Physical Sciences and Mathematics Commons^™

Quantum Phase Transitions In The Presence Of Disorder And Dissipation, Chetan Kotabage

Doctoral Dissertations

"A quantum phase transition is a phase transition at absolute zero occurring under variations in an external non-thermal parameter such as magnetic field or pressure. Quantum phase transitions are one among the important topics currently investigated in condensed matter physics. They are observed in various systems, e.g., in the ferromagnetic-paramagnetic phase transition in LiHoF₄ or in the superconductor-metal phase transition in nanowires.

A particular class of quantum phase transitions, which is phase transitions in the presence of disorder and dissipation, is investigated here. An example of this class is the ferromagnetic-paramagnetic phase transition in Ni₁₋ₓVₓ or CePd_1-xRhₓ caused …

Development Of A Versatile Man-Portable Obscurant Aerosol Generator: Characterization Of Aerosols In Laboratory And Field Environments, Robert William Schaub

Doctoral Dissertations

"The objective of research presented in this dissertation was to develop a readily deployable and environmentally benign obscurant system operating with a single liquid for the visible and near infrared regions. To achieve this objective, research efforts were directed in two areas: i. Evaluating suitable biogenic oils to replace the United States Army's "Fog Oil" as the obscurant fluid. ii. Design, fabrication and validation of a prototype man-portable / vehicle mountable modular obscurant aerosol generator. Petroleum middle distillate - "Fog Oil" has been the material of choice for wide area obscuration for several decades. Large quantities (thousands gallons) of the …

Probability Theory On Time Scales And Applications To Finance And Inequalities, Thomas Matthews

Doctoral Dissertations

"In this dissertation, the recently discovered concept of time scales is applied to probability theory, thus unifying discrete, continuous and many other cases. A short introduction to the theory of time scales is provided. Following this preliminary overview, the moment generating function is derived using a Laplace transformation on time scales. Various unifications of statements and new theorems in statistics are shown. Next, distributions on time scales are defined and their properties are studied. Most of the derived formulas and statements correspond exactly to those from discrete and continuous calculus and extend the applicability to many other cases. Some theorems …

Vascular Countercurrent Network For 3d Triple-Layered Skin Structure With Radiation Heating, Xiaoqi Zeng

Doctoral Dissertations

Heat transfer in living tissue has become more and more attention for researchers, because high thermal radiation produced by intense fire, such as wild fires, chemical fires, accidents, warfare, terrorism, etc, is often encountered in human's daily life. Living tissue is a heterogeneous organ consisting of cellular tissue and blood vessels, and heat transfer in cellular tissue and blood vessel is quite different, because the blood vessels provide channels for fast heat transfer. The metabolic heat generation, heat conduction and blood perfusion in soft tissue, convection and perfusion of the arterial-venous blood through the capillary, and interaction with the environment …

Preliminary Model Development Of Metal Complexation Of Polyester Derivatives Of 2,2'-Biimidazole, Shelonda Rena Taylor Finch

Doctoral Dissertations

"The objective of this study was to develop a chemical model for metal ion complex formation by a macroligand system with multi-metal binding sites using 2,2'-biimidazole as the starting molecule of the ligand system. Prior studies in this laboratory guided the selection of diesters and hydroxyethyl derivatives of 2,2'-biimidazole as model monomers. In addition, metal ion complexation studies with 2,2'-biimidazole derivatives were conducted. As a result, crystal structures of 1,1'-di(methylpropionato)-2,2-biimidazole, 2,2'-bis(1H-imidazolium) dinitrate and silver 2,2'-bis(1H-imidazolium) trinitrate, were reported. The crystal structures indicated a dependence upon the binding ability of the protonated 2,2'-biimidazole and counter ions. transesterification of the diesters and …

Ceeme: Compensating Events Based Execution Monitoring Enforcement For Cyber-Physical Systems, Thoshitha T. Gamage

Doctoral Dissertations

"Fundamentally, inherently observable events in Cyber-Physical Systems with tight coupling between cyber and physical components can result in a confidentiality violation. By observing how the physical elements react to cyber commands, adversaries can identify critical links in the system and force the cyber control algorithm to make erroneous decisions. Thus, there is a propensity for a breach in confidentiality leading to further attacks on availability or integrity. Due to the highly integrated nature of Cyber-Physical Systems, it is also extremely difficult to map the system semantics into a security framework under existing security models. The far-reaching objective of this research …

Epitaxial Electrodeposition Of Metal Oxide Films And Superlattices Which Exhibit Resistance Switching, Rakesh V. Gudavarthy

Doctoral Dissertations

"This dissertation presents an investigation of the electrodeposition of metal oxide films and superlattices on conducting polycrystalline and single crystal substrates. In the first part of the study, electrodeposition of magnetite (Fe₃O₄) films and superlattices in the magnetite/zinc ferrite system which exhibit resistance switching is studied. Paper I reports the electrodeposition of superlattices in the magnetite/zinc ferrite system and shows that only superlattices exhibit multistate resistance switching. In paper II, simple polycrystalline magnetite films electrodeposited on stainless steel crystals exhibit multistate resistance switching which can be tuned by controlling the composition of the films. Paper II describes the epitaxial electrodeposition …

Receiver Function Studies Of Crustal Structure, Composition, And Evolution Beneath The Afar Depression, Ethiopia, Sattam A. Almadani

Doctoral Dissertations

"The dissertation utilizes a set of sophisticated computer programs developed at the Geophysics group at Missouri S&T to characterize crustal properties beneath the Afar Depression in Ethiopia where extensional tectonics dominates. In this study, measurements of crustal thickness (H), crustal mean Vp/Vs [which is related to Poisson's ratio (Σ)], and the sharpness of the Moho (R) were determined using teleseismic data from 18 broadband seismic sensors that we deployed along a profile of 250 km long with a station spacing of ~ 10 km. The stations had been recording continuously for an entire year from December 2009 until December 2010. …

Modeling Hourly Electricity Prices: A Structural Time Series Approach Incorporating Modified Garch Innovations, Edirisinghe Mudiyanselage Asitha Edirisinghe

Doctoral Dissertations

"The main objective of this research is to develop time series based procedures for modeling day-ahead and real-time hourly electricity prices. Such empirical processes exhibit features that make the direct application of standard time series models infeasible. Four years of hourly day-ahead and real-time electricity price data from the region supplied by the American Electric Power (AEP) company through the PJM Regional Transmission Organization (RTO) and one half years of real-time electricity prices from the MISO RTO are utilized as an empirical basis for developing such procedures. The price data show several features, such as irregular seasonal behavior, weekly and …

One Pot Synthesis Of Metal, Carbides And Polymeric Aerogels, Naveen K. Chandrasekaran

Doctoral Dissertations

"Ultra-low density, three-dimensional assemblies of nanoparticles are referred to as aerogels, and typically are derived from supercritical fluid (SCF) drying of wet-gels. Aerogels are generally fragile materials, but that issue has been addressed successfully by X-aerogels, in which the inorganic nanoparticle framework plays the role of the template for the accumulation of polymer that connects covalently and crosslinks the nanoparticles. The resulting materials can be 300x stronger than the native network, for a nominal increase in density by a factor of 3x. Since the exceptional mechanical properties of X-aerogels are traced to the conformal polymer coating, it was reasonable to …

Minimal And Near Minimal Congruence Lattice Representations Of Finite Lattices By Finite Algebras On Sets Of Integers, Roger Lee Bunn

Doctoral Dissertations

"We give finite congruence lattice representations of some finite distributive, modular and nonmodular lattices by means of finite algebras on sets of integers. These representations are minimal or near minimal as determined by ρ, a mapping from the class R of finitely representable lattices into the natural numbers N"--Abstract, page iii.

Novel Electrochemical Detections Of Biologically And Environmentally Relevant Substances, Clarissa E. Tatum

Doctoral Dissertations

Development and studies of new electrochemical methods for the detection of various biologically and environmentally relevant substances are the focus of this dissertation. A dual amperometric sensor, capable of the simultaneous, real-time determination of NO and O,2, has been developed and optimized. Many tests were performed in order to reduce cross-talking between the two sensors, and an electro-deposited polymer, poly-5-amino-1-naphthol, was shown to reduce the cross-talking to insignificant levels. The use of bismuth-based electrodes in the detection of various metals has been explored. A bismuth bulk electrode has been developed, optimized, and used for the individual and simultaneous determination of …

Tantalum Carbene And Imide Complexes. Synthesis, Characterization, And Pathways Of Formation, Julia Kathryn Covington Abbott

Doctoral Dissertations

This dissertation focuses on two different types of organometallic compounds, carbenes and imides. The first project deals with the archetypal Schrock carbene, and the second project studies complexes that contain metal-nitrogen bonds, both amides and imides.

A summary of the research in this dissertation is discussed in Chapter 1. Chapter 2 begins the studies of the archetypal Schrock carbene (Bu^tCH₂)₃Ta=CHBu^t. The studies include the synthesis of deuterated compounds (Bu^tCD₂)₃TaCl₂ and Bu^tCD₂Li, observation and identification of the intermediate, Ta(CD₂Bu^{t …}

Spin-Lattice Coupling In The Iron-Pnictide High-Temperature Superconductors, Daniel E Parshall

Doctoral Dissertations

The recent discovery of the iron-pnictide superconductors has generated tremendous excitement, in part because there are many tantalizing similarities to the cuprate superconductors. As with the cuprates, it is strongly suspected that the spins contribute to superconductivity.

There seems to be a strong relationship between the lattice and magnetism in this system. Several authors have discussed the possibility of spin-phonon coupling, but direct experimental evidence has remained elusive.

This work discusses the relationship between the spins and the lattice in the $BaFe_{2}As_{2}$ family. We demonstrate the presence of negative thermal expansion in these materials, which is a strong indicator of …

A Visual Approach To Automated Text Mining And Knowledge Discovery, Andrey A. Puretskiy

Doctoral Dissertations

The focus of this dissertation has been on improving the non-negative tensor factorization technique of text mining. The improvements have been made in both pre-processing and post-processing stages, with the goal of making the non-negative tensor factorization algorithm accessible to the casual user. The improved implementation allows the user to construct and modify the contents of the tensor, experiment with relative term weights and trust measures, and experiment with the total number of algorithm output features. Non-negative tensor factorization output feature production is closely integrated with a visual post-processing tool, FutureLens, that allows the user to perform in depth analysis …

Human Decomposition Ecology At The University Of Tennessee Anthropology Research Facility, Franklin Edward Damann

Doctoral Dissertations

The University of Tennessee Anthropology Research Facility (ARF) is well known for its unique history as a site of human decomposition research in a natural environment. It has been integral to our understanding of the processes of human decomposition. Over the last 30 years 1,089 bodies have decomposed at this 1.28 acre facility, producing a density of 850 corpses per acre of land. This project evaluated the abiotic and biotic characteristics of the soil exposed to various levels of human decomposition in order to determine the effect on the physicochemical properties and the indigenous bacterial communities.

Specifically, 75 soil samples …

The Importance Of Chain Connectivity In The Formation Of Non-Covalent Interactions Between Polymers And Single-Walled Carbon Nanotubes And Its Impact On Dispersion, Dias Linton

Doctoral Dissertations

Polymer nanocomposites have garnered incredible promise in the field of material science due to the excellent mechanical strength, thermal and electrical conductivities of the nanoparticles and the extension of these properties to the processing flexibility inherent to plastics. However, practical realization of these nanoparticle-based materials has been hindered by the tendency of these nanoparticles to aggregate as a result of strong inter-particle forces. In this dissertation, we investigate the formation of non-covalent charge transfer interactions between polymers and single-walled carbon nanotubes (SWNTs) with the goal of optimizing interfacial adhesion and homogeneity of nanocomposites without modifying the SWNT native surface.

Nanocomposites …

Bioeconomic And Biophilic Intersect In Nature Centers - A Case Study Of One Nature Center, Carolyn Jeanne Price

Doctoral Dissertations

The purposes of this research were 1) to understand what stakeholders in one nature center are "thinking"about the focus of their center and the niche it occupies; 2) to characterize the role of one nature center in its local community; 3) to examine the nature center in terms of established characteristics of a "best" nature center; 4) to compare stakeholder perceptions with perceptions of directors of exemplar nature centers and environmental education organizations; and 5) to characterize visitor and member stakeholder perceptions and motivations in terms of the extrinsic value of ecosystem services, bioeconomics, versus the intrinsic value of nature, …

Differential Equation Models And Numerical Methods For Reverse Engineering Genetic Regulatory Networks, Mi Un Yoon

Doctoral Dissertations

This dissertation develops and analyzes differential equation-based mathematical models and efficient numerical methods and algorithms for genetic regulatory network identification. The primary objectives of the dissertation are to design, analyze, and test a general variational framework and numerical methods for seeking its approximate solutions for reverse engineering genetic regulatory networks from microarray datasets using the approach based on differential equation modeling. In the proposed variational framework, no structure assumption on the genetic network is presumed, instead, the network is solely determined by the microarray profile of the network components and is identified through a well chosen variational principle which minimizes …

Steps Toward Butternut (Juglans Cinerea L.) Restoration, Sunshine L. Brosi

Doctoral Dissertations

Butternut (Juglans cinerea L.), a lesser-known relative of black walnut (Juglans nigra L.), is a native tree species beneficial for wildlife, valuable for timber, and part of the great diversity of species in the eastern forests of North America. Populations of butternut are being devastated by butternut canker disease, caused by the fungus Sirococcus clavigignenti-juglandacearum (V.M.G. Nair, Kostichka, & Kuntz), which is thought to be introduced to North America. The disease causes multiple branch and stem cankers that eventually girdle trees. Small population sizes, lack of sprouting, and shade intolerance exacerbates the disease and results in permanent losses of butternut …

Polymeric Loop Formation At Hard And Soft Interfaces, Earl Ashcraft

Doctoral Dissertations

Copolymers are used to increase the interfacial strength of immiscible components and suppress recombination of the minor phase by steric hindrance. The experiments conducted in these studies are designed to investigate in situ polymer loop formation at soft interfaces and functionalized nanotube surfaces. Block copolymers are the most effective type of copolymer for compatibilization because they extend perpendicular to the interface, allowing good entanglement with the homopolymer chains. Multiblock copolymers are more effective than diblock copolymers for strengthening the interface because they can cross the interface multiple times, forming “loops” in each phase that provide entanglement points for the homopolymer. …

Sources And Transport Pathways Of Fecal Bacteria And Pathogens To Aquifers In Rural Bangladesh, Peter S. K. Knappett

Doctoral Dissertations

During the 1980’s millions of households in Bangladesh switched from drinking surface water to private groundwater wells to reduce their exposure to fecal microorganisms. Sadly, this switch to shallow groundwater resulted in the largest example of drinking water poisoning in history, with approximately 100 million people exposed to high concentrations of naturally occurring Arsenic in the groundwater. Spatial distribution of Arsenic in the shallow aquifers tends to be patchy, so the most economical mitigation option has been lateral switching from high Arsenic wells to nearby low Arsenic wells. The recently developed Arsenic flushing conceptual model, which explains the spatial distribution …

Density Functional Calculation Of X-Ray Absorption Spectra Within The Core Hole Approximation: An Implementation In Nwchem, William Ben Carlen

Doctoral Dissertations

Density functional theory is used to calculate the core excitation spectra of titanium structures. Specifically, the core-hole approximation is used. In this scenario, the excitation energies of core electrons are calculated using the approximation that the core energy level be frozen throughout the relaxation process of the orbitals. This allows a more acurate determination of the resulting X-ray spectra. The method described has been implemented in an NWChem module.

Supported Aqueous-Phase Catalysis For Atom Transfer Radical Polymerization, Ravi Aggarwal

Doctoral Dissertations

Atom transfer radical polymerization (ATRP) which utilizes transition metal based catalysts is a versatile methodology for the synthesis of a wide spectrum of polymers with controlled architectures. However, high concentrations of soluble catalyst required in an ATRP process makes the final polymer colored and toxic. Thus, the catalyst removal/reduction/recycling remains a challenge in the field of ATRP. Supported catalysts on insoluble solids such as silica gel, polystyrene beads, etc. have been used in ATRP to facilitate the catalyst recovery and recycling. However, the ability of the supported catalysts to mediate a polymerization is substantially reduced due to their reduced mobility …

Surface And Subsurface Structures Of The Western Valley And Ridge In Tennessee And Geometry And Kinematics That Permit Reconstruction Of The Tennessee Salient, Southern Appalachians, Jennifer Kathleen Whisner

Doctoral Dissertations

The southern and central Appalachian foreland fold-thrust belt comprises a series of orogen -scale curves that extend from Alabama to New York. One of these is the Tennessee salient, a foreland-convex curve that extends from Cartersville, Georgia, to Roanoke, Virginia. Development of a kinematic model for deformation in the salient has been hindered by a paucity of penetrative deformation in this generally low temperature, low volume-loss portion of the orogen.

Industry seismic reflection lines provide greater resolution of subsurface geometry of both the basement surface and the overlying fold-thrust belt, confirming some previous interpretations and changing others. A series of …

Multidimensional Liquid Chromatography Separations, Jacob N. Fairchild

Doctoral Dissertations

Many mixtures important to research consist of hundreds or even thousands of individual components of interest. These types of mixtures are far too complex to separate by a single chromatographic dimension in any reasonable amount of time. However, if a multidimensional approach is used, where a complex mixture is separated by an initial dimension, simpler fractions of that separation are collected and each of those fractions are analyzed individually, highly complex mixtures can be resolved in relatively short amounts of time. This dissertation serves as a guide to multidimensional chromatography, in particular, two-dimension liquid chromatography. There are many aspects of …

Spatiotemporal Dynamics In A Lower Montane Tropical Rainforest, Robert Michael Lawton

Doctoral Dissertations

Disturbance in a forest’s canopy, whether caused by treefall, limbfall, landslide, or fire determines not only the distribution of well-lit patches at any given time, but also the ways in which the forest changes over time. In this dissertation, I use a 25 year record of treefall gap formation find a novel and highly patterned process of forest disturbance and regeneration, providing a local mechanism by examining the factors that influence the likelihood of treefall. I then develop a stochastic cellular automaton for disturbance and regeneration based on the analysis of this long term data set and illustrate the potential …

Interplay Between Structure And Chemistry Of Materials And Their Physical Properties, Alaska Subedi

Doctoral Dissertations

First principles calculations provide a powerful tool for sorting out the interplay of chemical composition and structure with the physical properties of materials. In this dissertation, I discuss the physical properties and their microscopic basis within this framework for following illustrative examples. (i) The Zintl phase hydrides, where I find H is anionic and the formation of covalent sp2 bonds in the Al/Ga/Al-Si planes, which is a highly unusual bonding configuration for these elements. (ii) PbTe, which shows strong coupling between the longitudinal acoustic and transverse optic modes that may explain its low thermal conductivity. (iii) The double perovskites BiPbZnNbO6 …

Effects Of 2000-2050 Global Climate Change On Ozone And Particulate Matter Air Quality In The United States Using Models-3/Cmaq System, Yun-Fat Lam

Doctoral Dissertations

The Models-3/Community Multi-scale Air Quality modeling system (CMAQ), coupled with Goddard Institute for Space Studies (GISS) atmospheric General Circulation Model (GCM), fifth Generation Mesoscale Model system (MM5), and Goddard Earth Observing System-CHEMistry (GEOS-Chem), was used to simulate atmospheric concentration of ozone and particulate matter over the continental United States 12-km and 36-km (CONUS) domains at year 2000 and year 2050. In the study, GISS GCM model outputs interfaced with MM5 were utilized to supply the current and future meteorological conditions for CMAQ. The conventional CMAQ profile initial and boundary conditions were replaced by time-varied and layer-varied GEOS-Chem outputs. The future …

Towards Simulations Of Binary Neutron Star Mergers And Core-Collapse Supernovae With Genasis, Reuben Donald Budiardja

Doctoral Dissertations

This dissertation describes the current version of GenASiS and reports recent progress in its development. GenASiS is a new computational astrophysics code built for large-scale and multi-dimensional computer simulations of astrophysical phenomena, with primary emphasis on the simulations of neutron star mergers and core-collapse supernovae. Neutron star mergers are of high interest to the astrophysics community because they should be the prodigious source of gravitation waves and the most promising candidates for gravitational wave detection. Neutron star mergers are also thought to be associated with the production of short-duration, hard-spectral gamma-ray bursts, though the mechanism is not well understood. In …