Physical Sciences and Mathematics Commons^™

The Trentonian (Late Ordovician) Brachiopod Fauna Of Ontario: Evolution Through A Global Warming Event, Akbar Sohrabi Hashjin

Electronic Thesis and Dissertation Repository

This thesis, which examines the evolution of the Late Ordovician (early Katian) brachiopod fauna of Ontario, consists of two main parts: 1) a case study of the Late Ordovician Rhynchotrema–Hiscobeccus lineage of North America to investigate the morphological variations and evolutionary trends of brachiopod fauna in time and space, 2) the paleobiogeography of early Katian brachiopod fauna to explore their distribution patterns at a global scale and controlling factors.

During the Katian, the North American craton experienced a first-order marine transgression. The early stage of this event in the early Katian (Trentonian, Chatfieldian) was marked by the development …

Implementation,Validation And Application Of An Automated Motion Correction Algorithm In Hepatic Perfusion Ct For Image-Guided Radiotherapy, Nikolaj Kg Jensen

Electronic Thesis and Dissertation Repository

Functional imaging holds promise in guiding, evaluating and predicting efficacy of cancer treatment. Perfusion imaging provides high resolution functional information generated by applying a model to a dynamic series of contrast enhanced anatomical images.

The objectives of this thesis are: 1) to develop and validate a registration algorithm to reduce breathing motion artifacts in hepatic perfusion CT, and 2) to evaluate the potential of perfusion CT to improve radiotherapy of liver cancer.

An automated one-dimensional correlation-based registration algorithm was developed and validated in phantom and pig studies and against manual registration of patient scans. This algorithm was used to register …

A Variability Study Of The Typical Red Supergiant Antares A, Teznie J D Pugh

Electronic Thesis and Dissertation Repository

Red giants and red supergiants have long been known to be variable. In the last 40 years many of the features of this variability have been associated with large convective cells. Unfortunately, due to the long timescales of these variations they are not well studied, with the exception of the bright M-class supergiant Betelgeuse (α Orionis, M2 Iab). Betelgeuse has been well studied both observationally and theoretically, and has many features that are well described by models of convection. It was these studies of Betelgeuse that provided the main motivation for this thesis. We ask if the dramatic motions seen …

Ratio-Based Edge Detection Inspired Speckle Reducing Anisotropic Diffusion, Asaduzzaman Babu

Electronic Thesis and Dissertation Repository

Speckle Reducing Anisotropic Diffusion, SRAD, is a multiplicative speckle noise reduction method. In highly speckled environment, SRAD occasionally produces over-smoothed, dislocated/broadened edge lines and inadequate de-noising on homogeneous image regions where the speckles are well developed. Moreover, the performance of SRAD is highly dependent on the initial selection of a good homogeneous area. To overcome these weaknesses, we propose two different ratio-based edge detection inspired extensions to SRAD. One of the proposed extensions incorporates an edge-sensitive boosting factor to guide the gradient and Laplacian operator based edge detector of SRAD. The edge-sensitive boosting factor is defined by the global edge …

Fuzzy Expert-Cocomo Risk Assessment And Effort Contingency Model In Software Project Management, Ekananta Manalif

Electronic Thesis and Dissertation Repository

Software development can be considered to be the most uncertain project when compared to other types of projects due to the uncertainty in the customer requirements, the complexity of the process, and the intangible nature of the product. In order to increase the likelihood of success in managing a software project, the project manager(s) must invest more time and effort in the project planning phase. The two main activities in project planning phase are effort estimation and risk management which has to be executed together because the accuracy of the effort estimation is highly dependent on the size and nature …

Util-Dss: Utilization-Based Dynamic Strategy Switching For Improvement In Data Centre Operation, Graham Foster

Electronic Thesis and Dissertation Repository

Applications are shifting into large scale, virtualized data centres that provide resources on a pay-per-usage basis. With power consumption representing a major operational cost, data centres must prioritize efficiency while still providing enough resources to meet application requirements. To meet variable application demands, a dynamic approach to virtual machine (VM) management is required. This requires: (i) placing newly arrived VMs, (ii) migrating VMs from highly utilized machines to avoid performance degradation, and (iii) migrating VMs from underutilized machines so that they may be deactivated to save power. Here, a management strategy is considered to be policy-set that guides these three …

On The Physical Explanation For Quantum Computational Speedup, Michael Cuffaro

Electronic Thesis and Dissertation Repository

The aim of this dissertation is to clarify the debate over the explanation of quantum speedup and to submit, for the reader’s consideration, a tentative resolution to it. In particular, I argue that the physical explanation for quantum speedup is precisely the fact that the phenomenon of quantum entanglement enables a quantum computer to fully exploit the representational capacity of Hilbert space. This is impossible for classical systems, joint states of which must always be representable as product states. I begin the dissertation by considering, in Chapter 2, the most popular of the candidate physical explanations for quantum speedup: the …

Carbon Nitride And Conjugated Polymer Composite Materials, Josh Byers

Electronic Thesis and Dissertation Repository

The semiconductor and photovoltaic properties of carbon nitride (CNx) thin films prepared using a reactive magnetron sputtering technique were investigated both individually and as composites with the organic conjugated polymers polybithiophene (PBT) and poly(3-hextlthiophene) (P3HT). At low nitrogen content, the film structure was dominated by graphitic sp² percolation networks, whereas at higher nitrogen contents CNx films started to demonstrate semiconductor properties, as evidenced by the occurrence of photoconductivity and the development of a space charge region. When CNx was deposited onto a PBT substrate, it was found to function as an acceptor material improving the photocurrent generation both in …

A Multispectral Assessment Of Complex Impact Craters On The Lunar Farside, Bhairavi Shankar

Electronic Thesis and Dissertation Repository

Hypervelocity collisions of asteroids onto planetary bodies have catastrophic effects on the target rocks through the process of shock metamorphism. The resulting features, impact craters, are circular depressions with a sharp rim surrounded by an ejecta blanket of variably shocked rocks. With increasing impact energy, the inner crater cavity can preserve complex morphologies including terraced walls, central uplifts, and melted rocks. The lack of erosion due to the absence of water or an atmosphere makes the Moon the perfect target to study impact crater processes, in particular the distribution of highly shocked materials within impact craters of different sizes. …

Carboxylic Acid Functionalized Butyl Rubber: From Synthesis To Applications, Matthew John Mceachran

Electronic Thesis and Dissertation Repository

Butyl Rubber (RB) is a copolymer of isobutylene (IB) with small percentages of isoprene (IP). Typically these IP units serve as sites for the covalent cross-linking of the rubber, but they can also serve as sites to further functionalize RB. These modifications can expand the potential applications of RB. This thesis describes the synthesis of carboxylic acid functionalized RB and some properties and applications of these materials.

Persistence And Anti-Persistence: Theory And Software, Justin Quinn Veenstra

Electronic Thesis and Dissertation Repository

Persistent and anti-persistent time series processes show what is called hyperbolic decay. Such series play an important role in the study of many diverse areas such as geophysics and financial economics. They are also of theoretical interest. Fractional Gaussian noise (FGN) and fractionally-differeneced white noise are two widely known examples of time series models with hyperbolic decay. New closed form expressions are obtained for the spectral density functions of these models. Two lesser known time series models exhibiting hyperbolic decay are introduced and their basic properties are derived. A new algorithm for approximate likelihood estimation of the models using frequency …

Multi-Point Stride Coverage: A New Genre Of Test Coverage Criteria, Mohammad Mahdi Hassan

Electronic Thesis and Dissertation Repository

We introduce a family of coverage criteria, called Multi-Point Stride Coverage (MPSC). MPSC generalizes branch coverage to coverage of tuples of branches taken from the execution sequence of a program. We investigate its potential as a replacement for dataflow coverage, such as def-use coverage. We find that programs can be instrumented for MPSC easily, that the instrumentation usually incurs less overhead than that for def-use coverage, and that MPSC is comparable in usefulness to def-use in predicting test suite effectiveness. We also find that the space required to collect MPSC can be predicted from the number of branches in the …

Ph Responsive Hydrogen Bonding Motif To Improve The Sensitivity Of Tumor Imaging, Fatimah Mohammed Algarni

Electronic Thesis and Dissertation Repository

Magnetic resonance imaging (MRI) is a powerful non-invasive medical diagnostic technique. Superparamagnetic iron oxide nanoparticles (SPIO) are effective contrast agents and provide high sensitivity contrast in MRI. Recent research has demonstrated that nanoparticle clusters exhibit significantly higher relaxivity than individual nanoparticles.

In order to increase the sensitivity of tumor imaging, supramolecular chemistry was introduced to this field and a novel conjugation method was developed using click chemistry between azide functionalized nanoparticles and pH-sensitive hydrogen bonding building blocks. This pH-sensitive hydrogen bonded complex was synthesized to cluster nanoparticles under mildly acidic biological conditions.

Due to the unexpected X-ray crystal structure of …

A Support System For Graphics For Visually Impaired People, Hao Xu

Electronic Thesis and Dissertation Repository

As the Internet plays an important role in today’s society, graphics is widely used to present, convey and communicate information in many different areas. Complex information is often easier to understand and analyze by graphics. Even though graphics plays an important role, accessibility support is very limited for web graphics. Web graphics accessibility is not only for people with disabilities, but also for people who want to get and use information in ways different from the ones originally intended.

One of the problems regarding graphics for blind people is that we have few data on how a blind person draws …

Protein Structure And Interactions Studied By Electrospray Mass Spectrometry, Jiangjiang Liu

Electronic Thesis and Dissertation Repository

Since the emergence of electrospray ionization (ESI) mass spectrometry (MS) as a tool for protein structural studies, this area has experienced tremendous growth. ESI-MS is highly sensitive, and it allows the analysis of biological systems ranging in size from a few atoms to large multi-protein complexes. This work aims to solve questions in protein structural biology by using ESI-MS in conjunction with other techniques.

We initially apply ESI-MS for studying the monomeric protein cytochrome c (Chapter 2). The physical reasons underlying the irreversible thermal denaturation of this protein remain controversial. By utilizing deconvoluted charge state distributions, oxidative modifications were found …

The Periglacial Landscape Of Utopia Planitia; Geologic Evidence For Recent Climate Change On Mars., Mary C. Kerrigan

Electronic Thesis and Dissertation Repository

The northern plains of Utopia Planitia, Mars, hosts an abundance of potential periglacial landforms including scalloped depressions, gullies, and polygon networks. This research was undertaken to investigate the distribution and stratigraphy of scalloped depressions in Utopia Planitia and to reconstruct the past environment in which this periglacial landscape formed. To that end, a revised geologic map of the region has been produced. We define, for the first time, a new Periglacial Unit, the youngest geologic unit in Utopia Planitia. We have also developed a model for the formation and evolution of the periglacial landscape examined by assessing the use of …

X-Ray Absorption Fine Structure And X-Ray Excited Optical Luminescence Studies Of Gallium Nitride - Zinc Oxide Solid Solution Nanostructures, Matthew J. Ward

Electronic Thesis and Dissertation Repository

Gallium nitride – zinc oxide (GaN-ZnO) solid solutions have been realized as potential photocatalysts for overall water splitting due to a narrowing of the band-gap into the visible region of the solar spectrum. Although there has been much experimental and theoretical work on this novel class of semiconductors many questions about the nature of their electronic and chemical properties remain unanswered. In particular the mechanism of band-gap reduction in these materials is not clearly understood. It is also unclear what the local chemical environment of gallium, zinc, nitrogen, and oxygen is in both the surface and bulk of these solid …

The Study Of Optoelectronics In Semiconductor And Metallic Nanoparticle Hybrid Systems, Daniel G. Schindel

Electronic Thesis and Dissertation Repository

This thesis examines optoelectronics of photonic crystals and photonic nanofibers, especially with quantum dots and metallic nanoparticles doped into them. The simulations produced focus on the quantum dots, which are presented in an ensemble of 3-level systems.

In order to consider a photonic nanofiber in isolation, a model was developed for the density of photonic states. We studied two profiles, a square cross-section and a circular cross-section. In addition, we consider two architectures, one where a photonic crystal surrounds a dielectric fiber, and one where the fiber is another photonic crystal. We found several photonic nanofibers with a single bound …

A Study Of Gamma Radiation Induced Carbon Steel Corrosion, Kevin Daub

Electronic Thesis and Dissertation Repository

This thesis presents work on the development of a mechanistic understanding of the effect of ionizing radiation on the aqueous corrosion kinetics of carbon steel. Exposed to ionizing radiation, water decomposes into a range of oxidizing (O₂, •OH, HO₂•, H₂O₂) to reducing (•e_aq^–, •O₂^–, •H) species. The production of the redox active species by radiolysis can have a significant effect on the corrosion behaviour of a metal. Of particular interest is the effect of radiolysis on corrosion when the solution environment, such as temperature, pH, and …

Theory Of Model Kohn-Sham Potentials And Its Applications, Alex P. Gaiduk

Electronic Thesis and Dissertation Repository

The purpose of Kohn-Sham density functional theory is to develop increasingly accurate approximations to the exchange-correlation functional or to the corresponding potential. When one chooses to approximate the potential, the resulting model must be integrable, that is, a functional derivative of some density functional. Non-integrable potentials produce unphysical results such as energies that are not translationally or rotationally invariant. The thesis introduces methods for constructing integrable model potentials, developing properly invariant energy functionals from model potentials, and designing model potentials that yield accurate electronic excitation energies. Integrable potentials can be constructed using powerful analytic integrability conditions derived in this work. …

Stable Isotopes And Xrd Investigation Of Gold Mineralization At The Syenite-Hosted Young-Davidson Deposit, Matachewan, Ontario, Niloufar Naderi

Electronic Thesis and Dissertation Repository

The Young-Davidson mine is a syenite-hosted orogenic gold deposit at the western end of the Cadillac-Larder-Lake deformation zone in the southern Abitibi greenstone belt, Canada. This study utilized oxygen isotopes to assess the sources of the fluids and evaluate the role of magmatic and metamorphic fluids in gold mineralization. XRD analyses completed on whole-rock powder samples combined with petrography provides a better understanding of the distribution, timing, and nature of alteration patterns and their relationship to gold mineralization.

Temperatures calculated from mineral separates oxygen isotope thermometry indicate the fluids ranged from approximately 322 ± 25° to 431 ± 30°C. The …

Estimating Subsurface Anisotropy: Combining Waveform Tomography And Simulated Annealing, Michael Victor Afanasiev

Electronic Thesis and Dissertation Repository

Crosshole seismic tomography has been used by Vale to provide geophysical images of mineralized massive sulphides in the Eastern Deeps deposit at Voisey's Bay. High resolution seismic images are presented by applying acoustic waveform tomography to these data. In waveform tomography, an initial model is required which predicts the first arrival traveltimes to within a half-cycle of the lowest frequency in the data. Because seismic velocity anisotropy can be significant, the initial model must quantify the anisotropy, as well as the velocity, in order to meet the half-cycle criterion.

In our case study, difficulties were encountered in generating an accurate …

Fast Absolute Quantification Of In Vivo Water And Fat Content With Magnetic Resonance Imaging, Yifan Cui

Electronic Thesis and Dissertation Repository

Quantitative water fat imaging offers a non-invasive method for monitoring and staging diseases associated with changes in either water or fat content in tissue. In this work absolute water and fat mass density measurement with in vivo Magnetic Resonance Imaging (MRI) is demonstrated. T₁ independent, T₂^* corrected chemical shift based water-fat separated images are acquired. By placing a phantom with known mass density in the field of view for signal intensity calibration, absolute water or fat mass density can be computed, assuming the B₁⁺ (transmit) and B₁^- (receive) fields can be measured. Phantom …

Crystal Structure And Al/Si Cation Ordering In "Fassaite": A Combined Single Crystal, 27al And 29si Nmr Study, Monika M. Haring

Electronic Thesis and Dissertation Repository

Al-,Ti-rich diopside, referred to herein as fassaite, occurs in both terrestrial and extraterrestrial environments. The composition of fassaite, Ca(Mg,Al)(Si,Al)₂O₆, makes it ideal for Al/Si cation ordering studies. In this study, crystal XRD, ²⁷Al and 29Si MAS NMR as well as ²⁷Al 3QMAS NMR is used to study cation ordering in extraterrestrial fassaite from Allende CAIs and a terrestrial analogue from Fassa Valley Italy. From ²⁷Al and ²⁹Si spectroscopy, fassaite from Allende CAIs is found to have more local Al/Si cation ordering than terrestrial Fassaite. Both terrestrial and extraterrestrial have C2/c …

Automatic Classification Of Epilepsy Lesions, Junwei Sun

Electronic Thesis and Dissertation Repository

Epilepsy is a common and diverse set of chronic neurological disorders characterized by seizures. Epileptic seizures result from abnormal, excessive or hypersynchronous neuronal activity in the brain. Seizure types are organized firstly according to whether the source of the seizure within the brain is localized or distributed. In this work, our objective is to validate the use of MRI (Magnetic Resonance Imaging) for localizing seizure focus for improved surgical planning. We apply computer vision and machine learning techniques to tackle the problem of epilepsy lesion classification. First datasets of digitized histology images from brain cortexes of different patients are obtained …

An Outcome-Based Approach For Ensuring Regulatory Compliance Of Business Processes, Quanjun Yin

Electronic Thesis and Dissertation Repository

In service industries, such as healthcare, catering, tourism, etc., there exist regulations that require organisations’ service comply with the regulations. More and more regulations in the service sector are, or are aimed to be, outcome-focused regulations. An outcome prescribed in the regulation is what users should experience or achieve when the regulated business processes are compliant. Service providers need to proactively ensure that the outcomes specified in the regulations have been achieved prior to conducting the relevant part of the business or prior to inspectors discovering noncompliance. Current approaches check system requirements or business processes, not outcomes, against regulations and …

Automatic Foreground Initialization For Binary Image Segmentation, Wei Li

Electronic Thesis and Dissertation Repository

Foreground segmentation is a fundamental problem in computer vision. A popular approach for foreground extraction is through graph cuts in energy minimization framework. Most existing graph cuts based image segmentation algorithms rely on user’s initialization. In this work, we aim to find an automatic initialization for graph cuts. Unlike many previous methods, no additional training dataset is needed. Collecting a training set is not only expensive and time consuming, but it also may bias the algorithm to the particular data distribution of the collected dataset. We assume that the foreground differs significantly from the background in some unknown feature space …

Synthesis And Characterization Of Copper Nanoparticles And Copper-Polymer Nanocomposites For Plasmonic Photovoltaic Applications, Sabastine Chukwuemeka Ezugwu

Electronic Thesis and Dissertation Repository

Deposition techniques for the fabrication of metal nanostructures influence their morphological properties, which in turn control their optical behavior. Here, copper nanoparticles (np-Cu’s) were grown using a deposition system that was specifically set up during this work, and is based on a radio frequency (RF) sputtering source that can operate at high temperature and under bias voltage. The effect of deposition conditions (RF power, chamber pressure and substrate bias voltage) on RF sputtered np-Cu’s using RF sputtering has been studied. The study included a comparison between the morphological and optical properties of as-grown np-Cu’s and thermally treated samples. The characterization …

Charateristics And Impact Of Interpersonal Conflicts On Requirements Risks, Avinder Walia

Electronic Thesis and Dissertation Repository

Interpersonal conflicts in software projects have an impact on project’s success, product’s quality, team’s performance, etc. However, in Requirements Engineering (RE), there is dearth of research on this topic; previous research has focused largely on conflicts among requirements. We conducted a case study of an industrial project to determine the characteristics (e.g., type, severity, conflict management styles, etc.) and impact of interpersonal conflicts rooted in RE (RE-Conflicts), on project risks associated with requirements (e..g., inadequately identified requirements, incorrect requirements, etc). The findings show that the conflicts over administrative procedures (47%) had the highest frequency count. The highest number of …

Error Correction In Next Generation Dna Sequencing Data, Michael Z. Molnar

Electronic Thesis and Dissertation Repository

Motivation: High throughput Next Generation Sequencing (NGS) technologies can sequence the genome of a species quickly and cheaply. Errors that are introduced by NGS technologies limit the full potential of the applications that rely on their data. Current techniques used to correct these errors are not sufficient, and a more efficient and accurate program is needed to correct errors.

Results: We have designed and implemented RACER (Rapid Accurate Correction of Errors in Reads), an error correction program that targets the Illumina genome sequencer, which is currently the dominant NGS technology. RACER combines advanced data structures with an intricate analysis of …