Physical Sciences and Mathematics Commons^™

A Tga/Ftir And Mass Spectral Study On The Thermal Degradation Of Bisphenol A Polycarbonate, Bok Nam Jang, Charles A. Wilkie

Chemistry Faculty Research and Publications

The thermal degradation of polycarbonate under nitrogen was studied using TGA/FTIR, GC/MS and LC/MS as a function of mass loss. The gases evolved during degradation were inspected by in situ FTIR and then the evolved products were collected and analysed using FTIR, GC–MS and LC–MS. The structures of the evolved products are assigned on the basis of FTIR and GC/MS results. The main thermal degradation pathways follow chain scission of the isopropylidene linkage, and hydrolysis/alcoholysis and rearrangement of carbonate linkages. In the case of chain scission, it was proposed that methyl scission of isopropylidene occurs first, according to the bond …

Annotation Manager: An Automated Web-Based Content Management System For Digital Libraries With Annotated Bibliographies, Frenny Thomas

Theses and Dissertations

With the expansion of the World Wide Web in the 90s, individuals (especially students) are always on a quest for information resources especially in the form of Web sites. Yet many of them are overwhelmed when faced with deciding which site will best suit their research needs. As a result, these individuals may select a resource for less than optimal reasons. To ease some of the burden, libraries have made great advances to provide a place to organize information resources. Such places are called library portals, and they typically provide a gateway to web resources by categorizing and annotating them …

Temporal Variability Of Satellite-Derived Chlorophyll And Sea Suface Temperature In The California Current, Kasey Legaard

Electronic Theses and Dissertations

Physical forcing and biological response within the California Current coastal upwelling system are highly variable over a wide range of scales. Satellite remote sensing offers the only feasible means of quantifying this variability over the full extent of this current system. Here we quantify and compare patterns of physical and biological variability acting over seasonal, interannual and dominant intraseasonal time scales throughout the California Current System using more than five years (1997-2003) of daily SeaWiFS chlorophyll and NOAA/NASA AVHRR Oceans Pathfinder SST imagery. Mean seasonal cycles were modeled as the sum of annual and semiannual harmonics. Interannual variability was estimated …

Estimating The Economic Recreational Value Of Paracas National Reserve In Ica Peru: A Fair Fee Implementation Approach, Jaqueline Garcia-Yi

Electronic Theses and Dissertations

Paracas National Reserve (PNR) is one of the fifty-seven protected areas that belong to the National System of Protected Areas (SINANPE) of Peru. Located in Ica Department, on the Pacific coast of Peru, it is the only coastal-marine ecosystem currently protected by the Peruvian government. PNR has been internationally recognized, principally as a wintering area for bird migrations. It has been designated as a Regional Shorebird Reserve by the Western Hemisphere Shorebird Reserve Network (1991), a Ramsar site by the Ramsar Convention on Wetlands of International Importance Especially as Waterfowl Habitat (1992), and a Particular Sensitive Sea Area by the …

Afci Quarterly Input – Unlv October Through December, 2004, Harry Reid Center For Environmental Studies. Nuclear Science And Technology Division

Transmutation Research Program Reports (TRP)

Quarterly report highlighting research projects, activities and objectives of the Transmutation Research Program at the Nuclear Science & Technology Division, Harry Reid Research Center.

The University of Nevada, Las Vegas supports the AFCI through research and development of technologies for economic and environmentally sound refinement of spent nuclear fuel. The UNLV program has four components: infrastructure, international collaboration, student-based research, and management and program support. Management and program support highlights are the following: the UNLV TRP hosted the Eighth Annual IAEA Actinide and Fission Product Partitioning & Transmutation Information Exchange Meeting (Nov. 9 – 11). 120 people from 22 countries …

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry, Morphology, And Surface Preparation: Quarterly Report (October-December 2004), Allen L. Johnson, John Farley, Dale L. Perry

Transmutation Sciences Materials (TRP)

This project has four components:

(1) the fabrication of a materials test apparatus with unique capabilities,

(2) comparative studies of steel corrosion under gas phase conditions comparable to the Lead Bismuth Eutectic (LBE) oxygen control conditions,

(3) isotope labeling studies, and

(4) collaborative efforts with other workers in the field.

Reactor Physics Studies For The Afci Race Project: Reactor-Accelerator Coupling Experiments Project: Quarterly Progress Report September-December 2004, Denis Beller

Transmutation Sciences Physics (TRP)

In the RACE Project of the U.S. Advanced Fuel Cycle Initiative (AFCI), a series of accelerator driven subcritical systems (ADSS) experiments will be conducted at the Idaho State University’s Idaho Accelerator Center (ISU-IAC), at the University of Texas (UT) at Austin, and at the Texas A&M University. In these experiments we will use electron accelerators to induce bremsstrahlung photon-neutron reactions in heavy-metal targets; this source of about 10¹² to 10¹³ n/s will then initiate fission reactions in the subcritical systems. These systems will include a compact, transportable assembly at ISU and TRIGA reactors at UT-Austin and Texas A&M. …

The Electrochemical Separation Of Curium And Americium: Quaterly Report August-December 2004, David W. Hatchett, Kenneth Czerwinski

Separations Campaign (TRP)

This research report outlines the current status and progress associated with the electrochemical separation of Curium and Americium. The following pages outline the progress on our project to date. We have been actively performing research on this project for three months and are currently on schedule in terms of the proposed timelines.

The initial focus of the project involved setting up the laboratories for the studies outlined in the grant proposal. The instrumentation needed included an electrochemical work station that will perform the bulk of the electrochemical studies. This instrument will complement the electrochemical instrumentation in Dr. Hatchett’s laboratory and …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, October 2004 To December 2004, Earl Wolfram, Thomas Hartmann, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert matrix fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of ²³⁹Pu. Ceramics will be synthesized and characterized based on the reactor physics results. The solubility the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, will be investigated in a manner to provide …

Seasonal Variations Of The Gravity Wave Momentum Flux In The Antarctic Mesosphere And Lower Thermosphere, P. J. Espy, G. O.L. Jones, G. R. Swenson, J. Tang, Michael J. Taylor

All Physics Faculty Publications

Airglow imager and dynasonde/imaging Doppler interferometer (IDI) radar wind measurements at Halley Station, Antarctica (75.6S, 26.6W) have been used to estimate the seasonal variation of the vertical fluxes of horizontal momentum carried by highfrequency atmospheric gravity waves. The cross-correlation coefficients between the vertical and horizontal wind perturbations were calculated from sodium (Na) airglow imager data collected during the austral winter seasons of 2000 and 2001. These were combined with wind velocity variances from coincident radar measurements to estimate the daily averaged upper limit of the vertical flux of horizontal momentum due to gravity waves. The resulting momentum flux at the …

Generalised Surfaces In ℝ³, Brendan Guilfoyle, Wilhelm Klingenberg

Publications

The correspondence between 2-parameter families of oriented lines in ℝ³ and surfaces in Tℙ¹ is studied, and the geometric properties of the lines are related to the complex geometry of the surface. Congruences generated by global sections of Tℙ¹ are investigated, and a number of theorems are proven that generalise results for closed convex surfaces in ℝ³.

Earthquake Triggering At Alaskan Volcanoes Following The 3 November 2002 Denali Fault Earthquake, Seth C. Moran, John A. Power, Scott D. Stihler, John J. Sa´Nchez, Jacqueline Caplan-Auerbach

Geology Faculty Publications

The 3 November 2002 M_W 7.9 Denali fault earthquake provided an excellent opportunity to investigate triggered earthquakes at Alaskan volcanoes. The Alaska Volcano Observatory operates short-period seismic networks on 24 historically active volcanoes in Alaska, 247–2159 km distant from the mainshock epicenter. We searched for evidence of triggered seismicity by examining the unfiltered waveforms for all stations in each volcano network for ~1 hr after the M_W 7.9 arrival time at each network and for significant increases in located earthquakes in the hours after the mainshock. We found compelling evidence for triggering only at the Katmai volcanic cluster …

A Multiple Linear Regression Analysis On Mathematics Placement At The University Of Tennessee, Knoxville, Steven K. Moore

Masters Theses

This paper looks at solving the least squares problem and then using that theory to solve a simple multiple regression analysis for placing students into mathematics courses at the University of Tennessee, Knoxville.

The first chapter is an introduction and a basic outline of the problem. Chapter 2 outlines the theory behind solving an actual least squares problem for both the general case and for the particular case of nonsingular matrices. Chapter 3 discusses assumptions that must be made when running the analysis.

In chapters 4 and 5 computers are discussed and software output is explained. Finally, Chapter 6 gives …

Ellipsometric Measurement Of Swelling Properties Associated With Ph Responsive Hydrogels In Solution, James F. Patton

Masters Theses

Previous investigations have demonstrated that aqueous solutions containing hydrogels using 2-hydroxyethyl methacrylate (2-HEMA) as one of the monomer components swell reversibly under variable conditions of pH, temperature, and ionic strength, based upon weight gain ratios. A more unique approach will be employed to measure swelling properties associated with pH responsive hydrogels in buffered solutions, namely ellipsometry. Traditionally ellipsometry has been used to measure thickness of materials on a nanoscale dimension under ambient conditions. Finally, more novel approaches of employing hydrogel swelling response properties will be investigated; including response to glucose and enzyme loading schemes. The goal of our project will …

Understanding The Dynamics Of Molecular Solids, Roman Wesolowski

Masters Theses

Superconductors, single-molecule magnets, and spin-ladders materials are at the center of interest in condensed matter science. All of these materials have incredibly important potential applications and their exploration is the key to the future technologies. We carried out various measurements on representative compounds of each group of interest. The main tool for all these projects was optical spectroscopy, varied in each case to apply magnetic field or change temperature. In our magneto-optical measurements of κ-(ET)₂Cu[N(CN)₂]Br and κ-(ET)₂Cu[N(CN)₂]Cl, we sought to understand correlations between intramolecular vibrations and superconductivity. We found several …

A Watershed-Based Classification System For Lakes In Agriculturally-Dominated Ecosystems: A Case Study Of Nebraska Reservoirs, Henry N. N. Bulley

Department of Geography: Dissertations, Theses, and Student Research

In recent decades substantial progress has been made in improving the quality of surface waters in the United States (Hawkins et al., 2000; EPA, 2000; EPA, 2001); nevertheless, much work remains to be done in assessing the state of impairment of lake waters. Impairment implies that the existing water quality of a lake, as measured by selected criteria (e.g., nitrogen, phosphorus, chlorophyll-a, Secchi depth), exceeds a threshold value or standard that presumably reflects optimal attainable lake water quality conditions (or "reference" conditions) (Hughes, 1995; EPA, 2000; EPA, 2001). Such impaired waters are not suitable for designated uses such as drinking, …

Discovery Of Co Gas In The Inner Disk Of Tw Hydrae, Terrence W. Rettig, Joe Haywood, Theodore Simon, Sean D. Brittain, Erika Gibb

Publications

We report the detection of rovibrationally excited CO emission from the inner disk of the classical T Tauri star (cTTS) TW Hya. We observe ~6 × 1021 g of CO gas with a rotational temperature of 430 ± 40 K. The linearity of the excitation plot suggests that the CO is optically thin. Atypical for cTTSs, hot CO was not detected, implying that TW Hya has cleared its inner disk region out to a radial distance of ~0.5 AU. We discuss implications for the structure of the disk as it relates to replenishment and planet formation.

Ir Studies Of The Interaction Of Surfactants And Polyelectrolytes Adsorbed On Tio2 Particles, Haiyan Li

Electronic Theses and Dissertations

Polymers/surfactants are used to control and modify the interfacial properties of particulate suspensions. The resulting properties are dependent on the amount of adsorbed surfactants/polymers on the surface as well as the nature of the aggregated structures. Often these interactions are complex and not well understood. In this thesis we have used Attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) to identify surfactant, mixed surfactant, polyelectrolyte and mixed polyelectrolyte surfactant structures formed on charged Ti0₂ particles. In addition, the change occurring to the structure of an adsorbed polymer layer on Ti0₂ to flowing suspension of silica particles was studied. A …

Context-Specific Preference Learning Of One Dimensional Quantitative Geospatial Attributes Using A Neuro-Fuzzy Approach, Georgios Mountrakis

Electronic Theses and Dissertations

Change detection is a topic of great importance for modern geospatial information systems. Digital aerial imagery provides an excellent medium to capture geospatial information. Rapidly evolving environments, and the availability of increasing amounts of diverse, multiresolutional imagery bring forward the need for frequent updates of these datasets. Analysis and query of spatial data using potentially outdated data may yield results that are sometimes invalid. Due to measurement errors (systematic, random) and incomplete knowledge of information (uncertainty) it is ambiguous if a change in a spatial dataset has really occurred. Therefore we need to develop reliable, fast, and automated procedures that …

Niel Calculations For High-Energy Heavy Ions, John W. Wilson, I. Jun, M. A. Xapsos, E. A. Burke, F. F. Badavi, L. W. Townsend

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Calculations of NIEL are reported for heavy ions prominent in the space environment for energies ranging from 200 MeV per nucleon to 2 GeV per nucleon.

Diel Foraging Behavior Of American White Pelicans ()Pelecanus Erythrorhynchos) On Experimental Aquaculture Ponds , Scott J. Werner

United States Department of Agriculture Wildlife Services: Staff Publications

Videography and night vision equipment were used to observe the diurnal and nocturnal activities of American white pelicans (Pe1ecanus erythrorhynchos) (N= 6) foraging on three experimental (0.04 ha) channel catfish (Ictalurus punctatus) aquaculture ponds in March 2001. Captive pelicans spent most time foraging per hour from 1700 through 2300 h (CST). No foraging was observed from 0700 through 0800 h. Fish captures per hour were greatest from 1700 through 1900 h. On average, captive pelicans (N = 5) consumed 1.0 ± 0.2 kg of catfish per bird per day during the 10-d foraging …

Genetic Methods Improve Accuracy Of Gender Determination In Beavers, Christen Lenney Williams, Stewart W. Breck, Bruce W. Baker

United States Department of Agriculture Wildlife Services: Staff Publications

Gender identification of sexually monomorphic mammals can be difficult. We used analysis of zinc-finger protein (Zfx and Zfy) DNA regions to determine gender of 96 beavers (Castor canadensis) from 3 areas and used these results to verify gender determined in the field. Gender was correctly determined for 86 (89.6%) beavers. Incorrect assignments were not attributed to errors in any one age or sex class. Although methods that can be used in the field (such as morphological methods) can provide reasonably accurate gender assignments in beavers, the genetic method might be preferred in certain situations.

The Kinetics Following Photolysis Of Nitrosyl Bromide, Lori A. Mahoney

Theses and Dissertations

One candidate for the development of a tunable laser in the mid-infrared for use as a defensive countermeasure against passive sensors exploits the nitric oxide (NO) transition at 5.4 μm. However, the difficulty with this mechanism is that when bromine (Br₂) and NO are present in a mixture, nitrosyl bromide (BrNO) is also created. The absorption bands present in BrNO complicate the design of such a laser. This thesis determines the forward and reverse rate constants of the reaction of Br₂ and NO to form BrNO following the photolysis of BrNO using Fourier Transform Infrared absorption spectroscopy. …

Analysis Of Benzo(A)Pyrene-Induced Gene Expression Changes In Fisher 344 Rat Liver By Affymetrix Microarray And Quantitative Real-Time Pcr, Alhaji Umar N’Jai

Dissertations

No abstract provided.

The Glacial Geology Of Southern St. Joseph County, Michigan, Linda Nicks

Dissertations

The objective of the dissertation was to map the glacial geology in southern St. Joseph County, Michigan. The surficial geology was divided into three distinct land systems which are moraine, outwash and fan deposits. The Sturgis Moraine is the most prominent feature transecting the study area from east to west. The topography is further dissected by southwest-trending channels interpreted as tunnel channels.

Thick accumulations of sand and gravel in the study area indicate that glacial meltwater deposition played a dominant role in shaping the landscape. Based on the relative size of the channels and outwash deposits, the largest contribution from …

The John Muir Newsletter, Winter 2004/2005, The John Muir Center For Environmental Studies

Muir Center Newsletters (1981-2015)

Newsletter UNiVfeftsnY or the Pacific, Stockton, cA Volume 15, Number 1 Winter 2004/2005 Black Sheep of the in Muir's Motivations for Yosemite National hi] Jeimij Krone ERRA: GREAT! Park (he expansive 760,000-acre Yosemite National Park consists of meadows, forests, and mountains that presently awe over three million visitors annually.1 Yosemite Valley became the second national park in 1890 after an intense nationwide conflict that most tourists neglect to acknowledge when scaling the glacial-smoothened sides of Half Dome or navigating woodlands of sugar pines and giant sequoias. John Muir, a foremost figure in the early conservation movement, spearheaded the proposal and …

Unconformities And Age Relationships, Tongue River And Older Members Of The Fort Union Formation (Paleocene), Western Williston Basin, U.S.A., Edward S. Belt, Joseph H. Hartman, John A. Diemer, Timothy J. Kroeger, Neil E. Tibert, H. Allen Curran

Geosciences: Faculty Publications

An unconformable relationship is observed within the Paleocene Fort Union Formation in the western Williston Basin at the contact between the Tongue River Member and the underlying Lebo and Ludlow Members. Isotopic dates and pollen biozone data reported here are integrated with previously published data. A new correlation of these facies results in a revised history of localized depositional and tectonic events. One unconformity occurs at this lithological contact in the Pine Hills (PH), Terry Badlands (TB), and Ekalaka (E) areas west of the Cedar Creek anticline (CCA), and another unconformity occurs at the same lithological contact in the Little …

Single Muon Production And Implications For Charm In √Sn N = 200 Gev Au+Au Collisions, Andrew Miles Glenn

Doctoral Dissertations

The PHENIX experiment, located at the Brookhaven National Laboratory’s Rela- tivistic Heavy Ion Collider, is designed to study high energy proton+proton and nu- cleus+nucleus collisions in order to characterize hot and dense nuclear matter. This dissertation presents the first analysis of single muon production in √sN N = 200 GeV Au+Au reactions. Implications of the forward rapidity measurements for charm pro- duction are discussed. Motivation for charm production measurements and the role of open charm in characterizing the medium created in relativistic heavy ion collisions are presented, and the importance of measurements at forward rapidity is established. The results of …

Discovery Of The Near-Ir Afterglow And Of The Host Of Grb 030528, A. Rau, J. Greiner, S. Klose, M. Salvato, J. M. Castro Cerón, Dieter H. Hartmann, A. Fruchter, A. Levan, N. R. Tanvir, J. Gorosabel

Publications

The rapid dissemination of an arcmin-sized HETE-2 localization of the long-duration X-ray flash GRB 030528 led to a ground-based multi-observatory follow-up campaign. We report the discovery of the near-IR afterglow, and also describe the detection of the underlying host galaxy in the optical and near-IR bands. The afterglow is classified as “optically dark” as it was not detected in the optical band. The K-band photometry presented here suggests that the lack of optical detection was simply the result of observational limitations (lack of rapid and deep observations plus high foreground extinction). Simple power law fits to the afterglow in the …

Search For A Narrow Charmed Baryonic State Decaying To D*±P∓ In Ep Collisions At Hera, S. Chekanov, M. Derrick, J. H. Loizides, S. Magill, S. Miglioranzi, B. Musgrave, J. Repond, R. Yoshida, Margarita C. K. Mattingly, N. Pavel, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, A. Margotti, A. Montanari, R. Nania, F. Palmonari, A. Pesci, A. Polini

Faculty Publications

A resonance search has been made in the D*±p∓ invariant-mass spectrum with the ZEUS detector at HERA using an integrated luminosity of 126 pb-1. The decay channels D*+ -→ D0πs+ → (K -π+)πs+ and D*+ → D0πs+ → (K-π+π+π-) πs+ (and the corresponding antiparticle decays) were used to identify D*± mesons. No resonance structure was observed in the D*± p∓ mass spectrum from more than 60 000 reconstructed D*± mesons. The results are not compatible with a report of the H1 Collaboration of a charmed pentaquark, Θc0. © Springer-Verlag / Società Italiana di Fisica 2004.