Physical Sciences and Mathematics Commons^™

Chemistry And Thermochemistry Of Selected Fatty Acids Using Correlation Gas Chromatography, Joe A. Wilson

Dissertations

Correlation gas chromatography (c-GC) is a special application of the gas chromatography technique and is used for the evaluation of both vaporization enthalpy and vapor pressures of organic compounds. Its use in measuring vaporization enthalpies has been extensively documented. This method is useful for measurements of both liquids and solids. For substances that are solids, since each analyte is dilutely adsorbed on the condensed phase of the gas chromatographic column, it is not crystalline. The vapor pressure that it exhibits behaves as an excellent model of the sub-cooled liquid as demonstrated by various thermochemical cycles. Thermochemical measurements are important to …

Nanoporous Gold Characterization, Structural Modification And Use As A Solid Support For Biomolecule Immobilization, Abeera Sharma

Dissertations

Nanoporous gold (NPG) has immense technological applications owing to a plethora of properties like large surface area to volume ratio, plasmonic properties, stable gold-thiolate bond formation and a wide range of pore sizes. The surface morphology of nanoporous gold has been altered previously by dealloying and thermal annealing to increase/decrease the pore size and change the surface area. We provide a novel electrochemical annealing technique for post dealloying modification wherein electrochemical sweep cycles in different electrolytes at positive potentials leads to a subsequent increase in pore sizes of nanoporous gold as studied using scanning electron microscopy. Tailoring the surface of …

On Eulerian Irregularity And Decompositions In Graphs, Eric Andrews

Dissertations

Abstract attached as separate file.

Studies Of The Quantum Phase Transition In Chromium Using Inelastic X-Ray Scattering And Ab Initio Methods, Chengyang Li

Dissertations

In this project, inelastic x-ray scattering (IXS) was used to measure the phonon dispersion in chromium at high pressure and low temperature, and an ab initio method was used to simulate the phonon dispersion with different lattice constants and magnetic orders. The IXS measurements were carried out in Sector 30 at the Advanced Photon Source at Argonne National Laboratory. Data were taken at room temperature with pressures of 1.29 GPa, 8.15 GPa, 10.6 GPa, and at 5 K with a pressure of 18.36 GPa. The data shows similar phonon behavior in the antiferromagnetism (AFM) and the spin density wave (SDW) …

Biophysical Characterization Of The First Four Metal-Binding Domains Of Human Wilson Disease Protein, Alia V.H. Hinz

Dissertations

Wilson disease protein (WLNP) is a P_1b-type ATPase crucial for maintaining copper homeostasis in humans. Mutations in this protein result in the autosomal recessive disorder Wilson disease, a condition characterized by copper accumulation in the liver and brain. WLNP provides copper for incorporation into cuproproteins and exports excess copper into the bile for excretion. There are six metal-binding domains (MBDs) in WLNP, found within the first 650 amino acids of this 1,465 amino acid protein. Though each MBD has a different amino acid sequence, all MBDs possess a similar ferredoxin fold with a conserved hydrophobic core and a …

Lie Loops Associated With Gl(ℋ), ℋ A Separable Infinite Dimensional Hilbert Space, Alper Bulut

Dissertations

Abstract attached as separate file.

Connecting The Disciplinary Dots: Faculty Attitudes Toward The Professionalization Of Web Development, Kathleen Mary Kalata

Dissertations

Professionalization offers rewards such as prestige, financial benefits and autonomy. Fields such as nursing and social work have undergone the professionalization process. This exploratory study examined faculty attitudes regarding the professionalization of web development as defined by the Hall model of professionalism. The purpose of the study was to understand how faculty view web development as a profession. Based on the Hall’s Professionalism Scale (1968) and modified survey by Snizek (1972), the Web Development Professionalism Inventory (WDPI) was used to explore faculty attitudes toward professionalization.

This study surveyed faculty about their views on the structural and attitudinal components of web …

Opportunistic Service Differentiation And Cloud Resource Management In Support Of Enhanced Vehicular Applications, Mohammad Ali Salahuddin

Dissertations

An integral part of Intelligent Transportation Systems (ITS) are Vehicular Ad hoc Networks (VANETs), which consist of vehicles with on-board units (OBUs) and fixed road-side units (RSUs). Wireless Access in Vehicular Environment (WAVE) offers QoS via service differentiation by using application defined priorities. However, WAVE has unbounded delay and is oblivious to network load and severity of vehicles with respect to their environment. Our context severity metric innovatively enhances WAVE to be sensitive to vehicle and environment interactions. Our novel Opportunistic Service Differentiation (OSD) technique, dynamically readjusts the WAVE packet priorities to improve utilization of lower latency queues, prioritizing packets …

Mathematical Methods Of Analysis For Control And Dynamic Optimization Problems On Manifolds, Robert J. Kipka

Dissertations

Mathematical Methods Of Analysis For Control And Dynamic Optimization Problems On Manifolds Driven by applications in fields such as robotics and satellite attitude control, as well as by a need for the theoretical development of appropriate tools for the analysis of geometric systems, problems of control of dynamical systems on manifolds have been studied intensively during the past three decades. In this dissertation we suggest new mathematical techniques for the study of control and dynamic optimization problems on manifolds. This work has several components including: an extension of the classical Chronological Calculus to control and dynamical systems which are merely …

The Control Of The False Discovery Rate Under Structured Hypotheses, Gavin Lynch

Dissertations

The hypotheses in many multiple testing problems often have some inherent structure based on prior information such as Gene Ontology in gene expression data. However, few false discovery rate (FDR) controlling procedures take advantage of this inherent structure. In this dissertation, we develop FDR controlling methods which exploit the structural information of the hypotheses.

First, we study the fixed sequence structure where the testing order of the hypotheses has been pre-specified. We are motivated to study this structure since it is the most basic of structures, yet, it has been largely ignored in the literature on large scale multiple testing. …

Electro-Deformation Of A Moving Boundary: A Drop Interface And A Lipid Bilayer Membrane, Herve Nganguia

Dissertations

This dissertation focuses on the deformation of a viscous drop and a vesicle immersed in a (leaky) dielectric fluid under an electric field. A number of mathematical tools, both analytical and numerical, are developed for these investigations. The dissertation is divided into three parts. First, a large-deformation model is developed to capture the equilibrium deformation of a viscous spheroidal drop covered with non-diffusing insoluble surfactant under a uniform direct current (DC) electric field. The large- deformation model predicts the dependence of equilibrium spheroidal drop shape on the permittivity ratio, conductivity ratio, surfactant coverage, and the elasticity number. Results from the …

Data Analysis And Simulation For Warranties And Golf Handicaps, Sonia Bandha

Dissertations

In this dissertation, we discuss the application of data analysis and numerical simulation in order to gain insight into problems related to warranty cost management and the effectiveness of the golf handicap system. Despite the commonalities of the approaches, we will discuss these problems in turn.

For many moderately high value items with a substantial sales volume (such as automobiles), a warranty is used as an important element of marketing products as a better warranty typically signals higher product quality to customers. Much recent research on modeling and optimization of servicing costs for Non-Renewing Free Replacement Warranties (NR-FRW) assumes that …

Fwer Controlling Procedures For Testing Multiple Hypotheses With Hierarchical Structure And Applications In Clinical Trials, Zhiying Qiu

Dissertations

In applications of clinical trials, the hypotheses to be tested often exhibit a hierarchical structure, and are usually hierarchically ordered based on their importance, clinical relevance, or dose concentration, etc. Thus, they are tested in a pre-defined fixed sequence. In some more complex cases, the hypotheses to be tested are hierarchically grouped into several families, and thus the families are tested in a sequential order. Although such problems of structured multiple testing have received much attention and several popular FWER controlling procedures, such as conventional fixed sequence procedure, fallback procedure and gatekeeping procedure have been introduced, not much progress has …

Computational Methods For The Analysis Of Next Generation Sequencing Data, Wei Wang

Dissertations

Recently, next generation sequencing (NGS) technology has emerged as a powerful approach and dramatically transformed biomedical research in an unprecedented scale. NGS is expected to replace the traditional hybridization-based microarray technology because of its affordable cost and high digital resolution. Although NGS has significantly extended the ability to study the human genome and to better understand the biology of genomes, the new technology has required profound changes to the data analysis. There is a substantial need for computational methods that allow a convenient analysis of these overwhelmingly high-throughput data sets and address an increasing number of compelling biological questions which …

Investigation Of New Feature Descriptors For Image Search And Classification, Atreyee Sinha

Dissertations

Content-based image search, classification and retrieval is an active and important research area due to its broad applications as well as the complexity of the problem. Understanding the semantics and contents of images for recognition remains one of the most difficult and prevailing problems in the machine intelligence and computer vision community. With large variations in size, pose, illumination and occlusions, image classification is a very challenging task. A good classification framework should address the key issues of discriminatory feature extraction as well as efficient and accurate classification. Towards that end, this dissertation focuses on exploring new image descriptors by …

Analysis Of Far-Infrared Optical Spectra Of Multiferroics, Eric C. Standard

Dissertations

The optical spectra of multiferroic crystals Dy₃Fe₅O₁₂, Tb₃Fe₅O₁₂, and four hexagonal RMnO₃ (5D= Er, Tm, Yb, Lu) are studied using intense bright synchrotonic light in the infrared spectral range. In regards to the materials analyzed, two rare earth iron garnets and four rare earth manganites in total are examined. These materials have attracted much attention due to their interesting magnetoelectric properties. They could serve as the basis for the next generation of faster and more energy efficient memory and logic devices. To examine these materials, two …

Nanocarbon Immobilized Membrane For Separation And Analysis, Madhuleena Bhadra

Dissertations

Membrane processes classically cover a wide range of applications associated with various aspects of separation and purification. Over the last few years, membrane based processes have received much interest due to their compact and modular architecture, low energy consumption and cost effective separation. With the development of diverse nanomaterials which can serve as nanosorbents, or provide specific morphology for selective solute transport, recent years have witnessed the emergence of nanocarbon based membranes that can address some of the limitations of conventional membrane processes and make feasible the next generation of breakthroughs.

The objective of this research is the exploration of …

Inverse Methods For Sound Speed Estimation In The Ocean, Tao Lin

Dissertations

This dissertation presents theoretical and computational approaches for estimating sound-speed in the ocean under different conditions. The first part of the dissertation discusses a fast approach for solving the inverse problem of estimating sediment sound-speed based on the Deift-Trubowitz trace formula. Under certain assumptions, this algorithm can recover the sound speed profile in the seabed using pressure field measurements in the water column at low frequencies. The inversion algorithm requires solving a non-linear integral equation. In the past, Stickler and Zhou employed a first order Born approximation for solving the integral equation. This work introduces two new methods. The first …

Basis Function Approaches For Two Dimensional Cochlear Models, Lihua Li

Dissertations

The human cochlea possesses the amazing ability of analyzing audio signals. The structures and mechanisms behind its characteristic response to sound stimuli has been an active area of research for decades. It has been demonstrated that mathematical cochlear modeling poses a promising alternative to discover the elusive activities in an in vivo cochlea. However, despite the successful application of numerical methods such as the Wentzel-Kramers-Brillouin (WKB) method, finite difference method (FDM) and finite element method (FEM), the critical effects of the choice of basis functions have not been studied exclusively for the numerical solutions of cochlea models. This work presents …

Biogeochemistry Of Trace Elements In The Mixing Zone Of The Mississippi And Atchafalaya Rivers And Chemical Distributions As Affected By The Deepwater Horizon Blowout, Dongjoo Joung

Dissertations

Selected trace elements (TEs), dissolved organic carbon, and nutrients were studied in Louisiana Shelf waters including the Mississippi (MR) and Atchafalaya (AR) River plumes during periods of high, intermediate, and low river discharges. Seasonal variations in TEs were observed at low salinity, reflecting seasonal changes in the river water endmembers. Shelf surface water dissolved Mo, Cs, U, Ni, and Cu showed conservative behavior with minor scattering in some high salinity waters. Based on associated mixing experiments, nutrient and chlorophyll distributions, as well as surface-bottom concentration contrasts, the non-conservative behavior of TEs was variously related to colloidal flocculation (Fe, Cr), biological …

Natural Radioactivity In Groundwater, Rocks And Sediments From Some Areas In The Uae: Distribution, Sources And Environmental Impact, Dalal Matar Al Shamsi

Dissertations

Groundwater contains a certain amount of natural radioactivity that generally results from the decay of uranium, thorium and 40K isotopes. Knowledge of concentration levels, spatial distribution and sources of these isotopes in groundwater is crucial for environmentally safe and sustainable groundwater resources in the United Arab Emirates (UAE). This dissertation focuses on investigating the distribution, environmental impact and sources of 235U, 238U, 232Th, as well as the activity of gross β and α in groundwater in some locations in the UAE. Additionally, groundwater samples from Oman and selected aquifer rocks and sediments from the UAE were analyzed for comparison. A …

Community Detection And Influence Maximization In Online Social Networks, Kanna Gharib Al-Falahi

Dissertations

The detecting and clustering of data and users into communities on the social web are important and complex issues in order to develop smart marketing models in changing and evolving social ecosystems. These marketing models are created by individual decision to purchase a product and are influenced by friends and acquaintances. This leads to novel marketing models, which view users as members of online social network communities, rather than the traditional view of marketing to individuals. This thesis starts by examining models that detect communities in online social networks. Then an enhanced approach to detect community which clusters similar nodes …

Dynamics Of Phase Locking In Neuronal Networks In The Presence Of Synaptic Plasticity, Zeynep Akcay

Dissertations

The behavior generated by neuronal networks depends on the phase relationships of its individual neurons. Observed phases result from the combined effects of individual cells and synaptic connections whose properties change dynamically. The properties of individual cells and synapses can often be characterized by driving the cell or synapse with inputs that arrive at different phases or frequencies, thus producing a feed-forward description of these properties. In this study, a recurrent network of two oscillatory neurons that are coupled with reciprocal synapses is considered. Feed-forward descriptions of the phase response curves of the neurons and the short-term synaptic plasticity properties …

Improving The Design Of Cluster-Randomized Trials In Education: Informing The Selection Of Variance Design Parameter Values For Science Achievement Studies, Carl D. Westine

Dissertations

The purpose of this three-essay dissertation is to provide practical guidance to evaluators planning cluster-randomized trials (CRTs) of science achievement. In an educational setting, interventions are often administered at the cluster level, while outcomes are typically measured at the student level through standardized achievement testing. When evaluating an intervention, a CRT is appropriate because it allows for treatment to be modeled at a different level than the unit of analysis, and properly accounts for the violation of independence that occurs due to nesting. Accurately designing a CRT involves estimating variance parameters (i.e., intraclass correlations [ICCs] and percent of variance explained …

A Metaevaluation Of Energy Efficiency Evaluations, Brandy Brown

Dissertations

This study systematically reviews the methodological characteristics of energy efficiency evaluations and uses metaevaluation to assess its quality. Metaevaluation is used to systematically assess the quality of evaluation products, confirm that evaluations deliver sound findings and conclusions, are useful to the client, are credible, are ethically conducted, and are done as cost-effective as possible. The results of this study show that the ability to accurately assess evaluation for methodological quality using evaluations reports as a primary data source depends on the presence of detailed descriptions of evaluation methods. Furthermore, the study suggests that methodological variations of energy efficiency evaluations coalesce …

Multivariate Autoregressive Time Series Using Schweppe Weighted Wilcoxon Estimates, Jaime Burgos

Dissertations

The increasing needs of forecasting techniques has led to the popularity of the vector autoregressive model in multivariate time series analysis, which has become of typical use across different fields due to its simplicity in application. The traditional method for estimating the model parameters is the least squares minimization, due to the linear nature of the model and its similarity with multivariate linear regression. However, since least squares estimates are sensitive to outliers, more robust techniques have become of interest. This manuscript investigates a robust alternative by obtaining the estimates using a weighted Wilcoxon dispersion with Schweppe-type weights. The first …

A Metaevaluation Of Evaluations Of Health Care Programs That Employ The Chronic Care Model, Jan Fields

Dissertations

Background: The purpose of this dissertation is to explore the use of metaevaluation to evaluate the quality of healthcare studies conducted on programs that employ the Chronic Care Model (CCM) to provide chronic illness care. In this study, healthcare studies of CCM programs are regarded as program evaluations. Method: Using a non-experimental cross-sectional design, 28 healthcare studies of CCM programs were evaluated using the accuracy standards portion of the Program Evaluations Metaevaluation Checklist (Stufflebeam, 2011). The results of the metaevaluations were analyzed and compared to the HEAL grade of the same healthcare studies as determined by the Hierarchy of Evidence …

Harnessing Complexity: Analysis Methodology And Ethical Framework To Facilitate Utilization Of Video Data In Evaluations, Kurt A. Wilson

Dissertations

Most evaluations in the nonprofit and international development sectors are conducted in contexts of complexity; the specific intervention being evaluated is but one of many interrelated factors influencing the desired outcome. Video data, especially when directly generated by program participants, can provide both exceptionally rich qualitative data as well as contextually-relevant feedback within complex systems. Despite these unique strengths and opportunities, video data is underutilized in the field of evaluation. This dissertation addresses specific barriers associated with video data through three inter-related papers: Papers one and two (Chapters II and III) present the findings from two interrelated studies of an …

Synthesis, Characterization And Potential Applications Of Palladium And Ruthenium Nanostructures, Clara Patrice Adams

Dissertations

Controlling the size and shape of metal nanostructures is important for tuning the intrinsic chemical and physical properties of materials, and consequently their potential technological applications. Modulating the morphology of metal nanostructures is essential to understanding the structure-function relationship (for example, optical, magnetic, catalytic, and electronic properties) under various environmental conditions. Our work describes the development of new procedures for the synthesis of well-defined isotropic and anisotropic nanoparticles consisting of palladium (Pd) and ruthenium (Ru). Characterization of the nanostructures was carried out using transmission electron microscopy (TEM), high resolution-TEM (HRTEM), powder x-ray diffraction (XRD), selected area electron diffraction (SAED) and …

Size-Dependent Interactions Of Metal Nanoparticles With Fluorophores And Semiconductors, Liyana A. Wajira Ariyadasa

Dissertations

In recent years, nanoscale metallic particles have gained considerable interest due to their potential applications in advanced technology. Despite such interest, synthetic procedures that produce gram-scale, well-defined metallic nanoparticles with controlled size and shape, especially with diameters less than 5 nm remains a challenge. Our work has focused on developing synthetic procedures that produce well-defined platinum and palladium metal nanoparticles in the 1-5 nm size range. Thioether ligands were used as stabilizers and resulted in metal nanoparticles with controlled size. The nanoparticles were characterized using transmission electron microscopy (TEM), x-ray diffraction (XRD), selected area electron diffraction (SAED), x-ray photoelectron spectroscopy …