Physical Sciences and Mathematics Commons^™

One-Pot Reactions Of Ethyl Propiolate, Ana Maria Neferu

Honors Theses

Through an efficient one-pot reaction sequence, ethyl propiolate can be transformed into a complex, usefully functionalized bicyclic product. Thioconjugate addition yielding Z-selective enoates has been developed for both aromatic thiols (trialkylamine-catalyzed) and aliphatic thiols (KOt-Bu-catalyzed). The oxidation of the thioenoates thus generated is followed by Li-catalyzed oxidation to sulfones using mCPBA, and Li-catalyzed Diels–Alder addition of cyclopentadiene. These subsequent steps are performed in situ, without any purification of intermediates. The yields obtained using the described synthesis are acceptable for a one-pot three-step sequence. Preliminary conjugate addition results with alcohols and amines as nucleophiles are also presented.

Power Distribution In The European Union, Dayton Steele

Honors Theses

The Treaty of Lisbon, the latest treaty governing law-making in the European Union (EU), was ratified in 2009 and goes fully into effect in 2014. This treaty, with its change to voting procedures in the Council of Ministers, claims to make decision-making in the EU more democratic and more efficient. Since the EU serves as an economic and political entity, we will assess these claims by comparing each member state's GDP and population to its power as modeled using the concept of a power index from the game theory literature. We will utilize the normalized Banzhaf index, the Shapley-Shubik index, …

Interstellar Navigation By Pulsars, Andrew Dahir

Honors Theses

No abstract provided.

Not Extinct: A Year In The Life Of The American Chesnut, Kristen Julina Stanfill

Honors Theses

After the widespread infection of the American chestnut tree (Castanea dentata) due to the fungus Cryphonectria parasitica the species was nearly brought to extinction and now merely exists as stump sprouts. Since the fungus infects the bark of the tree but not the root systems new shoots are able to emerge and grow before once again being girdled by the fungus. Cryphonectria parasitica is believed to have been brought to America on Asian species of chestnut which possess resistance to the blight caused by the fungus. It is the plan of the American Chestnut Foundation (TACF) to integrate the genes …

Pictures Versus Digits In The Irrelevant Sound Effect, Corey Mcgill

Honors Theses

No abstract provided.

My Experience Exploring The Effects Of Lead (Pb +2) Toxicity In Drosophila Melanogaster Using Sociability Interaction Testing And Microarrays At The University Of Puerto Rico-Rio Piedras In San Juan, Puerto Rico, Charlton Diaz

Honors Theses

Lead is an environmental contaminant widely dispersed throughout the world. Exposure to lead causes neurological damage in humans and may be linked to neurodevelopmental pathologies such as attention deficit hyperactivity disorder, antisocial behavior, and autistic spectrum disorders (ASD). Drosophila melanogaster (fruit flies) have been used to understand the behavioral, synaptic, and molecular changes that occur after developmental exposure to lead and to study ASD-associated pathology. Flies were exposed through the mother and until eclosion to either a lead-laced medium or a control corn-based medium and were isolated until the beginning for the behavioral studies. Sociability testing was done using a …

Investigating The Interaction Of Zinc-Finger Peptides And Nicked Dna Using Phage Display, Rachel Maria Guerra

Honors Theses

Recognition of structural features of DNA such as gaps, nicks and abasic sites is critical for many DNA-binding proteins, such as those involved in DNA damage repair. This study explores a novel strategy to model these protein-DNA interactions using phage display. Phage display has been commonly used to identity zinc fingers that bind to DNA sequences, but selection of peptides that binding to specific DNA structures has not been reported in the literature. A phage library of 109 variants was created based on one of three zinc finger domains of the DNA repair protein poly (ADP-ribose) polymerase I. The library, …

Metallic Mineral Mining In Maine, Kaitlyn Bernard

Honors Theses

In 2012 the Maine State Legislature passed a bill directing the Maine Department of Environmental Protection (DEP) to rewrite the regulations governing metallic mineral mining in Maine. The bill was introduced after pressure from Maine’s largest private land owner and timber company, J.D. Irving, Limited. The company has a lucrative mineral deposit on one of their landholdings in northern Maine and is interested in pursuing a mining development project. The bill aimed to streamline the regulatory framework around mining operations and make the permitting process more conducive to mineral development throughout the state. The 2012 Maine Metallic Mineral Mining Act …

Massive Quiescent Disk Galaxies In The Candels Survey, Aurora Y. Kesseli

Honors Theses

We used data from the GOODS-S field of the CANDELS survey in order to confirm previous studies that found that large fractions of high-redshift galaxies (z ∼ 2) are disk-dominated (McGrath et al. 2008; van der Wel et al. 2011). In the GOODS-S field we selected out all the massive quiescent disk galaxies by imposing a mass limit of M > 10¹⁰M_⊙ and a redshift range of 0.5 ≤ z ≤ 2.5, and then choosing the quiescent red galaxies from a color-color plot. Once we had our sample, we did a qualitative visual classification of each galaxy and …

Massive Gravity Theories, Greg Seyfarth

Honors Theses

We examine Fierz and Pauli's work in 1939 of adding a mass term to the Lagrangian for linearized gravity with the form ?? where h is a small perturbation away from flat spacetime and showing that the only value for ? which gives a ghost-free theory with the correct five degrees of freedom expected for a massive spin- 2 particle such as the graviton is ? [1]. We start by rederiving the Lagrangian formulation for classical electrodynamics and giving examples of a ghost. Then we solve the linearized massless gravity equations to show their two degrees of freedom. We perform …

The Eichler-Selberg Trace Formula For Level-One Hecke Operators, Alex Barron

Honors Theses

This paper explains the steps involved in the proof of the Eichler-Selberg Trace Formula for Hecke operators of level one. It is based on an appendix in Serge Lang's Introduction to Modular Forms written by Don Zagier, though I also draw heavily from sections of Toshitsune Miyake's Modular Forms and Xueli Wang's and Dingyi Pei's Modular Forms with Integral and Half-Integral Weights.

Section 2 summarizes the necessary background in the theory of modular forms. The material covered here is standard, so I've left out most of the details and proofs. Most of the section is based on Chapter VII of …

Scattering Off Of An Unusual Boundary, Jerome Weston

Honors Theses

No abstract provided.

A Raman Spectroscopic Study Of The Effects Of Hydrogen Bonding On 1,2,3-Triazole, Anna Craig

Honors Theses

The goal of this thesis is to analyze the effects of hydrogen bonding on liquid 1H- 1,2,3-triazole. Spectra of neat 1H-1,2,3-triazole are compared to simulated spectra and are found to differ greatly. The experimental spectrum, however, matches the simulated spectra of 1H-1,2,3-triazole dimers very well. This suggests that dimers play a large role in the liquid structure of 1H-1,2,3-triazole. Though tautomerism is thought to play a large role in the vibrational behavior of 1,2,3- triazole, the Raman spectra obtained here suggest that molecular dimers dominate the liquid state much more so than tautomerism. Even in aqueous solution, the simulated spectra …

Spectroscopic Study Of Charge Transfer Induced Blue Shifting Of Pyrimidine/Water Mixtures On Silver Substrate, Annie Katherine Mcclellan

Honors Theses

Surface enhanced Raman spectroscopy (SERS) is a chemical method gaining much popularity in recent years. With the use of a roughened metal surface or metal nanoparticles, surface plasmon resonances enhance the electromagnetic field allowing for increased Raman signal. Pyrimidine, having two lone pairs of electrons, is capable of charge transfer interactions contributing to a SERS chemical enhancement factor as well. It has recently been reported that hydrogen bonding with water results in the blue-shifting of certain normal modes of pyrimidine. By comparing experimental polarized Raman spectra with the results of electronic structure calculations, the origin of this blue-shifting was found …

Ph Dependent Proteolysis Of Neural Cadherin, Candice Ashton Walters

Honors Theses

Cadherins are the primary calcium-dependent cell-cell adhesion molecule and are essential to vertebrates. They ensure the integrity of epithelial barriers that allow for maintenance of homeostasis in humans and protection against invading microorganisms. A common invader capable of forging past this line of defense is the fungus Candida albicans. The main virulence mechanism of C. alibans in acidic environments is its secreted aspartyl proteinases (SAPs), which are hydrolytic enzymes that degrade cadherin-mediated cell adhesion leading to infection of the underlying tissues. Cadherin is normally resistant to cleavage by proteases due to stabilization of the protein structure by bound calcium and …

Effects Of Micro-Solvation On Room Temperature Ionic Liquids, Joseph Wellington Golden

Honors Theses

Room temperature ionic liquids (RTILs) have received much attention lately. These compounds are made completely of ions and are liquid at or near room temperature. These liquid salts have a number of unique properties that make them an interesting system to study. These properties include almost zero vapor pressure, thermal stability, large liquidus range, etc. Due to these properties and others, ionic liquids (ILs) have attracted much attention in the emerging field of green chemistry as potentially new solvents for many of the hazardous and volatile solvents currently in use. Moreover, the complex interactions of the anion and cation systems …

Influence Of Tidal Cycles On Movements Of Atlantic Bottlenose Dolphins (Tursiops Truncatus) In South Carolina Coastal Environments, Lauren Albrittain

Honors Theses

When studying estuarine environments that are directly fed by the ocean tides, the impact of the changing tide is vital in studying the migration and travel behaviors of organisms within those environments. This study was aimed at determining the influence of the daily tidal currents on movement with or against the tides by Atlantic bottlenose dolphins (Tursiops truncatus). Data collection occurred from March to October 2012, at three study sites: the ACE River Basin National Wildlife Refuge, the Hilton Head estuary, and the Cape Romain National Wildlife Refuge. Photo identification transect surveys were conducted to observe resident Atlantic bottlenose dolphins …

Title Ix Compliance: A Comparison Of Division I Equality, Jacqueline Leake

Honors Theses

The passage of Title IX of the Education Amendments of 1972 has had a significant impact on college athletics. However, there is still a large disparity between opportunities offered for men and women. This study determined the true gender equality within Division I athletics. Inequalities were assessed in the areas of athletic participation, athletically related student aid, recruiting expenses, and total expenses. Data from these areas were gathered from the Equity in Athletics Disclosure Analysis Cutting Tool. Ratios and the difference between the ideal and current values were calculated for each category. Institutions were ranked in each category, as well …

Investigating Volatility Trends Of Silver Through An Analysis Of Stock Options Prices, Dylan Houston

Honors Theses

Volatility is a statistical measure that describes the amount of fluctuation in prices for a given investment; generally, the higher the volatility for an investment, the riskier it is perceived to be. Traders study volatility history so that they can make informed decisions on how to invest capital. The purpose of this article is to analyze implied volatility values, which are derived from the investment's price and are considered the market's estimate of the investment's actual volatility, for silver electronically traded fund (ETF) options in periods of both high and low price movement. In doing so, we desired to see …

Potential Changes To The Cubitt Creek System After Dredging, Hillary Sparagna

Honors Theses

Dredging is the process of removing sediments from beneath the water's surface to increase the depth of the area. Many times, dredging is used to deepen navigational channels for boats in inlets and bays, control river flow, and environmental remediation of contaminated sediments. Sustainable dredging is when the sediments that have been dredged are used to replenish beaches. This method saves money, minimizes ecological impact, saves capacity at deposit sites, and can be used for habitat restoration.

The Politics Of Rsfs: An Antidote To Reversing The Resource Curse In Latin America?, Sarah Gagnon

Honors Theses

Over the past three decades, the world has become highly globalized. As such, most countries around the world depend on exports for a large portion of their national income. However, some countries’ dependency on exports is extreme, especially those that heavily rely on natural resource commodities. Despite the natural resource wealth that these commodities grant countries, due to the instability of global prices and the intensive focus of the resource extraction industry, scholars have theorized this type of dependency as a “resource curse.” The resource curse is a paradox where countries that are so rich in natural resources have not …

The State Of Sustainable Transportation At Union College: A Transportation Audit Of Union College Students And Faculty, Benjamin Engle

Honors Theses

Union College has established a Climate Action Plan with the goal of carbon neutrality by 2060 as part of its commitment to sustainability. A significant component of Union’s carbon footprint, however, is student and faculty transportation. The purpose of this research was to analyze the transportation behavior of students and faculty to determine the carbon emissions that result from the use of various transportation methods. Two campus‐wide surveys were conducted; one was distributed to students and the other targeted faculty. For comparison purposes, survey questions were designed to be compatible with, but more focused than, those of a survey conducted …

Sustainable Cities As The Gateway To The Future: A Case Study Of New Rochelle, Andrea B. Grenadier

Honors Theses

This thesis explores the characteristics of sustainable cities and uses New Rochelle, New York as a case study to further describe initiatives synonymous with green communities. Five prominent topics of sustainable cities and urban planning are discussed within the literature review and later mirrored throughout the case study of New Rochelle. These topics include, smart growth, energy efficiency, green buildings, transportation, and recycling. The mayor of New Rochelle and Sustainability Coordinator completed questionnaires and their responses contributed to an assessment of the contemporary issues facing sustainable cities.

Environmental Risk Explored Through Oil Spills And Hydraulic Fracturing: Attempting Environmental Protection Through Policy, Samantha M. Guidon

Honors Theses

History demonstrates the dangers of ignoring the environmental risks that correspond to resource extraction, especially in precarious locations. This project analyzed three cases: (1) the 1989 Exxon Valdez oil spill, (2) the 2010 Deepwater Horizon oil spill, and (3) the current question of hydraulic fracturing in New York’s Marcellus Shale. The case studies assessed whether policies for protecting the environment from the risks of human activity have improved and whether such policies can be made both economically efficient and environmentally less risky. While the Exxon Valdez case demonstrated the dangers of not planning for disaster, it did result in the …

Putting The Wind At Our Backs: Assessing U.S. Potential For 20% Wind Energy By 2030, Kevin T. Harnett

Honors Theses

The discussion surrounding the future of energy, particularly in the United States, has gained significant momentum in recent years for an obvious reason — it’s daunting. Our dependence on fossil fuels has positioned our nation in an undesirable predicament with a questionable future. With the associated consequences, principally Climate Change, it is essential that energy be addressed as a primary national concern. Renewables need to flip the switch.

Evolutionary Fabrication: An Autonomous System Of Invention, Tim Kuehn

Honors Theses

Evolutionary algorithms have had success in designing complex objects, ranging from antennae used in NASA's Space Technology 5 mission to astronomical telescope lenses. However, evolutionary design is limited by the ability of a simulation to accurately represent the physical world. Addition-ally, evolved designs may be well described, but they carry no set of speci˝c instructions describing how to physically create such a design. Evolutionary Fabrication (EvoFab) recti˝es this: EvoFab is a machine built upon a process that can, in principle, automatically invent and build anything, from soft robots to new toys, by evolving the process, not the product. We have …

Une Histoire De La Formation Mathématique En France: Les Réformes Et Les Philosophies De L’Enseignement Primaire Et Secondaire De 1420 Jusqu'À Aujourd’Hui, Rebecca Robinson

Honors Theses

France has produced many illustrious mathematicians who have profoundly impacted mathematics as they are today. While Descartes, Cauchy, and Borel (among others) viewed math as a lifelong pursuit, they began their education in an elementary school classroom with everybody else. In this study, I explore mathematical reforms and governmental documents throughout history to show how the education system has grown to emphasize a strong mathematical curriculum for all students and have consulted many philosophical articles on both the importance of math in a student’s education as well as different views on the manner in which mathematics should be taught to …

Glacial Lacustrine Records Of Holocene Climate Variations In The Tropical Peruvian Andes, Sasha Rothenberg

Honors Theses

Lake sediment cores taken from glacial lakes and wetlands are valuable proxies of glacial activity because they offer a continuous record of sediment input. Tropical alpine glaciers are especially sensitive to changes in precipitation and temperature, and thus the history of glaciation can be used in the reconstruction of past climates. Owing to a steep east-­‐to-­‐west moisture gradient across the Andes, glaciers in the eastern cordillera are more sensitive to changes in temperature whereas those in the drier, western, cordillera are more sensitive to changes in precipitation. Multiple lacustrine sediment cores were taken from two sites in the central Peruvian …

Prediction Of Metal Charge-Dependent Amide Hydrogen Exchange Rates For The Proteins Rubredoxin And Azurin, Stephen Scoglio

Honors Theses

Although it has been shown that the hydrogen exchange rates between the most slowly exchanging amide protons of a protein and the solvent can be used to predict the global thermodynamic stability of a protein, the great majority of amide hydrogens along the backbone of a protein exchange from either partially or fully folded conformations, and their rate of exchange strongly depends upon the environment in that folded state. We are examining the electrostatic and conformational dependence of the hydrogen exchange kinetics of Pseudomonas aeruginosa azurin, which can bind either the diamagnetic Cu(I) or Zn(II) in its active site and …

Anti-Nuclear Activism And The Past, Present And Future Of United States Nuclear Energy Policy, Isabel C. Zellweger

Honors Theses

Nuclear power has had a long and controversial history leading people to have many different views on the topic. Even though nuclear power does provide the nation with a significant portion of its electricity, many still fear its risks, especially after the events at Fukushima last spring. This thesis explores how public opinion, current events, and anti-nuclear activism have shaped nuclear power in America today. After reviewing the literature on nuclear energy in the United States, I discuss the past and current state of United States nuclear energy policy, and then describe changing American attitudes toward nuclear power over time. …