Physical Sciences and Mathematics Commons^™

Geophysical Imaging Of Karst Features In Missouri, Jeremiah Chukwunonso Obi

Doctoral Dissertations

"Automated electrical resistivity tomography (ERT) supported with multichannel analysis of surface waves (MASW) and boring data were used to map karst related features in Missouri in order to understand karst processes better in Missouri. Previous works on karst in Missouri were mostly surficial mapping of bedrock outcrops and joints, which are not enough to define the internal structure of karst system, since most critical processes in karst occur underground. To understand these processes better, the density, placement and pattern of karst related features like solution-widened joints and voids, as well as top of bedrock were mapped. In the course of …

Existence And Classification Of Nonoscillatory Solutions Of Two Dimensional Time Scale Systems, Özkan Özturk

Doctoral Dissertations

"During the past years, there has been an increasing interest in studying oscillation and nonoscillation criteria for dynamic equations and systems on time scales that harmonize the oscillation and nonoscillation theory for the continuous and discrete cases in order to combine them in one comprehensive theory and eliminate obscurity from both.

We not only classify nonoscillatory solutions of dynamic equations and systems on time scales but also guarantee the (non)existence of such solutions by using the Knaster fixed point theorem, Schauder - Tychonoff fixed point theorem, and Schauder fixed point theorem. The approach is based on the sign of nonoscillatory …

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan

Doctoral Dissertations

"As the rapid growing of nanotechnology, the release of engineered nanoparticles (ENPs) into the environment is inevitable. After entering the real environment, ENPs tend to react with different components of the ecosystem (e.g. water, soil, air, plants) and make their characterization difficult. Analyzing ENPs in these complex matrices still remains as a grand challenge. ENPs characterization is normally the first step of risk assessment. Current analytical techniques have shown some limitations in revealing the unique characteristics of ENPs in complex matrices and reliable analytical techniques are in urgent need. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) is an emerging …

Contribution Of New Thiol Antioxidant In The Treatment Of Acetaminophen Toxicity, Ahdab Naeem Khayyat

Doctoral Dissertations

"Acetaminophen (N-acetyl-p-aminophenol, APAP) is one of the most widely used over-the-counter antipyretic analgesic medications. It is safe at therapeutic doses, but an overdose can result in severe hepato-nephrotoxicity, a leading cause of drug-induced acute liver failure in the U.S. Although a few different mechanisms have been proposed for APAP-induced toxicity, a significant amount of evidence has pointed to the potential involvement of oxidative stress in acetaminophen toxicity. Depletion of glutathione (GSH) is one of the initiating steps in APAP-induced toxicity; therefore, one strategy for restricting organ damage is to restore GSH levels by using GSH prodrugs like N-acetylcysteine (NAC). Although …

Boundary Control Of Parabolic Pde Using Adaptive Dynamic Programming, Behzad Talaei

Doctoral Dissertations

"In this dissertation, novel adaptive/approximate dynamic programming (ADP) based state and output feedback control methods are presented for distributed parameter systems (DPS) which are expressed as uncertain parabolic partial differential equations (PDEs) in one and two dimensional domains. In the first step, the output feedback control design using an early lumping method is introduced after model reduction. Subsequently controllers were developed in four stages; Unlike current approaches in the literature, state and output feedback approaches were designed without utilizing model reduction for uncertain linear, coupled nonlinear and two-dimensional parabolic PDEs, respectively. In all of these techniques, the infinite horizon cost …

Assessment Of Highway Condition Using Combined Geophysical Surveys, Abdallah Alhadi Dera

Doctoral Dissertations

"Four pavement sections were investigated using ground penetrating radar (GPR) and Ultrasonic Surface Wave (USW). The objective of this research was to compare the effectiveness of two non-destructive geophysical tools, GPR and the PSPA, in assessing the condition of the pavements, composed of different construction materials. The GPR data were acquired using a 1.5 GHz antenna along five traverses spaced at two ft. intervals approximately 1000 ft. long. On the other hand, the PSPA data were acquired at the stations spaced at 1000 ft. along the five GPR traverses. Core samples were collected at each site to constrain the interpretation …

Modeling Daily Electricity Load Curve Using Cubic Splines And Functional Principal Components, Abdelmonaem Salem Jornaz

Doctoral Dissertations

"Forecasting electricity load is very important to the electric utilities as well as producers of power because accurate predictions can cut down costs by avoiding power shortages or surpluses. Of specific interest is the 24-hour daily electricity load profile, which provides insight into periods of high demand and periods where the use of electricity is at a minimum. Researchers have proposed many approaches to modeling electricity prices, real-time load, and day-ahead demand, with varying success. In this dissertation three new approaches to modeling and forecasting the 24-hour daily electricity load profiles are presented. The application of the proposed methods is …

Palynological Studies Of Holocene Lake Sediments In The Missouri Ozarks, Robert D. Haselwander

Doctoral Dissertations

"Five small lakes in southeast Missouri (Frisco, Pine Forest, and Bray Area lakes [Phelps County], and Cypress and Blue ponds [Bollinger County]) were cored for paleolimnological studies. Cores were evaluated for their sedimentology, palynology, and geochemistry. In two of these lakes (Bray Area and Pine Forest lakes) the planktonic algae were also studied in the water column, along with ecological parameters. Algae in the sediments were compared to algae in the water to understand the resistance of different species to decay, and a suggested methodology for this work is described. Reconstructions of the past environments around each lake were created …

Continuous Flow Reactor For Carbonic Acid Hydrolysis/Pretreatment Of Microalgal Biomass To Produce Bioethanol, Nicholas Dudenhoeffer

Doctoral Dissertations

"In order to maximize bioethanol production an efficient pretreatment method for the hydrolysis of polysaccharides to fermentable sugars is necessary. Commonly used pretreatment methods are the slow enzymatic hydrolysis and the corrosive mineral acid hydrolysis process that requires a post-treatment neutralization step and generates waste stream. We investigated the high temperature water with carbonic acid catalyst as an alternative method. Carbonic acid generated from dissolved CO₂ is inexpensive and environmentally benign, and easily removed by decompression. A high pressure continuous flow reactor that can continuously process the wet biomass stream and perform the carbonic acid hydrolysis in-situ using the …

Methodology Investigations For Shear Wave Splitting Analysis, Fansheng Kong

Doctoral Dissertations

"Over the past several decades, shear wave splitting analyses have been increasingly utilized to delineate mantle structure and probe mantle dynamics. However, the reported splitting parameters (fast polarization orientations and splitting times) are frequently inconsistent among different studies, partially due to the different techniques used to estimate the splitting parameters. Here the study conduct research on methodology investigations for shear wave splitting analysis, which are composed of two sub-topics, i.e., a systematic comparison of the transverse minimization (TM) and the splitting intensity (SI) techniques and applicability of the multiple-event stacking technique (MES). Numerical experiments are conducted using both synthetic and …

Algorithms Leveraging Smartphone Sensing For Analyzing Explosion Events, Srinivas Chakravarthi Thandu

Doctoral Dissertations

"The increasing frequency of explosive disasters throughout the world in recent years have created a clear need for the systems to monitor for them continuously to improve the post-disaster emergency events such as rescue and recovery operations. Disasters both man-made and natural are unfortunate and not preferred, however monitoring them may be a lifesaving phenomenon in emergency scenarios. Dedicated sensors deployed in the public places and their associated networks to monitor such events may be inadequate and must be complemented for making the monitoring more pervasive and effective. In the recent past, modern smartphones with significant processing, networking and storage …

Global And Regional Assessments Of Unsustainable Groundwater Use In Irrigated Agriculture, Danielle S. Grogan

Doctoral Dissertations

Groundwater is an essential input to agriculture world-wide, but it is clear that current rates of groundwater use are unsustainable in the long term. This dissertation assesses both current use of groundwater for country- to global-scale agriculture, and looks at the future of groundwater. The focus is on 1) quantifying food directly produced as a result of groundwater use across spatially-varying agricultural systems, 2) projecting future groundwater demands with consideration of climate change and human decision-making, and 3) understanding the system dynamics of groundwater re-use through surface water systems. All three are addressed using a process-based model designed to simulate …

Effects Of The Green Life Nature Education Program For 4th Grade Students Who Attend Bay Area Title One Schools: A Mixed-Methods Study, Jessica Blundell

Doctoral Dissertations

This explanatory sequential design mixed-methods evaluation measures the effects of the GLNE program on (a) students’ personal and social skills (b) students’ stewardship of the environment (c) students’ knowledge and understanding of science concepts. Quantitative survey data and qualitative data from a phenomenologically-based study are analyzed and compared in order to understand the impact of attending Green Life Nature Education (GLNE) program, the only Bay Area Residential Outdoor School that serves urban youth with no-cost programing.

The quantitative data from student surveys implies that in general, attending GLNE has a neutral impact on students. While there were several negative impacts …

Synthesis And Functionalization Of A Triaryldiamine-Base Photoconductive/Photorefractive Composite, And Its Application To Aberrated Image Restoration, Yichen Liang

Doctoral Dissertations

"Organic photorefractive (PR) composites have recently emerged as an important class of materials for applications including high-density data storage, optical communication, and biomedical imaging. In an effort to further improve their performance, this study focused on the utilization of functionalized semiconductor nanocrystals to photosensitize triaryamine (TPD)-based PR composites, as well as the application of TPD-based PR composites in the restoration of aberrated optical information. A novel approach to functionalize CdSe quantum dot (QCdSe) was firstly introduced where the sulfonated triarydiamine (STPD) was used as charge-transporting ligand to passivate QCdSe. TPD-based photoconductive and PR composites were photosensitized with the STPD-passivated QCdSe …

Models Of Leader Elections And Their Applications, Stephen Curtis Jackson

Doctoral Dissertations

"New research about cyber-physical systems is rapidly changing the way we think about critical infrastructures such as the power grid. Changing requirements for the generation, storage, and availability of power are all driving the development of the smart-grid. Many smart-grid projects disperse power generation across a wide area and control devices with a distributed system. However, in a distributed system, the state of processes is hard to determine due to isolation of memory. By using information flow security models, we reason about a process's beliefs of the system state in a distributed system. Information flow analysis aided in the creation …

Construction Of Multi-State Potential Energy Surfaces For Spectroscopy And Dynamics, Phalgun Lolur

Doctoral Dissertations

"This dissertation is about construction and visualization of multi-state Born-Oppenheimer potential energy surfaces which are essential for studying spectroscopy and dynamics. A potential energy surface is a mathematical function that represents the energy of a system as a function of its molecular geometry. The Born-Oppenheimer approximation enables us to solve the Schrödinger equation by separating the nuclear and electronic motions. Construction of potential energy surfaces has become a basic and crucial operation for chemists in order to compute various electronic states of molecules for understanding the spectroscopy, kinetics and dynamics of molecules. These methods have been used to successfully (i) …

Blended Learning In Chemistry Laboratory Courses: Enhancing Learning Outcomes And Aligning Student Needs With Available Resources, Shayna Brianne Burchett

Doctoral Dissertations

"Freshman science courses are intended to prepare students for the rigor and expectations of subsequent college science. While secondary education aims to prepare students for the college curriculum, many incoming freshman lack the sense of responsibility for their own learning that is essential for success in a college-level course. The freshman general-chemistry laboratory course at Missouri University of Science and Technology (Missouri S&T) was identified as a bottleneck course with a demand beyond accommodation capacity. To address the bottleneck and develop a sense of learner responsibility, a decision was made to investigate laboratory course delivery strategies. As a result of …

Integrated Geophysical Approach Using Electrical Resistivity Tomography And Multichannel Analysis Of Surface Wave In Assessing Wilson Spring Development, Ibrahim E. Ahmed

Doctoral Dissertations

"This research investigated fractured zones leading to preferential flow paths of Wilson Spring. In this context, electrical resistivity tomography (ERT) data and multi-channel analyses of surface waves (MASW) data were acquired at studied site with the purpose of mapping a variable depth to top of bedrock and geological structures.

Interpretation of the boreholes, MASW, and ERT data indicated that a depth to top of rock does vary significantly at the studied site due to many solution-widened fractures. Multiple near-vertical solution-widened fractures were mapped in the studied site based on the interpretation of the ERT data. The mapped solution-widened fractures appear …

Detecting, Segmenting And Tracking Bio-Medical Objects, Mingzhong Li

Doctoral Dissertations

"Studying the behavior patterns of biomedical objects helps scientists understand the underlying mechanisms. With computer vision techniques, automated monitoring can be implemented for efficient and effective analysis in biomedical studies. Promising applications have been carried out in various research topics, including insect group monitoring, malignant cell detection and segmentation, human organ segmentation and nano-particle tracking.

In general, applications of computer vision techniques in monitoring biomedical objects include the following stages: detection, segmentation and tracking. Challenges in each stage will potentially lead to unsatisfactory results of automated monitoring. These challenges include different foreground-background contrast, fast motion blur, clutter, object overlap and …

Electrodeposition And Characterization Of Metals And Metal Oxides For Energy Conversion And Storage, Ying-Chau Liu

Doctoral Dissertations

"This dissertation investigates the electrodeposition of metal and metal oxide thin films applicable to solar water splitting cells. Paper I describes the synthesis of cobalt hydroxide, ß-Co(OH)₂, by electrochemically reducing tris(ethylenediamine)cobalt(III) in alkaline solution. Paper II presents a scheme to convert the ß-Co(OH)₂ to CoOOH and Co₃O₄ and compares their catalytic activity for the oxygen evolution reaction. Co₃O₄ appears to be a more active catalyst than CoOOH based on Tafel analysis. However, when the observed current densities are corrected for the measured electrochemically active surface area, the linear region of the …

Methodology For Generating Simplified Cross Section Data Sets For Neutron Transport Calculations, Thomas Jay Harrison

Doctoral Dissertations

Neutron shielding problems involve radiation transport calculations over a wide range of energies. Fission neutrons have initial energy on the order of MeV, fusion neutrons have initial energy on the order of 10s of MeV, and space-origin neutrons have initial energy on the order of 100s of MeV or higher. Shielding calculations must track the neutrons from their initial energies until they are no longer of interest; for deep-penetration neutrons, this final energy can be on the order of eV before the neutron is no longer tracked. Thus, for deep-penetration space radiation shielding problems, the calculation may require tracking the …

Understanding The Influence Of Non-Covalent Interactions And Nanoparticle Geometries In Carbon Based Polymer Nanocomposites, Bradley Carroll Miller

Doctoral Dissertations

Low-loading polymer nanocomposites (PNC) are an area of great interest in polymer science. As nanoparticles (NP) are typically expensive in comparison to matrix materials; the low loading regime makes the most efficient use of materials, and represents the optimum for realizing cost effective, high-performance PNCs. However, formulating effective low-loading composites is not without challenges. In addition to the typical requirement of good dispersion for efficient translation of NP properties to the bulk, low-loading composites can sometimes exhibit anomalous (non-classical) dynamics, and unpredictable properties. It is within this context that this thesis aims to examine the effects of NP geometry and …

Rare Earth Production And Characterization Studies, Jake Anson Stewart

Doctoral Dissertations

The rare earths include elements Sc, Y, and La through Lu are important in many modern technologies. With the exception of Sc and Ce the rare earths are all have similar chemical behaviors with the preferred oxidation state in aqueous solution being +3. Currently, industrial purification of the rare earths is completed by counter current solvent extraction (CCSX). In most CCSX separations, Y extracts with Ho making their separation difficult. However, in a few systems Y exhibits an itinerant behavior. Carboxylic acids of varying sizes and substitutions were investigated in a study of Y itinerant behavior. It was found when …

Interface And Morphology Engineering In Solution-Processed Electronic And Optoelectronic Devices, Sanjib Das

Doctoral Dissertations

The first part of this dissertation focuses on interface and morphology engineering in polymer- and small molecule-based organic solar cells. High-performance devices were fabricated, and the device performance was correlated with nanoscale structures using various electrical, spectroscopic and microscopic characterization techniques, providing guidelines for high-efficiency cell design.

The second part focuses on perovskite solar cells (PSCs), an emerging photovoltaic technology with skyrocketing rise in power conversion efficiency (PCE) and currently showing comparable PCEs with those of existing thin film photovoltaic technologies such as CIGS and CdTe. Fabrication of large-area PSCs without compromising reproducibility and device PCE requires formation of dense, …

Solution And Surface Properties Of Architecturally- And Compositionally-Complex Block Copolymers And Their Binary Mixtures, Jesse Lawrence Davis

Doctoral Dissertations

The spontaneous generation of complex structures from polymeric building blocks provides a simple yet effective route to create useful soft matter structures having potential application in a variety of nanotechnologies. The topology, chemical structure, block composition, and sequence of the constituent building blocks of polymers are tunable through synthetic chemistry. This tunability offers attractive opportunities to generate complex, yet well-defined structures with control over the geometry, packing symmetry, and microdomain structure. This thesis work involves the study of the self-assembly behaviors of architecturally complex amphiphilic block copolymers (ABCs). ABCs are composed of two or more chemically distinct blocks that are …

Effective Field Theory Approach To Collective Motion In Atomic Nuclei, Eduardo Antonio Coello Perez

Doctoral Dissertations

Collective motion in heavy nuclei has been studied within collective and algebraic models, and within density functional theory. While they reproduce the energy spectra of these systems, their predictions for some electromagnetic transitions and moments do not lie within experimental uncertainty; in other words, these predictions are inconsistent with experimental data. An effective field theory approach to collective motion in heavy nuclei solves this long standing problem. Based on symmetry arguments only, the effective field theories, constructed as expansions in powers of a small parameter, consistently describe the energy spectra of nuclei exhibiting collective motion at low order in the …

Solar Modulation Of The Cosmic Ray Intensity And The Measurement Of The Cerenkov Reemission In Nova’S Liquid Scintillator, Philip James Mason

Doctoral Dissertations

The NOνA (NuMI Off-axis electron neutrino Appearance) experiment is a long baseline neutrino oscillation experiment at Fermi National Accelerator Laboratory. Its purpose is to observe the oscillation of ν_μ (muon neutrino) to ν_e (electron neutrino) and to investigate the neutrino mass hierarchy and CP violation in the neutrino sector. Two detectors have been built for this purpose, a Near Detector 300 feet underground at Fermilab, and a Far Detector, on the surface at Ash River, Minnesota.

The completion of NOνA’s Far Detector in October 2014 enabled not only the recent measurement of neutrino oscillations, but an array of …

Computational Simulation Of Mass Transport And Energy Transfer In The Microbial Fuel Cell System, Shiqi Ou

Doctoral Dissertations

This doctoral dissertation introduces the research in the computational modeling and simulation for the microbial fuel cell (MFC) system which is a bio-electrochemical system that drives a current by using bacteria and mimicking bacterial interactions found in nature. The numerical methods, research approaches and simulation comparison with the experiments in the microbial fuel cells are described; the analysis and evaluation for the model methods and results that I have achieved are presented in this dissertation.

The development of the renewable energy has been a hot topic, and scientists have been focusing on the microbial fuel cell, which is an environmentally-friendly …

Neuron Clustering For Mitigating Catastrophic Forgetting In Supervised And Reinforcement Learning, Benjamin Frederick Goodrich

Doctoral Dissertations

Neural networks have had many great successes in recent years, particularly with the advent of deep learning and many novel training techniques. One issue that has affected neural networks and prevented them from performing well in more realistic online environments is that of catastrophic forgetting. Catastrophic forgetting affects supervised learning systems when input samples are temporally correlated or are non-stationary. However, most real-world problems are non-stationary in nature, resulting in prolonged periods of time separating inputs drawn from different regions of the input space.

Reinforcement learning represents a worst-case scenario when it comes to precipitating catastrophic forgetting in neural networks. …

Novel Thermoplastic Elastomers Based On Benzofulvene: Synthesis And Mechanical Properties, Weiyu Wang

Doctoral Dissertations

Thermoplastic elastomers (TPEs) are of great importance both academically and technologically. Currently TPEs are the predominated form of styrene-diene copolymers. However, these styrenic TPEs have serious limitations in applications, especially at higher temperature, because of their low upper service temperature (UST). The work described in this dissertation aimed to developing thermoplastic elastomers with a higher UST and lower cost.

In order to develop TPEs with a higher UST, we employed benzofulvene, an anionically polymerizable monomer in hydrocarbon solvent at room temperature, as the glassy block and copolymerized it with isoprene to prepare polybenzofulvene-polyisoprene-polybenzofulvene (FIF) triblock copolymers. Among all triblock copolymers …