Physical Sciences and Mathematics Commons^™

The Microwave Spectrum, Ab Initio Analysis, And Structure Of The Fluorobenzene–Hydrogen Chloride Complex, M. Eugenia Sanz, Sonia Antolinez, Jose Alonso, Juan Lopez, Robert Kuczkowski, Sean Peebles, Rebecca Peebles, Faith Boman, Elfi Kraka, Dieter Cremer

Faculty Research and Creative Activity

The fluorobenzene–hydrogen chloride π-hydrogen-bonded complex has been studied by high resolution microwave spectroscopy and ab initio calculations. Rotational spectra of the C6H5F–H35Cl, C6H5F–H37Cl, and C6D5F–H35Cl isotopomers were assigned using pulsed molecular beam techniques in a Fourier-transform microwave spectrometer. The spectra are consistent with a structure of the complex in which the HCl is above the fluorobenzene ring near the ring center, similar to the benzene–HCl prototype dimer. An analysis of the inertial data and the chlorine quadrupole coupling tensor results in two mathematically possible locations for the HCl subunit with respect to the fluorobenzene arising from sign ambiguities in interpreting …

The Microwave Spectrum, Ab Initio Analysis, And Structure Of The Fluorobenzene–Hydrogen Chloride Complex, M. Eugenia Sanz, Sonia Antolinez, Jose L. Alonso, Juan C. Lopez, Robert L. Kuczkowski, Sean A. Peebles, Rebecca A. Peebles, Faith C. Boman, Elfi Kraka, Dieter Cremer

Faculty Research and Creative Activity

The fluorobenzene–hydrogen chloride π-hydrogen-bonded complex has been studied by high resolution microwave spectroscopy and ab initio calculations. Rotational spectra of the C6H5F–H35Cl, C6H5F–H37Cl, and C6D5F–H35Cl isotopomers were assigned using pulsed molecular beam techniques in a Fourier-transform microwave spectrometer. The spectra are consistent with a structure of the complex in which the HCl is above the fluorobenzene ring near the ring center, similar to the benzene–HCl prototype dimer. An analysis of the inertial data and the chlorine quadrupole coupling tensor results in two mathematically possible locations for the HCl subunit with respect to the fluorobenzene arising from sign ambiguities in interpreting …

Short-Term Effects Of Ambient Particles On Mortality In The Elderly: Results From 28 Cities In The Aphea2 Project, E. Aga, E. Samoli, G. Touloumi, K. Katsouyanni, H.R. Anderson, E. Cadum, B. Forsberg, Patrick J. Goodman, A. Goren, F. Kotesovec, B. Kriz, M. Macarol-Hiti, S. Medina, A. Paldy, C. Schindler, J. Sunyer, P. Tittanen, B. Wojtyniak, D. Zmirou, J. Schwartz

Articles

ABSTRACT: Within the framework of the APHEA2 (Air Pollution on Health: a European Approach) project, the effects of ambient particles on mortality among persons o65 yrs were investigated. Daily measurements for particles with a 50% cut-off aerodynamic diameter of 10 mm (PM10) and black smoke (BS), as well as the daily number of deaths among persons o65 yrs of age, from 29 European cities, have been collected. Data on other pollutants and meteorological variables, to adjust for confounding effects and data on city characteristics, to investigate potential effect modification, were also recorded. For individual city analysis, generalised additive models extending …

Upper Spokane River Model: Model Calibration, 2001, Chris Berger, Robert Leslie Annear, Benjamin Welle

Civil and Environmental Engineering Faculty Publications and Presentations

The Upper Spokane River system under consideration is located in the Northeastern part of Washington State and runs from the Stateline with Idaho, River mile (RM) 96.0, downstream to Long Lake dam at RM 32.5. Figure 1 shows the river system and an outline the boundaries of the City of Spokane.

The Washington Department of Ecology (Ecology) is interested in a water quality model for the Upper Spokane River system for use in developing Total Maximum Daily Loads (TMDLs). As a result, Ecology and the Corps of Engineers funded a study to develop a water quality and hydrodynamic model of …

Sensor Networks: An Overview, Malik Tubaishat, Sanjay Kumar Madria

Computer Science Faculty Research & Creative Works

Advances in hardware and wireless network technologies have created low-cost, low-power, multifunctional miniature sensor devices. These devices make up hundreds or thousands of ad hoc tiny sensor nodes spread across a geographical area. These sensor nodes collaborate among themselves to establish a sensing network. A sensor network can provide access to information anytime, anywhere by collecting, processing, analyzing and disseminating data. Thus, the network actively participates in creating a smart environment.

Two Distributed Algorithms For E-Ticket Validation Protocols For Mobile Clients, H. Mohanty, Sanjay Kumar Madria, T. Suman Kumar Reddy, R. K. Ghosh

Computer Science Faculty Research & Creative Works

The e-ticket (electronic ticket) validation problem has relevance in mobile computing environment because of the multiple submission of a ticket that is possible due to intermittent disconnections and mobility of hosts. Here, we propose protocols that are not only sensitive to disconnection but also to location. One of the proposed protocols is the variant of the distributed protocol proposed by Pedone (2000) for Internet users. This shows that a distributed protocol for static network can be restructured for distributed computation in a mobile computing environment. We have also proposed another protocol that uses a hierarchical location database of mobile hosts …

Computer Assisted Screening Of Digital Mammogram Images, John Terry Sample

LSU Doctoral Dissertations

The use of computer systems to assist clinicians in digital mammography image screening has advantages over traditional methods. Computer algorithms can enhance the appearance of the images and highlight suspicious areas. Screening provides a more thorough examination of the images. Any computer system that does screening of digital mammograms contains components to address multiple tasks such as: image segmentation, mass lesion detection and classification, and microcalcification detection and classification. This dissertation provides both effective and efficient improvements to existing algorithms, which segment mammogram images and locate mass lesions. In addition, we provide a new algorithm to evaluate and report the …

The Extinction Properties Of Reddened Galactic Ob Sightlines, Lynne Angela Valencic

LSU Doctoral Dissertations

A solid understanding of dust grains and their extinction properties is needed to better remove the effects of extinction from data and to comprehend the nature of the processes which modify grains. This requires a large sample of Galactic sightlines, extending far beyond the solar neighborhood, sampling not only a large volume of space but also a wide variety of environments. To fulfill this requirement, a database of sightlines toward 426 young, reddened stars was constructed using extinction curves based on IUE spectra. The curves were fit and the Fitzpatrick-Massa (FM) parameters were found. FM parameters allow for a quantitative …

Low Salinity Waters In Deep Sedimentary Basins, David Scott Szalkowski

LSU Master's Theses

While the composition and origin of brines in deep sedimentary basins has been extensively discussed, the composition and origin of low salinity waters is not as well documented. Since the 1960s, the presence of deep, low-salinity waters has been observed in some sedimentary basins and is commonly present in overpressured sections. The episodic release of low salinity, overpressured fluids upward into sediments containing high salinity formation waters likely occurs at <100-year intervals. Because there is a growing body of evidence that suggests mixing formation waters of varying salinity could induce the dissolution and precipitation of minerals, it is important to have detailed information about chemical compositions of both end-member fluids to adequately predict such mixing results. This study concludes that low salinity waters (<35 g/l) are generally not unique in major solute composition when compared to high salinity waters (>35 g/l). On log-log plots, monovalent cations plot along 1:1 slopes with respect to salinity and total anionic charge, while divalent cations plot along 2:1 slopes. However, this study concludes …

Million City Traveling Salesman Problem Solution By Divide And Conquer Clustering With Adaptive Resonance Neural Networks, Samuel A. Mulder, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

The Traveling Salesman Problem (TSP) is a very hard optimization problem in the field of operations research. It has been shown to be NP-complete and is an often-used benchmark for new optimization techniques. One of the main challenges with this problem is that standard, non-AI heuristic approaches such as the Lin-Kernighan algorithm (LK) and the chained LK variant are currently very effective and in wide use for the common fully connected, Euclidean variant that is considered here. This paper presents an algorithm that uses adaptive resonance theory (ART) in combination with a variation of the Lin-Kernighan local optimization algorithm to …

Rate-Based End-To-End Congestion Control Of Multimedia Traffic In Packet Switched Networks, Mingsheng Peng, S. R. Subramanya, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

This paper proposes an explicit rate-based end-to-end congestion control mechanism to alleviate congestion of multimedia traffic in packet switched networks such as the Internet. The congestion is controlled by adjusting the transmission rates of the sources in response to the feedback information from destination such as the buffer occupancy, packet arrival rate and service rate at the outgoing link, so that a desired quality of service (QoS) can be met. The QoS is defined in terms of packet loss ratio, transmission delay, power, and network utilization. Comparison studies demonstrate the effectiveness of the proposed scheme over New-Reno TCP (a variant …

Representation Of Web Data In A Web Warehouse, Sourav S. Bhowmick, Sanjay Madria, Wee Keong Ng

Computer Science Faculty Research & Creative Works

We believe that, to manage Web data effectively, there is a need to build a data warehouse of Web data, i.e. a Web warehouse. in this paper, we focus on how to represent and store relevant hyperlinked Web documents effectively in a Web warehouse called WHOWEDA (WareHouse of WEb DAta) for further querying and manipulation. We present a simple and general model for representing metadata, structure and content of Web documents and hyperlinks in WHOWEDA. We discuss node and link objects which are used to represent Web documents and hyperlinks respectively in WHOWEDA. These objects are first class objects in …

Using Functional Distance Measures When Calibrating Journey-To-Crime Distance Decay Algorithms, Joshua David Kent

LSU Master's Theses

Spatial analysis has long been a valuable tool used within the criminal investigative process. This is especially true for serial offence cases where criminologists apply geographic profiling to model offender mobility and crime distribution patterns in order to estimate a criminal’s likely residence. Yet, traditional analytical methodologies have avoided the utilization of functional distance measures when modeling an offender’s journey-to-crime within an anisotropic landscape. By substituting straight-line Euclidean distances with travel path functional distance measures, the predictive utility and technological prerequisites associated with geographically profiling a localized serial offender was assessed using mathematically calibrated distance decay models. Both the travel-path …

Toward A Sustainable Energy Future?: A Comparison Between U.S. And European Energy Sectors, Annett Moehner

LSU Master's Theses

Since 1987, the concept of sustainable development, which tries to combine economic, social and environmental concerns into one benign development model, has become increasingly popular worldwide. To explore and explain the differences in accomplishing sustainable development, this thesis looks at one specific aspect: the energy sectors in the United States and the European Union. After giving an overview on the political and theoretical aspects of sustainable development, the various sustainability dimensions in the energy sector are explored. The following four reasons which warrant the change of the current fossil fuel intense energy sector are discussed: first, air pollution; second, insecurity …

Regional Water Quality Models For The Prediction Of Eutrophication Endpoints, Anindita Das

LSU Master's Theses

Eutrophication is a process by which a waterbody progresses from its origin to its extinction. During this period, there is a gradual accumulation of nutrients and organic biomass, accompanied by a decrease in average depth of the water due to sediment accumulation, and an increase in primary productivity, usually in the form of dense algal blooms. Cultural eutrophication occurs when humans, through their various activities, greatly accelerate this process. Eutrophication can cause loss in species diversity, fish kills, and decrease the aesthetic value of a waterbody. The EPA is trying to prevent cultural eutrophication by setting standards for water quality …

Detrital Tourmaline As An Indicator Of Provenance: A Chemical And Sedimentological Study Of Modern Sands From The Black Hills, South Dakota, David Brent Viator

LSU Master's Theses

Detrital tourmaline has proven useful as a provenance indicator mineral of ancient sedimentary/metasedimentary units due to its presence in many rock types, chemical responsiveness to environments of formation, complex and variable chemical compositions, high resistance to chemical and mechanical weathering, and stability through diagenesis and metamorphism. This study further establishes detrital tourmaline as a provenance indicator mineral by examining the chemical and sedimentological relationships between modern detrital tourmalines in the sediments of the Black Hills, South Dakota, USA, and in situ tourmalines from southern Black Hills’ tourmaline-bearing metasedimentary rocks, granites, and rare-element enriched pegmatites. Results show that detrital tourmaline is …

Middle Miocene Grounding Events On The Ross Sea Outer Continental Shelf, Antarctica, Juan Manuel Chow

LSU Master's Theses

The middle Miocene δ¹⁸O enrichments from deep-sea data and eustatic sea level falls are traditionally attributed to expansion of the East Antarctic Ice Sheet. Interpretations of such data have led many to conclude that the West Antarctic Ice Sheet (WAIS) was not well-developed until the late Miocene. In such a scenario, middle Miocene glaciation on the Ross Sea shelf would have had to be minimal, perhaps in the form of ice caps, to be consistent with proxy data. New seismic-stratigraphic analysis of the Ross Sea outer continental shelf suggests that at least five grounding events (ice sheet advances …

A Parametrization Approach For Solving The Hamilton-Jacobi-Equation And Application To The A2 Toda Lattice, Mohammad Dikko Aliyu

LSU Master's Theses

Hamilton-Jacobi (HJ)-theory is an extension of Lagrangian mechanics and concerns itself with a directed search for a coordinate transformation in which the equations of motion can be easily integrated. The equations of motion of a given mechanical system can often be simplified considerably by a suitable transformation of variables such that all the new position and momemtum coordinates are constants. A particular type of transformation is chosen in such a way that the new equations of motion retain the same form as in the former coordinates; such a transformation is called canonical or contact and can greatly simplify the solution …

The Effect On Water Quality Of Riverine Input Into Coastal Wetlands, Robert Raymond Lane

LSU Doctoral Dissertations

This dissertation focuses on impact on water quality of two freshwater diversions, the Bonnet Carre Spillway and the Caernarvon freshwater diversion, as well as the Atchafalaya River Estuarine Complex. As water passed through the Bonnet Carre Spillway, there were reductions in total suspended sediment concentrations of 82-83%, in nitrite+nitrate of 28-42%, in total nitrogen (TN) of 26-30%, and in total phosphorus (TP) of 50-59%. The Si:N ratio generally increased and the N:P ratio decreased from the river to the plume edge in Lake Pontchartrain. At the Caernarvon diversion, there were reductions in concentrations of dissolved inorganic Si, N, and P …

An Investigation Of A Salt-Dome Environment At South Timbalier 54, Gulf Of Mexico, Robert E. Little, Jr

LSU Master's Theses

Salt domes have been studied in the Gulf Coast region to look at how, why, and where saline waters are located within these field areas. Fluid flow model and pathway studies can be helpful to the research of saline water migration because it can be correlated to hydrocarbon migration in petroleum exploration. The South Timbalier 54 field occurs over a salt dome that sits at approximately 3,048 meters beneath the seafloor. Two major faults were found originating from the salt dome up into the shallow section of the field. The sands were deposited in fluvial, deltaic, or marine environments. The …

Correlation Of Core Characteristics To Outcrop Upper Jackfork Group Turbidites, Degray Lake, Arkansas, Daniel James Golob

LSU Master's Theses

Pennsylvanian age Jackfork Group cores from the DeGray Lake Dam and outcrop from the east wall of the DeGray Lake Spillway, Arkansas, provide an opportunity for a detailed study on the transport and depositional characteristics of a fine-grained, deep-water depositional system. Two phases of resedimentation processes are responsible for deposition of the sediments in the cores and the outcrop. Primary resedimentation processes transport terrigenous sediments from the shelf or basin edge into the middle fan environment, while secondary resedimentation alter the sediments after they are initially deposited in the environment. Debris flows, slurry flows, and high and low density turbidity …

An Intelligent Early Warning System For Software Quality Improvement And Project Management, Xiaoqing Frank Liu, Gautam Kane, Monu Bambroo

Computer Science Faculty Research & Creative Works

One of the main reasons behind unfruitful software development projects is that it is often too late to correct the problems by the time they are detected. It clearly indicates the need for early warning about the potential risks. In this paper, we discuss an intelligent software early warning system based on fuzzy logic using an integrated set of software metrics. It helps to assess risks associated with being behind schedule, over budget, and poor quality in software development and maintenance from multiple perspectives. It handles incomplete, inaccurate, and imprecise information, and resolve conflicts in an uncertain environment in its …

Detecting And Representing Relevant Web Deltas In Whoweda, Sanjay Kumar Madria, Wee Keong Ng, Sourav S. Bhowmick

Computer Science Faculty Research & Creative Works

In this paper, we present a mechanism for detecting and representing changes, given the old and new versions of a set of interlinked Web documents, retrieved in response to a user''s query. In particular, we show how to detect and represent Web deltas, i.e., changes in the Web documents that are relevant to a user''s query in the context of our Web warehousing system called WHOWEDA (Warehouse of Web Data). In WHOWEDA, Web information is materialized views stored in Web tables in the form of Web tuples. These Web tuples, represented as directed graphs, can be manipulated using a set …

Searching Sequence Databases, Dan E. Krane, Michael L. Raymer

Computer Science and Engineering Faculty Publications

Presentation prepared for BIO/CS 471: Algorithms for Bioinformatics. The lecture comprises material from the text Fundamental Concepts of Bioinformatics.

Example Protein Folds, Dan E. Krane, Michael L. Raymer

Computer Science and Engineering Faculty Publications

Presentation prepared for BIO/CS 471: Algorithms for Bioinformatics. The lecture comprises material from the text Fundamental Concepts of Bioinformatics.

Physical Mapping Of Dna, Dan E. Krane, Michael L. Raymer

Computer Science and Engineering Faculty Publications

Presentation prepared for BIO/CS 471: Algorithms for Bioinformatics. The lecture comprises material from the text Fundamental Concepts of Bioinformatics.

Protein Structure, Function, And Folding, Dan E. Krane, Michael L. Raymer

Computer Science and Engineering Faculty Publications

Presentation prepared for Intro to Bioinformatics. The lecture comprises material from the text Fundamental Concepts of Bioinformatics.

Lessons Learned In A Math Excel Workshop: The Importance Of Maintaining High Cognitive Demands, T. Dick

Journal of Mathematics and Science: Collaborative Explorations

Uri Treisman's Emerging Scholars Workshop model has been implemented on many college campuses over the last twenty years. The Treisman model is based on groups of students meeting regularly in a social atmosphere to work collaboratively in solving challenging mathematics problems related to their introductory coursework. Emerging Scholars Programs (or Math Excel as it is called in many settings, including ours) have been particularly successful in increasing the academic success and participation of underrepresented groups in mathematics. The primary responsibilities of a workshop leader include the design of a session’s worksheet, as well as the facilitation of students' problem solving …

Making Upper Division Mathematics Courses Relevant For Pre-Service Teachers, G. Hill

Journal of Mathematics and Science: Collaborative Explorations

This article addresses the disconnect that in-service and pre-service secondary school teachers feel between the material presented in upper division mathematics courses and high school classroom practice. Two examples are given from an abstract algebra course in which this problem is addressed.

Persistence In Mathematics By Underrepresented Students: Experiences Of A Math Excel Program, C. M. Hake, M. L. Crow, T. Dick

Journal of Mathematics and Science: Collaborative Explorations

Success in mathematics by underrepresented and nontraditional college students is measured not only by academic performance (grades), but also by the continued participation and persistence of these students in mathematics coursework. The Math Excel program at Oregon State University attempts to build "learning communities" with a sharp academic focus in support of students concurrently taking introductory level mathematics courses. The Math Excel program is based heavily on Uri Treisman's Emerging Scholars Workshop model of collaborative problem solving. In this article, we examine the experience of minority students in the Educational Opportunities Program participating in the Math Excel program. While the …