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Articles 5821 - 5850 of 8341
Full-Text Articles in Physical Sciences and Mathematics
Real-Time Virus Analysis Via Image Charge Detection Surface Induced Dissociation Tandem Mass Spectrometry, Seth T. Call
Real-Time Virus Analysis Via Image Charge Detection Surface Induced Dissociation Tandem Mass Spectrometry, Seth T. Call
Theses and Dissertations
This thesis reports on the development of a novel mass spectrometer combining image charge detection with surface induced dissociation for real-time analysis of intact viruses. Protonated viruses produced using electrospray are accelerated and subsequently impact on a solid surface. Capsid peptides released during the impact are analyzed using time-of-flight mass spectrometry. Image charge detection is used to measure the mass and charge states of structurally intact, electrosprayed viruses prior to impact. Since virus capsids are composed of loosely-bound proteins, collision of viruses with surfaces at moderate impact energies could release intact proteins. The masses and numbers of different protein types …
Supporting Remote Manipulation: An Ecological Approach, John A. Atherton
Supporting Remote Manipulation: An Ecological Approach, John A. Atherton
Theses and Dissertations
User interfaces for remote robotic manipulation widely lack sufficient support for situation awareness and, consequently, can induce high mental workload. With poor situation awareness, operators may fail to notice task-relevant features in the environment often leading the robot to collide with the environment. With high workload, operators may not perform well over long periods of time and may feel stressed. We present an ecological visualization that improves operator situation awareness. Our user study shows that operators using the ecological interface collided with the environment on average half as many times compared with a typical interface, even with a poorly calibrated …
Design And Characterization Of A Human Exposure Chamber And Inversion Episodes In Salt Lake City, Utah In January/February Of 2009, Roman Yuri Kuprov
Design And Characterization Of A Human Exposure Chamber And Inversion Episodes In Salt Lake City, Utah In January/February Of 2009, Roman Yuri Kuprov
Theses and Dissertations
Research on health effects of particulate matter (PM) has been a very active area in the last two decades. One plausible mechanism by which exposure to PM affects human health includes modification of autonomic endothelium function. Decreased endothelium activity causes heightened risks of cardiovascular disease. A human exposure chamber designed to conduct experiments to quantify diminished function of endothelium from short term exposure to PM is described. The chamber consists of two stages for containment and pre-treatment of PM and exposure of human subjects. Concentrations of CO, CO2, NO, NO2, O3, and PM2.5, are monitored and controlled in the exposure …
An Examination Of The Decision Analysis Approach To R&D Portfolios, Kelly Duncan
An Examination Of The Decision Analysis Approach To R&D Portfolios, Kelly Duncan
Theses and Dissertations
A portfolio can be defined as “a purposeful combination of items” (Chien and Sainfort 1998). As the topic relates to research and development (R&D) the items in question are technologies, projects or products under consideration for inclusion in a given portfolio. As described by surveys from Cooper et al (1998), companies have widely varying practices for portfolio selection. This thesis examines existing literature to determine the key characteristics of good portfolio and portfolio method. The approach needs to handle multiple objectives, account for project interactions, and address the social aspect of decision making. The resulting portfolio should be aligned with …
Solar Variability And Climate Processes: The Influence Of Fluctuating Solar Spectral Irradiance On Differential Surface Heating As A Function Of Soil Geochemistry And Radiation Absorption Characteristics, Susan Wahl
Theses and Dissertations
The influence of solar variability on climate has received increasing attention. Much of the research has dealt with fluctuating ultraviolet radiation and its effects in the stratosphere; decadal signatures in cloud cover and their relationship to cosmic rays; and correlations of surface air temperature with various proxies (e.g., sunspot numbers; 10Be from ice cores and marine sediments). Much of the research has focused on changing solar radiation within the upper atmosphere and the propagating effects into the troposphere. However, there is a missing component involving differential surface heating as a function of soil composition and corresponding spectral radiation absorption properties …
A Graphical Analysis Of Simultaneously Choosing The Bandwidth And Mixing Parameter For Semiparametric Regression Techniques, Derick L. Rivers
A Graphical Analysis Of Simultaneously Choosing The Bandwidth And Mixing Parameter For Semiparametric Regression Techniques, Derick L. Rivers
Theses and Dissertations
There has been extensive research done in the area of Semiparametric Regression. These techniques deliver substantial improvements over previously developed methods, such as Ordinary Least Squares and Kernel Regression. Two of these hybrid techniques: Model Robust Regression 1 (MRR1) and Model Robust Regression 2 (MRR2) require the choice of an appropriate bandwidth for smoothing and a mixing parameter that allows a portion of a nonparametric fit to be used in fitting a model that may be misspecifed by other regression methods. The current method of choosing the bandwidth and mixing parameter does not guarantee the optimal choices in either case. …
A Hop-By-Hop Architecture For Multicast Transport In Ad Hoc Wireless Networks, Manoj Kumar Pandey
A Hop-By-Hop Architecture For Multicast Transport In Ad Hoc Wireless Networks, Manoj Kumar Pandey
Theses and Dissertations
Ad hoc wireless networks are increasingly being used to provide connectivity where a wired networking infrastructure is either unavailable or inaccessible. Many deployments utilize group communication, where several senders communicate with several receivers; multicasting has long been seen as an efficient way to provide this service. While there has been a great deal of research on multicast routing in ad hoc networks, relatively little attention has been paid to the design of multicast transport protocols, which provide reliability and congestion control. In this dissertation we design and implement a complete multicast transport architecture that includes both routing and transport protocols. …
A Sequential Algorithm To Identify The Mixing Endpoints In Liquids In Pharmaceutical Applications, Akriti Saxena
A Sequential Algorithm To Identify The Mixing Endpoints In Liquids In Pharmaceutical Applications, Akriti Saxena
Theses and Dissertations
The objective of this thesis is to develop a sequential algorithm to determine accurately and quickly, at which point in time a product is well mixed or reaches a steady state plateau, in terms of the Refractive Index (RI). An algorithm using sequential non-linear model fitting and prediction is proposed. A simulation study representing typical scenarios in a liquid manufacturing process in pharmaceutical industries was performed to evaluate the proposed algorithm. The data simulated included autocorrelated normal errors and used the Gompertz model. A set of 27 different combinations of the parameters of the Gompertz function were considered. The results …
A Top-Down Proteomic Approach For The Discovery Of Novel Serum Biomarkers Of Pregnancy-Related Disease, Karen Merrell
A Top-Down Proteomic Approach For The Discovery Of Novel Serum Biomarkers Of Pregnancy-Related Disease, Karen Merrell
Theses and Dissertations
The serum fraction of blood is an ideal material in which to search for novel biomarkers for disease. It is easily obtained through relatively non-invasive means, routinely collected, and a rich treasure-trove of information about the health of an individual. Cells react to signal molecules, take up nutrients, and release waste products, fragments that are the result of proteolysis, and other molecules out into the bloodstream. If these components are unique to the cells in question, that part of the complex mixture that is the blood stream can potentially characterize the health of the tissue or organ those cells are …
Massively Parallel Indirect Dielectrophoresis Controlled Placement Of Carbon Nanotubes, Hiram Jacob Conley
Massively Parallel Indirect Dielectrophoresis Controlled Placement Of Carbon Nanotubes, Hiram Jacob Conley
Theses and Dissertations
Placement of single walled carbon nanotubes is demonstrated through massively parallel indirect dielectrophoresis (MPID). MPID is shown to be able to control the placement of carbon tubes as well as the number of tubes placed. Lumped element analysis for AC circuits is used to model MPID. This model allows for predictions of the number of tubes that will be captured in a trap. This model has been consistent with experimental data of numbers of nanotube placed in a junction. Carbon nanotubes placed with MPID are shown to be electrically active.
Factors Limiting Benthic Algal Abundance In Virginia Streams Of The Coastal Plain, Michael Brandt
Factors Limiting Benthic Algal Abundance In Virginia Streams Of The Coastal Plain, Michael Brandt
Theses and Dissertations
Algae are important components of stream food webs and often used in biomonitoring assessments. Little is known regarding the factors that limit their abundance in streams of the VA Coastal Plain. The surficial geology of the Coastal Plain is predominately sandy deposits which comprise the dominant substrate in streams of this region. In a comparative study of five streams located near the VCU Rice Center, we quantified substrate composition, light availability, and nutrient concentrations to assess their relative importance in determining benthic algal abundance. The proportion of stream area comprised of hard substrates was a significant predictor of variation in …
Extreme Ultraviolet Polarimetry With Laser-Generated High-Order Harmonics: Characterization Of Uranium, Nicole Brimhall
Extreme Ultraviolet Polarimetry With Laser-Generated High-Order Harmonics: Characterization Of Uranium, Nicole Brimhall
Theses and Dissertations
We developed an extreme ultraviolet (EUV) polarimeter, which employs laser-generated high-order harmonics as the light source. This relatively high-flux, directional EUV source has available wavelengths between 10 nm and 47 nm with easily rotatable linear polarization. The polarimeter has allowed us to characterize the optical constants of materials that may be useful for EUV optics. The instrument has a versatile positioning system and a spectral resolution of about 180, and we have demonstrated that reflectance as low as 0.1% can be measured repeatably at EUV wavelengths. We investigate the high harmonic source used for polarimetry measurements by documenting the spatial …
Four-Body Problem With Collision Singularity, Duokui Yan
Four-Body Problem With Collision Singularity, Duokui Yan
Theses and Dissertations
In this dissertation, regularization of simultaneous binary collision, existence of a Schubart-like periodic orbit, existence of a planar symmetric periodic orbit with multiple simultaneous binary collisions, and their linear stabilities are studied. The detailed background of those problems is introduced in chapter 1. The singularities of simultaneous binary collision in the collinear four-body problem is regularized in chapter 2. We use canonical transformations to collectively analytically continue the singularities of the simultaneous binary collision solutions in both the decoupled case and the coupled case. All the solutions are found and more importantly, we find a crucial first integral which describes …
Modeling The Problem Of Assigning Virginia’S Localities To Dcr’S Regional Offices, Sudharshana Srinivasan
Modeling The Problem Of Assigning Virginia’S Localities To Dcr’S Regional Offices, Sudharshana Srinivasan
Theses and Dissertations
Virginia’s Department of Conservation and Recreation (DCR) assigns all of Virginia localities to Regional Offices to help conserve the natural resources in a certain region. In this paper, we present a mathematical model for optimizing such assignments by minimizing the travel time and cost of these assignments. With the growing increase in fuel costs and tighter budgets, our solution finds alternate assignments that will help cut costs by 14% annually. We have used integer programming techniques to find optimal assignments which satisfy requirements, respect limitations and minimize cost. Several plans are suggested, some keeping soil and water conservation districts together …
The Expectation Of Transition Events On Finite-State Markov Chains, Jeremy Michael West
The Expectation Of Transition Events On Finite-State Markov Chains, Jeremy Michael West
Theses and Dissertations
Markov chains are a fundamental subject of study in mathematical probability and have found wide application in nearly every branch of science. Of particular interest are finite-state Markov chains; the representation of finite-state Markov chains by a transition matrix facilitates detailed analysis by linear algebraic methods. Previous methods of analyzing finite-state Markov chains have emphasized state events. In this thesis we develop the concept of a transition event and define two types of transition events: cumulative events and time-average events. Transition events generalize state events and provide a more flexible framework for analysis. We derive computable, closed-form expressions for the …
The Orbifold Landau-Ginzburg Conjecture For Unimodal And Bimodal Singularities, Natalie Wilde Bergin
The Orbifold Landau-Ginzburg Conjecture For Unimodal And Bimodal Singularities, Natalie Wilde Bergin
Theses and Dissertations
The Orbifold Landau-Ginzburg Mirror Symmetry Conjecture states that for a quasihomogeneous singularity W and a group G of symmetries of W, there is a dual singularity WT and dual group GT such that the orbifold A-model of W/G is isomorphic to the orbifold B-model of WT/GT. The Landau-Ginzburg A-model is the Frobenius algebra HW,G constructed by Fan, Jarvis, and Ruan, and the B-model is the Orbifold Milnor ring of WT . The unorbifolded conjecture has been verified for Arnol'd's list of simple, unimodal and bimodal quasi-homogeneous singularities with G the maximal diagonal symmetry group by Priddis, Krawitz, Bergin, Acosta, et …
Relaxation Of Vibrationally Excited Trifluorobenzene And Tetrafluorobenzene By Collisions With Carbon Dioxide, Alan M. Johnson
Relaxation Of Vibrationally Excited Trifluorobenzene And Tetrafluorobenzene By Collisions With Carbon Dioxide, Alan M. Johnson
Theses and Dissertations
An investigation into the relaxation of highly vibrationally excited trifluorobenzene and tetrafluorobenzene following collisions with carbon dioxide was performed using diode laser transient absorption spectroscopy. A 248 nm excimer laser prepared the vibrationally hot (E'~41,000 cm-1) fluorobenzene molecules. Large amounts of translational and rotational energy are transferred through collisions between the hot donor molecule and CO2. Rate constants and collisional probabilities were calculated by probing the high J states (J=58~80) of CO2 in the vibrational ground state, 0000, with measurements taken 1 µsec, ¼ the mean gas collision time, following each excimer laser pulse. The energy transfer probability distribution function, …
Estimating The Effect Of Disability On Medicare Expenditures, David Morris Burk
Estimating The Effect Of Disability On Medicare Expenditures, David Morris Burk
Theses and Dissertations
We consider the effect of disability status on Medicare expenditures. Disabled elderly historically have accounted for a significant portion of Medicare expenditures. Recent demographic trends exhibit a decline in the size of this population, causing some observers to predict declines in Medicare expenditures. There are, however, reasons to be suspicious of this rosy forecast. To better understand the effect of disability on Medicare expenditures, we develop and estimate a model using the generalized method of moments technique. We find that newly disabled elderly generally spend more than those who have been disabled for longer periods of time. Also, we find …
Ion Transport Behaviors Upstream And Downstream From The Sampling Cone Of An Inductively Coupled Plasma Mass Spectrometer, Haibin Ma
Theses and Dissertations
Inductively coupled plasma - mass spectrometry (ICP-MS) is the technique of choice worldwide for trace elemental determinations because of its excellent ionization ability, low detection limits and fast analysis speeds. However, the ICP-MS still suffers from some disadvantages, such as spectral overlap and severe matrix effects. Matrix effects or interferences, partly arise from changes in the analyte transmission through the interfacial region between the ICP and mass spectrometer with changes in sample matrix. Better understanding of the transmission behaviors of analyte through the sampling and skimmer cones will provide the insights needed to alleviate matrix interferences and to improve the …
The Role Of Smpb In The Early Stages Of Trans-Translation, Deanna June Cazier
The Role Of Smpb In The Early Stages Of Trans-Translation, Deanna June Cazier
Theses and Dissertations
Ribosomes stall on defective messenger RNA transcripts in eubacteria. Without a mechanism to release stalled ribosomes, these cells would die. Transfer-messenger RNA (tmRNA) and small protein B (SmpB) reactivate stalled ribosomes in a process known as trans-translation. Together, tmRNA and SmpB mimic alanyl-tRNA, entering the A site of stalled ribosomes and accepting transfer of the stalled polypeptide. A portion of tmRNA is then positioned as a template for the ribosome to resume translating. The tmRNA open reading frame encodes a proteolysis tag to mark the aberrant polypeptide for degradation and a stop codon to release the ribosome. How are tmRNA …
Some Congruence Properties Of Pell's Equation, Nathan C. Priddis
Some Congruence Properties Of Pell's Equation, Nathan C. Priddis
Theses and Dissertations
In this thesis I will outline the impact of Pell's equation on various branches of number theory, as well as some of the history. I will also discuss some recently discovered properties of the solutions of Pell's equation.
Zero-Inflated Censored Regression Models: An Application With Episode Of Care Data, Jonathan P. Prasad
Zero-Inflated Censored Regression Models: An Application With Episode Of Care Data, Jonathan P. Prasad
Theses and Dissertations
The objective of this project is to fit a sequence of increasingly complex zero-inflated censored regression models to a known data set. It is quite common to find censored count data in statistical analyses of health-related data. Modeling such data while ignoring the censoring, zero-inflation, and overdispersion often results in biased parameter estimates. This project develops various regression models that can be used to predict a count response variable that is affected by various predictor variables. The regression parameters are estimated with Bayesian analysis using a Markov chain Monte Carlo (MCMC) algorithm. The tests for model adequacy are discussed and …
Evans Function Computation, Blake H. Barker
Evans Function Computation, Blake H. Barker
Theses and Dissertations
In this thesis, we review the stability problem for traveling waves and discuss the Evans function, an emerging tool in the stability analysis of traveling waves. We describe some recent developments in the numerical computation of the Evans function and discuss STABLAB, an interactive MATLAB based tool box that we developed. In addition, we verify the Evans function for shock layers in Burgers equation and the p-system with and without capillarity, as well as pulses in the generalized Kortweg-de Vries (gKdV) equation. We conduct a new study of parallel shock layers in isentropic magnetohydrodynamics (MHD) obtaining results consistent with stability.
Numerical Solutions For Stochastic Differential Equations And Some Examples, Yi Luo
Numerical Solutions For Stochastic Differential Equations And Some Examples, Yi Luo
Theses and Dissertations
In this thesis, I will study the qualitative properties of solutions of stochastic differential equations arising in applications by using the numerical methods. It contains two parts. In the first part, I will first review some of the basic theory of the stochastic calculus and the Ito-Taylor expansion for stochastic differential equations (SDEs). Then I will discuss some numerical schemes that come from the Ito-Taylor expansion including their order of convergence. In the second part, I will use some schemes to solve the stochastic Duffing equation, the stochastic Lorenz equation, the stochastic pendulum equation, and the stochastic equations which model …
Properties Of The Zero Forcing Number, Kayla Denise Owens
Properties Of The Zero Forcing Number, Kayla Denise Owens
Theses and Dissertations
The zero forcing number is a graph parameter first introduced as a tool for solving the minimum rank problem, which is: Given a simple, undirected graph G, and a field F, let S(F,G) denote the set of all symmetric matrices A=[a_{ij}] with entries in F such that a_{ij} doess not equal 0 if and only if ij is an edge in G. Find the minimum possible rank of a matrix in S(F,G). It is known that the zero forcing number Z(G) provides an upper bound for the maximum nullity of a graph. I investigate properties of the zero forcing number, …
Meta-Analysis Using Bayesian Hierarchical Models In Organizational Behavior, Michael David Ulrich
Meta-Analysis Using Bayesian Hierarchical Models In Organizational Behavior, Michael David Ulrich
Theses and Dissertations
Meta-analysis is a tool used to combine the results from multiple studies into one comprehensive analysis. First developed in the 1970s, meta-analysis is a major statistical method in academic, medical, business, and industrial research. There are three traditional ways in which a meta-analysis is conducted: fixed or random effects, and using an empirical Bayesian approach. Derivations for conducting meta-analysis on correlations in the industrial psychology and organizational behavior (OB) discipline were reviewed by Hunter and Schmidt (2004). In this approach, Hunter and Schmidt propose an empirical Bayesian analysis where the results from previous studies are used as a prior. This …
Musical Query-By-Content Using Self-Organizing Maps, Kyle B. Dickerson
Musical Query-By-Content Using Self-Organizing Maps, Kyle B. Dickerson
Theses and Dissertations
The ever-increasing density of computer storage devices has allowed the average user to store enormous quantities of multimedia content, and a large amount of this content is usually music. Current search techniques for musical content rely on meta-data tags which describe artist, album, year, genre, etc. Query-by-content systems, however, allow users to search based upon the actual acoustical content of the songs. Recent systems have mainly depended upon textual representations of the queries and targets in order to apply common string-matching algorithms and are often confined to a single query style (e.g., humming). These methods also lose much of the …
Modeling Temperature Reduction In Tendons Using Gaussian Processes Within A Dynamic Linear Model, Richard David Wyss
Modeling Temperature Reduction In Tendons Using Gaussian Processes Within A Dynamic Linear Model, Richard David Wyss
Theses and Dissertations
The time it takes an athlete to recover from an injury can be highly influenced by training procedures as well as the medical care and physical therapy received. When an injury occurs to the muscles or tendons of an athlete, it is desirable to cool the muscles and tendons within the body to reduce inflammation, thereby reducing the recovery time. Consequently, finding a method of treatment that is effective in reducing tendon temperatures is beneficial to increasing the speed at which the athlete is able to recover. In this project, Bayesian inference with Gaussian processes will be used to model …
Finding Alternatives To The Hard Disk Drive For Virtual Memory, Bruce Albert Embry
Finding Alternatives To The Hard Disk Drive For Virtual Memory, Bruce Albert Embry
Theses and Dissertations
Current computer systems fill the demand of operating systems and applications for ever greater amounts of random access memory by paging the least recently used data to the hard disk drive. This paging process is called "virtual memory," to indicate that the hard disk drive is used to create the illusion that the computer has more random access memory than it actually has. Unfortunately, the fastest hard disk drives are over five orders of magnitude slower than the DRAM they are emulating. When the demand for memory increases to the point that processes are being continually saved to disk and …
Radio Determination On Mini-Uav Platforms: Tracking And Locating Radio Transmitters, Braden Russell Huber
Radio Determination On Mini-Uav Platforms: Tracking And Locating Radio Transmitters, Braden Russell Huber
Theses and Dissertations
Aircraft in the US are equipped with Emergency Locator Transmitters (ELTs). In emergency situations these beacons are activated, providing a radio signal that can be used to locate the aircraft. Recent developments in UAV technologies have enabled mini-UAVs (5-foot wingspan) to possess a high level of autonomy. Due to the small size of these aircraft they are human-packable and can be easily transported and deployed in the field. Using a custom-built Radio Direction Finder, we gathered readings from a known transmitter and used them to compare various Bayesian reasoning-based filtering algorithms. Using a custom-developed simulator, we were able to test …