Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

2001

Discipline
Institution
Keyword
Publication
Publication Type
File Type

Articles 2641 - 2670 of 3030

Full-Text Articles in Physical Sciences and Mathematics

Investigation Of The Microporous And Mesoporous Structures Of The Reşadiye (Tokat/Turkey) Bentonite And Its Fractions, Müşerref Önal, Yüksel Sarikaya, Tülay Alemdaroğlu Jan 2001

Investigation Of The Microporous And Mesoporous Structures Of The Reşadiye (Tokat/Turkey) Bentonite And Its Fractions, Müşerref Önal, Yüksel Sarikaya, Tülay Alemdaroğlu

Turkish Journal of Chemistry

It was determined by X-ray diffraction that, besides containing clay minerals such as montmorillonite and illite, the original bentonite contained also clinoptilolite, opal-C, quartz, calcite and dolomite. The original bentonite was separated into four fractions by decantation and precipitation from its aqueous suspension. The adsorption and desorption of nitrogen on the original bentonite and its fractions at 77 K were investigated. The specific surface areas of the samples were determined according to the methods of Brunauer-Emmett-Teller, de Boer-Lippens, and Harkins-Jura by using the adsorption data. The mesopore size distribution curves were plotted by using the desorption data. The specific micropore …


Investigations On The Electrochemical Surface Treatment Of Carbon Fibers, Erdal Bayramli, Levent Toppare, Naci̇ Kutay Eri̇nç Jan 2001

Investigations On The Electrochemical Surface Treatment Of Carbon Fibers, Erdal Bayramli, Levent Toppare, Naci̇ Kutay Eri̇nç

Turkish Journal of Chemistry

Desized polyacrylonitrile (PAN) based carbon fibers (CF) were chemically and electrochemically oxidized and reduced. CF surfaces were activated via cyclic voltammetry studies with anodic and cathodic scans. The changes in CF surfaces were studied by contact angle measurements. Lifshitz-van der Waals and acid-base components of single fibers were determined. In general, oxidation resulted in the formation of an acidic surface energy component and reduction gave rise to no change in the number of basic functionalities at the CF surface.


Modification Of Poly(Maleic Anhydride-Co-Styrene) With Hydroxyl Containing Compounds, Oya Gali̇oğlu Atici, Ahmet Akar, Roshan Rahimian Jan 2001

Modification Of Poly(Maleic Anhydride-Co-Styrene) With Hydroxyl Containing Compounds, Oya Gali̇oğlu Atici, Ahmet Akar, Roshan Rahimian

Turkish Journal of Chemistry

Soluble and cross-linked poly(maleic anhydride-co-styrene) copolymers were reacted with hydroxyl containing compounds such as salicylic acid, 2-phenyl ethanol, eugenol and paracetamole in acetone or dioxane solution at 50-80°C. The hydrolytic and controlled release behavior of the copolymers containing these compounds in water was studied. The extent of hydrolysis was found to be affected by the type of polymer support as well as time, temperature and the type of supported compound.


Secondary Amine Mediated Ring-Opening Of Tetrahydroimidazo[1,5- B ][1,2,4]Oxadiazol-2(1 H )-Ones, Necdet Coşkun Jan 2001

Secondary Amine Mediated Ring-Opening Of Tetrahydroimidazo[1,5- B ][1,2,4]Oxadiazol-2(1 H )-Ones, Necdet Coşkun

Turkish Journal of Chemistry

5,6,7,7a-Tetrahydroimidazo [1,5- b ][1,2,4]oxadiazol-2(1 H )-ones 1a-g converted to imidazoles in the presence of secondary amines. cis-Imidazooxadiazolones 1d-g gave the imidazoles 4d-g when treated with secondary amines, while the treatment of these compounds with tertiary amines afforded imidazoline 3-oxides 5d-g. In case of 1a-c, where R^1 is a hydrogen, tertiary amines induced elimination to give imidazoles 4a-c. In the case of 1a-c, probable trans elimination caused by triethylamine and pyridine and in the case of 1d-f, a concerted double cis elimination mediated by secondary amines is discussed.


Towards The Asymmetric Synthesis Of Ascochlorin, Özdemi̇r Doğan, Wolfgang Oppolzer Jan 2001

Towards The Asymmetric Synthesis Of Ascochlorin, Özdemi̇r Doğan, Wolfgang Oppolzer

Turkish Journal of Chemistry

A synthetic approach is described to the asymmetric synthesis of ascochlorin (1), an antiviral antibiotic, based on the construction of a sesquiterpene unit via asymmetric Diels-Alder reaction of tigloyl sultam 4 & butadiene, and the introduction of the aromatic side chain (C9-C12 unit) by employing cuprate chemistry.


Determination Of Some Of The Physicochemical Properties Of Fine Alumina Powders Prepared By Emulsion Evaporation, Yüksel Sarikaya, İsmet Sevi̇nç, Müşerref Önal, Tülay Alemdaroğlu Jan 2001

Determination Of Some Of The Physicochemical Properties Of Fine Alumina Powders Prepared By Emulsion Evaporation, Yüksel Sarikaya, İsmet Sevi̇nç, Müşerref Önal, Tülay Alemdaroğlu

Turkish Journal of Chemistry

In order to prepare fine alumina powders, an emulsion was prepared under optimum conditions. The emulsion was examined by optical microscopy and the prepared fine alumina powders were characterised by electron microscopy. The particles were formed of porous spheres and their sizes were between 1 and 10 \\mum. The powder samples were sintered by varying the temperature between 700 and 1600°C. The adsorption and desorption of nitrogen on these samples were investigated. By using the adsorption data, the specific surface areas were calculated according to different procedures and the correlation between them was discussed. The specific micropore and mesopore volumes …


Copper Extraction From Aqueous Solution By Pentaerythrityl Tetrabenzylamine, Derya Kara, Mahi̇r Alkan, Ümi̇t Çakir Jan 2001

Copper Extraction From Aqueous Solution By Pentaerythrityl Tetrabenzylamine, Derya Kara, Mahi̇r Alkan, Ümi̇t Çakir

Turkish Journal of Chemistry

The extraction of copper(II) from the aqueous phase with pentaerythrityl tetrabenzylamine (PETBA), which was synthesized from pentaerythrityl tetrabromide and benzyl amine, was studied. The influences of ionic strength, extraction time, pH and temperature were evaluated. The extraction results showed that the ionic strength had no effect on extraction efficiency and that the extraction equilibrium was established in a few minutes. The extraction percentage was independent of pH up to pH 7.6 and then decreased gradually to zero at about pH 11.5. The stoichiometry of the compound formed was estimated to be Cu_2L(NO_3)_4, where L is PETBA. It was concluded that …


Flow Injection Analysis For Boron Determination By Using Methyl Borate Generation And Flame Atomic Emission Spectrometry, Deni̇z Yurtsever Sarica, Nusret Ertaş Jan 2001

Flow Injection Analysis For Boron Determination By Using Methyl Borate Generation And Flame Atomic Emission Spectrometry, Deni̇z Yurtsever Sarica, Nusret Ertaş

Turkish Journal of Chemistry

Boron is one of the least sensitive elements in atomic emission spectrometry. As various refractory substances interfere in the analysis and because of the low sensitivity, sample enrichment and the separation of the interfering matrix is needed. Methyl borate has many advantages because of its simple generation conditions and its stability in the absence of moisture. New procedures for the generation of methyl borate without using external heating have also been investigated to produce a more rapid determination of boron. The on-line combination of flow injection analysis using methyl borate generation with flame atomic emission spectrometry as the detector is …


Adsorption Of Non-Ionic Surface Active Agent On Fine Coal And Lignite, Zeki̇ Aktaş Jan 2001

Adsorption Of Non-Ionic Surface Active Agent On Fine Coal And Lignite, Zeki̇ Aktaş

Turkish Journal of Chemistry

The adsorption of Triton X-100 in aqueous solution on the less than 53 \\mum size fractions of Tunçbilek lignite and Zonguldak bituminous coal was studied. The adsorption isotherms were formed for 5, 30 and 1,440 (equilibrium) minutes. The isotherms were evaluated using both Langmuir and Freundlich adsorption equations. Concentrations of the reagent in the monolayer after equilibrium adsorption were determined to be 8.17 and 7.27 \\muM/g coal for the lignite and bituminous coal using the Langmuir adsorption equation. The specific adsorption capacity per unit area of Zonguldak bituminous coal was 5.3 times higher than that of Tunçbilek lignite. The adsorption …


Thermogravimetric Investigation Of The Dehydration Kinetics Of Ksf, K10 And Turkish Bentonite, Yalçin Tonbul, Kadi̇r Yurdakoç Jan 2001

Thermogravimetric Investigation Of The Dehydration Kinetics Of Ksf, K10 And Turkish Bentonite, Yalçin Tonbul, Kadi̇r Yurdakoç

Turkish Journal of Chemistry

The kinetic parameters for the dehydration of bentonite from Turkey, KSF and K10 were determined by using dynamic TG techniques. The Ozawa method is better for the dehydration of the clay samples than the first order equation of Coats and Redfern. The former function calculates consistently higher activation energies than the latter. The mean values of the activation energies in the \\alpha range 0.1-0.7, are 56-66 kJ mol^{-1} in the Ozawa method.


Selenium Speciation In Karakaya Dam Lake's Water (Malatya-Turkey), F. Zehra Küçükbay, Mustafa Demi̇r Jan 2001

Selenium Speciation In Karakaya Dam Lake's Water (Malatya-Turkey), F. Zehra Küçükbay, Mustafa Demi̇r

Turkish Journal of Chemistry

Concentrations of total inorganic selenium, Se(IV), Se(VI) and organically bonded selenium from samples of Karakaya dam lake\\\'s water were determined using ammonium pyrollidine dithio carbamate (APDC) as a chelating agent and subsequent adsorption on amberlite type XAD-8 resins. Eluted analytes are taken up in a matrix free acidic solution suitable for graphite furnace atomic absorption spectroscopy (GFAAS). According to our results, levels of the total inorganic selenium, Se(IV), Se(VI) and organically bonded selenium were found to be between 0.11 \\pm 0.01 and 0.17 \\pm 0.01 \\mug/L, 0.07 \\pm 0.01 and 0.12 \\pm 0.01 \\mug/L, 0.02 \\pm 0.01 and 0.05 \\pm …


Lewis Acid Catalyzed 1,3-Dipolar Cycloadditon Reactions Of Stabilized Azomethine Ylides, Özdemi̇r Doğan, Hasan Koyuncu, Ümi̇t Kanişkan Jan 2001

Lewis Acid Catalyzed 1,3-Dipolar Cycloadditon Reactions Of Stabilized Azomethine Ylides, Özdemi̇r Doğan, Hasan Koyuncu, Ümi̇t Kanişkan

Turkish Journal of Chemistry

Diethylzinc was tested for the first time as the Lewis acid in 1,3-dipolar cycloaddition reactions of azomethine ylides to synthesize pyrrolidine derivatives. A new, easily applicable and highly selective method was developed for the synthesis of highly substituted pyrrolidines. By the application of this method, the synthesis of three new pyrrolidine derivatives was achieved.


Synergistic Solvent Extraction Of Zinc(Ii) And Cadmium(Ii) From Sulfate Medium By A Mixture Of 1 - Phenyl - 3 - Methyl - 4 - Benzoylpyrazol - 5 - One And Methyl - Isobutyl Ketone, Djamel Barkat, Zoubir Derriche, Abdelkader Tayeb Jan 2001

Synergistic Solvent Extraction Of Zinc(Ii) And Cadmium(Ii) From Sulfate Medium By A Mixture Of 1 - Phenyl - 3 - Methyl - 4 - Benzoylpyrazol - 5 - One And Methyl - Isobutyl Ketone, Djamel Barkat, Zoubir Derriche, Abdelkader Tayeb

Turkish Journal of Chemistry

The solvent extraction of zinc(II) and cadmium(II) from sulfate medium by 1 - phenyl - 3 - methyl - 4 - benzoylpyrazol - 5 - one (HPMBP) was studied in the following parameter functions: pH, concentration of the extractant, nature of diluent, concentration of the mineral anion and synergism. In the absence of the synergic agent methyl - isobutyl ketone (MIBK), the complexes extracted are ZnL_2(H_2O)_{x(org)} and CdL_2(H_2O)_{y(org)} . In the presence of MIBK, the curves of extraction show the presence of several species of complexes that depend on the concentration of MIBK. For very weak concentrations, the extracted complexes …


Characterization Of Lipids And Fatty Acid Methyl Ester Contents In Leaves And Roots Of Crocus Vallicola, Nuretti̇n Yayli, Zerri̇n Kiran, Hasan Seymen, Hasan Genç, Mustafa Küçüki̇slamoğlu Jan 2001

Characterization Of Lipids And Fatty Acid Methyl Ester Contents In Leaves And Roots Of Crocus Vallicola, Nuretti̇n Yayli, Zerri̇n Kiran, Hasan Seymen, Hasan Genç, Mustafa Küçüki̇slamoğlu

Turkish Journal of Chemistry

The chemical composition of the fatty acids methyl esters (FAMEs) and other lipids in leaves and roots of Crocusvallicola were analyzed by gas chromatography-mass spectrometry(GC-MS). In this work, twenty-eight compounds, including 22 FAMEs, 1 aldehyde, 3 hydrocarbons (substitute alkane and alkene), 2 alcohols in the leaves and twenty-one compounds (17 FAMEs, 1 anhydride, 1 substitute alcohol, 1 ketone, 1 substitute amide) in the roots were identified by GC-MS from C. vallicola. The FAMEs in leaves and roots were highly similar; only the amounts of the esters were different. Key Words: Crocus vallicola, leaves, roots, FAMEs


Effect Of Acid Treatment On Volumetric Swelling Ratios Of Coals, Nejat Mesci̇, Aki̇f Şenelt, Taner Toğrul, Aral Olcay Jan 2001

Effect Of Acid Treatment On Volumetric Swelling Ratios Of Coals, Nejat Mesci̇, Aki̇f Şenelt, Taner Toğrul, Aral Olcay

Turkish Journal of Chemistry

To remove Ca^{2+} ions, six low rank coals and one coking coal were treated with 0.1 and l.0 N HC1 for 24 h. IR spectra and proximate analysis of the lignites indicated that only slight structural changes had occurred during acid treatment. The swelling ratios of parent and acid-treated coal samples showed that removal of Ca^{2+} resulted in an increase in the swelling ratios. Higher swelling ratios were obtained with acid-washed coal samples. While the highest swelling ratios of the parent lignites were obtained in ethylenediamine, those of acid-treated samples were obtained in pyridine and dimethylformamide.


Calculation Of Multi-Center Integrals For The Region Of Moderate And Weak Overlap, Abdulhali̇k Karabulut, Gökhan Budak, Lütfü Demi̇r, Nagi̇f Sefteroğlu Nabi̇yev, Yusuf Şahi̇n Jan 2001

Calculation Of Multi-Center Integrals For The Region Of Moderate And Weak Overlap, Abdulhali̇k Karabulut, Gökhan Budak, Lütfü Demi̇r, Nagi̇f Sefteroğlu Nabi̇yev, Yusuf Şahi̇n

Turkish Journal of Chemistry

In this study a general formula was established for multi-center integrals over Gaussian basis sets using the two-center expansion of nuclear attraction and electron repulsion potentials. The terms of the formula are the analytical functions of interatomic distances. Three kinds of integrals contained in these formulae can be evaluated analytically. In the presented method, unlike many other popular methods, the numerical integrations procedure is unnecessary since it does not contain the incomplete gamma function. A computer program was written and tested for various orbitals. The calculations show that the series converge very rapidly.


The Influence Of Transition Metal Ions On The Kinetics Of Ascorbic Acid Oxidation By Methylene Blue In Strongly Acidic Media, M. Nasiruddin Khan, Anila Sarwar Jan 2001

The Influence Of Transition Metal Ions On The Kinetics Of Ascorbic Acid Oxidation By Methylene Blue In Strongly Acidic Media, M. Nasiruddin Khan, Anila Sarwar

Turkish Journal of Chemistry

The kinetics of the oxidation of L-ascorbic acid (H_{2} A) by methylene blue was investigated in strongly acidic media over the temperature range 22-40 ^oC. The kinetic studies were carried out as a function of different variables like concentration, pH, ionic strength and temperature. The rate was found to be a linear relation with [H_{2} A], [M.B.] and [H^{+}]. Ionic strength dependence formation indicated complex formation by monocationic and anionic species in solution. The reaction rate was greatly catalyzed by the presence of trace amounts of copper (II) ion. Possible mechanisms for the catalyzed and uncatalyzed reactions are proposed. Kinetic …


Synthesis Of Azobenzo[B]Thiophene Derivatives And Their Dyeing Performance On Polyester Fibre, Hari Raghav Maradiya Jan 2001

Synthesis Of Azobenzo[B]Thiophene Derivatives And Their Dyeing Performance On Polyester Fibre, Hari Raghav Maradiya

Turkish Journal of Chemistry

Ethyl 2-amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate was synthesised by the reaction of cyclohexanone and sulphur with ethylcyanoacetate. The 2-aminothiophene derivative was diazotised and coupled with various N-arylmaleimides to give monoazo disperse dyes. The dyeing performance of these dyes was assessed on polyester fabric. These dyes were found to give light pink to reddish pink shades with very good depth and levelness on polyester fabric. The dyed fabric showed fair light fastness and excellent washing, rubbing, perspiration and sublimation fastness. The dyebath exhaustion on polyester fabric was found to be good and acceptable.


Purification And Partial Characterisation Of Superoxide Dismutase From Chicken Erythrocytes, Tüli̇n Aydemi̇r, Leman Tarhan Jan 2001

Purification And Partial Characterisation Of Superoxide Dismutase From Chicken Erythrocytes, Tüli̇n Aydemi̇r, Leman Tarhan

Turkish Journal of Chemistry

Superoxide dismutase (SOD), which plays a very important role in protecting organisms from oxygen toxicity, was purified from chicken erythrocyte and partially characterised. Erythrocyte membranes were disintegrated via freeze-thaw methods in the presence of Triton X-100. Following ethanol precipitation, SOD-containing solution was applied to DEAE-cellulose and then Sephadex G-100 gel columns. Chicken erythrocyte SOD was purified 508-fold with a specific activity of 8,480 units per mg. The molecular weight was estimated to be 30.6 kDa \pm 0.4 by gel filtration. The enzyme was composed of two subunits of equal size and contained one atom of copper and one atom of …


Study Of The Effect Of Number Of Layers On The Electrosynthesis Of Cobalt(Iii) Acetate In A Bipolar Packed-Bed Flow Reactor, Altan Güvenç, Belgi̇n Karabacakoğlu Jan 2001

Study Of The Effect Of Number Of Layers On The Electrosynthesis Of Cobalt(Iii) Acetate In A Bipolar Packed-Bed Flow Reactor, Altan Güvenç, Belgi̇n Karabacakoğlu

Turkish Journal of Chemistry

Cobalt(III) acetate, which is an important oxidizing agent and catalyst in organic reactions, was electrosynthesized from cobalt(II) acetate solution in a bipolar packed-bed flow reactor. In order to determine the effect of the number of layers on the yield of cobalt(III) acetate, experiments were performed in three different lengths of bipolar electrode cells, namely 16, 29 and 55 layers of graphite Raschig rings. The experiments were carried out at controlled potentials of 50-450 V, measuring the total current and using the solution (5% H_{2}O, 95% CH_{3}COOH, 0.06MCo(CH_{3}COO)_{2}.4H_{2}O, 0.2M CH_{3}COONa.3H_{2}O) at 298 K and 0.133 L.h^{-1} flow rate. According to the …


Voltammetry Of The Anticancer Drug Mitoxantrone And Dna, Arzum Erdem, Mehmet Özsöz Jan 2001

Voltammetry Of The Anticancer Drug Mitoxantrone And Dna, Arzum Erdem, Mehmet Özsöz

Turkish Journal of Chemistry

The interaction of mitoxantrone (MTX) with calf thymus double-stranded DNA (dsDNA) and calf thymus single-stranded DNA (ssDNA) was studied electrochemically by using differential pulse voltammetry (DPV) and cyclic voltammetry (CV) at a carbon paste electrode (CPE). The changes in the experimental parameters (the concentration of MTX, the concentration of DNA and the accumulation time of MTX) were studied by DPV; in addition, the detection limit and the reproducibility were determined. It was observed for the interaction of MTX with dsDNA and ssDNA that the signal of the bare electrode was higher than the signal of the dsDNA modified CPE. The …


Separation Process Of Citric Acid With Tertiary Amines/Diluents In Supercritical Co_{2}, Arzu Koparan, Afi̇fe Güvenç, Nurcan Kapucu, Ülkü Mehmetoğlu, Ayla Çalimli Jan 2001

Separation Process Of Citric Acid With Tertiary Amines/Diluents In Supercritical Co_{2}, Arzu Koparan, Afi̇fe Güvenç, Nurcan Kapucu, Ülkü Mehmetoğlu, Ayla Çalimli

Turkish Journal of Chemistry

Reactive extraction of citric acid was investigated at atmospheric and supercritical conditions. The most suitable diluent and amine from among the tertiary amines and eight different diluents were determined at atmospheric conditions. The distribution coefficient values obtained with Hostarex A 327 were higher than those of Alamine 336. The selected amine (Hostarex A327) and the diluent (Oleyl alcohol) were used for reactive extraction of citric acid at supercritical conditions. Separation yields of citric acid were obtained in the temperature ranges of 308 to 328 K and in the pressure ranges of 80 to 180 bars in a supercritical extraction system …


Synthesis And Spectrophotometric Investigation Of A New Vic-Dioxime Ligand And Its Transition Metal Complexes, Mustafa Dolaz, Mehmet Tümer, Ayşegül Gölcü, Selahatti̇n Seri̇n Jan 2001

Synthesis And Spectrophotometric Investigation Of A New Vic-Dioxime Ligand And Its Transition Metal Complexes, Mustafa Dolaz, Mehmet Tümer, Ayşegül Gölcü, Selahatti̇n Seri̇n

Turkish Journal of Chemistry

A new vic-dioxime ligand and its Cu(II), Co(II), Ni(II), Pd(II), VO(IV) and Zn(II) complexes have been prepared and characterized by elemental analyses, infrared, electronic spectra, magnetic moment and molar conductance data. The Ni(II), Pd(II) and Zn(II) complexes have a diamagnetic character. The ^{1}H- and ^{13}C-nmr and GC/MS spectra of the vic-dioxime ligand and its Ni(II), Pd(II) and Zn(II) complexes were recorded. In addition, all compounds are non-electrolyte.


Conductimetric And Potentiometric Titration Of Some Hydroxylated Cinnamic Acids With Tetrabutylammonium Hydroxide In Non-Aqueous Media, A.Hakan Aktaş, Gülsüm Yaşar, Güleren Özkan Alsancak, Şahi̇nde Demi̇rci̇ Jan 2001

Conductimetric And Potentiometric Titration Of Some Hydroxylated Cinnamic Acids With Tetrabutylammonium Hydroxide In Non-Aqueous Media, A.Hakan Aktaş, Gülsüm Yaşar, Güleren Özkan Alsancak, Şahi̇nde Demi̇rci̇

Turkish Journal of Chemistry

In this study, four hydroxycinnamic acids, namely 3,4-dihydroxycinnamic acid, 4-hydroxycinnamic acid, 4-hydroxy --3- methoxycinnamic acid and 4-hydroxy-3,5-dimethoxycinnamic acid, were titrated conductimetrically and potentiometrically using triethylamine and tetrabutylammonium hydroxide in acetonitrile, 2-propanol, and pyridine solvents under a nitrogen atmosphere at 25 ^oC. In conductimetric titration with tetrabutylammonium hydroxide all of the compounds exhibited conventional stoichiometric titration curves in 2-propanol . As is evident from the titration curves, all these compounds gave two well-defined end points. The first end point corresponds to exactly one equivalent and the second one to the two equivalents of the base. In conductimetric titration with tetrabutylammonium hydroxide, …


New Photochemical And Electrochemical Methods For The Degradation Of Pesticides In Aqueous Media. Environmental Applications, J. J. Aaron, Mehmet A. Oturan Jan 2001

New Photochemical And Electrochemical Methods For The Degradation Of Pesticides In Aqueous Media. Environmental Applications, J. J. Aaron, Mehmet A. Oturan

Turkish Journal of Chemistry

The development of new electrochemical and photochemical methods for the decontamination of natural water containing significant concentrations of aromatic pesticides is described. The electrochemical method is based on the electro-Fenton process, i.e. the simultaneous reduction of O_{2} and Fe^{3+} ions. Hydroxyl (OH^{.}) radicals are electrosynthesized in aqueous solutions, followed by complete mineralization of the initial pollutants. The photochemical methods involve either a direct photodegradation reaction of pesticides by UV light, or indirect photodegradation processes including H_{2}O_{2} photolysis or photo-Fenton reagents (H_{2}O_{2}/ Fe^{3+} ). Examples of the application of these methods to chlorophenoxy acid herbicides and four aromatic pesticides (bendiocarb, pirimiphos-methyl, …


Heavy Metal Contents Of Lake Sapanca, Nevi̇n Yalçin, Vahdetti̇n Sevi̇nç Jan 2001

Heavy Metal Contents Of Lake Sapanca, Nevi̇n Yalçin, Vahdetti̇n Sevi̇nç

Turkish Journal of Chemistry

The heavy metal pollution of Lake Sapanca located in the Marmara region (Turkey), was investigated over time. The lake is the drinking water source of the city of Adapazarı and its environs. The D-80 (TEM) motorway passes about 5 km along the lake's zero point in the Sapanca district. The motorway's wastewater drainages have been connected to the lake without having been subjected to any wastewater treatment. The motorway was opened to service in October 1990. Analyses were performed in 1991 and were repeated in 1999 in order to observe changes in Pb, Fe and Zn contents. Samples were collected …


Biodiversity: Connecting With The Tapestry Of Life, Elise F. Granek, Francisco Dallmeier, Alfonso Alonso, Peter H. Raven Jan 2001

Biodiversity: Connecting With The Tapestry Of Life, Elise F. Granek, Francisco Dallmeier, Alfonso Alonso, Peter H. Raven

Environmental Science and Management Faculty Publications and Presentations

Biodiversity is the extraordinary variety of life on Earth – from genes and species to ecosystems and the valuable functions they perform. E.O. Wilson, the noted biologist and author who coined the term “biodiversity,” explains it as “the very stuff of life.” Species and the ecosystems in which they live are indelibly linked. Conversion or loss of ecosystems inevitably impairs the species that depend on them. As well, changes in the life cycle of one species could impact the life cycles of many other species (including humans), alter ecosystems and ecosystem functions, and contribute to local, regional and, ultimately, global …


Spatial Distribution Of Phosphorus In Fluvial Sediments From The James River Basin, Sw Missouri, Briain Fredrick Jan 2001

Spatial Distribution Of Phosphorus In Fluvial Sediments From The James River Basin, Sw Missouri, Briain Fredrick

MSU Graduate Theses

Degraded ·water quality in the James River Arm of Table Rock Lake, southwest Missouri has raised concerns about sources and transport of nutrients, especially phosphorus, in the James River Basin. Sections of the James River Basin have been identified as having excessive nutrient problems on the Missouri Department of Natural Resources 303d list and ranked fifth in the state for water quality improvements. Understanding the sources and transport patterns of phosphorus in the James River is necessary to evaluate contamination problems and the effectiveness of management efforts to reduce phosphorus inputs to the lake. This study uses bed sediments to …


Successive Toroidal Compactifications Of A Closed Bosonic Strings, N. Mebarki, A. Taleb, H. Aissaoui, Nadir Belaloui, M. Haouchine Jan 2001

Successive Toroidal Compactifications Of A Closed Bosonic Strings, N. Mebarki, A. Taleb, H. Aissaoui, Nadir Belaloui, M. Haouchine

Turkish Journal of Physics

Successive toroidal compactifications of a closed bosonic string are studied and some Lie groups solutions are derived.


The Theoretical Analysis Of The Second Order Coherence G^{(2)}(\Tau) And Power Stabilization Of Two-Mode He-Ne Laser, Erol Taşal, M. Selami̇ Kiliçkaya Jan 2001

The Theoretical Analysis Of The Second Order Coherence G^{(2)}(\Tau) And Power Stabilization Of Two-Mode He-Ne Laser, Erol Taşal, M. Selami̇ Kiliçkaya

Turkish Journal of Physics

In this study, second-order coherence and its frequency-dependent characteristics and the photon statistical properties of the two-mode He-Ne laser field are investigated.