Physical Sciences and Mathematics Commons^™

Geology Of The North Beulah, Center, And Glenharold Lignite Mines In Mercer And Oliver Counties, Southwestern North Dakota, Roy E. Kulland

Theses and Dissertations

The geology of the North Beulah, Center, and Glenharold lignite mines in Mercer and Oliver Counties, southwestern North Dakota, were examined. Stratigraphically, all mines lie within the Sentinel Butte Formatiom. The North Beulah Mine lies 70 m below the top of the Sentinel Butte Formation and the Center and Glenharold Mines lie about 80 m above the base of the Tongue River Formation.

Four sedimentary types are recognized arid common to all mines; these are: silt and clay, silty sand, sand, and lignite. The silt and clay were deposited in floodbasins and shallow lakes occupying the lowest parts of the …

Petrography Of Precambrian Iron Formation, Pembina County, North Dakota, Ronald E. Richardson

Theses and Dissertations

In October of 1964 the Topographic Branch of the United States Geological Survey reported difficulties in using magnetic compasses while mapping in the areas of Akra and Hensel, Pembina County, North Dakota. University of North Dakota geologists located anomalies of 67,500 gammas 1.6 lon east of Akra and 71,500 gammas 4 km east of Hensel, the normal magnetic field in this area being about 60,000 gammas. The rock bodies producing the magnetic anomalies were drilled and examination of diamond drill core showed them to consist of oxide and silicate facies iron formation interlayered with quartz-biotite schist of Precambrian age. The …

Quaternary Geology Of The Southern Part Of The Grand Forks And Bemidji Quadrangles, Donald K. Sackreiter

Theses and Dissertations

Northwestern Minnesota is an area at the southwestern edge of the Canadian Shield that is mantled by thick Pleistocene sediment. The Pleistocene material included a variety of glacial, shoreline, offshore, fluvial, and eolian sediment.

The lithology of the glacial sediment reflects the rock and sediment over which the depositing glacier flowed. Glaciers that advanced from the northeast (Canadian Shield) deposited sandy, granitic-rich material. Glaciers that advanced from the north· (Manitoba Lowland) deposited loamy, calcareous-rich material. Glaciers that advanced from the northwest (eastern North Dakota and southwestern Manitobal deposited clayey, shale-ridt material. A variety of fluvial and lacustrine sediments are typically …

Petrology And Geochemistry Of The Killdeer Carbonates, John J. Delimata

Theses and Dissertations

The strata of the proposed Killdeer Formation (Stone, W. J., 1972) in the Killdeer Mountains of Dunn County, North Dakota is composed of a sequence of tuffaceous, calcareous, dolomitized and silicified flat lying sedimentary rocks of Tertiary age. It is the purpose of this report to describe and integrate the petrology and geochemistry of these sediments.

Fieldwork was conducted during the summer of 1972. Forty-three stratigraphic sections were measured and representative samples of each were collected for further analysis. Seven section were selected as representative of the area, and samples from these were studied in thin section with the petrographic …

The Historical Development Of Wasatch Trails In Salt Lake County, Clyde Brian Hardy

Theses and Dissertations

In this study investigation was made concerning the etiology of the foot trails that thread their way through Wasatch Forest lands in Salt Lake county. The time delimitation was 1847 to 1975.

The origin of the majority of these trails dates back to the nineteenth century and is closely tied to the efforts of pioneers who labored to wrest a living from semi-arid land. Early lumbering, livestock operations, mining activities, water collection systems, and pioneer recreation all provided impetus for trail development. In a sense these trails are a kind of anthology of human endeavor.

Passing into the twentieth century …

Stratigraphy Of Offshore Sediment Of Lake Agassiz, North Dakota, Michael B. Arndt

Theses and Dissertations

Lake Agassiz occupied the Red River Valley between about 13,800 and 9,000 years ago. The Late Wisconsinan ice sheet that covered the Red River Valley retreated far enough to expose the drainage divide in northern South Dakota and south-central Minnesota sometime after 14,000 B.P. and meltwater ponded behind this divide in Richland County. Before 13,800 the ice readvanced over this area and then retreated again. As the ice margin retreated northward, deposition of the Argusville and Wylie Formations took place. Sometime before 12,800 the ice advanced again into the Red River Valley as far as Traill County; the terminus of …

Natural Science Of The Great Plains As It Relates To The American Indian : A Syllabus And Sourcebook, Mary E. Bluemle

Theses and Dissertations

This dissertation, which includes a sourcebook of pertinent reference materials, sample lesson plans, and natural science roadlogs, is an initial attempt at providing an Indian Studies field course in natural science. It also includes a syllabus which stresses natural science processes and serves as a unifying factor for field work, lecture, and course discussions. The dissertation stresses geographical and ecological concepts, climatic and geological processes, and the natural habitats of North Dakota. It includes discussions of North Dakota vertebrates and early man and his relation to his environment; discussions of_ the geologic features, geologic history, vegetation and animal life of …

Pleistocene Geology Of The Grand Forks-Bemidji Area, Northwestern Minnesota, Kenneth L. Harris

Theses and Dissertations

This is a report of a reconnaissance study of the Quaternary geology of an area in northwestern Minnesota. Surface geology was studied in an area extending from Grand Forks, North Dakota, in the northwest to Bemidji, Minnesota, in the southeast, an area of 10 723 square kilometres (4140 square miles). Near-surface stratigraphy was studied in the area of surface study and an adjacent area of equal size to the south.

Surface materials mapped range in age from Pleistocene to Holocene and include glacial, glaciofluvial, lacustrine, bog, eolian, and alluvial sediments.

Sixteen power-auger test holes, two measured sections along the Red …

Stratigraphy Of The Upper Part Of The Fort Union Group In Southwestern Mclean County, North Dakota, Leroy A. Hemish

Theses and Dissertations

Southwestern McLean County is an area characterized by glacial topography and glacially-modified bedrock topography, with limited exposures of bedrock. Outcropping bedrock formations include the Cannonball, Tongue River, and Sentinel Butte Formations, all in the Fort Union Group of Paleocene age.

The Cannonball Formation crops out only in the southeastern part of the area studied (at Washburn), where 18 feet of laminated, gray-brown sandy mudstone is exposed. A yellow-brown, cross-bedded sand unit directly overlies the mudstone. I have tentatively selected the base of this sand unit, which is present in the subsurface throughout southwestern McLean County and reaches thicknesses of more …

Glacial Stratigraphy Of Northeastern North Dakota, Howard Hobbs

Theses and Dissertations

Seven lithostratigraphic units (formations} composed dominantly of glacial sediment have been recognized in northeastern North Dakota. Three formations, the Falconer Formation (Harris and others, 1974}, the Dahlen, and Gardar Formations (Salomon, 1975). Have been previously recognized. Four formations, the Hansboro, Vang, Tiber and Cando Formations are newly recognized. Uncorrelated units of glacial sediment are described but not named. The formations are differentiated and correlated primarily by the proportion of crystalline (igneous and metamorphic rock fragments), carbonate, and shale grains in the coarse sand fraction (1 to 2 mm) of the glacial sediment. The proportion of shale grains was. Found to …

The Purification And Characterization Of Methylmalonyl Coa Mutase From Bovine Brain, Damon Martin

Theses and Dissertations

Methylmalonyl CoA mutase has been purified over 2300-fold from bovine brain using fractional precipitation, ion exchange resins, and gel filtration procedures. The crude extract had an equal mixture of mutase in the halo- and apoenzyme form. After the final purification step the ratio had changed to 86% holo-enzyme and 14% apoenzyme. The mutase enzyme had a pH optimum of 7. 0 in Tris-HCI buffer. The Km values for L-methylmalonyl CoA and succinyl CoA were 7.7 x 10^-4 M and 1.8 x 10^-4 M respectively. The equiIibrium constant in the direction of succinyl CoA formation was 19. Inhibition with N-ethylmalei-mide was …

The Attack Of Hard And Soft Nucleophiles On 6-Methylsulfonyl-, 6-Methylsulfinyl-, And 6-Methylthioaminopteridines, William David Johnston

Theses and Dissertations

In an attempt to prepare 6-anilino and 6-benzylaminopteridines, 2,4,7-triamino-6-methylsulfonyl and 2,4,7-triamino-6-methylsulfinylpteridines were prepared and reacted with a number of benzylamines and aniline. These hard nucleophiles gave amine exchange products with no displacement at the 6 position. Aliphatic amines gave exchange in the 2,4-and 7-positions. The exchange occurring in the 7-position must be occurring by an AE mechanism. This is the first such exchange reported in a ring other than a 1,3-azine. Aniline gave no exchange product except in an acid catalyzed reaction, and then gave exchange in only the 2 and 4-positions. Numerous reactions on related substrates, are reported. Soft …

Thermodynamic Stability Constants Of Silver Bromide Complexes In Water And Water-Acetone Mixtures Determined By Ion-Selective Electrode Measurements, Arthur Lee Cummings

Theses and Dissertations

Thermodynamic equilibrium constants for silver(I) bromide complexes were determined by ion-selective membrane electrode potential measurements in water and in mixtures of water and acetone of approximately 5, 10 and 15 percent acetone by weight. Values of the solubility product constant were determined in each solvent system by calibration of a silver bromide membrane electrode with silver nitrate solutions and with sodium bromide solutions. Stability constants of silver(I) bromide complexes were determined using a silver ion-selective, silver sulfide membrane electrode in unsaturated solutions in which the formal concentrations of silver(I) and of bromide ranged from approximately I x 10-8 to 7 …

The Benthic Communities Of The Eastern Rocky Shore Areas Of Goshen Bay, Utah Lake, Thomas Whitney Toole

Theses and Dissertations

Information about the benthic macroinvertebrate populations along the eastern shore of Goshen Bay, Utah Lake, Utah, can be used, in part, to determine future management of the lake. In the project herein reported, cement artificial substrate samplers were used to sample two types of substrate: rubble and compacted calcareous tufa. Monthly samples were obtained from each type of substrate from March 1972 to May 1973. An amphipod, Hyalela azteca and a chironomid, Dicrotendipes fumidus were the dominant organisms in numbers and tiomass. Amphipod numbers were dependent upon the amount of algal standing crop. Elimination of this area could affect the …

Metabolism Of 3-Isopropyl-4h-2,1,3-Benzothiadiazin-4-(3h)-One-2,2-Dioxide (Bentazon) In Agitated And Non-Agitated Sediment, David Cortez Gutierrez

Theses and Dissertations

Bentazon, (3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-l-2,2-dioxide) a new experimental herbicide, was studied under the effects of sterile and non-sterile conditions, 12 hours light: 12 hours dark and totally dark conditions, and agitated and non-agitated conditions in aquatic sediment. The effects of the different levels of BOD/COD values on the decomposition of Bentazon were studied. Photoperiod, sterility, and BOD/COD levels appeared to have no influence in the breakdown of Bentazon. Agitation-time interaction appeared to be the only factor that influenced the more rapid degradation of Bentazon. Bentazon was the major 14C-residue found in the water; it was followed by an unknown. The third major metabolite …

Part I. Catalytic Hydrocarbon Reforming By Technetium Catalysts.|Npart Ii.|Pacetone Azine And 3,5,5-Trimethyl-2-Pyrazoline Adducts Of Palladium Chloride, James Lynn Palmer

Theses and Dissertations

Technetium catalyzes hydrocarbon reforming reactions of dehydrocyclization, isomerization, hydrogenolysis, and coke formation. A kinetic equation was derived and E_a and A_o evaluated for dehydrocyclization of n-heptane, isomerization of n-pentane, and dehydrogenation of methylcyclohexane and cyclohexane. The results were related to the metal, the form of the catalyst, catalyst support, and the deactivation of the catalyst. The effect of sulfur compounds was determined. No residual radioactivity in the product was observed. The ligands, acetone azine (AA) and 3,5,5-trimethyl-2- pyrazoline (Py), reacted with (C_6H_5CN)_2PdCl_2 to form adducts, L_2PdCl_2 and (LPdCl_2)_n. Their structures were characterized by spectroscopic methods and some molecular weights determined. …

A Remote Aerosol Sampler To Be Used With Charged-Particle X-Ray Fluorescence Analysis, Steven Dee Rowley

Theses and Dissertations

A remote aerosol sampler, capable of up to 3 weeks continuous sampling has been developed. It consists of an Anderson 2000 Inc. mini-sampler or personnel monitor requiring an air flow of 1.4 e/min, a flow meter, a vacuum meter, a bleed valve, a dry gas volume meter, and a pump. The pump is a Brailsford Model TD-4X2, and operates on a 24 volt D.C. power supply. The sampler consists of four impaction stages with a 0.4 μ Nuclepore backup filter. Particulates are removed from the plates in an ultrasonic cleaner with hexane solvent. The suspended particulates are collected on a …

A Calorimetric Study Of Metal Binding In Carboxypeptidase, Carbonic Anhydrase And Concanavalin A, Gary E. Hatch

Theses and Dissertations

The purpose of this study was to perfect a new calorimetric method for identifying and counting ionizable chemical groups on proteins. To do this, calorimetric and electrometric titrations were performed (using HCl and NaOH as titrant) on native carboxypeptidase, carbonic anhydrase and concanavalin A plus their apo and organic ligand bound derivatives. Readily identifiable endpoints were seen in the calorimetric titrations and general agreement was found between ΔH values obtained in this study and literature ΔH values of model compounds undergoing the same reaction. Imidazole groups were those most easily counted. Many assumptions had to be made, however, in concluding …

The Solution Photochemistry Of Benzaldehyde In Benzene, Ethanol, And 1-Hexyne, Ronald Douglas Knudsen

Theses and Dissertations

The photoreactions of benzaldehyde in benzene, ethanol, and 1-hexyne have been studied. Irradiation of benzaldehyde in benzene produces benzoin (I), hydrobenzoin (II), and deoxybenzoin (III). Irradiation of benzoin (I) in this solvent results in benzaldehyde formation as well as small amounts of (II) and (III). The ethanol irradiation of benzaldehyde resulted, predominantly, in the formation of (II) with (I) formed in small amounts. The photolysis of benzaldehyde in 1-hexyne produces (I), (II), (III) cis-2-heptenophenone (VII), trans-2-heptenophenone (VIII), heptanophenone (IX), and 2-(n-butyl)- 1,4-diphenyl-1,4-butanedione (X). Mechanistic pathways for the formation of these photoproducts are discussed. Separation and characterization of cis- and trans-2- …

Trace Metal Analysis Of Hair By Charged Particle X-Ray Fluorescence, George M. Allison

Theses and Dissertations

A method for the trace element analysis of hair by charged particle X-ray fluorescence is presented. The validity of the method is shown by the analysis of NBS SRM 1577--Bovine Liver, obtained from the National Bureau of Standards. Excellent correlation is obtained between results from the analysis by the X-ray method and those certified by NBS. Hair samples are ashed by a low temperature oxidation process and analyzed by the X-ray method. The results from the analysis by the X-ray method are compared to those obtained from the analysis of the same hair samples by atomic absorption. Good correlation is …

Macrocyclic Polyether Sulfide Syntheses, The Preparation Of Thia-Crown-3, 4, 6, And 7 Compounds, Yau-Kwong Joseph Hui

Theses and Dissertations

Macrocyclic polyether sulfides have been prepared by reacting an oligoethylene glycol dichloride with a dithiol or sodium sulfide in ethanol. The following new compounds were prepared: 1-thia-(9-crown-3), 1,4-dithia-(9-crown-3), 1,4-dithia-(12-crown-4), 1,4,7-trithia-(12-crown-4), 1-thia-(18-crown-6), I,4-dithia-(18-crown-6), 1,7-dithia-(18-crown-6), 1,4,7-trithia-(18-crown-6), 1,7-dithia-(21-crown-7), 1,4,7-trithia-(21-crown-7). Four other previously reported macrocyclic polyether sulfides were also prepared. The symmetry of the nmr spectra of these compounds give added evidence for the proposed ring structures. The following subjects were presented and discussed: studies of cyclization by-products, dependence of cyclization yield on the size of the rings, high dilution principle and its application, medium-sized rings, effect of hetero-atoms on cyclization and melting point …

The Mormon Role In Irrigation Beginnings And Diffusions In The Western States: An Historical Geography, Kelly C. Harper

Theses and Dissertations

Irrigation has played an important part in the development of the Western States. Its beginnings have often been associated with the Mormon settlement in Utah. However, irrigation had its inception in the West long before the Mormons came to the Great Basin in 1847. The spatial extent of irrigation before this date included limited acreage in nearly every Western State.

Before their arrival in the Great Basin the Mormons had become acquainted with irrigation methods. Knowledge of irrigation had diffused to them primarily from the Spanish in the Southwest. Thus, they were well prepared to begin their irrigation enterprises in …

The Foraminiferids Of The Cannonball Formation (Paleocene, Danian) And Their Paleoenvironmental Significance : Grant, Morton And Oliver Counties, North Dakota, William E. Fenner

Theses and Dissertations

Two hundred-forty samples (of which fifty-five contained micro fossils) were collected from six measured sections in the Cannonball Formation (Paleocene, Danian) in Grant, Morton and Oliver Counties, North Dakota. Twenty-six species of benthonic foraminiferids were identified from these samples: 6 textulariines, 2 miliolines and 18 rotaliines. No planktonic foraminiferids were found. The fauna is characterized by a predominance of individuals of textulariines, especially the lituolids. Although the Cannonball Formation is characterized by an alternating sequence of sandstones and mudstones> the foraminiferid fauna was restricted to the mudstone facies in the upper and upper-middle part of the formation. Two characteristic assemblages …

The Physical And Petrographic Characteristics Of Formcoke Produced Experimentally From Lignite And Subbituminous Coal, Bruce L. Ramsey

Theses and Dissertations

Formcoke was produced experimentally from a North Dakota lignite and a Wyoming subbituminous coal. The effect of initial charring tem perature (600°C or 900°C), of char grain size (less than 18 mesh, less than 35 mesh, or less than 60 mesh), of briquetting pressure (1000, 2000, 3000, 4000, 5000, 6000, 7000, 8000, 9000 or 10,000 psi) of binder percentage (5, 10, 15, 20 or 25 per cent), and of final carbonization heating rate (18°C/:min, 12°C/min or 6°C/min) on formcoke briquet com pressive strength was studied.

A final carbonization heating rate of 6°C/min produced uniform shape briquets. Rates of 12°C/min and …

A Mechanical Well Log Study Of The Popular Interval Of The Mississippian Madison Formation In North Dakota, C. W. Cook

Theses and Dissertations

The Poplar interval of interbedded evaporites and carbonates forms the uppermost part of the Mississippian Madison Forr.1ation in western North Dakota. A detailed mechanical well log study of the Poplar interval in North Dakota was conducted to interpret the Poplar's regional geology and to attempt to locate areas with potential for petroleum production. Limestone, dolomite, anhydrite and salt were differentiated using mechanical well logs.

The complex facies of the Madison are subdivided into para-time rock units (the Poplar interval is one) on the basis of extensive thin anhydrite beds which are considered time-parallel.

The base of the Poplar interval is …

Paleontology Of Brackish-Water Faunas In Two Tongues Of The Cannonball Formation (Paleocene, Danian), Slope And Golden Valley Counties, Southwestern North Dakota, James B. Van Alstine

Theses and Dissertations

In June and July, 1972, four stratigraphic sections were mea sured and described in Slope and Golden Valley Counties, southwestern North Dakota. Within the sections, the Cannonball and Ludlow Formations are recognized. The Cannonball consists of two tongues in the upper part of the Ludlow (perhaps equivalent to the Lebo Member), separated stratigraphically by about 30 roof Ludlow. The U tongue (upper tongue in the study area) is up to 11. 7 m thick. The L tongue (lower tongue. in the study area) is up to 3.8 m thick. The Cannonball is composed mostly of mudstones and the Ludlow consists …

State Of Bacterial Dna After Uptake Into The Roots Of Germinating Barley Seeds, Larry Dale Lawson

Theses and Dissertations

Germinating barley seeds have been shown to take up Bacillus subtilis DNA labelled with 5-bromouracil and tritiated thymidine and retain the DNA in the root system without substantially degrading it. The percentage of bacterial DNA recovered from the total root DNA was independent of the amount of bacterial DNA available for uptake. Four observations indicated the stability of bacterial DNA after uptake into barley roots: (1) the bacterial DNA retained its transforming ability after recovery from the roots; (2) the labelled B. subtilis DNA showed similar CsCl density gradient patterns before uptake and after uptake; (3) most of the radioactivity …

I. An Isothermal Titration Microcalorimeter. Ii. Importance Of Micronutrients In Nutrition. Iii. Zinc Bibliography, John Willard Gardner

Theses and Dissertations

I. An isothermal titration microcalorimeter having a colume of 4 ml and capable of temerature control to ±2 x 10-5°C is described. Major components include a constant temperature water bath controlled to ±3 x 10-4°C, a platinum reation vessel, and an isothermal control circuit consisting of constant Peltier thermoelectric cooling and variable Joule heating controlled by a thermistor in an AC Wheatstone bridge circuit. The calorimeter was tested by measuring the heat of ionization of water and was found to produce data accurate to ± 0.1% where small samples are used such as in the investigation of many biological systems.

Reactions Of N₂F₄ And Sf₆ With H₂ Induced By Co₂ Laser Pulses And By Electrical Discharge, John Leslie Lyman

Theses and Dissertations

A high power pulsed CO_2 laser was used to induce reactions in gas mixtures containing either N_2F_4 or SF_6. The rate of laser induced dissociation of N_2F_4 to NF_2 was as much as 1000 times faster than the thermal rate, and the rate law was of lower order than the thermal, bimolecular rate law. Explosion threshold and induction time data were obtained for butene stabilized mixtures of N_2F_4 and H_2. HF laser gain was observed during the first few microseconds of CO_2 laser pulse, but it was strongly quenched by the explosion. The laser driven reaction of SF_6 with H_2 …

Development Of Standard Procedures For Determination Of [Delta]G° (K), [Delta]H° And [Delta]S° Values Via Potentiometric And Calorimetric Titration Techniques, Jack Hugh Ruckman

Theses and Dissertations

Standard computer techniques were developed for computation of ΔG° values from potentiometric titration data and ΔH° values from calorimetric titration data. The procedures developed can be used for any systems having the general equations HA = W^+ + A^- ; H_2A = 2H^+ + A^2- ; and H_3A = 3H^+ + A^3-, where the proton ionizations may be consecutive or simultaneous. The thermodynamic values ΔG°(K), ΔH° and ΔS° were determined for the ionization of protons from the protonated compounds methionine (-NH_3^+ group only), phosphoethanalomine and phosphoserine. The compounds studied were selected because they contain one, two and three ionizable protons …