Physical Sciences and Mathematics Commons^™

Polyhedral Oligomeric Silsesquioxane-Phosphate Glass Matrix Nanocomposites With Additional Chapter On Phosphate Glass-Poly(Ethylene Terephthalate) Matrix Composites, Kyoungtae Kim

Dissertations

Preparation and characterization of tin fluorophosphate glass (Pglass) matrix nanocomposites incorporating polyhedral oligomeric silsesquioxane (POSS) were investigated on the structural, thermal, morphological, mechanical, and rheological properties. Various processes including synthesis, extrusion and sintering processes were applied to prepare the nanocomposite samples. Another application of POSS with hydrophobic functional groups on the well-structured nanoscale silicate cage with three silanol groups was investigated to present the feasibility to use POSS molecule as a coating material on the surface of the hydrophilic inorganic glass. In addition, Poly(ethylene terephthalate) polymer matrix composites incorporating Pglass was studied to present the benefits of the Pglass with …

Predicted Deepwater Bathymetry From Satellite Altimetry: Non-Fourier Transform Alternatives, Maxsimo Salazar

Dissertations

Robert Parker (1972) demonstrated the effectiveness of Fourier Transforms (FT) to compute gravitational potential anomalies caused by uneven, non-uniform layers of material. This important calculation relates the gravitational potential anomaly to sea-floor topography. As outlined by Sandwell and Smith (1997), a six-step procedure, utilizing the FT, then demonstrated how satellite altimetry measurements of marine geoid height are inverted into seafloor topography. However, FTs are not local in space and produce Gibb’s phenomenon around discontinuities. Seafloor features exhibit spatial locality and features such as seamounts and ridges often have sharp inclines. Initial tests compared the windowed-FT to wavelets in reconstruction of …

Effect Of Network Structure On Free Volume And Gas Transport Properties Of Thiol-Ene And Epoxy-Amine Networks, Ramesh Krishnan Ramakrishnan

Dissertations

Network parameters such as cross-link density or intermolecular interactions were used as effective parameters to control polymer chain packing or free volume and thereby control the mass transport properties of networks.

A series of polyethylene glycol (PEG) based thiol-ene elastomeric networks having a broad range of molecular weight between cross-links, M_c, (inverse of cross-link density) was prepared. The specific volume of the networks was studied as a function of temperature and pressure using high pressure dilatometry, and the obtained PVT data was fit using Simha-Somcynsky equation of state (S-S eos) analysis. Fractional free volume, quantified through S-S eos …

Structure-Property Relationships Of Solvent-Cast Organic Thin Films For Model Corrosion Control Coatings, Austin Maples

Dissertations

This dissertation aimed at answering several fundamental questions, specifically: 1) What is the effect of scribing parameters on visual corrosion assessments? 2) What role do molecular weight, residual solvent, and polymer composition have on morphological changes in organic thin films? 3) What alternatives to visual assessments could be implemented to better understand and detect corrosion before macroscopic failure? This research definitively proved that scribes can vary in type and dimensions, and yet are still comparable if the scribe dimensions before exposure are known. Furthermore, it demonstrated that solvents common to a variety of coating industries could become trapped within the …

Computational Modeling Of Radiation Interactions With Molecular Nitrogen, Tyler Reese

Dissertations

The ability to detect radiation through identifying secondary effects it has on its surrounding medium would extend the range at which detections could be made and would be a valuable asset to many industries. The development of such a detection instrument requires an accurate prediction of these secondary effects. This research aims to improve on existing modeling techniques and help provide a method for predicting results for an affected medium in the presence of radioactive materials. A review of radioactivity and the interactions mechanisms for emitted particles as well as a brief history of the Monte Carlo Method and its …

Exploring Potential Water-Ice Occurrence On Asteroid 4 Vesta Using Orbital Radar Observations By The Dawn Mission, Elizabeth M. Palmer

Dissertations

Airless, differentiated planetesimals in the inner solar system were presumed to have been depleted of most of their initial volatile content during formation. However, water-ice has been discovered at the lunar poles (Li et al., 2018), is inferred to exist in polar craters on Mercury (e.g., Butler, Slade & Muhleman, 1993, and suggested to survive beneath the dusty regolith of objects in the main asteroid belt if buried at sufficient depths—at least one meter for small-bodies in the outer main-belt (Schorghofer, 2008). Hence, the study of volatile occurrence, past or present, on airless, desiccated small-bodies provides insights into the timing, …

Assessing Land Deformation And Sea Encroachment In The Nile Delta: A Radar Interferometric And Modeling Approach, Esayas Gebrekidan Gebremichael

Dissertations

Many of the deltas of the world are experiencing land deformation, subsidence or uplift of landmass, due to natural or anthropogenic causes, or a combination of both processes and causes. These deltaic settings are densely populated and border some of our world’s largest water bodies (oceans and seas). The land deformation, especially the subsidence component, when combined with the climate change-induced sea level rise, coastal erosion, and other anthropogenic drivers, will undoubtedly impact the population and economy of coastal areas of deltas. For the Nile Delta of Egypt, the land deformation processes and the factors that control the deformation processes …

Radiative Double Electron Capture (Rdec) By Fully-Stripped Fluorine Ions In Collisions With Nitrogen, Nuwan Sisira Kumara

Dissertations

Radiative double electron capture (RDEC) by highly-stripped ions in collisions with atomic targets is a fundamental process that can be used to study electron-electron correlation, the interaction between two electrons, in the vicinity of the Coulomb field of a bare ion. In this process two electrons from the target are captured to bound states of the projectile with the simultaneous emission of a single photon. RDEC is closely related to the well-known one-step atomic process of radiative electron capture (REC), in which a target electron is captured to the projectile and a photon is simultaneously emitted. REC and RDEC can …

Generalized Line Graphs, Mohra Abdullah Z. Alqahtani

Dissertations

With every nonempty graph, there are associated many graphs. One of the best known and most studied of these is the line graph L (G) of a graph G, whose vertices are the edges of G and where two vertices of L (G) are adjacent if the corresponding edges of G are adjacent. This concept was implicitly introduced by Whitney in 1932. Over the years, characterizations of graphs that are line graphs have been given, as well as graphs whose line graphs have some specified property. For example, Beineke characterized graphs that are line graphs by forbidding certain graphs …

Protecting Privacy Of Data In The Internet Of Things With Policy Enforcement Fog Module, Abduljaleel Al-Hasnawi

Dissertations

The growth of IoT applications has resulted in generating massive volumes of data about people and their surroundings. Significant portions of these data are sensitive since they reflect peoples' behaviors, interests, lifestyles, etc. Protecting sensitive IoT data from privacy violations is a challenge since these data need to be handled by public networks, servers and clouds, most of which are untrusted parties for data owners. In this study, a solution called Policy Enforcement Fog Module (PEFM) is proposed for protecting sensitive IoT data. The primary task of the PEFM solution is mandatory enforcement of privacy polices for sensitive IoT data-whenever …

Application Of Glycosyl Imidates And Nitrates In Carbohydrate Synthesis, Tinghua Wang

Dissertations

Carbohydrates are the most abundant molecules among the four essential classes of biomolecules that also include nucleic acids, lipids and proteins. Unlike proteins and nucleic acids, which follow template-driven synthetic pathways, there is no general route to the synthesis of carbohydrates. The stereoselectivity of the formation of O-glycosidic linkages and the regioselectivity of protection and deprotection of specific hydroxyl groups over others represent two of the major challenges in carbohydrate chemistry. This thesis is dedicated to the development of novel strategies for efficient synthesis of carbohydrate building blocks and stereocontrolled glycosylations for step-economy oligosaccharide synthesis. Novel glycosyl donors with difluoro-3H-indol-2-yl …

Divisibility In The Stone-Cech Compactification Of N, Salahddeen Khalifa

Dissertations

Let S a discrete semigroup. The associative operation on S extends naturally to an associative operation on βS,the Stone Cech compactification of S. This involves both topology and algebra and leads us to think how to extend properties and operations that are defined on S to βS. A good application of this is the extension of relations and divisibility operations that are defined on the discrete semigroup of natural numbers (N,.) with multiplication as operation to relations and divisibility operations that are defined on (βN,?) where (?) is the extension of the operation (.). In this research I studied extending …

Geotraces And Beyond: Studies Of Trace Elements In Coastal And Open Ocean Waters With An Emphasis On The Effects Of Oxygen Depletion And Hydrothermal Plumes, Peng Ho

Dissertations

We investigated various dissolved trace element (dTE) distributions in two distinct areas: the coastal northern Gulf of Mexico and the eastern tropical Pacific Ocean.

A multi-year (2007‒2011) chemical time series of eight stations in the western Mississippi Sound (MS) and northwestern Mississippi Bight (MB) was undertaken to examine the factors affecting chemical distributions in this dynamic region. Key findings include the frequent development of bottom water hypoxia in MB during late spring-summer, the likely contribution of submarine groundwater discharge (SGD) to the material flows, and observation of effects of episodic events including tropical storms and the opening of the Bonnet …

Synthetic And Theoretical Studies For Cyclization Reactions To Form C-C And C-N Bonds, Nicholas Jentsch

Dissertations

Natural product total synthesis provides an alternative method for obtaining medicinally relevant compounds in a more efficient process with higher yields than what nature can provide. Natural products pose significant synthetic challenges due to the unique heterocyclic skeletons with fused and spirocyclic ring systems. Therefore, it is paramount to develop efficient reaction methodologies targeting substructures such as cyclic ureas and spiro[4.5]decanes which are prominent among marine natural products and Lycopodium alkaloids, respectively. Presented here is a compilation of research seeking to develop synthetic methods for the construction of cyclic moieties such as those previously mentioned. The objectives that are addressed …

Probabilistic And Extremal Problems In Combinatorics, Sean English

Dissertations

Graph theory as a mathematical branch has been studied rigorously for almost three centuries. In the past century, many new branches of graph theory have been proposed. One important branch of graph theory involves the study of extremal graph theory. In 1941, Turán studied one of the first extremal problems, namely trying to maximize the number of edges over all graphs which avoid having certain structures. Since then, a large body of work has been created in the study of similar problems. In this dissertation, a few different extremal problems are studied, but for hypergraphs rather than graphs. In particular, …

Adaptive Meshfree Methods For Partial Differential Equations, Jaeyoun Oh

Dissertations

There are many types of adaptive methods that have been developed with different algorithm schemes and definitions for solving Partial Differential Equations (PDE). Adaptive methods have been developed in mesh-based methods, and in recent years, they have been extended by using meshfree methods, such as the Radial Basis Function (RBF) collocation method and the Method of Fundamental Solutions (MFS). The purpose of this dissertation is to introduce an adaptive algorithm with a residual type of error estimator which has not been found in the literature for the adaptive MFS. Some modifications have been made in developing the algorithm schemes depending …

The Effect Of An Historical Geology Course On Students’ Attitudes Towards Science And Their Knowledge Of Deep Time As A Threshold To Their Knowledge Of Evolution, Allan Nolan

Dissertations

In America there exists a conflict between a small group of its citizens and the concept of evolution. Researchers have studied this conflict and the ways in which teachers might approach educational methodologies that not only address evolution in a sensitive manner, but also remain legally acceptable.

This research was designed to address teaching evolution in the context of deep time – the concept that time is vast and that geology and biology operate in a timescale of hundreds of millions to billions of years. In previous peer-reviewed works, it has been stated that deep time acts as a threshold …

The Feasibility Of Using Inherent Optical Properties And The Apparent Optical Property Remote Sensing Reflectance To Estimate Suspended Particulate Matter, Particularly For Use In Airborne Hydrographic Surveys, Sarah Epps

Dissertations

Airborne hydrographic surveys are routinely used to create and update nautical charts around the world. This research is intended to assist in maximizing the utility of the data products made available from those surveys in accordance with the current survey–once, use–many–times initiatives. Specifically, this project evaluates the feasibility of using the data available airborne hydrographic systems that utilize bathymetric lasers and hyperspectral sensors to estimate the concentration of suspended particulate matter (SPM). SPM is sometimes also called suspended sediment. The ability to chart spatial distributions of SPM utilizing hydrographic survey systems already in operation will assist researchers, managers, and stakeholders …

Investigation Of Vaporization Enthalpies And Vapor Pressures Of Organic Compounds By Correlation Gas Chromatography, Carissa Nelson

Dissertations

Thermodynamic properties of organic compounds are useful to scientists and manufacturers in many areas of research and technology. This work focuses on measuring and reporting these properties on materials of commercial, environmental and scientific interest. Vaporization enthalpies and vapor pressures of several organic compounds have been studied using correlation gas chromatography (CGC) and are reported here as well as in recent publications. The CGC method allows for the indirect measurement of these properties in instances where these materials are available only in mixtures or in very small amounts.

The qualities of these measurements for any chosen target are directly related …

Improving K-Nn Search And Subspace Clustering Based On Local Intrinsic Dimensionality, Arwa M. Wali

Dissertations

In several novel applications such as multimedia and recommender systems, data is often represented as object feature vectors in high-dimensional spaces. The high-dimensional data is always a challenge for state-of-the-art algorithms, because of the so-called "curse of dimensionality". As the dimensionality increases, the discriminative ability of similarity measures diminishes to the point where many data analysis algorithms, such as similarity search and clustering, that depend on them lose their effectiveness. One way to handle this challenge is by selecting the most important features, which is essential for providing compact object representations as well as improving the overall search and clustering …

Applications Of Big Knowledge Summarization, Ling Zheng

Dissertations

Advanced technologies have resulted in the generation of large amounts of data ("Big Data"). The Big Knowledge derived from Big Data could be beyond humans' ability of comprehension, which will limit the effective and innovative use of Big Knowledge repository. Biomedical ontologies, which play important roles in biomedical information systems, constitute one kind of Big Knowledge repository. Biomedical ontologies typically consist of domain knowledge assertions expressed by the semantic connections between tens of thousands of concepts. Without some high-level visual representation of Big Knowledge in biomedical ontologies, humans cannot grasp the "big picture" of those ontologies. Such Big Knowledge orientation …

Novel Image Descriptors And Learning Methods For Image Classification Applications, Ajit Puthenputhussery

Dissertations

Image classification is an active and rapidly expanding research area in computer vision and machine learning due to its broad applications. With the advent of big data, the need for robust image descriptors and learning methods to process a large number of images for different kinds of visual applications has greatly increased. Towards that end, this dissertation focuses on exploring new image descriptors and learning methods by incorporating important visual aspects and enhancing the feature representation in the discriminative space for advancing image classification.

First, an innovative sparse representation model using the complete marginal Fisher analysis (CMFA-SR) framework is proposed …

Theoretical Studies Of Photoinduced Dynamics And Topological States In Materials With Strong Electron-Lattice Couplings, Linghua Zhu

Dissertations

First, we study the nonequilibrium dynamics of photoinduced phase transitions in charge ordered (CO) systems with a strong electron-lattice interaction and analyze the interplay between electrons, periodic lattice distortions, and a phonon thermal reservoir. Simulations based on a tight-binding Hamiltonian and Boltzmann equations reveal partially decoupled oscillations of the electronic order parameter and the periodic lattice distortion during CO melting, which becomes more energy efficient with lower photon energy. The cooling rate of the electron system correlates with the CO gap dynamics, responsible for an order of magnitude decrease of the cooling rate upon the gap reopening. The work also …

Thermosetting Polymers Via Azide Alkyne Cycloaddition, Richard H. Cooke Iii

Dissertations

This dissertation exploits properties inherent to azide-alkyne cycloaddition and applies practical solutions to difficult problems. Chapter II addresses structure-property relationships in glassy azido-alkyne matrices by varying the identity of the central linkage within tetrapropargyl bis-aniline-type crosslinkers, and by the addition or omission of Cu(I) catalyst. This systematic study showed that an ether or methylene linkage yielded lower melting tetrapropargyl crosslinkers that were soluble in, and produced homogeneous, networks when cured with, a standard azido resin, di(3-azido-2-hydroxypropyl) ether of bisphenol-A; in contrast, a sulfone linkage yielded a relatively insoluble crosslinker and poorly dispersed, heterogeneous networks when reacted with the same …

Induced Graph Colorings, Ian Hart

Dissertations

An edge coloring of a nonempty graph G is an assignment of colors to the edges of G. In an unrestricted edge coloring, adjacent edges of G may be colored the same. If every two adjacent edges of G are colored differently, then this edge coloring is proper and the minimum number of colors in a proper edge coloring of G is the chromatic index χ^/(G) of G. A proper vertex coloring of a nontrivial graph G is an assignment of colors to the vertices of G such that every two adjacent vertices of …

Nanojars: Versatile Platform For Pyrazole Synthesis And Chemistry, And Selective Extraction Of Anions, Basil Mohammed Ahmed

Dissertations

This work is centered around nanojars, a family of nano-sized anion-incarcerating agents. It addresses various aspects of nanojar chemistry, such as synthesis strategies (including green methodologies) for pyrazole ligands needed for the preparation of nanojars, characterization and study of the mechanism of assembly of nanojars, and selective extraction of anions from water using nanojars.

Nanojars are neutral, supramolecular coordination complexes of the general formula [anion⊂ {Cu(μ-OH)(μ-pz)}_n], formed by the reaction of Cu²⁺, HO^‒ and pyrazolate ions (C₃H₂N₂‒, pz^‒) in the presence of oxoanions with large hydration energy …

Exploring The Role Of Semi-Supervised Deep Reinforcement Learning And Ensemble Methods In Support Of The Internet Of Things, Mehdi Mohammadi

Dissertations

Smart services are an important element of the Internet of Things (IoT) ecosystem where insights are drawn from raw data through the use of machine learning techniques. However, the pathway to develop IoT smart services is complicated as IoT data presents several challenges for machine learning, including handling big data, shortage of labeled data, and the need to benefit from the spatio-temporal relations hidden in the training data.

In this dissertation, after reviewing the state-of-the-art deep learning (DL) and deep reinforcement learning (DRL) techniques and their use in support of IoT applications, this study proposes to extend DRL to semi-supervised …

Detection Of Bedrock Fractures And Joints Beneath Cover: Geophysical Approaches To An Engineering Geology Problem, Muthanna Yousif Yaqoob Aldiney

Dissertations

This research used geophysical methods to detect the presence of sub-vertical failure planes, their direction(s), and their frequency in bedrock beneath soil or glacial drift overburden. Azimuthal measurements using the seismic, electrical resistivity (ER), and electromagnetic conductivity were made to evaluate which techniques might provide the best indication of the bedrock joints, faults, or shear zones. Measurements were made at multiple sites near each of three locations: Jackson, Alpena, and Grand Ledge, Michigan. The first two are former limestone quarries and the third is underlain by sandstone. Seismic measurements began with one or two linear refraction spreads, used to establish …

The Bellringer Sequence: Investigating What And How Preservice Mathematics Teachers Learn Through Pedagogies Of Enactment, Mary A. Ochieng

Dissertations

This study examines preservice teacher learning through pedagogies of enactment—approaches to teacher education that allow preservice teachers to learn by doing what teachers do. Preservice teacher (PST) learning is examined through the implementation of the Bellringer Sequence (BRS), a pedagogy of enactment conceptualized in the study. The BRS is centered around bellringers—brief mathematical tasks implemented as students arrive for class. The BRS is a sequence of four activities centered on a bellringer: preparation (for teaching a bellringer) implementation (of the bellringer with peers), debriefing (discussing the implementation as colleagues), and written reflection (about the effectiveness of the bellringer).

Practice-based approaches …

Graceful Colorings And Connection In Graphs, Alexis D. Byers

Dissertations

For a graph G of size m, a graceful labeling of G is an injective function f : V (G) → {0, 1, . . . , m} that gives rise to a bijective function f ¹ : E(G) → {1, 2, . . . , m} defined by f ¹(uv) = |f (u) − f (v)|. A graph is graceful if it has a graceful labeling. Over the years, a number of variations of graceful …