degree of cation ordering, and reaction rate are controlled by Mg:Ca, temperature, molarity, and salinity of the formative solution. Thus, it is posited here that dolomite stoichiometry may be a useful proxy for fluid chemistry, as are stable isotope and trace element composition of ancient dolomites. High-frequency sample intervals (cm-scale) from the Cretaceous Upper Glen Rose Formation (Comanche …

From Multi-Prime To Subset Labelings Of Graphs, Bethel I. Mcgrew

Dissertations

A graph labeling is an assignment of labels (elements of some set) to the vertices or edges (or both) of a graph G. If only the vertices of G are labeled, then the resulting graph is a vertex-labeled graph. If only the edges are labeled, the resulting graph is an edge-labeled graph. The concept was first introduced in the 19th century when Arthur Cayley established Cayley’s Tree Formula, which proved that there are n^n-2 distinct labeled trees of order n. Since then, it has grown into a popular research area.

In this study, we first review several types …

Advancing The Use Of Quality Control Tools For High-Density Data In Modern Manufacturing, Romina Dastoorian

Dissertations

In modern manufacturing, advanced metrology systems are continually being incorporated into quality control (QC) systems to provide high-density (HD) datasets. These datasets can contain millions of measurements that can be used to represent a part’s whole geometry. While integrating HD datasets into QC systems has brought several opportunities to enhance the performance of QC systems, it has resulted in new challenges in this area as well. While significant amounts of research have been performed in this area, the QC research community still strives to tackle these challenges. This study identifies key challenges regarding incorporating HD datasets into QC systems. Specifically, …

On Prediction Of Early Signs Of Alzheimer’S— A Machine Learning Framework, Abdalrahman Alsaedi

Dissertations

Dementia is a collective term used to indicate a loss of memory functions with the presence of at least one additional loss of a major cognitive ability that hinders a person’s previous level of functioning. Studies show that dementia is highly age- associated and that the most common cause of dementia is Alzheimer’s disease. Early recognition of Alzheimer’s disease, before irreversible damage to the brain has already occurred, is paramount to slowing or preventing the disease. Therefore, algorithms for the prediction of early signs of dementia are essential. Machine learning approach has been reported to use several data sources such …

Construct Linear Quasi-Interpolants On Infinite Intervals, Johara Farah Albaliwi

Dissertations

In solving the data interpolation problem, which is fundamental in data analysis, we typically deal with the data samples spread in a finite interval [a, b], which results in the operations involving finite-dimensional matrices. There are many interesting results developed under this framework. However, when the data samples are given from an infinite interval [a, ∞) (for certain special types of real-world applications), many existing results would not work anymore due to the special properties of the infinite data samples. A new framework should be established to support the infinite data samples.

In this dissertation, we develop a special tool …

Matrix Product Structure Of A Permuted Quasi Cyclic Code And Its Dual, Perian Perdhiku

Dissertations

In my Dissertation I will work mostly with Permuted Quasi Cyclic Codes. They are a generalization of Cyclic Codes, one of the most important families of Linear Codes in Coding Theory. Linear Codes are very useful in error detection and correction. Error Detection and Correction is a technique that first detects the corrupted data sent from some transmitter over unreliable communication channels and then corrects the errors and reconstructs the original data. Unlike linear codes, cyclic codes are used to correct errors where the pattern is not clear and the error occurs in a short segment of …

Ready To Engage? Urban Middle School Teachers’ Responsiveness To Targeted Engagement Interventions On Their Virtual Instructional Practices: An Action Research Study, Svetlana Nikic

Dissertations

Teachers’ effectiveness is associated with their instructional practices and is ultimately linked to students’ learning outcomes. In order to impact teachers’ effectiveness, schools focus substantial effort and resources on professional development led by an assumption that teachers’ classroom practices can be improved through targeted interventions. Even if this premise is correct, little information is available about how much a teacher’s practice may change through interventions, or which aspects of instructional practice are more receptive to improving teacher effectiveness (Garret et al., 2019).

This study took place at an urban middle school and examined teachers’ responsiveness to targeted engagement intervention in …

Instantaneous Frequency Estimation And Signal Separation Using Fractional Continuous Wavelet Transform, Abdelbaset R. Zeyani

Dissertations

In the signal processing field, time-frequency representations (TFR's) have intensively been improved to provide effective and powerful tools for reliable signal analysis. One of the most valuable and frequently used tools is Fourier transform (FT) which has been used to study the frequency content of stationary signals in the Fourier domain (FD). However, FT is not sufficient to study the frequency of non-stationary signals. For this particular type of signals to be best analyzed, some transforms such as the short time Fourier transform (STFT) and the continuous wavelet transform (CWT) have been introduced to provide us with a signal representation …

Development Of Small Molecule Inhibitors Of Therapeutic Target Enzymes: Paths To Discover Novel Antimicrobials, Thahani Shifna Habeeb Mohammad

Dissertations

The rising antimicrobial resistance to antibiotics is a major global problem, which has been exacerbated by the inappropriate use of antibiotics. The effectiveness of frequently prescribed penicillin derivatives and β-lactamase inhibitors are compromised by the evolution of bacterial β-lactamases and antibiotic-resistant bacteria. Consequently, design and synthesis of small-molecule inhibitors of identified novel antibiotic targets is an urgent unmet medical need. We previously demonstrated that N-functionalized α-aminocyclobutanones can act as peptidomimetic enzyme inhibitors, including inhibition of a key esterase in Francisella Tularensis. The carbonyl of a cyclobutanone is electrophilic due to ring strain, therefore cyclobutanone derivatives can serve as transition state …

Identification Of New Pathways For Co Oxidation On Rh(111) & Spatial And Structural Control Of O-Induced Reconstruction Of Ag(111), Marie Turano

Dissertations

Understanding the fundamentals of oxygen surface structures under a variety of conditions is pivotal to determining reactivity of heterogeneous catalysis. Exposure of catalytically active metal surfaces to high oxygen coverages results in a myriad of surface structures. A further complication is the formation of subsurface oxygen (Osub) or oxygen present in the near subsurface region of the metal. It is known to form in transition metals yet the absorption of oxygen and resultant formation of Osub is not equivalent across all catalytically relevant metals. As a result, it is difficult to predict the stability and efficacy of the formation of …

Can Generative Adversarial Networks Help Us Fight Financial Fraud?, Sean Mciver

Dissertations

Transactional fraud datasets exhibit extreme class imbalance. Learners cannot make accurate generalizations without sufficient data. Researchers can account for imbalance at the data level, algorithmic level or both. This paper focuses on techniques at the data level. We evaluate the evidence of the optimal technique and potential enhancements. Global fraud losses totalled more than 80 % of the UK’s GDP in 2019. The improvement of preprocessing is inherently valuable in fighting these losses. Synthetic minority oversampling technique (SMOTE) and extensions of SMOTE are currently the most common preprocessing strategies. SMOTE oversamples the minority classes by randomly generating a point between …