Physical Sciences and Mathematics Commons^™

Phase Field Crystal Approach To The Solidification Of Ferromagnetic Materials, Niloufar Faghihi

Electronic Thesis and Dissertation Repository

The dependence of the magnetic hardness on the microstructure of magnetic solids is investigated, using a field theoretical approach, called the Magnetic Phase Field Crystal model. We constructed the free energy by extending the Phase Field Crystal (PFC) formalism and including terms to incorporate the ferromagnetic phase transition and the anisotropic magneto-elastic effects, i.e., the magnetostriction effect. Using this model we performed both analytical calculations and numerical simulations to study the coupling between the magnetic and elastic properties in ferromagnetic solids. By analytically minimizing the free energy, we calculated the equilibrium phases of the system to be liquid, non-magnetic …

Methods For Shape-Constrained Kernel Density Estimation, Mark A. Wolters

Electronic Thesis and Dissertation Repository

Nonparametric density estimators are used to estimate an unknown probability density while making minimal assumptions about its functional form. Although the low reliance of nonparametric estimators on modelling assumptions is a benefit, their performance will be improved if auxiliary information about the density's shape is incorporated into the estimate. Auxiliary information can take the form of shape constraints, such as unimodality or symmetry, that the estimate must satisfy. Finding the constrained estimate is usually a difficult optimization problem, however, and a consistent framework for finding estimates across a variety of problems is lacking.

It is proposed to find shape-constrained density …

Deep Crustal Evolution Of The Western Churchill Province, Nunavut, Canada: Isotopic (U-Pb, O), Trace Element And Micro-Structural Analysis Of Zircon From Lower Crustal Xenoliths, Duane C. Petts

Electronic Thesis and Dissertation Repository

Zircon from lower crustal xenoliths can preserve unique crustal formation records of unexplored levels of the lithosphere. The first such records for the western Churchill province (Nunavut, Canada) are presented here. Zircon SIMS U-Pb geochronology and oxygen isotope analysis were conducted on kimberlite-hosted granulite-facies xenoliths: four metabasites (#9864; #9865; #9866; #9870) from the Rankin Inlet region, and five metabasites (#10162; #10163; #10167; #10169; #10179) and three metatonalite/anorthosites (#10158; #10164; #10168) from the Repulse Bay region. For the Rankin Inlet suite, oscillatory planar zoned, igneous cores from metabolite xenolith #9865 record dates between ca. 2.9–2.6 Ga, whereas complex to radial-sector zoned …

High-Pressure Study Of Molecular Solids And 1d Nanostructures By Vibrational Spectroscopy And Synchrotron X-Ray Diffraction, Zhaohui Dong

Electronic Thesis and Dissertation Repository

Pressure plays a critical role in regulating the structures and properties of materials. Since Percy Bridgeman was recognized by the 1946 Nobel Prize for his contribution to high-pressure physics, high-pressure research as an interdisciplinary area has attracted extensive attentions. Nowadays, the high-pressure research involves broad frontier areas, such as chemistry, physics, biology, material and earth science. For instance, brand new classes of inorganic materials of unusual stoichiometries and crystal structures, with wide range of optical, mechanical, electronic and magnetic properties, have been produced at high pressure. Pressure-induced structural transformations between crystalline and amorphous materials, as well as among insulators, conductors …

The Synthesis And Reactivity Of New Pnictogen(Iii) Cations, Allison L. Brazeau

Electronic Thesis and Dissertation Repository

Chelating nitrogen based ligands are well known for their use with transition metals while their chemistry with p-block elements has been relatively underdeveloped. This thesis examines the structure, bonding and reactivity of group 15 elements supported by a pyridyl tethered 1,2-bis(imino)acenaphthene (“clamshell”) and various homo- and heteroleptic guanidinate frameworks.

The unique “clamshell” ligand contains a pendant Lewis base and has been used to support N-heterocyclic phosphenium and arsenium cations. Reactivity studies with the phosphorus analogue demonstrate the ability of the ligand to act as a Lewis base, while the phosphorus centre provides a Lewis acidic site, showing the amphoteric …

Mri-Based Attenuation Correction In Emission Computed Tomography, Harry R. Marshall

Electronic Thesis and Dissertation Repository

The hybridization of magnetic resonance imaging (MRI) with positron emission tomography (PET) or single photon emission computed tomography (SPECT) enables the collection of an assortment of biological data in spatial and temporal register. However, both PET and SPECT are subject to photon attenuation, a process that degrades image quality and precludes quantification. To correct for the effects of attenuation, the spatial distribution of linear attenuation coefficients (μ-coefficients) within and about the patient must be available. Unfortunately, extracting μ-coefficients from MRI is non-trivial. In this thesis, I explore the problem of MRI-based attenuation correction (AC) in emission tomography.

In particular, I …

Heterogeneity Issues In The Meta-Analysis Of Cluster Randomization Trials., Shun Fu Chen

Electronic Thesis and Dissertation Repository

An increasing number of systematic reviews summarize results from cluster randomization trials. Applying existing meta-analysis methods to such trials is problematic because responses of subjects within clusters are likely correlated. The aim of this thesis is to evaluate heterogeneity in the context of fixed effects models providing guidance for conducting a meta-analysis of such trials. The approaches include the adjusted Q statistic, adjusted heterogeneity variance estimators and their corresponding confidence intervals and adjusted measures of heterogeneity and their corresponding confidence intervals. Attention is limited to meta-analyses of completely randomized trials having a binary outcome. An analytic expression for power of …

Sedimentology And Allostratigraphy Of The Cardium Formation (Turonian-Coniacian) In Southern Alberta, And Equivalent Strata In Northern Montana, Joel Shank

Electronic Thesis and Dissertation Repository

The Turonian-Coniacian Cardium Formation of southern Alberta consists of marine sandstone and mudstone, deposited in a foreland basin over ~2.3 m.y. The formation thins from 150 m in the western foredeep to 50 m 350 km to the east. Correlation of 10 regional flooding surfaces in >1200 well logs and 25 outcrops provides an allostratigraphic framework. Mapping of two previously-unrecognized erosion surfaces (E5.2 and E5.5) reveals additional complexity within sandstone of the Raven River Member.

Facies successions coarsen upwards from thinly-bedded and bioturbated mudstone, to heterolithic facies (either bioturbated or bedded), to clean sandstone. Where conglomerate unconformably overlies this succession, …

Complementary And Self-Complementary Hydrogen Bond Double Helical Complexes, Bhanu P. Mudraboyina

Electronic Thesis and Dissertation Repository

The design of artificial or synthetic strands that self-assemble to form double-helical complexes have been of great interest to chemists and researchers since the discovery of the double helical DNA structure in 1953 by Watson and Crick. Most of the complexes were self-complementary double-helical homodimers and while few heterodimer complexes are also known. The present thesis describes the design, synthesis and characterization of complementary and self-complementary hydrogen bond arrays built from heterocycles such as pyridine, thiazine dioxide and indole connected in different sequences. The sequence-based stabilities, insolubility issues, substitution and preorganization effects in these arrays have been studied in detail. …

Electrohydrodynamic Enhancement Of Heat Transfer And Mass Transport In Gaseous Media, Bulk Dielectric Liquids And Dielectric Thin Liquid Films, Seyed Reza Mahmoudi

Electronic Thesis and Dissertation Repository

Controlling transport phenomena in liquid and gaseous media through electrostatic forces has brought new important scientific and industrial applications. Although numerous EHD applications have been explored and extensively studied so far, the fast-growing technologies, mainly in the semiconductor industry, introduce new challenges and demands. These challenges require enhancement of heat transfer and mass transport in small scales (sometimes in molecular scales) to remove highly concentrated heat fluxes from reduced size devices. Electric field induced flows, or electrohydrodynamics (EHD), have shown promise in both macro and micro-scale devices.

Several existing problems in EHD heat transfer enhancements were investigated in this thesis. …

Bacterial Communities And Their Influence On The Formation And Development Of Potholes In Sandstone Surfaces Of The Semi-Arid Colorado Plateau, Kebbi A. Hughes

Electronic Thesis and Dissertation Repository

Potholes are weathering features, of various sizes and shapes, which are found in exposed rock surfaces that lack vegetative and soil cover. Biofilms associated with the ephemeral aquatic pothole environments of the Colorado Plateau were examined as initial and intermediate stages of colonisation of arid, oligotrophic rock surfaces.

Imaging of the interface between pothole biofilms and their host rock revealed features of biological weathering; chiefly, the breakdown of silicate minerals and precipitation of clay and carbonate minerals. High pH measured in pothole water reflected deposition of secondary carbonate minerals at some locations and indicated the development of high pH microenvironments …

Heme Binding And Transfer In The Isd Heme Scavenging Pathway Of Staphylococcus Aureus, Michael T. Tiedemann

Electronic Thesis and Dissertation Repository

The antibiotic resistant bacterium Staphylococcus aureus is a significant problem in hospitals and communities worldwide. Survival of the bacterium in the host is reliant on iron scavenging. Staphylococcus aureus has adopted specialized mechanisms for scavenging iron from the host. The cell wall and membrane-associated iron regulated surface determinant (Isd) proteins allow Staphylococcus aureus to scavenge iron from the heme in hemoglobin. There are nine Isd proteins (IsdH, IsdB, IsdA, IsdC, IsdE, IsdD, IsdF, IsdG and IsdI) located at different depths in the cell wall and membrane. Magnetic circular dichroism (MCD) spectroscopy and electrospray ionization mass spectrometry (ESI-MS) have been used …

Metallogenic Setting Of High-Grade Iron Ores, Mary River District, North Baffin Island, Nunavut, Meghan E. Macleod

Electronic Thesis and Dissertation Repository

Supracrustals of the 2.76-2.71 Ga Mary River Group form the northeastern segment of the Committee Bay Belt. Field mapping has determined that this succession is preserved in structural keels marginal to high-grade gneiss domes and is characterized by lower metasedimentary rocks and an upper BIF-komatiite-quartzite succession. Algoma-type BIF sited at the dome/keel boundary is host to bodies of high-grade iron ore, the largest being Deposit 1 which has an estimated reserve of 500 mt averaging 64 wt % Fe.

Field mapping, petrography, and EMPA indicates 3 main stages of ore formation. Stage 1 was characterized by the formation of the …

Game Challenge: A Factorial Analysis Approach, Ian J. Fraser

Electronic Thesis and Dissertation Repository

Video games that customize to a player's experience level and abilities have the potential to allow a broader range of players to become engaged and maintain interest as they progress in experience level. A game that uniquely customizes the player's experience could attract additional demographics to gaming, which will result in a distinct edge in marketability and potential revenue. This thesis examines a subsection of adaptive gaming systems from the perspective of identifying game factors that alter the level of difficulty. Our focus is to provide a solution useful to both research and commercial gaming communities by developing a system …

3d Velocity Retrieval And Storm Tracking Using Multiple Radars, Yong Zhang

Electronic Thesis and Dissertation Repository

Severe weather forecasting is one of the most important and urgent tasks in the meteorology field. This thesis builds on previous work by Barron and Mercer and their graduate students, concerning the use of 3D optical flow to retrieve 3D wind velocity from 3D Doppler radial velocity datasets and tracking 3D severe weather storms using fuzzy points realized as ellipsoids to represent storms and a fuzzy algebra machinery in a relaxation labeling framework to track storms in Doppler precipitation datasets.

We first extend the original 3D optical flow (both least squares and regularization methods) for recovering 3D wind velocity from …

The Weathering Of Platinum From Nuggets And Platinum Immobilisation By Cupriavidus Metallidurans, Sean Gordon Campbell

Electronic Thesis and Dissertation Repository

Two studies were conducted to investigate the biogeochemistry of platinum. In the first project, platinum nuggets were examined to evaluate mineral dissolution-precipitation processes occurring at the nugget-‘soil solution’ interface. The presence of dissolution ‘pits’, cavities, and striations as well as acicular, iron oxides coating the grain surface evidence that this interface is an important site of mechanical and chemical weathering. Element mapping revealed that structural and chemical signatures can be linked to morphological features on the grain surface. In the second study, the soil bacterium Cupriavidus metallidurans was reacted with aqueous platinum chloride and rapidly immobilised platinum. XANES/EXAFS analysis of …

A Study On The Turbulent Characteristics Within The Hurricane Boundary Layer, Sunwei Li

Electronic Thesis and Dissertation Repository

As the medium between the sea surface and the upper atmosphere in a hurricane, the Hurricane Boundary Layer (HBL) plays a key role in the overall dynamics of a tropical cyclone, and therefore turbulence exchanges within the HBL deserve a thorough investi- gation. However, since it is dangerous and difficult to take direct measurements within the HBL, studies of the HBL turbulence processes based on direct observations are rare. Thanks to the newly developed dropwindsonde equipped with a Global Position System (GPS) receiver, it is now possible to measure wind velocities and other meteorological variables with an unprecedented accuracy and …

Kinetics Of O2 Reduction On Oxide-Covered Ni-Cr-Mo Alloys, Xiangrong (Sarah) Zhang

Electronic Thesis and Dissertation Repository

Ni-Cr-Mo alloys exhibit exceptional corrosion resistance and are widely used in chemical processing industries. The reliable performance of these alloys under extreme industrial conditions, are generally attributed to the presence of a passive film on the alloy surface. O₂ reduction is the most likely cathodic process able to sustain metal oxidation (corrosion) in industrial environments. However, the kinetics of O₂ reduction on these oxide-covered alloys has hardly been studied, despite the possibility it may be the rate controlling process for corrosion, especially localized corrosion. The objectives of this research are to characterize the properties of the oxide film …

Applicability Of The Eshelby Formalism To Viscous Power-Law Materials: A Numerical Validation, Zhenyu Zhong

Electronic Thesis and Dissertation Repository

Fabric is important for the interpretation of tectonic evolutions. In the process of extrapolating small-scale fabric to tectonics, modeling frameworks are needed. Neither the early kinematic models nor the contemporary computational geodynamics are able to capture the complexities of the fabric development in natural deformation systems. Eshelby proposed a formalism in micro-mechanics, and it is now well understood that this formalism works well for the linear viscous deformations. However, given that most of the natural rocks are power-law materials, the Eshelby Formalism cannot be directly applied to geological problems. This problem was largely solved when Lebensohn and Tom (1993, Acta …

Structural Motifs Of Novel Metallothionein Proteins, Duncan E K Sutherland

Electronic Thesis and Dissertation Repository

Metallothioneins (MT) are a family of small cysteine rich proteins, which have been implicated in toxic metal detoxification, protection against oxidative stress, and as a metallochaperone. The most well studied member of the family is the mammalian MT, which consists of two domains: a β-domain with 9 cysteine residues, which sequesters 3 Cd²⁺/Zn²⁺, and an α-domain with 11 cysteine residues, which sequesters 4 Cd²⁺/Zn²⁺. The exact functions of MT are unknown but must relate to its metalation status. Several areas that could lead to the assignment of function include 1) the determination …

Automation Of The Registration Of Range Plant Images Using Geomagic Studio, Quazi M. Akter

Electronic Thesis and Dissertation Repository

As plant science advances, the quantitative measurement of 3D plant growth has become an essential tool to evaluate the growth performance of genetically modified seeds or plants. In the past, “wet volumes” had been used to quantitatively measure plant growth which result in the destruction of the plants. Other traditional methods like interferometry methods or mechanical methods are also inefficient because they are either invasive or unable to provide sufficient growth information of the plant body. On the other hand, computer vision methods, especially optical and range flow techniques, are non-contact, more accurate, and relatively less expensive. But they require …

A Method To Measure The Detective Quantum Efficiency Of Radiographic Systems In Clinical Setting, Michael C. Mcdonald

Electronic Thesis and Dissertation Repository

The risks associated with exposure to radiation make it critical that digital imaging systems give the best possible images for a given dose to the patient. The DQE is the most widely accepted measure of performance and dose efficiency for digital radiography systems, however it is not commonly measured in a clinical environment as part of routine quality assurance. The primary reason for this is that the data provided to the user by clinical systems has typically undergone image processing and therefore may have a non-linear characteristic response. This is a problem because the Fourier metrics of the DQE require …

Solid-State Nuclear Magnetic Resonance Spectroscopy Of Unreceptive Quadrupolar Nuclei In Inorganic Materials, Andre Sutrisno

Electronic Thesis and Dissertation Repository

Preparation and characterization of inorganic materials is a crucial practice because understanding the relationship between structure and property is important for improving current performance and developing novel materials. Many metal centers in technologically and industrially important materials are unreceptive low-γ quadrupolar nuclei (i.e., possessing low natural abundance, low NMR frequencies and large quadrupole moments) and they usually give rise to very broad NMR resonances and low signal-to-noise ratios, making it difficult to acquire their solid-state NMR spectra. This thesis focuses on the characterization of inorganic materials using solid-state NMR (SSNMR) spectroscopy at very high magnetic field of …

Enhancing Raman And Fluorescence Spectroscopies With Nanosphere Lithography Platforms, Shabila Fayyaz

Electronic Thesis and Dissertation Repository

Localized surface plasmon resonance (LSPR) is of particular interest to enhance the limit of detection for spectroscopic techniques such as Raman and fluorescence via a surface enhancement from metallic nanostructures. In this study, using nanosphere lithography (NSL) technique, a series of gold nanostructures over glass surfaces are prepared. These nanostructures are used to record the surface enhanced Raman scattering (SERS) spectrum of benzenethiol and azobenzene thiol and the vibrational modes are compared to literature. Once protected with an ultrathin layer of SiO₂, the gold nanostructures are investigated using scanning confocal fluorescence microscopy to detect the fluorescence from a …

Hearts And Minds: Examining The Evolution Of The Egyptian Excerebration And Evisceration Traditions Through The Impact Mummy Database, Andrew D. Wade

Electronic Thesis and Dissertation Repository

Egyptian mummification and funerary rituals were a transformative process, making the deceased a pure being; free of disease, injury, and disfigurements, as well as ethical and moral impurities. Consequently, the features of mummification available to specific categories of individuals hold social and ideological significance. This study refutes long-held classical stereotypes, particularly dogmatic class associations; demonstrates the apocryphal nature of universal heart retention; and expands on the purposes of excerebration and evisceration implied by synthetic and radiological analyses.

Features of the embalming traditions, specifically the variable excerebration and evisceration traditions, represented the Egyptian view of death. Fine-grain analyses, through primary imaging …

The Research On The L(2,1)-Labeling Problem From Graph Theoretic And Graph Algorithmic Approaches, Zhendong Shao

Electronic Thesis and Dissertation Repository

The L(2,1) -labeling problem has been extensively researched on many graph classes. In this thesis, we have also studied the problem on some particular classes of graphs.

In Chapter 2 we present a new general approach to derive upper bounds for L(2,1)-labeling numbers and applied that approach to derive bounds for the four standard graph products.

In Chapter 3 we study the L(2,1)-labeling number of the composition of n graphs.

In Chapter 4 we consider the Cartesian sum of graphs and derive, both, lower and upper bounds for their L(2,1)-labeling number. We use two different approaches to derive the upper …

Synthesis Of Self-Immolative Monomers And Their Applications In Polymeric Materials, Matthew A. Dewit

Electronic Thesis and Dissertation Repository

Self-immolative spacers are a unique class of molecules employed in a variety of applications, particularly in the biomedical field. Most commonly, they are molecules containing two reactive termini with a capping group at one terminus and a substrate of interest at the other. Upon removal of the capping group, the spacer undergoes an intramolecular reaction that results in its removal from the molecule and liberation of the substrate. These spacers have been extensively studied in monomeric form within prodrugs, as well as to form dendrimers that have been used for applications such as signal amplification, molecular logic gates and amplified …

Late Quaternary Histories Of Lakes Huron And Michigan: A Stable Isotope Investigation Of Sediment Cores And Modern Biogenic Carbonates, Rebecca A. Macdonald

Electronic Thesis and Dissertation Repository

Late Quaternary histories are investigated here for sediment cores from Lakes Huron and Michigan, using the oxygen- and carbon-isotope compositions of biogenic carbonates and the oxygen- and hydrogen-isotope compositions of porewater. Age models for these cores are based on sedimentological information, and where possible, radiocarbon and pollen dates. The Michigan Basin cores provide a thick record of the late Pleistocene, whereas the Huron Basin cores primarily record Holocene deposition. Taken together, the histories recorded in biogenic carbonates from these sediments provide a clear account of lakewater isotopic changes – and their significance – over much of the history of the …

An Investigation Of Deformation Structures And Their Tectonic Significance Across The Grenville Front Tectonic Zone In The Vicinity Of Sudbury, Ontario, Canada, Changcheng Li

Electronic Thesis and Dissertation Repository

The Grenville Front Tectonic Zone (GFTZ) is a polyphase deformation belt in the northwest of the Grenville Province which was shaped in the continent-continent-collision-induced Grenvillian Orogeny.

This thesis focuses on the evolution of deformation fabrics in the GFTZ between the Sudbury Basin and French River in Ontario, Canada. Geological mapping using a new digital mapping system was conducted within this segment of the GFTZ, in its northwest vicinity in the Southern Province, and in its southeast vicinity in the Grenville Province. The new digital mapping system includes a personal digital assistant equipped with an internal GPS and a mobile GIS …

Reconstructing Fire Severity From The Oxygen-Isotope Compositions Of Plant Char, Michael W. Hamilton

Electronic Thesis and Dissertation Repository

This study assessed whether variations in the oxygen-isotope compositions of char formed from biomass burning could be related to burning severity. Ground samples of oak (Quercus alba), pine (Pinus resinosa), and grass (Andropogon gerardii) were charred for 5 and 30 minutes at constant temperatures between 200 and 900°C under oxygenated versus anaerobic conditions. Char oxygen-isotope values became progressively depleted of ¹⁸O by up to 25.8‰ for wood and 16.5‰ for grass as temperature, duration of burning, and amount of oxygen increased. The primary reason for the decrease in oxygen-isotope values is the loss …