Physical Sciences and Mathematics Commons^™

Internal Motion In Weakly Bound Halomethane Complexes, Amelia J. Thomas

Masters Theses

No abstract provided.

Utilization Of Phosphorus Ylides Towards The Synthesis Of Extended Cinnamaldehydes And Stellettins, John M. Saathoff

Masters Theses

No abstract provided.

Ruthenium Polypyridyl Complexes That Utilize Azo-Dyes To Enhance Absorption Of Visible Photons, Akram Hazeen

Masters Theses

No abstract provided.

Simultaneous Electrochemical Determination Of Tryptamine And Barbituric Acid, Luxshani Thangarajah

Masters Theses

No abstract provided.

Electrochemical Characterization Of Thin-Film Perovskite-Type La1-Xsrxmno3 Electrodes Obtained By Pulsed Laser Deposition (Pld), Keerthi Chandra

Masters Theses

The implementation of fuel cells into commercial usage is prenominally dependent on the activity of cathode at which oxygen reduction reaction (ORR) takes place. Fuel cells currently use noble metals like platinum, palladium etc as cathode for the reduction reaction. These metals showed poor performance during changes in red ox environment. Perovskite oxides which were proven to be efficient as cathodes in solid oxide fuel cells operating at high temperature was studied to understand its ability to carry out ORR in alkaline fuel cells operating at room temperature.

La_1-XSr_xMnO₃ (LSMO), thin film perovskite oxide, a …

Exploring Phenyl Embrace Interactions In Trityloxy And Tritylamino Aromatic Compounds, Premnath Basa

Masters Theses

The area of supramolecular chemistry seeks to understand the organization of molecular structures and the interactions that hold such assemblies together by non-covalent interactions such as electrostatic, hydrogen bonding, π-π stacking interactions, and hydrophobic or solvatophobic effects. One such example that comes under supramolecular chemistry is the phenyl embrace interaction. These interactions occur due to the cooperative participation of at least three or more neighboring phenyl groups arranged as an interlocking propeller configuration to give complementary edge-to-face or offset face-to-face interactions. In order to understand the effect of functional groups on the tendencies of organic compounds to form phenyl embrace …

An Application Of Optical Tweezers, Patrick W. Swanson

Masters Theses

No abstract provided.

Educational Technology: Podcasts, Vodcasts, And Blogs In The Science Classroom, Danielle N. Thompson

Masters Theses

No abstract provided.

Robust Evolutionary Algorithms, Brian Wesley Goldman

Masters Theses

"Evolutionary Algorithms (EAs) have shown great potential to solve complex real world problems, but their dependence on problem specific configuration in order to obtain high quality performance prevents EAs from achieving widespread use. While it is widely accepted that statically configuring an EA is already a complex problem, dynamic configuration of an EA is a combinatorially harder problem. Evidence provided here supports the claim that EAs achieve the best results when using dynamic configurations. By designing methods that automatically configure parts of an EA or by changing how EAs work to avoid configurable aspects, EAs can be made more robust, …

Palynomorph And Palynofacies Assemblages Of Neutral-Alkaline And Acid Lakes South Of Norseman, Southern Western Australia, Lutfia Grabel

Masters Theses

"The Yilgarn Craton in Western Australia hosts hundreds of shallow ephemeral hypersaline lakes, the majority of which have acid to neutral pH values. As part of a multidisciplinary study of the evolution of hypersalinity and acidity in the region, three drill cores were studied for their palynofacies and palynomorph contents in order to characterize palynofloral response to environmental changes. Drill cores from two acid lakes, Prado Lake (PL1-09 and PL2-09) and Twin Lake West (TLW1-09), and the neutral-alkaline Gastropod Lake (GLE1-09) south of Norseman recovered Miocene to Holocene sediments of the Revenge and Polar Bear formations. Transmitted light microscopy was …

Under Pressure: A Psychophysiological Analysis Of The Effect Of Temporal Constraints On Information Processing And Decision Making, Nagaratna Krishna Sneha Pochinapeddi

Masters Theses

"In recent times, decision making under time pressure has become more common than ever and hence, it has become a hot topic for behavioral researchers. This research studies the effects of temporal constraints on users' decision quality and decision strategy. The paper primarily addresses two research questions: (i) Does time pressure affect decision quality? (ii) Does time pressure affect decision strategy? The decision accuracy and decision strategy of the participants were measured for three time-pressure conditions namely, No time pressure, Reasonable time pressure and Extreme time pressure. Research results from the past revealed that, Cognitive style is also observed to …

Physiochemical Characteristics Contributing To The Cytotoxicity Of Transition Metal Oxides, Chi-Heng Wu

Masters Theses

"In the past ten years nanotechnology has not only evolved to play a prominent role in our economy but also increased the concern over potential adverse effects caused by nanomaterials to human health and the environment. Nanotoxicity is to understand the nature and origin of the toxicity imposed by nanomaterials. Studies from our laboratory have shown that nanoparticle induces oxidative stress, perturbs calcium homeostasis, alter gene expression, and produces pro-inflammatory responses. We also identified a trend of toxicity: TiO₂ < Cr₂O₃ < Fe₂O₃ < Mn₂O₃ < NiO < ZnO < CuO. We then asked a question: what are physiochemical factors of transition metal nanoparticles that contributed to this increasing cytotoxicity. In this thesis I investigated the correlation between physicochemical properties and toxicity of the transition metal oxides in the 4th Period of the Periodic Table of Elements. Particle size, BET surface area, point of zero charge, metal dissolution, and degree of surface adsorption of transition metal oxide nanoparticles were measured. There were no increasing trends in both particle size and specific surface area. The point of zero charge showed an increasing trend as TiO₂ < Cr₂O₃ < Fe₂O₃ < NiO < CuO = ZnO < Mn₂O₃. The number of available binding sites of nanoparticle showed an increasing trend as Cr₂O₃ > ZnO > CuO > NiO > Fe₂O₃ > Mn₂O₃ > TiO₂. The degree of adsorption on the surface of nanoparticles showed an increasing trend with atomic …

Capture-Recapture Of White-Tailed Deer Using Dna Sampling From Fecal Pellet-Groups, Matthew James Goode

Masters Theses

Reliable density estimates of game and keystone species such as white-tailed deer (Odocoileus virginianus) are desirable to set proper management strategies and for evaluating those strategies over time. However, traditional methods for estimating white-tailed deer density have been inhibited by behavior, densely forested areas that can hamper observation (detection), and invalid techniques of estimating effective trapping area. We wanted to evaluate a noninvasive method of mark-recapture estimation using DNA extracted from fecal pellets as the individual marker and for gender determination, coupled with a spatial detection function to estimate density (Spatially Explicit Capture-Recapture, SECR). We collected pellet groups …

Late Pleistocene And Holocene Hydroclimate Change In The Southeastern United States: Sedimentary, Pedogenic, And Stable Carbon Isotope Evidence In Tennessee River Floodplain Paleosols, James Joseph Kocis

Masters Theses

In order to understand hydroclimate variability of future climate change, it is important to know the timing and range of natural climate change in the past. The Southeastern United States (SE) is situated along the poleward extent of projected subtropical drying, where the expression of past hydrological balances remains unclear. The lack of high-resolution paleohydroclimate records in the SE forces climate modelers to base interpretations on better-understood regions of North America. The SE likely experienced significant changes in precipitation regimes resulting from its position at the convergence of several oceanic and continental air masses. To reconstruct precipitation variability, this study …

Aeolian Simulations: A Comparison Of Numerical And Experimental Results, With Projections For Titan., Oscar Lee Mathews

Masters Theses

Aeolian processes are major determinants of geomorphology on bodies in the Solar System possessing an atmosphere-surface interface and transportable sediment, including Earth, Mars, Venus, and Titan. Substantial efforts have been made over the last few decades to understand these processes using specialized wind tunnels, field studies, and, more recently, numerical simulations. This thesis describes a model of aeolian sediment transport using computational fluid dynamics (CFD), and compares the results with those obtained in the Martian Surface Wind Tunnel (MARSWIT) testing conducted in the Planetary Aeolian Laboratory at NASA Ames Research Center. The ultimate goal of the thesis was to develop …

Cytongrasp: Cyton Alpha Controller Via Graspit! Simulation, Nicholas Wayne Overfield

Masters Theses

This thesis addresses an expansion of the control programs for the Cyton Alpha 7D 1G arm. The original control system made use of configurable software which exploited the arm’s seven degrees of freedom and kinematic redundancy to control the arm based on desired behaviors that were configured off-line. The inclusions of the GraspIt! grasp planning simulator and toolkit enables the Cyton Alpha to be used in more proactive on-line grasping problems, as well as, presenting many additional tools for on-line learning applications. In short, GraspIt! expands what is possible with the Cyton Alpha to include many machine learning tools and …

Processes Controlling The Composition Of First-Cycle Sediments Deposited In An Arid-Climate, With Implications For Provenance Reconstruction Studies, Aubrey Lynn Modi

Masters Theses

Petrologic analysis of first-cycle clastic sediments derived from a single source in an arid environment provides a means to determine how well they resemble the petrology and geochemistry of their source. The Stepladder Mountains, located in the Mojave Desert of southeastern California, represents a well-controlled location (i.e., arid environment; single, known source; short transport distance) to examine how naturally formed sediments acquire their compositions. Compositional modifications associated with sediment production were resolved through direct examination of the weathered components (regolith, grus, and sediments). Sediment compositions strongly vary by grain size, indicating that, after the source itself, hydrodynamic sorting played the …

Effect Of Landscape Position And Dairy Manure Addition On Bioavailable Forms Of Soil Phosphorus Using Enzyme Hydrolysis, Themis Mahalia Stone

Masters Theses

Bioavailable phosphorus (P) has traditionally been measured as inorganic orthophosphate (PO₄) while organic P (P_o) has been considered of limited relevance to short-term biological consumption. However, enzymes secreted by bacteria and fungi which serve to mineralize P_o are ubiquitous in the environment and may contribute significant bioavailable P over time. In order to assess environmentally-relevant, potentially bioavailable P in soils with added dairy wastes, microcosms of identical soil series but differing management histories and landscape positions were incubated at 24 C° for three weeks. Subsamples were taken weekly from microcosms and analyzed by: 1) Mehlich-3 …

Nuclear Modification Factor For Production Of Open Heavy Flavor At Forward Rapidity In Cu+Cu Collisions, Archil Garishvili

Masters Theses

The PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory with its muon spectrometer has the ability to detect muons over the range of pseudorapidity 1.1 < |eta| < 2.25. Single muon production is an important tool for studying heavy flavor production via semi-leptonic decays of open heavy flavor mesons. Because of their large mass, heavy quarks are produced in earlier stages of heavy ion collisions. Therefore, heavy flavor production can serve as an important probe of the Quark Gluon Plasma, a novel state of matter predicted to be created at RHIC. The measurement of the nuclear modification factor of open heavy flavor at forward rapidity in Cu+Cu collisions at sqrt{s_{NN}}=200 GeV is presented. Measurements of heavy flavor production in p+p collisions at sqrt{s_{NN}}=200 GeV will be also presented.

Automated Pollen Image Classification, Nicholas Quentin Haas

Masters Theses

This Master of Science thesis reviews previous research, proposes a method anddemonstrates proof-of-concept software for the automated matching of pollen grainimages to satisfy degree requirements at the University of Tennessee. An ideal imagesegmentation algorithm and shape representation data structure is selected, alongwith a multi-phase shape matching system. The system is shown to be invariantto synthetic image translation, rotation, and to a lesser extent global contrast andintensity changes. The proof-of-concept software is used to demonstrate how pollengrains can be matched to images of other pollen grains, stored in a database, thatshare similar features with up to a 75% accuracy rate.

Structural And Stratigraphic Relationships Near The Southern Terminus Of The Pulaski Fault, Northeast Tennessee, Phillip Michael Derryberry

Masters Theses

The Pulaski fault is one of the master thrust faults in the Appalachian Alleghanian fold-thrust belt. Detailed geologic mapping of Cambrian and Ordovician strata in northeastern Tennessee revealed key structural and stratigraphic characteristics for distinguishing the Pulaski thrust sheet from its footwall, the Saltville thrust sheet. Unlike most thrust systems in the Valley and Ridge, the Pulaski records at least two deformation phases. Geometric and crosscutting relationships along parts of the Pulaski thrust sheet in this study area and in southwestern Virginia suggest hanging wall and possibly some footwall deformation prior to the emplacement of the thrust sheet. The initial …

Transverse Waves In Simulated Liquid Rocket Engines With Arbitrary Headwall Injection, Charles Toufic Haddad

Masters Theses

This work introduces a closed-form analytical solution for the transverse vorticoacoustic wave in a circular cylinder with arbitrary headwall injection. This particular configuration mimics the conditions leading to the onset of traveling radial and tangential waves in a simple liquid rocket engine (LRE). Assuming a short cylindrical chamber with an injecting headwall, regular perturbations are used to linearize the problem’s mass, momentum, energy, ideal gas and isentropic relations. A Helmholtz decomposition is subsequently applied to the first-order disturbance equations, thus giving rise to a compressible, inviscid and acoustic set that is responsible for driving the unsteady motion and to an …

Improvements In Multi-Tool Surveying Efficiency For Archaeological Geophysics, Caitlyn Marie Williams

Masters Theses

Conventional archaeological excavation methods are, by nature, extremely invasive and result in study areas being irrevocably altered for the sake of research. For this reason, near-surface geophysical techniques have been incorporated into archaeological investigations to aid in determining the locations of buried features with minimal damage to the site. The objective of this research was to perform a geophysical survey at an archaeological site on the Akrotiri Peninsula in Cyprus to locate evidence of a Roman naval base and to develop an improved data management workflow that will improve the usefulness of geophysical data to archaeologists.

An on-site archaeologist determined …

Exploring The Effectiveness Of Environmentally Sustainable Practices In Municipal Government: A Case Study Of The City Of Knoxville’S Department Of Parks And Recreation, Anthony Michael Brown

Masters Theses

Sustainability practices produce programs and services that meet current needs while preserving the environment and natural resources for the future. City parks and recreation departments are facing budget shortfalls and increasing expectations from customers. Governments are now embracing sustainability practices to create financial savings while also fostering relations with customers.

The purpose of this single case study was twofold: (1) to examine the effectiveness of one city department’s strategies in outsourcing its environmental sustainability program through a performance contract with Ameresco; and (2) to examine the perceptions of key department employees about the effectiveness of the sustainability initiative. A …

An Analysis Of Boosted Regression Trees To Predict The Strength Properties Of Wood Composites, Dillon Matthew Carty

Masters Theses

The forest products industry is a significant contributor to the U.S. economy contributing six percent of the total U.S. manufacturing gross domestic product (GDP), placing it on par with the U.S. automotive and plastics industries. Sustaining business competitiveness by reducing costs and maintaining product quality will be essential in the long term for this industry. Improved production efficiency and business competitiveness is the primary rationale for this work. A challenge facing this industry is to develop better knowledge of the complex nature of process variables and their relationship with final product quality attributes. Quantifying better the relationships between process variables …

On Cyclotomic Primality Tests, Thomas Francis Boucher

Masters Theses

In 1980, L. Adleman, C. Pomerance, and R. Rumely invented the first cyclotomicprimality test, and shortly after, in 1981, a simplified and more efficient versionwas presented by H.W. Lenstra for the Bourbaki Seminar. Later, in 2008, ReneSchoof presented an updated version of Lenstra's primality test. This thesis presents adetailed description of the cyclotomic primality test as described by Schoof, along withsuggestions for implementation. The cornerstone of the test is a prime congruencerelation similar to Fermat's \little theorem" that involves Gauss or Jacobi sumscalculated over cyclotomic fields. The algorithm runs in very nearly polynomial time.This primality test is currently one of …

Examination Of 4he Droplets And Droplets Containing Impurities At Zero Kelvin Using A Density Functional Approach, Ellen Brown

Masters Theses

Abstract

Detailed in this manuscript is a methodology to model ground state properties of ⁴He droplets at zero pressure and zero Kelvin using a density functional theory of liquid helium. The density functional approach examined here consists of two noted functionals from the literature and corresponding mean field definitions. A mean field and trial density are defined for each system and optimized to self-consistency using a matrix diagonalization technique. Initial calculations of planar slabs are performed and demonstrate reasonable agreement with experiment and with prior studies using density functional theory. Quantum properties of droplets and droplets containing atomic dopants …

Mixture Model Cluster Analysis Under Different Covariance Structures Using Information Complexity, Bahar Erar

Masters Theses

In this thesis, a mixture-model cluster analysis technique under different covariance structures of the component densities is developed and presented, to capture the compactness, orientation, shape, and the volume of component clusters in one expert system to handle Gaussian high dimensional heterogeneous data sets to achieve flexibility in currently practiced cluster analysis techniques. Two approaches to parameter estimation are considered and compared; one using the Expectation-Maximization (EM) algorithm and another following a Bayesian framework using the Gibbs sampler. We develop and score several forms of the ICOMP criterion of Bozdogan (1994, 2004) as our fitness function; to choose the number …

Non-Thermal Plasma Inactivation Of Bacillus Amyloliquefaciens Spores, Yaohua Huang

Masters Theses

Bacterial spores have remarkable resistance to a variety of harsh conditions, causing spoilage in food industry and becoming the primary bacterial agent in biowarfare and bioterrorism. In this study, inactivation mechanisms of Bacillus amyloliquefaciens (BA) spores by non-thermal plasma (NTP) were investigated by using Fourier-transform infrared spectroscopy (FTIR) as a major tool to exam spores after NTP treatment. Chemometric techniques, such as multivariate classification models based on soft independent modeling of Class Analogy (SIMCA) and Principal Component Analysis (PCA), were employed to identify functional group changes in FTIR spectra. The IR absorbance bands correlated to dipicolinic acid (DPA) decreased after …

Inventory, Characterization, And Classification Of Minesoils In The Big South Fork National River And Recreation Area, Cassi Savage Jones

Masters Theses

The aim of Part One was to discover and investigate the physical and chemical properties of coal minesoils occurring within the Big South Fork National River and Recreation Area (BSF) in order to better understand the nature of these anthropogenic soils. In particular, this information was to identify which, if any, un-reclaimed or recently reclaimed minesoils were actively producing acid mine drainage (AMD) and what properties were inhibiting revegetation. Historical knowledge and maps were used to locate more than 30 un-reclaimed and reclaimed minesoil sites, which were mapped with GPS. Soil profiles were exposed on 18 sites and grab samples …