Physical Sciences and Mathematics Commons^™

Modeled Uranium Series Disequilibria In A Heterogeneous Mantle Underlying Iceland, Dana Andersen

Honors Theses

Regional lithologic heterogeneities in Earth’s mantle may significantly contribute to variations in magma productivity and crustal generation. Such heterogeneities may be a key factor in the anomalously high rates of magmatism and thickened crust of Iceland, which are not fully explained by the presence of a mantle plume. However, the exact lithologic composition of the mantle underlying Iceland is largely unknown. Recent trace element modeling has suggested a two-component melt source beneath Iceland, consisting of a typical upper mantle peridotite mixing with one of several compositions of pyroxenitic material. This study further investigates these potential melt sources by calculating U-series …

A Simulation Of Nuclear Pasta Using The Lattice Boltzmann Computational Method, Alexander Westbrooks

Honors Theses

No abstract provided.

Constraining H0 Via Extragalactic Parallax, Nicholas Ferree

Honors Theses

We examine the prospects for measurement of the Hubble parameter 𝐻₀ via observation of the secular parallax of other galaxies due to our own motion relative to the cosmic microwave background rest frame. Peculiar velocities make distance measurements to individual galaxies highly uncertain, but a survey sampling many galaxies can still yield a precise 𝐻₀ measurement. We use both a Fisher information formalism and simulations to forecast errors in 𝐻₀ from such surveys, marginalizing over the unknown peculiar velocities. The optimum survey observes ∼ 102 galaxies within a redshift 𝐻₀max = 0.06. The required errors …

The Parental Labor Gap: The Impact Of Daycare Access On The Parental Labor Force During The Covid-19 Pandemic, Acacia Wyckoff

Honors Theses

In the two years since the COVID-19 pandemic began, the landscape for work has shifted dramatically. Many companies and employers switched to telework when the pandemic hit, and many still do not require workers to come into the office. Research suggests these COVID-induced changes have led to a closing of the gap in childcare duties between men and women in households. Comparing parents in positions with telework eligibility versus in-person positions, Heggeness and Suri (2022) found that while telework improved the labor participation rate of mothers slightly, there was still a major gap in labor force participation between mothers and …

Synthesis And Characterization Of Rhenium 2,2′-Pyridylnaphthyridine Metal Complexes, Benjamin F. Solomon

Honors Theses

Rhenium (Re) is a group 7 heavy 5d transition metal in the same family as manganese (Mn) and technetium (Tc). Re-carbonyl complexes are known to be catalysts for many different kinds of reactions from C-C bond formation to reduction reactions like CO₂ reduction (CO₂RR)^1,2. With this in mind, we have prepared a set of six Re-carbonyl complexes of 2,2′-pyridyl-1,6-naphthyridine (1,6- pynap) and 2,2′-pyridyl-1,8-naphthyridine (1,8-pynap), a redox non-innocent ligand containing a bpy moiety as well as an additional aryl nitrogen binding location at which another metal-ligand bond could form. We have synthesized these complexes as precursors …

Study Of Missing Mass Background In The Clas12 Detector, Jessie Hess, Gerard P. Gilfoyle, Lamya Baashen

Honors Theses

At Jefferson Lab we use the CLAS12 detector to measure the neutron magnetic form factor. An accurate measurement of the CLAS12 neutron detection efficiency (NDE) is required. We use the nuclear reaction ���� → ��′��+�� as a source of tagged neutrons and obtain the NDE from the ratio of expected neutrons to detected ones. We assume the final state consists of ��′��+�� only, use the ��′��+ information to predict the neutron's position(expected) and then search for that neutron(detected). We select neutrons with the missing mass (MM) technique. We use simulation to validate our methods. We simulated events with the Monte-Carlo …

The 2015 Ncaa Cost-Of-Attendance Stipend And Its Effects On Institutional Financial Aid Packages, Sara Greene

Honors Theses

In 2015, the National Collegiate Athletic Association (NCAA) allowed “Cost of Attendance” (COA) stipends to be offered to athletic recruits for Division I schools. These stipends are intended to allow schools to grant aid to student-athletes beyond a full-ride scholarship to cover additional costs imposed on student-athletes. These stipends created an opportunity for the “Autonomy” Power 5 programs to utilize a competitive tactic to try to win over the top recruits. There is evidence that these COA stipends have caused an increase in the estimated cost of attendance reported by the university. This paper examines if the COA stipends have …

The Rotational Period Distribution Of Massive Magnetic White Dwarfs, Zorayda Martinez

Honors Theses

Rapidly rotating white dwarfs (WDs) have the potential to come about by either double degenerate mergers or weak coupling between the core and the outer envelope during the asymptotic giant branch (AGB). For both cases, knowledge of the rotational period distribution places tight constraints on the evolution of angular momentum transfer. Here we present initial results from a study of the rotational period distribution of 19 massive (M > 0:9M), magnetic, DA WDs observed by the Transiting Exoplanet Survey Satellite (TESS) and 17 observed with ground-based telescopes and analyzed with the Lightkurve python package. We present periodograms, folded light curves, and …

The Luminous Power Of Accretion Disks In Active Galactic Nuclei, Imogen Jade Courtney

Honors Theses

Active Galactic Nuclei (AGN) are the most luminous long-lived objects in the universe. The phenomenon of the immense luminosities we observe for AGN has interested physicists and astronomers for over a century and continues to fascinate scientists today. The work in this thesis aims to provide an introductory exploration of this phenomenon. This thesis uses a simple model of AGN accretion disks that was developed under the standard disk model proposed by Shakura & Sunyev in 1973 under the simplest assumptions. The model accurately demonstrates how physical parameters, such as the temperature, radiative flux, luminosity, and spectra, scale through an …

Race, Gender And Rawls' "A Theory Of Justice.", Robert Carico

Honors Theses

Should we use the concepts developed by John Rawls in his A Theory of Justice to guide research questions relevant to issues concerning race and gender? This paper argues not only that the concepts from A Theory of Justice should not be used as the primary tool in any debate concerning race and gender, but it also challenges the abstract thinking of 21st Century Western Philosophers to develop a theory of justice that acknowledges the fact that people have their own interests and depending on what race and/or gender they identify with, might not have equal rights protected under the …

Characterization Of Shinella 6-Hydroxy-(L)-Nicotine Oxidase (6hlno-Se), Kaitrin Funckes

Honors Theses

6-hydroxy-(L)-nicotine oxidase, isolated from the organism Shinella sp. HZN7 (6HLNO-SE), is an enzyme that during the catabolism of nicotine catalyzes the oxidation of (S)-6-hydroxynicotine to 6-hydroxypseudeooxynicotine. This enzyme is a member of the monoamine oxidase (MAO) structural family of flavoproteins, which contain a highly conserved FAD-binding domain. Within the binding domain is a conserved lysine residue that can be traced throughout evolutionary history in this family. 6HLNO isolated from Arthrobacter nicotinovorans serves as a model enzyme for the one isolated from Shinella as both catalyze the same reaction in this biochemical pathway and much has been studied about the Arthrobacter …

From Big Farm To Big Pharma: A Differential Equations Model Of Antibiotic-Resistant Salmonella In Industrial Poultry Populations, Rilyn Mckallip

Honors Theses

Antibiotics are used in poultry production as prophylaxis, curative treatment, and growth promotion. The first use is as prophylaxis, or prevention of common bacterial diseases. The crowded conditions in concentrated animal feeding operations necessitate management of infectious disease to ensure overall animal health and the profitability of such operations. In these farms, between 20,000 and 125,000 birds are raised in shed-like enclosures [3], with an average of less than one square foot of space per chicken [34]. Antibiotics are currently used in chicken farms to manage and prevent common bacterial diseases such as respiratory and digestive tract infections, as well …

Computational Study Of The Rotational Barrier In Indole Derivatives, Javaughn Martinez

Honors Theses

The purpose of this computational study is to understand the rotational barrier in indole derivatives, leading to stereoisomers, specifically atropisomers, which will impact the research direction focused on the development of a porphyrin hosts in Professor Starnes’s group. The Starnes research group is working to synthesize a porphyrin host that can function as a sensor or to remove harmful and deleterious anions such as phosphate and nitrates (Busschaert, et al, 2015). We will utilize the data provided to understand the required energy to restrict a rotation around the indole-benzene bond. To do so, the indole derivatives will be studied using …

The Public Trust Doctrine: Roman Law Roots And Future In Environmental Litigation, Phoebe Liccardo

Honors Theses

The public trust is an ancient and enduring legal doctrine. With roots in Roman law, the public trust persists through English law, and into the United States. Scholars and jurists in the field of Roman and environmental law do not all agree on the history and continuity of the public trust doctrine (PTD). There are those who argue the Roman law introducing a public trust did not assert the same protections present in the doctrine today. Conversely, there are those who believe the Roman law did enshrine similar protections, and further, that it calls for an expansion of PTD in …

Optimal Method For Reconstructing Polychromatic Maps From Broadband Observations With An Aysmmetric Antenna Pattern, Brianna Cantrall, Emory F. Bunn, Solomon Quinn

Honors Theses

Broadband time-ordered data obtained from telescopes with a wavelength-dependent, asymmetric beam pattern can be used to extract maps at multiple wavelengths from a single scan. This technique is especially useful when collecting data on cosmic phenomena such as the Cosmic Microwave Background (CMB) radiation, as it provides the ability to separate the CMB signal from foreground contaminants. We develop a method to determine the optimal linear combinations of wavelengths (“colors”) that can be reconstructed for a given telescope design and the number of colors that are measurable with high signal-to-noise ratio. The optimal colors are found as eigenvectors of a …

The Commutant Of The Fourier–Plancherel Transform, Brianna Cantrall

Honors Theses

One can see that this matrix is unitary and has eigenvalues {1,−i,−1, I}, each of infinite multiplicity. Throughout the remainder of this thesis, we will convince the reader that the above linear transformation is actually the Fourier transform. We will compute the commutant, as well as its invariant subspaces. The key to do this relies on the Hermite polynomials. Why do we recast the Fourier transform from its well-known and well studied integral form to the matrix form shown above? As we will see, the matrix form allows us to efficiently discover the operator theory of the Fourier transform obfuscated …

Length Bias Estimation Of Small Businesses Lifetime, Simeng Li

Honors Theses

Small businesses, particularly restaurants, play a crucial role in the economy by generating employment opportunities, boosting tourism, and contributing to the local economy. However, accurately estimating their lifetimes can be challenging due to the presence of length bias, which occurs when the likelihood of sampling any particular restaurant's closure is influenced by its duration in operation. To address the issue, this study conducts goodness-of-fit tests on exponential/gamma family distributions and employs the Kaplan-Meier method to more accurately estimate the average lifetime of restaurants in Carytown. By providing insights into the challenges of estimating the lifetimes of small businesses, this study …

Computer Organization And Assembly Language Embedded Firmware Overhaul, Elaine Yun Ru Chan

Honors Theses

The WMU Computer Organization and Assembly Language class has encountered some difficulties in the past several years regarding the procurement of required hardware and software for the curriculum. This has led to a number of challenges for students, including:

• Difficulty in obtaining the necessary hardware and software

• Inability to complete assignments and projects due to hardware or software failures

• Frustration and anxiety caused by the challenges of the course

To address these challenges, a new choice of embedded firmware was researched and developed. This firmware allows for more reliable flashing of the MSP430 Microcontroller and remains reliable on modern operating …

Membership Probabilities Of White Dwarfs In Open Star Clusters, Sarah Phillips

Honors Theses

This thesis explores the relationship between astronomical position data and star cluster membership. Our research project focuses on the mathematical probability of cluster membership for white dwarf stars (WDs), specifically membership candidates within the open cluster Messier 35. Through Gaussian analysis of proper motion data, we examine the membership probability of each candidate. Establishing cluster membership has broad applications and can allow further determination of a star’s characteristics including stellar age and evolution. Of particular interest are two WD member candidates for Messier 35: LAWDS 4, a DB WD with a helium-dominated atmosphere as opposed to the more common hydrogen-dominated …

Evaluating Neutron Star Binding Energies Using Rotating Accreting Models, Nathan Moore

Honors Theses

Neutron star binding energy increases due to accreting matter from neighboring astronomical bodies, and decreases due to the star spinning up, increasing its angular velocity. We present a novel set of models that account for both increasing angular velocity and accreting matter to track a neutron star’s evolution. We arrive at these models through studying and reconfiguring computational investigations from the past, particularly a code which generates a model for a given fixed baryon mass and angular velocity and another that takes it from one baryon mass and angular velocity to the next one through accretion, to obtain a full …

Substituent Effect Analysis On Halogen Bonding Interactions, Summer Hanson

Honors Theses

This study was used to determine the significance of substituents placed on aromatic molecules and how electron-donating groups (EDG) and electron-withdrawing groups (EWG) affect the strength of the halogen bond. Each study involved the same substituents, each differing in electron-withdrawing and electron-donating capability. Five different systems were created on computational software to evaluate the distance between the halogen bond donor and halogen bond acceptor. In two studies, the goal was to find the best electron-donor on the halogen bond acceptor (donor of electron density) while the halogen bond donor remained constant. For one study, the goal was to determine the …

Tracking System Effectiveness For Texas Police Departments In Low-Income Communities, Jakob Scarcelli

Honors Theses

No abstract provided.

Computational Investigation Of Porphyrin-Based Host Design For Anions And Ion Pairs, Symphony Hill

Honors Theses

Little research has heretofore been devoted to studying the binding interactions between porphyrin-based molecular hosts and anions or ion pairs. Such interactions could be important in synthesizing molecules capable of detecting, binding, extracting, and transporting ions of biological, environmental, and industrial significance. With this in mind, computational studies of nine different porphyrin hosts were performed to examine the structural and binding properties of each molecule and potential ion guests. Using the Spartan computational chemistry software, each porphyrin was modeled and binding was tested with a number of ions of different shapes and sizes. Data was then collected regarding the distances …

Extraction And Analytical Method For N-Nitrosoatrazine Using Liquid Chromatography Paired With Tandem Mass Spectrometry, Carolyn Billings

Honors Theses

Atrazine is an herbicide used in the United States to control weeds. When combined with nitrite, atrazine can be nitrosated to form N-nitrosoatrazine (NNAT) in vivo and in vitro under acidic conditions. Atrazine can also be metabolized to atrazine mercapturate, deethylatrazine (DEA), didealkylatrazine (DDA), and deisopropylatrazine (DIA). Atrazine is monitored in drinking water due to its possible carcinogenicity. The objective of this study was to develop extraction and analytical methods for NNAT, atrazine, and atrazine metabolites. An instrument detection limit, extraction methods comparison, and extraction method detection limit were determined. To compare methods, Fischer 344 rat tissue samples were …

The Concentration Of Heavy Metals In Lincoln Nebraska's Tap Water, Evan Neuhaus

Honors Theses

Heavy metals are commonplace in nature, and are typically found in scarce quantities in all drinking sources. However, in high enough concentrations, they can have a myriad of negative health effects. This study seeks to find the concentrations of such metals in the Lincoln water supply utilizing the resources of the Water Center at the University of Nebraska at Lincoln. To test for discrete concentrations of trace elements, a method of using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) was implemented. ICP-MS uses plasma to ionize and atomize a sample which is then filtered into a series of cones into a …

The Influence Of Complex Coastlines On The Sea Breeze And Convection Initiation In Coastal North Carolina, Logan Howard, Adam L. Houston

Honors Theses

The sea breeze is a common phenomenon in coastal regions around the world. Their development and propagation can be treated as a density current. It is well known that many factors influence density current propagation, including wind. Depending on the orientation, the wind speed and shear can enhance or inhibit the development of the sea breeze. In places like eastern North Carolina, complex coastal geography can create river and sound breezes that, upon collision, have the potential to initiate thunderstorms. Using Cloud Model 1, simulations were conducted to model the behavior of the sea breezes in eastern North Carolina and …

Using Game Theory To Model Tripolar Deterrence And Escalation Dynamics, Grace Farson

Honors Theses

The study investigated how game theory can been utilized to model multipolar escalation dynamics between Russia, China, and the United States. In addition, the study focused on analyzing various parameters that affected potential conflict outcomes to further new deterrence thought in a tripolar environment.

A preliminary game theoretic model was created to model and analyze escalation dynamics. The model was built upon framework presented by Zagare and Kilgour in their work ‘Perfect Deterrence’. The model is based on assumptions and rules set prior to game play. The model was then analyzed based upon these assumptions using a form of mathematical …

Modeling The Particle-On-A-Ring Theory In An Undergraduate Laboratory, Courtney Deslauriers

Honors Theses

In early chemistry education, students are often taught to think about electrons as small, negatively charged particles existing in planetary orbits around the nucleus of an atom, rather than creating an electron cloud. In reality, electrons exhibit wave-particle duality, and are best described as wave functions. This idea that the electrons travel as waves and are moving around the nucleus so quickly that it is not possible to know the speed or location of an electron at any given moment is extremely abstract and difficult to visualize. This concept is essential to the theory of quantum mechanics, and therefore is …

Deposited Cigarette Smoke As A Driver Of Oxidation And Partitioning Processes On Indoor Surfaces, April Hurlock

Honors Theses

Despite the large amount of time that individuals spend indoors during their lives, very little attention was paid to the chemistry that occurs on indoor surfaces until recently. Although not visible to the naked eye, physical and chemical processes, such as partitioning and oxidation, are occurring on virtually every indoor surface in a typical household. Indoor pollutants, ranging from skin oils to environmental cigarette smoke, drive a lot of these processes. The transformation of indoor surfaces by indoor pollutants can increase chemical exposure risks as new irritants or carcinogens can be introduced to the surfaces. In this thesis, I describe …

On The Pursuit Of Developer Happiness: Webcam-Based Eye Tracking And Affect Recognition In The Ide, Tamsin Rogers

Honors Theses

Recent research highlights the viability of webcam-based eye tracking as a low-cost alternative to dedicated remote eye trackers. Simultaneously, research shows the importance of understanding emotions of software developers, where it was found that emotions have significant effects on productivity, code quality, and team dynamics. In this paper, we present our work towards an integrated eye-tracking and affect recognition tool for use during software development. This combined approach could enhance our understanding of software development by combining information about the code developers are looking at, along with the emotions they experience. The presented tool utilizes an unmodified webcam to capture …