Physical Sciences and Mathematics Commons^™

Literature Review Nature-Based Art Therapy Exploring Connections And Relationships, Janell Lopez-Curtis

Expressive Therapies Capstone Theses

Art therapy is a modality used in clinical psychotherapy. It is supported through both quantitative and qualitative research. Branching out from art therapy is nature-based art therapy. This branch of expressive therapies holds the potential to be beneficial as art therapy due to the interconnected access to the scientific fields of ecology, ecopsychology, art therapy, expressive therapies, and other nature-based therapeutic activities; this includes intersectionality in ecological theories such as ecofeminism and deep ecology as well. Through an exploration of literature, this paper will provide definitions and theory-based support through reviewing clinical psychotherapy, evidence-based practices, and art therapy theories. The …

Development Of Stochastic And Time-Dependent Quantum Chemical Methods For Accurate Description Of Light-Matter Interactions With Applications In Photoionization And Inverse Photoemission In Nanomaterials, Nicole Spanedda

Dissertations - ALL

There are three main focuses of this work. First, the theoretical details of the Stratified Stochastic Enumeration of Molecular Orbitals (SSE-MO) method is presented, along with its application for calculating ionization potentials (IPs) of quantum dots. The SSE-MO method can readily be applied for the purpose of efficiently and accurately calculating ionization potentials, by constructing the frequency-dependent self-energy operator and then subsequently, solving the associated Dyson equation. Constructing the frequency-dependent self-energy operator is challenging because the scaling of the computational cost with respect to system size, becomes prohibitive for large systems, such as quantum dots. This is due to the …

Construction Of Quot-Schemes, Majid Dehghani

Electronic Theses and Dissertations

The Quot Scheme is a construction representing parameter spaces for quotient objects of sheaves or coherent modules over a scheme. It encapsulates families of quotients by fixing a certain quotient's structure. The Hilbert Scheme, a specific type of Quot Scheme, focuses on parameterizing subschemes of a fixed projective space by fixing their Hilbert polynomials. After recalling the basic concepts of the theory, we explain the Grothendieck’s Quot scheme construction and its Grassmannian embedding. Then we continue to an explicit construction of Quot scheme in the case of graded modules over graded rings.

A Target-Based And A Targetless Extrinsic Calibration Methods For Thermal Camera And 3d Lidar, Farhad Dalirani

Electronic Thesis and Dissertation Repository

This thesis introduces two novel methods for the extrinsic calibration of a thermal camera and a 3D LiDAR sensor, which are crucial for seamless data integration. The first method employs a distinctive calibration target, leveraging lines and plane equations correspondence in both modalities for a single pose, and incorporating more poses by matching the target's edges. It achieves reliable results, even with just one pose yielding 10.82% translation and 0.51-degree rotation errors. This outperforms alternative methods, which require eight pairs for similar results. The second method eliminates the need for a dedicated target. Instead, by collecting data during the sensor …

Luminescent Group 11 Metal (I) Chalcogen Clusters With A Conjugated Diphosphine Ligand, Kai Yu Jeffrey Li

Electronic Thesis and Dissertation Repository

Polynuclear Au (I) complexes exhibit rich photochemical properties and have the potential to find applications as molecular sensors, switches, or energy storage devices. Although dinuclear Au (I) complexes with bridging diphosphines have been extensively examined, most of those reported do not contain rigid-diphosphine ligands.

This thesis examines how the rigid diphosphine, 4,6-bis(diphenylphosphino)dibenzofuran (DBFDP) can be incorporated for the controlled assembly of photoluminescent gold (I) metal – chalcogenolate (chalcogenolate = RS^-, RSe^-; R = organic moiety) and gold (I) chalcogenide (chalcogenide = S^2-, Se^2-) bimetallic complexes. In these studies, the chalcogen …

If You Build It, Will They Come? Assessing Habitat Quality For Marsh Birds At Created Marshes In Southeastern Louisiana, Katherine Aylett Lipford

LSU Master's Theses

Wetland loss occurs at an alarming pace globally, with extremely high rates along the northern Gulf of Mexico. Louisiana loses a football field of wetland every 100 minutes: that is 77,000 m² of wetland bird habitat lost daily. In Louisiana, marsh creation projects combat wetland loss, and while wildlife habitat is often used as a justification for restoration, wildlife receives little to no consideration during and after construction. Habitat characteristics such as site-specific hydrology, vegetation composition, and habitat structure affect the abundance of wetland birds and understanding these features is crucial to creating habitat that will benefit birds. My …

Exploring The Reactivity Of Metal-Ligand Cooperative Complexes With Dioxazolones, Terminal Alkynes, And 2-Ethynylbenzyl Alcohol, Megan A. Hoffer Miss

Electronic Thesis and Dissertation Repository

N-Acyl ketenimines were attempted to be synthesized catalytically by [Ru(Cp)(P^Ph₂N^Ph₂)(NCMe)]PF₆ with phenylacetylene and 3-phenethynyl-1,2,4-dioxazol-5-one. Trapping agents were employed to identify the major product of the reaction, as many products were formed. [Ru(Cp)(P^Ph₂N^Ph₂)(NCMe)]PF₆ reacts with 3-phenethynyl-1,2,4-dioxazol-5-one generating an isocyanate via the Curtius rearrangement, confirmed by a forced Curtius rearrangement with 3-phenethynyl-1,2,4-dioxazol-5-one and 1,2,4-triazole. Rates of vinylidene formation using [Ru(Cp)(P^Ph₂N^Ph₂)(NCMe)]PF₆ and various terminal alkynes of different sterics and electronics were evaluated using a Hammett analysis for and simple rate comparisons. …

The Shifting Landscape Of Adolescent Wellness In Boarding Schools: Can Time Spent Off Screens And Outdoors Improve Adolescent Wellbeing?, Kristen H. Peterson

Dartmouth College Master’s Theses

For nearly twenty years I have worked directly with adolescents as an independent school educator. Whether in the classroom, on the field, or in the dorm, I have observed and supported students through their middle and high school experiences. During this time, I have witnessed an alarming shift in adolescent physical, emotional, and social wellbeing. Concurrently, I have observed a dramatic increase in the amount of time students spend using screen-based devices, and a decrease in their time spent outdoors.

Using research to ground my anecdotal accounts in empirical understanding, my thesis examines whether or not screen use might help …

Knowledge Informed Fake News Detection Using Large Language Models, Jess Joseph Joseph Benny

Electronic Theses and Dissertations

The spread of false or misleading information as news has been a significant threat to governments, organizations and the economy for a long time. However, it has become more prevalent and influential in recent years due to the growing popularity of social media, which is now the primary source of information for more than half of the world’s population. Detecting fake news used to rely mostly on statistical and linguistic analysis of texts, but with the advancement of AI and computer-assisted writing tools, fake news authors can now deceive statistical models. Therefore, more sophisticated methods that use document representations from …

Open System Neural Networks, Bradley Hatch

Theses and Dissertations

Recent advances in self-supervised learning have made it possible to reuse information-rich models that have been generally pre-trained on massive amounts of data for other downstream tasks. But the pre-training process can be drastically different from the fine-tuning training process, which can lead to inefficient learning. We address this disconnect in training dynamics by structuring the learning process like an open system in thermodynamics. Open systems can achieve a steady state when low-entropy inputs are converted to high-entropy outputs. We modify the the model and the learning process to mimic this behavior, and attend more to elements of the input …

On A Class Of James-Stein’S Estimators In High-Dimensional Data, Arash Aghaei Foroushani

Electronic Theses and Dissertations

In this thesis, we consider the estimation problem of the mean matrix of a multivariate normal distribution in high-dimensional data. Building upon the groundwork laid by Chételat and Wells (2012), we extend their method to the cases where the parameter is the mean matrix of a matrix normal distribution. In particular, we propose a novel class of James-Stein’s estimators for the mean matrix of a multivariate normal distribution with an unknown row covariance matrix and independent columns. Given a realistic assumption, we establish that our proposed estimator outperforms the classical maximum likelihood estimator (MLE) in the context of high-dimensional data. …

Boat Wake Attenuation Through Artificial Vegetation - A Case Study From Peche Island, Jamie Kathryn Lilly

Electronic Theses and Dissertations

The use of nature-based solutions and engineering ideas has sparked interest in the value of vegetated shorelines for protecting against erosion. However, there is a lack of field data, and more research is needed to understand how effective vegetation is in reducing the impact of wind waves and boat wakes. The difference in period between wind waves and boat wakes suggests that they may be attenuated differently, requiring further study to determine the optimal management design. The purpose of this study is to quantify the ability of artificial vegetation to attenuate boat wakes and calculate the drag coefficient for model …

Dynamic Metal-Ligand Interactions In Semiconducting Π-Conjugated Materials, Peter Blake Joseph St Onge

Electronic Theses and Dissertations

Over the years, the development of materials has seen a vast amount of expansion into a variety of disciplines which have demonstrated usefulness in a large span of applications. One of these new and developing themes is the use of metals and ligands which are incorporated into polymers to modify their properties, which can enable different desired properties. Incorporation of metal-ligand complexes in materials chemistry has proven to be an area of rising interest, however, many of these interactions and systems remained completely unexplored. Understanding the key fundamental principles of how these materials can be changed and modified through metal-ligand …

Adaptive Model Selection In Stock Market Prediction: A Modular And Scalable Big Data Analytics Approach, Mohammadehsan Akhavanpour

Electronic Theses and Dissertations

In today's globalized economy, financial markets are more interconnected than ever, generating vast amounts of data from thousands of sources every second. The need to accurately analyze and interpret this data is crucial for investors, analysts, and researchers alike. Traditional models for market prediction are limited by their ability to adapt to the real-time nature and 'big data' dimensions of these complex financial datasets. To address these challenges, this thesis proposes and implements a novel framework that combines Apache Kafka with a microservices framework. This framework offers a scalable, real-time solution for financial market prediction that effectively manages the 5Vs …

Stimulated Raman Spectroscopy With Widely Tunable Probe Pulse For Measuring Dissolved Inorganic Phosphorus In The Great Lakes, Nathan Gregory Drouillard

Electronic Theses and Dissertations

The eutrophication of freshwater ecosystems remains a persistent global problem threatening biodiversity, drinking water, and economic interests. Among the Laurentian Great Lakes, Lake Erie is most severely impacted by eutrophication, experiencing annual harmful algal blooms that are thought to result from excess phosphate deposition into the ecosystem. Efforts to study and mitigate the effects of eutrophication require accurate monitoring of phosphate concentrations. The current method for measuring phosphate, the molybdenum blue method, suffers from signal interference. In this thesis, I recommend Raman spectroscopy as a label-free, reagent-free spectroscopic technique for accurately measuring phosphate in freshwater. I verify the Raman spectrum …

Medicinal Mushrooms: The Extraction And Analysis Of Bioactive Compounds From Hericium Erinaceus And Ganoderma Lucidum Mushrooms., Jhanielle Amanda-Kaye James

Electronic Theses and Dissertations

Medicinal mushrooms, such as Hericium erinaceus (lion's mane) and Ganoderma lucidum (reishi), have a rich history of traditional use in natural remedies, garnering attention for their bioactive compounds and nutritional benefits. Renowned for being protein-rich and low in fat, these fungi exhibit antimicrobial, anti-tumor, antioxidant, anti-diabetic, and anti-hypercholesterolemic properties attributed to their diverse bioactive components, including polysaccharides, proteins, terpenes, sterols, vitamins, polyphenols, and fatty acids. This study aimed to optimize extraction techniques, comparing maceration, ultrasound-assisted maceration, and Soxhlet extraction on fresh and dried lion's mane and reishi mushrooms. Varying solvent polarities and extraction times revealed that 8-hour extractions with dried …

Quantifying Survival And Behaviour Of Hatchery-Reared Juvenile Bloater Stocked Across Bathymetric Depths In Lake Ontario, Lydia L. Paulic

Electronic Theses and Dissertations

Over 20 million native and non-native fishes are stocked into the Great Lakes annually as part of restoration initiatives and to support commercial and recreational fisheries. Bloater (Coregonus hoyi), a deep-water planktivore that was extirpated from Lake Ontario in the 1980s, has been consistently stocked in the lake since 2012 by Canadian and American natural resource agencies with the goal of producing a self-sustaining population. Previous research has highlighted challenges with stocking such as poor survival, attributed to high predation, potential maladaptive behaviour and barotrauma resulting from introducing a hatchery-reared species into a foreign environment. To address these survival challenges, …

Study Of Dusty Torus In The Vicinity Of Active Supermassive Black Holes, Arya Sudhakaran

University Departments

No abstract provided.

Study Of Soalr Atmospheric Heating Due To Active Regions, Munjiba M. M

University Departments

No abstract provided.

Determination Of Thermal Neutron Capture Cross Sections Of Cerium Isotopes, Samrudhi R. Kanjarpane

University Departments

No abstract provided.

Statistical Consulting In Academia: A Review, Ke Xiao

Major Papers

This paper reviews the state of statistical consulting in academia by performing a literature review on this topic in chapters 1 and 2. Chapter 1 overviews general aspects of statistical consulting and types of centers that conduct such services in academia. In Chapter 2 we summarise the literature about the common logistics and processes for conducting statistical consulting in academia. In Chapters 3 and 4, we analyze data on statistical consulting centers for the largest 100 universities in the USA. We also review the literature on the future of statistical consulting in academia in the era of big data and …

Fish Assemblage Structure In Great Lakes Coastal Wetlands Over Ten Years, Matthew S. Silverhart

Masters Theses

Coastal wetlands in the Laurentian Great Lakes are important habitats for many fish species. The geographic scale of the watershed and the diversity of land uses in the region result in substantial environmental variation among coastal wetlands. During 2011-2020, annual surveys were conducted as part of the Great Lakes Coastal Wetland Monitoring Program (GLCWMP) to better understand the status and trends of coastal wetlands. Fish sampling consisted of fyke netting in monodominant vegetation zones. During this time, 1225 unique monodominant plant zones in coastal wetlands were sampled, resulting in 584,125 fishes captured that consisted of 113 different species. Yellow Perch …

The Sudden Escalation In Average Fastball Velocity: A Biomechanical And Cost-Benefit Analysis, Jacob Meiners

Capstone Projects

Average fastball velocity throughout Major League Baseball has increased dramatically over the previous 15 years. This research examines the factors leading to this increase and provides a cost-benefit analysis to determine whether throwing consistently at high velocities is worth the injury risks, compared to financial benefits, from the player perspective. Additionally, this analysis examines if paying hard-throwing pitchers is worth the monetary risk from a team executive’s perspective, due to increases in leaguewide throwing injury rates. The production of advanced motion capture technology to obtain real-time biomechanical data has given way to the optimization of pitchers’ biomechanics, with the goals …

Investigating The Roles Of Plants, Fungi, And Biocrusts In Nutrient Movement Within Dryland Ecosystems, Catherine E. Cort

Open Access Theses & Dissertations

In dryland ecosystems, plant productivity and microbial decomposition are often separated in space and time due to the asynchronous availability of soil moisture and organic matter inputs. It has been proposed that fungi play a key functional role in connecting these cycles by facilitating movement of water, carbon (C), and nitrogen (N) through a network of shared hyphae between plant roots and biological soil crust (biocrust) communities at the soil surface. This connection, also known as the â??fungal loop,â?? effectively re-couples processes of nutrient release and uptake between primary producers and minimizes ecosystem N losses due to leaching, erosion, and …

Outpatient Fall Prevention In Ambulatory Adults 65 Years Old And Over, Dorothy L. Osborne-White

Doctor of Nursing Practice (DNP) Scholarly Projects

Abstract

Background: In the United States (U.S.), falls are the leading cause of injury among adults 65 and over, resulting in 36 million falls yearly (Moreland et al., 2020). According to the Centers for Disease Control and Prevention (CDC, 2023), one in four older adults experiences a fall each year. Falls are the world's second most prominent cause of accidental deaths (World Health Organization [WHO], 2021). Falls are the leading cause of both fatal and non-fatal injuries among older adults (Moreland et al., 2020).

Methods: A quality improvement project that included a fall bundle was implemented in a primary clinic. …

Mitigating Safety Issues In Pre-Trained Language Models: A Model-Centric Approach Leveraging Interpretation Methods, Weicheng Ma

Dartmouth College Ph.D Dissertations

Pre-trained language models (PLMs), like GPT-4, which powers ChatGPT, face various safety issues, including biased responses and a lack of alignment with users' backgrounds and expectations. These problems threaten their sociability and public application. Present strategies for addressing these safety concerns primarily involve data-driven approaches, requiring extensive human effort in data annotation and substantial training resources. Research indicates that the nature of these safety issues evolves over time, necessitating continual updates to data and model re-training—an approach that is both resource-intensive and time-consuming. This thesis introduces a novel, model-centric strategy for understanding and mitigating the safety issues of PLMs by …

Recent Paleolimnological History Of Jackson Lake, Grand Teton National Park, Wyoming (Usa), Hillary Johnson

Theses and Dissertations--Earth and Environmental Sciences

This study utilizes a recently acquired, high-resolution CHIRP seismic reflection dataset and a deepwater sediment core to analyze the recent stratigraphy of Jackson Lake (Wyoming, USA). The western shoreline of Jackson Lake is situated adjacent to the Teton fault, a down-to-the-east normal fault that produces the spectacular high topography of Grand Teton National Park. The sediments of Jackson Lake are underexplored and consequently, their value as indicators of hydroclimatic and tectonic changes is unknown. Here, the sedimentary fill of Jackson Lake is explored as a natural archive of environmental change, specifically in reference to the influence of human outlet engineering …

(Meta-)Physical Artworks: Digital Augmentation In Art Observation, Macy A. Toppan

Dartmouth College Master’s Theses

Augmented art— the subgenre of art that incorporates physical and digital artwork— is a rapidly growing field driven by advancing technology and a new generation for whom that tech is a given. Yet the presence of media like augmented and virtual reality in exhibition remains a controversial subject. Rather than focusing on the many theoretical debates about whether digital pieces can qualify as "good" art, we study it in practice through the eyes of the casual art observer. This paper highlights the audience in a within-participant study that asked viewers to take in a physical sculpture intentionally built with virtual …

Judging Our New Judges: Why We Must Remove Artificial Intelligence From Our Courtrooms Now, Kieran Duffy Newcomb

Honors Theses and Capstones

In this paper, I explore some of the ways in which artificial intelligence might enhance the sentencing process through recidivism prediction technology. Notably, this technology can increase the accuracy of risk predictions and the speed with which sentencing decisions are reached. I then show, however, that the recidivism prediction technology is likely to turn into what data scientist Cathy O’Neil calls a Weapon of Math Destruction. The potential harmfulness of this technology is due not to the inherent nature of the technology, but the symbiotic relationship it will have with our already harmful criminal justice system. I argue that the …

Applying Synchrotron Saxs And Xas To Study The Microstructure Of Energy Conversion And Storage Materials, Lingzhe Fang

Graduate Research Theses & Dissertations

The microstructure of energy conversion and storage materials is a key determinant of physical properties and electrochemical performance. Synchrotron X-ray techniques, with their strengths of high flux and exceptional brightness, play an irreplaceable role in understanding nano and sub-nano structures. This helps the study of reaction mechanisms and benefits material design in energy conversion and storage area. Electrifying CO2 transformation using renewable energy offers a carbon-neutral solution to CO2 recycling and fuel generation. Among various feedstocks from the CO2 reduction reaction, CO, HCOOH, and CH4 have approached the performance thresholds for industry implementation. The application of single atom catalysts (SACs) …