Physical Sciences and Mathematics Commons^™

Developing Synthetic Methods To Prepare Discrete Metal-Organic Nanotubes, Derek L. Mull

Masters Theses

Metal-organic nanotubes (MONTs) are an emerging class of discrete materials that are the 1D variant of metal-organic frameworks (MOFs). MONTs have potential to become an alternative 1D material to carbon nanotubes, metal oxide nanotubes, and boron nitride nanotubes because they possess an organic ligand that can be functionalized and tuned for specific applications. Despite this potential, only a handful of structures have been reported and only two examples of discrete MONTs exist in the literature. It is thus imperative to develop general methods to prepare and characterize discrete MONTs to bring them to the forefront of the scientific literature.

Efforts …

Effects Of Bullying And Victimization On Friendship Selection, Reciprocation, And Maintenance In Elementary School Children, Marisa Lynn Whitley

Masters Theses

This study examined the effects of elementary school children’s bullying and victimization experiences on their friendships over time. The majority of children experience acts of aggression or bullying before the end of elementary school, and bullying and peer victimization is associated with academic, social, behavioral, and psychological difficulties. This study used social networks analysis (R SIENA 4.0) to examine whether peer reports of forms of bullying and victimization (i.e., overt and relational) affect the likelihood of friendship selection, reciprocation, and maintenance in 2^nd-4^th grade children. Children (N = 143) from the Midwestern region of the United …

Opportunities In Sustainability: Maize Seeders For The Developing World And Alternative Fertilizers In The United States, Rebecca Mattingly Harman

Masters Theses

Sustainable agricultural systems are needed for both large and small-scale farmers the world over. Central to the sustainability of these systems is the availability of cheap and effective seeders for smallholder farmers and effective utilization of less energy intensive nitrogen sources. In the first two chapters, this thesis considers maize seeders for smallholder use in a Conservation Agriculture system. To sustain the smallholder sector, soil fertility and soil erosion must be addressed and a Conservation Agriculture model seeks to improve soil conditions in agriculture. The technologies available to smallholder farmers, though, need to be tested in a no-till system before …

Impacts Of Biofumigation And Anaerobic Soil Disinfestation On Strawberry Production, Jennifer Renee’ Wheeler

Masters Theses

Due to the phase-out of methyl bromide, there is a need for alternative, nonchemical fumigation treatments in strawberry production. Anaerobic soil disinfestation and biofumigation are two non-chemical methods for controlling soilborne plant pathogens of strawberry. This study was designed to observe strawberry fruit nutrition and soil volatiles of a strawberry field being treated with biofumigation treatments, anaerobic soil disinfestation treatments, and a combination of the two alternative methods. A trial was conducted with 11 pre-plant soil-incorporated treatments arranged in a randomized complete block design with 6 rows (blocks). Biofumigation treatments consisted of deactivated mustard meal, deoiled mustard meal, mustard pellets, …

Improving Ventricular Catheter Design Through Computational Fluid Dynamics, Sofy Hefets Weisenberg

Masters Theses

Cerebrospinal fluid (CSF) shunts are fully implantable medical devices that are used to treat patients suffering from conditions characterized by elevated intracranial pressure, such as hydrocephalus. In cases of shunt failure or malfunction, patients are often required to endure one or more revision surgeries to replace all or part of the shunt. One of the primary causes of CSF shunt failure is obstruction of the ventricular catheter, a component of the shunt system implanted directly into the brain's ventricular system. This work aims to improve the design of ventricular catheters in order to reduce the incidence of catheter obstruction and …

Tennessee Tornado Frequency, Vulnerability, And Relation To A Large-Scale Climate Variability, Vincent Marshall Brown

Masters Theses

This work explores the climatologies of isolated tornadoes and tornado outbreaks across the state of Tennessee, a state that in some years experiences more tornadoes than states in the heart of Tornado Alley. Part one assesses tornado frequency characteristics and fatality statistics within 100 km of three major Tennessee cities (Nashville, Memphis, and Knoxville) between 1950 and 2013. Nashville reported the most tornadoes, (426) but Memphis reported the most fatalities. Knoxville and Nashville tornadoes occurred on fewer days, while Memphis tornadoes were spread across more tornado days. Spring was the most active season for tornadoes, but Memphis still experienced approximately …

Cd Transport In Eutectic Licl-Kcl And Contamination Of Zr Metal And Thermal Dehydration Of Bulk Licl-Kcl, Nicholas Azoy Earle

Masters Theses

Researchers at Idaho National Labs have noted unexpectedly high Cd content in empty cladding hulls after processing in the Mark-IV ER. It has been theorized that Cd metal is transporting from the LCC pool through the eutectic LiCl-KCl salt bath to the anode baskets containing the empty hull where it is retained as a Zr-Cd intermetallic. This study sought to replicate the Cd contamination in a dry Ar glovebox using small-scale analogue of the Mark-IV ER salt-Cd metal system.

Anhydrous eutectic LiCl-KCl was an essential regent in this research and experiments were conducted to investigate the feasibility of dehydrating nominally …

Incorporating Carbon Nanotubes Into Carbon Fiber Via Surface Modification, Robert Benjamin Ripy

Masters Theses

Ever more advanced materials need to be designed to further the exploration of avenues of science and engineering. Metals and traditional composites are not meeting the needs of today’s stringent demands for lightweight and strong materials. There is a need for advanced materials that are lighter and stronger to replace conventional materials; carbon fiber composites became the obvious choice because of their outstanding mechanical properties. Polyacrylonitrile (PAN) based carbon fiber has reached its apex in terms of its strength to weight ratio. Carbon nanotubes (CNTs) offer a lightweight and potentially stronger alternative to PAN based fibers. However, it is difficult …

Magnetron Sputtering And Corrosion Of Ti-Al-C And Cr-Al-C Coatings For Zr-Alloy Nuclear Fuel Cladding, Devin Alan Roberts

Masters Theses

The disaster at the Fukushima Daiichi Nuclear Power Plant in March 2011 bought renewed focus to the issue of corrosion in nuclear fuel cladding applications. This thesis reports on the background behind these issues, the investigation strategy, and the analysis of experiments focused on mitigating oxidation of Zr-alloy fuel cladding. This thesis seeks to develop magnetron sputtered Ti-Al-C and Cr-Al-C coatings for Zr-alloy substrates and characterize the as-deposited and corroded samples.

Ti-Al-C and Cr-Al-C coatings were deposited onto ZIRLO, Si, and Al₂O₃ [Aluminum Oxide] substrates under various sputtering conditions. A combinatorial sputtering method was employed to refine …

Optical Sensors For The Analysis Of Alcohols In Fuels, Kendhl Kate Witt

Masters Theses

This thesis reports the development of optical sensors to analyze alcohols in fuel samples. One optical sensor enables the analysis of phenol in aviation fuels and cellulosic biofuels. It is critical to monitor the concentration of phenols in fuels because they increase the presence of solid oxidative deposits and lower the thermal stability of fuels. Preliminary studies of another optical sensor have been conducted to detect ethanol in E10 gasoline samples. Gasoline containing ethanol is widely available and used, but the exact percentage of ethanol is not specified and varies between samples and regions. Higher concentrations of ethanol in gasoline …

Application Of Electrospray Ionization Mass Spectrometry For Ionic Liquids And Their Biodegradation Products, Sepideh Rahbarirad

Masters Theses

Ionic liquids (ILs) are organic salts with unique physico-chemical properties and are used as green alternatives to volatile organic solvents. ESI-MS is a sensitive technique to detect these stable, permanent ions. My research focused on (1) Identification of biodegradation products of ionic liquids and (2) Multiplexed tandem MS by modulation of ionization efficiency.

Studies, have demonstrated that ILs are toxic to the environment, which makes their biodegradability an important consideration. In this work, metabolites generated during the biodegradation of 1-butyl-3-methylimidazolium chloride (BMIM), a degradation resistant and commonly used ionic liquid, are identified using high performance liquid chromatography-mass spectrometry (LC-MS).

Multiplexed …

Stable Isotope Investigations Of Two Components Of The Cryosphere: Snow And Icicle Formation, Thomas C. Brubaker

Masters Theses

Understanding the processes that govern the cryosphere is necessary to understand the water budget within an area that receives significant winter precipitation. This research investigates two components of the cryosphere, namely snow and icicle formation, through the application of the stable isotopes of oxygen and hydrogen.

Stable isotope measurements from precipitation collected throughout the winter of 2013-2014 are presented. The measured isotope values are in discord with known isotope effects. This discrepancy hints at a previously unexplored atmospheric phenomenon, where the enriched oxygen isotope signature of atmospheric ozone was incorporated, via photochemical reactions, into water vapor which subsequently fell as …

Evaluation Of An Alternative Natural Surfactant For Non Aqueous Phase Liquid Remediation, Brian A. Beach

Masters Theses

Applications of surfactant technology in the environmental remediation industry can greatly enhance the success of non-aqueous phase liquid (NAPL) remediation. Saponins derived from the bark of the Quillaja soapbark tree were evaluated as an alternative natural surfactant. Properties including the critical micelle concentration, emulsion kinetics and the solubilization enhancement of sixteen PAHs (polycyclic aromatic hydrocarbons) were measured. The critical micelle concentration (CMC) for Quillaja saponin was found to be 60 mg/L. Soil contaminated with NAPL from a former manufactured gas plant was used to evaluate saponin’s ability to enhance the solubilization of PAHs commonly found in NAPL. Although solubilization enhancement …

Environmental Applications Of Chromatography-Mass Spectrometry, Wisam Abdulabbas Flayyih Al Isawi

Masters Theses

Gas chromatography-mass spectrometry (GC-MS) and liquid chromatographymass spectrometry (LC-MS) are powerful analytical techniques that combine the separation power in a stationary phase with the detection power of mass spectrometry. GCMS and LC-MS have gained dominant positions in identifying and quantifying different analyte species due to their high selectivity, high sensitivity, and high reproducibility.

My research utilizes the analytical power of LC-MS and GC-MS to address two environmental issues: 1) Identification of biodegradation products of the ionic liquid 1- butyl-3-methylimidazolium chloride (BMIMCl) by an activated sludge microbial community using LC-MS and 2) identification and quantification of polycyclic aromatic hydrocarbons (PAHs) in …

Geochemical And Petrological Characterizations Of Peridotite And Related Rocks In Marquette County, Michigan, Andrew Lloyd Sasso

Masters Theses

This study characterizes the following rock units in Marquette County, Michigan in terms of geochemistry and petrology: (1) Presque Isle Peridotite, (2) Deer Lake Peridotite, (3) Yellowdog Peridotite, and (4) Black Rock Point Gabbro. Analyses were conducted to determine if any petrological or geochemical relationships exist between these units, and to assess the potential of these units to host magmatic sulfide deposits.

The generated data and chosen geotectonic proxies indicate that Black Rock Point Gabbro and Deer Lake Peridotite crystallized from unrelated magmas, probably during the formation of the Great Lakes Tectonic Zone (2.7-1.85 Ga). No evidence was found which …

Extent Of Capillary Rise In Sands And Silts, Rachel Lynn Salim

Masters Theses

The values reported in literature for the height of capillary rise in fine sands, silts, and clays are contradictory. Most of the values were based on mathematical models, which used estimated rather than measured input data. This work measured capillary rise values in laboratory experiments in fine-grained sands and silts.

Two uniform sands with grains 0.35--0.7 mm in diameter and 0.3-0.6 mm in diameter, silt with an average grain size below 40 microns, and 0.35--0.7 mm sand coated with a water-repellant spray were carefully packed into two-inch diameter glass columns. These columns were placed into clear plastic tanks with water …

Lnfluence Of Persulfate On Solidification/Stabilization Characteristics Of Iss Treatment, Jeffrey M. Hudson

Masters Theses

Two environmental remediation technologies that lend themselves well to being combined in a single application are In Situ Chemical Oxidation (ISCO) using activated persulfate (PS), and In Situ Stabilization (ISS). Persulfate can be activated by increasing the pH to 10.5 and/or increasing temperatures to 30ºC. Many common ISS amendments increase temperature to 30°C and/or pH to 10.5 when in contact with soil water. Laboratory experiments were conducted with various soils to determine the ability of eight ISS amendments to activate persulfate. All eight ISS amendments activated persulfate. This work also showed that the relative contribution of heat vs. alkaline activation …

Slug Tests In Unconfined Aquifers, Rozkar Izzaddin Ismael

Masters Theses

This research presents a hydraulic conductivity (K) analysis of unconfined aquifers using slug tests. Slug tests are used to determine in situ aquifer hydraulic conductivity more quickly and economically than by a pump test. This study examines how to best conduct a slug test using a physical slug. Different common slug test analysis methods are compared, including Bouwer and Rice (1976), Hvorslev (1951), Dagan (1978) and Kansas Geological Survey (KGS, 1994). Questions that motivated this study include: Which methods are better for performing and analyzing slug tests? Does the size of the physical slug affect the results? Do large initial …

Geochemical And Petrological Studies On The Origin Of Nickel-Copper Sulfide Mineralization At The Eagle Lntrusion In Marquette County, Michigan, Benjamin Davis Hinks

Masters Theses

The Eagle magmatic intrusion is located in the Upper Peninsula of Michigan in Marquette County. It hosts a high grade magmatic nickel-copper sulfide ore deposit. Country rocks surrounding the Eagle intrusion are metamorphosed slate and greywacke of the Proterozoic Michigamme Formation and Archean granite-gneiss. The aim of this thesis is to characterize the magmatic sulfide mineral deposit at Eagle and to establish its relationship to the surrounding host rocks of the Baraga Basin area.

The Eagle East intrusion is located 600 meters east of the Eagle intrusion. These two intrusions are similar in composition and sulfide mineralization. Sulfide textural domains …

Characterizing Groundwater Recharge And Streamflow Using Stable Isotopes Of Oxygen And Hydrogen, Chanse M. Ford

Masters Theses

Potential changes to climate and precipitation patterns from anthropogenic influences like global climate change could have an impact on Michigan’s groundwater resources. Indirectly this could have an effect on Michigan’s surface waters as well, since groundwater and surface waters are intimately linked to form one system.

This investigation utilized stable isotopes of oxygen and hydrogen found in precipitation, groundwater and surface waters to better understand the contribution of different types of precipitation to recharge of a shallow aquifer in Manistee National Forest, MI. The study also examines the contribution of this shallow groundwater to streamflow in the nearby White River. …

Differentiating Saginaw From Huron-Erie Lce Lobe Meltwater Deposits In South Central Michigan Using Longitudinal Profiles, Grain Size Analysis, And Lithology, Nathan R. Erber

Masters Theses

The Saginaw and Huron-Erie lobes of the Laurentide Ice Sheet had a significant impact on the landscape of south-central Michigan after the Late Glacial Maximum. During the advances and retreats of these lobes, a complicated network of meltwater channels developed. Two goals of this study are: 1) to use sand-grain lithology, grain-size analysis, and longitudinal profiles to determine if a difference exists between Saginaw lobe and Huron-Erie lobe meltwater deposits; and 2) to determine if a large meltwater sluiceway containing the modern St. Joseph River had a source of meltwater and outwash from the Huron-Erie lobe. Two cores from drumlinized …

Scalable Parallelization Of A Markov Coalescent Genealogy Sampler, Philip E. Davis

Masters Theses

Coalescent genealogy samplers are effective tools for the study of population genetics. They are used to estimate the historical parameters of a population based upon the sampling of present-day genetic information. A popular approach employs Markov chain Monte Carlo (MCMC) methods. While effective, these methods are very computationally intensive, often taking weeks to run. Although attempts have been made to leverage parallelism in an effort to reduce runtimes, they have not resulted in scalable solutions. Due to the inherently sequential nature of MCMC methods, their performance has suffered diminishing returns when applied to large-scale computing clusters. In the interests of …

Care-Chair: Opportunistic Health Assessment With Smart Sensing On Chair Backrest, Rakesh Kumar

Masters Theses

"A vast majority of the population spend most of their time in a sedentary position, which potentially makes a chair a huge source of information about a person's daily activity. This information, which often gets ignored, can reveal important health data but the overhead and the time consumption needed to track the daily activity of a person is a major hurdle. Considering this, a simple and cost-efficient sensory system, named Care-Chair, with four square force sensitive resistors on the backrest of a chair has been designed to collect the activity details and breathing rate of the users. The Care-Chair system …

Automated Design Of Boolean Satisfiability Solvers Employing Evolutionary Computation, Alex Raymond Bertels

Masters Theses

"Modern society gives rise to complex problems which sometimes lend themselves to being transformed into Boolean satisfiability (SAT) decision problems; this thesis presents an example from the program understanding domain. Current conflict-driven clause learning (CDCL) SAT solvers employ all-purpose heuristics for making decisions when finding truth assignments for arbitrary logical expressions called SAT instances. The instances derived from a particular problem class exhibit a unique underlying structure which impacts a solver's effectiveness. Thus, tailoring the solver heuristics to a particular problem class can significantly enhance the solver's performance; however, manual specialization is very labor intensive. Automated development may apply hyper-heuristics …

Composite Model Representation For Computer Aided Design Of Functionally Gradient Materials, Fangquan Wang

Masters Theses

"Functionally Gradient Materials (FGMs) feature smooth transition from one material to another within a single object. FGMs modeling is considered to be one of the new challenges in Computer Aided Design (CAD) area. To overcome this challenge, this thesis presents a composite approach to model FGMs. The input in STL format can be meshed and voxelized in FGMs modeling system. The material composition in each voxel can be generated from multiple different types of control features. And LTI filters including Gaussian Filter and Average Filter are applied to blur default material features in order to generate FGMs inside models. The …

Numerical Analysis Of Flexural Slip During Viscoelastic Buckle Folding, Davi Rodrigues Damasceno

Masters Theses

"Flexural slip is considered to be an important folding mechanism contributing in the development of different folds such as chevron, and kink-band buckle folds. Various filed studies have provided a general conceptual and qualitative understanding of flexural slip. However, quantitative evidence of the importance of the flexural slip mechanism during fold evolution is sparse, as the actual amount of surface parallel displacement, and timing, is difficult to measure accurately, due to the lack of suitable strain markers.

In this study 2D finite element analysis is used to overcome these disadvantages and to simulate flexural slip during viscoelastic buckle folding. Variations …

White-Rot Fungi As Pretreatment Agents For Wood Destined For Biofuel Applications, Ryan M. Kalinoski

Masters Theses

Efficient and economical conversion of lignocellulosic biomass to biofuels is often hampered by the chemical recalcitrance of the material. Inexpensive and environmentally-friendly pretreatment processes are therefore desirable in order to lower the cost of biofuel production and minimize negative environmental impacts. To that end, we have explored the use of a naturally occurring white-rot fungus, Trametes versicolor, as a direct pretreatment agent for hardwood destined for biofuel applications. Specifically, we examined the pretreatment effects on the hardwood mixture after treatment with the wild-type strain of T. versicolor (52J) compared with those from a cellobiose dehydrogenase (CDH)-deficient strain (m4D) , …

Theoretical Investigations Of Difluorobenzene Interacting With Ne And Infrared Analysis Of 1,1-Dichloroethylene From Synchrotron Data, Seri P. Kamari

Masters Theses

The intermolecular interactions between two molecules are of great importance in proteins, polypeptides, DNA binding, and drug binding interactions. Dimers of chemical rings such as difluorobenzene with hydrogen containing molecules such as acetylene (HCCH) and atoms such as neon are classic systems for investigating weak interactions; however, the microwave spectrum of 1,2-difluorobenzene...Ne does not behave as expected. Possible explanation of this phenomenon is that there is some large amplitude motion perturbing the spectrum.

A computational study was performed to analyze the potential energy surface (PES) of Ne or Ar with ortho, meta, and para difluorobenzene, and reveal the …

Functionalized Bodipy Dyes For Dye-Sensitized Solar Cells, Mahmoud A. Elkhalifa

Masters Theses

It is predicted that more than 20 terawatts of carbon-free energy will be demanded by 2050 to maintain a sufficient energy supply for the increasing global population, and photovoltaics are predicted to contribute significantly to the global energy needs. Dye-sensitized solar cells (DSCs) are an emerging class of photovoltaics (PV) that has produced promising power conversion efficiencies at low costs. Currently, electron recombination, dye aggregation, weak adsorption, and inefficient absorbance are among of the largest contributors to low DSC efficiencies.

BODIPY dyes are one of the most promising classes of dyes emerging for DSC application. These low molecular weight fluorophores …

Reprocessing And Structural Interpretation Of Multichannel Seismic Reflection Data From Penobscot, Nova Scotia, Fulya Gizem Yagci

Masters Theses

"Penobscot area is located in the Scotian Basin, which was occurred as a result of extension in the eastern North America border. 2-D data set that was utilized for the study consists of three multichannel seismic profiles that were collected from Penobscot Parcel 8. The main purpose of the study was to enhance signal-to-noise ratio of the seismic reflection sections suppressing high frequency noise and multiples, and removing diffractions. In addition, while the resolution of the sections were enhanced, determining the correct processing techniques and parameters for better results was the another important criteria.

The processing steps included deconvolution, minimum …