Physical Sciences and Mathematics Commons^™

The Thermochemistry Of 2,4-Pentanedione Revisited: Observance Of A Nonzero Enthalpy Of Mixing Between Tautomers And Its Effects On Enthalpies Of Formation, Manuel Temprado, Maria Victoria Roux, Patamaporn Umnahanant, Hui Zhao, James S. Chickos

James Chickos

No abstract provided.

Cluster Analysis Of Genomic Data With Applications In R, Katherine S. Pollard, Mark J. Van Der Laan

U.C. Berkeley Division of Biostatistics Working Paper Series

In this paper, we provide an overview of existing partitioning and hierarchical clustering algorithms in R. We discuss statistical issues and methods in choosing the number of clusters, the choice of clustering algorithm, and the choice of dissimilarity matrix. In particular, we illustrate how the bootstrap can be employed as a statistical method in cluster analysis to establish the reproducibility of the clusters and the overall variability of the followed procedure. We also show how to visualize a clustering result by plotting ordered dissimilarity matrices in R. We present a new R package, hopach, which implements the hybrid clustering method, …

Multiple Testing Procedures And Applications To Genomics, Merrill D. Birkner, Katherine S. Pollard, Mark J. Van Der Laan, Sandrine Dudoit

U.C. Berkeley Division of Biostatistics Working Paper Series

This chapter proposes widely applicable resampling-based single-step and stepwise multiple testing procedures (MTP) for controlling a broad class of Type I error rates, in testing problems involving general data generating distributions (with arbitrary dependence structures among variables), null hypotheses, and test statistics (Dudoit and van der Laan, 2005; Dudoit et al., 2004a,b; van der Laan et al., 2004a,b; Pollard and van der Laan, 2004; Pollard et al., 2005). Procedures are provided to control Type I error rates defined as tail probabilities for arbitrary functions of the numbers of Type I errors, V_n, and rejected hypotheses, R_n. These error rates include: …

A Full-Wave Investigation Of The Use Of A ‘‘Cancellation Factor’’ In Gravity Wave–Oh Airglow Interaction Studies, Michael P. Hickey Ph.D., Yonghui Yu

Publications

Atmospheric gravity waves (GWs) perturb minor species involved in the chemical reactions of airglow emissions in the upper mesosphere and lower thermosphere. In order to determine gravity wave fluxes and the forcing effects of gravity waves on the mean state (which are proportional to the square of the wave amplitude), it is essential that the amplitude of airglow brightness fluctuation be related to the amplitude of major gas density fluctuation in a deterministic way. This has been achieved through detailed modeling combining gravity wave dynamics described using a full-wave model with the chemistry relevant to the airglow emission of interest. …

Glossary Of Terms For Use With The 'A Million Hectares For The Future' Salinity Management Workshops, Rebecca Heath, Paul Raper

Agriculture reports

This Glossary has been developed as part of the GRDC/NDSP-funded, 'A Million Hectares for the Future' project with support and input from key personnel from the Department of Agriculture, Western Australia.

Robust Inferences For Covariate Effects On Survival Time With Censored Linear Regression Models, Larry Leon, Tianxi Cai, L. J. Wei

Harvard University Biostatistics Working Paper Series

Various inference procedures for linear regression models with censored failure times have been studied extensively. Recent developments on efficient algorithms to implement these procedures enhance the practical usage of such models in survival analysis. In this article, we present robust inferences for certain covariate effects on the failure time in the presence of "nuisance" confounders under a semiparametric, partial linear regression setting. Specifically, the estimation procedures for the regression coefficients of interest are derived from a working linear model and are valid even when the function of the confounders in the model is not correctly specified. The new proposals are …

Algorithmic Beauty Of Buildings Methods For Procedural Building Generation, Jess Martin

Computer Science Honors Theses

As virtual reality simulations, video games, and computer animated movies become more prevalent, the need arises to generate the content the three-dimensional models via an algorithm rather than crafting them by hand. Previous research in the area of procedural building generation has focused merely on the external appearance of commercial buildings. These methods are unsatisfactory for certain applications due to the lack of a walk-through feature. A new algorithm is proposed to generate residential units with realistic floor plans based partially on the architectural observations of Christopher Alexander. Results for the algorithm display real-time performance and a resemblance to real …

Integration Of Epitaxial Colossal Magnetoresistive Films Onto Si(100) Using Srtio3 As A Template Layer, Aswini K. Pradhan, S. Mohanty, Kai Zhang, J.B. Dadson, E.M. Jackson, D. Hunter, Rakhim R. Rakhimov, G.B. Loutts, Jun Zhang, David J. Sellmyer

David Sellmyer Publications

We report on the integration of epitaxial colossal magnetoresistive La_0.67Ba_0.33MnO films on Si(100) semiconductor using SrTiO₃ template layer by pulsed-laser deposition. X-ray diffraction reveals the superior quality of the manganite film that grows epitaxially on heteroepitaxially grown SrTiO₃ template layer on Si substrate. The epitaxial films demonstrate remarkable surface morphology, magnetic transition and hysteresis, magnetoresistance, and ferromagnetic resonance, illustrating the ferromagnetic nature of the film and possible device applications at room temperature.

High-Throughput Inference Of Protein-Protein Interaction Sites From Unassigned Nmr Data By Analyzing Arrangements Induced By Quadratic Forms On 3-Manifolds, Ramgopal R. Mettu, Ryan H. Lilien, Bruce Randall Donald

Computer Science Technical Reports

We cast the problem of identifying protein-protein interfaces, using only unassigned NMR spectra, into a geometric clustering problem. Identifying protein-protein interfaces is critical to understanding inter- and intra-cellular communication, and NMR allows the study of protein interaction in solution. However it is often the case that NMR studies of a protein complex are very time-consuming, mainly due to the bottleneck in assigning the chemical shifts, even if the apo structures of the constituent proteins are known. We study whether it is possible, in a high-throughput manner, to identify the interface region of a protein complex using only unassigned chemical shift …

Introduction To Salinity - Workshop Manual For Participants, T M. Lacey

Agriculture reports

This is the first in a series of workshops looking at dryland salinity and options to manage it. These ?Million hectares? workshops have the common themes of environmental improvement. They provide information to help participants identify the risks within the catchment and at a farm level, assess both the likelihood of the risk occurring and consequences if the risk is not managed and determine the best course of action for individual. Participants will determine their courses of action based on their specific circumstances and goals. There is no one recipe that is suited to all participants. The Participants Notes when …

Modifications Of Human Βa1/Βa3-Crystallins Include S-Methylation, Glutathiolation, And Truncation, Veniamin N. Lapko, Ronald Cerny, David L. Smith, Jean B. Smith

Ronald Cerny Publications

Disulfide bonding of lens crystallins contributes to the aggregation and insolubilization of these proteins that leads to cataract. A high concentration of reduced glutathione is believed to be key in preventing oxidation of crystallin sulfhydryls to form disulfide bonds. This protective role is decreased in aged lenses because of lower glutathione levels, especially in the nucleus. We recently found that human [1]-crystallins undergo S-methylation at exposed cysteine residues, a reaction that may prevent disulfide bonding. We report here that βA1/A3-crystallins are also methylated at specific cysteine residues and are the most heavily methylated of the human lens crystallins. Among the …

Five-Year Review Of Executive Order 13112 On Invasive Species

National Invasive Species Council

Invasive species inhabit all regions of the United States and every nation. The price society pays for invasives is reflected not only in significant economic damage but also in high level of environmental degradation, loss of recreational opportunities, and harm to animal, plant, and human health. Executive Order 13112 (EO) was issued in 1999 to enhance federal coordination and response to the complex and accelerating problem of invasive species. As directed by the EO, the National Invasive Species Council has approved this report for the Office of Management and Budget to assess the effectiveness of the EO and evaluate whether …

Guidelines For Ranking Invasive Species Control Projects

National Invasive Species Council

Invasive species issues challenge all of us everyday. Whether you are formally tasked with land management or simply active in exploring and protecting ecosystems, dealing with the threats presented by the multitude of terrestrial, aquatic, or microbial invasive species is a complicated matter. The National Invasive Species Council (NISC) has been tasked, since the signing of Executive Order 13112 in 1999, with assisting in the coordination of efforts to combat invasive species. The NISC developed the National Invasive Species Management Plan (Plan) and Action Item #32 of the Plan states: By January 2003, NISC will develop and issue guidance for …

Canada Thistle

National Invasive Species Council

Alternate Names

Synonyms

Description

Similar Species

Family: Asteraceae

Ecological Impact

Biology and Invasive Potential

Distribution and Abundance

Management

Notes

St. Croix National Scenic Riverway Aquatic Invasive Species Interagency Task Force: 2005 Action Plan For The Lower St. Croix River

National Invasive Species Council

This plan outlines strategies and actions proposed by the participating agencies for the 2005 season to help accomplish the Task Force purpose and implement actions from the St. Croix Scenic Riverway Comprehensive Interstate Management Plan.

Implementing this action plan will help attain the following goals of the comprehensive interstate management plan:

Goal I: Prevent or slow the spread of aquatic invasive species into and within the St. Croix River.

Goal II: Abate harmful ecological, economic, social and public health impacts resulting from infestation of aquatic invasive species.

Asian Carps Of The Genus Hypophthalmichthys (Pisces, Cyprinidae) ― A Biological Synopsis And Environmental Risk Assessment, Cindy S. Kolar, Duane C. Chapman, Walter R. Courtenay Jr., Christine M. Housel, James D. Williams, Dawn P. Jennings

National Invasive Species Council

Carps of the family Cyprinidae, the largest family of freshwater fishes in the world (Nelson 1994), have long been introduced beyond their native ranges, a practice that continues today. Although carps have been introduced for several centuries, the widespread introduction of the genus Hypophthalmichthys, the bigheaded carps, is a relatively recent phenomenon. All three recognized species of Hypophthalmichthys—H. nobilis, in North America referred to as Bighead Carp; H. molitrix; Silver Carp; and H. harmandi, Largescale Silver Carp—are native to fresh waters of eastern Asia. Largescale Silver Carp have been introduced elsewhere in west-central Asia as a …

Focus Group Conference Report And Pathways Ranking Guide: June- August 2005

National Invasive Species Council

This document represents the second version of a guide and process for pathway definition, analysis and prioritization. It is expected that this document will undergo another trial test and revision prior to full implementation, though we strongly believed this is a ‘workable’ product that only requires refinement.

Throughout this systems development process, the Pathways Work Team struggled with several issues relevant to scientific data and public policy. While this report in no way attempts to resolve such intricate issues, it is essential that these considerations be brought to the forefront for future decision-making efforts and as such are enumerated below: …

Enhancing Message Privacy In Wired Equivalent Privacy., Darshan Purandare

Electronic Theses and Dissertations

The 802.11 standard defines the Wired Equivalent Privacy (WEP) and encapsulation of data frames. It is intended to provide data privacy to the level of a wired network. WEP suffered threat of attacks from hackers owing to certain security shortcomings in the WEP protocol. Lately, many new protocols like WiFi Protected Access (WPA), WPA2, Robust Secure Network (RSN) and 802.11i have come into being, yet their implementation is fairly limited. Despite its shortcomings one cannot undermine the importance of WEP as it still remains the most widely used system and we chose to address certain security issues and propose some …

An Introduction To Hellmann-Feynman Theory, David Wallace

Electronic Theses and Dissertations

The Hellmann-Feynman theorem is presented together with certain allied theorems. The origin of the Hellmann-Feynman theorem in quantum physical chemistry is described. The theorem is stated with proof and with discussion of applicability and reliability. Some adaptations of the theorem to the study of the variation of zeros of special functions and orthogonal polynomials are surveyed. Possible extensions are discussed.

Graph-Theoretic Approach To Modeling Propagation And Control Of Network Worms, Zoran Nikoloski

Electronic Theses and Dissertations

In today's network-dependent society, cyber attacks with network worms have become the predominant threat to confidentiality, integrity, and availability of network computing resources. Despite ongoing research efforts, there is still no comprehensive network-security solution aimed at controling large-scale worm propagation. The aim of this work is fivefold: (1) Developing an accurate combinatorial model of worm propagation that can facilitate the analysis of worm control strategies, (2) Building an accurate epidemiological model for the propagation of a worm employing local strategies, (3) Devising distributed architecture and algorithms for detection of worm scanning activities, (4) Designing effective control strategies against the worm, …

Affective Design In Technical Communication, Michael Alan Rosen

Electronic Theses and Dissertations

Traditional human-computer interaction (HCI) is based on 'cold' models of user cognition; that is, models of users as purely rational beings based on the information processing metaphor; however, an emerging perspective suggests that for the field of HCI to mature, its practitioners must adopt models of users that consider broader human needs and capabilities. Affective design is an umbrella term for research and practice being conducted in diverse domains, all with the common thread of integrating emotional aspects of use into the creation of information products. This thesis provides a review of the current state of the art in affective …

The Scintillation Index In Moderate To Strong Turbulence For The Gaussian Beam Wave Along A Slant Path, Fredrick Eugene Thomas

Electronic Theses and Dissertations

Scintillation is one of the most common statistics in the literature of mathematical modeling of laser propagation through random media. One approach to estimating scintillation is through the Rytov approximation, which is limited to weak atmospheric turbulence. Recently, an improvement of the Rytov approximation was developed employing a linear filter function technique. This modifies the Rytov approximation and extends the validity into the moderate to strong regime. In this work, an expression governing scintillation of a Gaussian beam along an uplink slant path valid in all regimes of turbulence is presented, as well as results for the limiting cases of …

Decision Theory Classification Of High-Dimensional Vectors Based On Small Samples, David Bradshaw

Electronic Theses and Dissertations

In this paper, we review existing classification techniques and suggest an entirely new procedure for the classification of high-dimensional vectors on the basis of a few training samples. The proposed method is based on the Bayesian paradigm and provides posterior probabilities that a new vector belongs to each of the classes, therefore it adapts naturally to any number of classes. Our classification technique is based on a small vector which is related to the projection of the observation onto the space spanned by the training samples. This is achieved by employing matrix-variate distributions in classification, which is an entirely new …

Insulator-Insulator Contact Charging As A Function Of Pressure, Michael Hogue

Electronic Theses and Dissertations

Metal - metal and to an extent metal - insulator contact or triboelectric charging are well known phenomena with good theoretical understanding of the charge exchange mechanism. However, insulator – insulator charging is not as well understood. Theoretical and experimental research has been performed that shows that the surface charge on an insulator after triboelectric charging with another insulator is rapidly dissipated with lowered atmospheric pressure. This pressure discharge is consistent with surface ions being evaporated off the surface once their vapor pressure falls below the saturation vapor pressure. A two-phase equilibrium model based on an ideal gas of singly …

Reaction Rates For The Dehalogenation Of Trichloroethylene Using Various Types Of Zero-Valent Iron, Neil Stewart

Electronic Theses and Dissertations

Remediation of trichloroethylene (TCE) and other chlorinated solvents is of great concern due to their toxicity and their persistence in the environment. Iron has been used extensively in the past decade as a subsurface reactive agent for the remediation of dense, nonaqueous-phase liquids (DNAPLs). Permeable reactive barrier walls (PRBW) have been installed at many sites around the country to treat contaminated plumes resulting from the presence of DNAPL pools. The use of zero-valent metals, such as iron, to effectively reductively dechlorinate DNAPLs has been employed as the reactive material in these PRBWs (Gillham et al., 1993). However, limited work has …

Contributions To Automatic Particle Identification In Electron Micrographs: Algorithms, Implementation, And Applications, Vivek Singh

Electronic Theses and Dissertations

Three dimensional reconstruction of large macromolecules like viruses at resolutions below 8 Ã… - 10 Ã… requires a large set of projection images and the particle identification step becomes a bottleneck. Several automatic and semi-automatic particle detection algorithms have been developed along the years. We present a general technique designed to automatically identify the projection images of particles. The method utilizes Markov random field modelling of the projected images and involves a preprocessing of electron micrographs followed by image segmentation and post processing for boxing of the particle projections. Due to the typically extensive computational requirements for extracting hundreds of …

Refractive Indices Of Liquid Crystals And Their Applications In Display And Photonic Devices, Jun Li

Electronic Theses and Dissertations

Liquid crystals (LCs) are important materials for flat panel display and photonic devices. Most LC devices use electrical field-, magnetic field-, or temperature-induced refractive index change to modulate the incident light. Molecular constituents, wavelength, and temperature are the three primary factors determining the liquid crystal refractive indices: ne and no for the extraordinary and ordinary rays, respectively. In this dissertation, we derive several physical models for describing the wavelength and temperature effects on liquid crystal refractive indices, average refractive index, and birefringence. Based on these models, we develop some high temperature gradient refractive index LC mixtures for photonic applications, such …

Multizoom Activity Recognition Using Machine Learning, Raymond Smith

Electronic Theses and Dissertations

In this thesis we present a system for detection of events in video. First a multiview approach to automatically detect and track heads and hands in a scene is described. Then, by making use of epipolar, spatial, trajectory, and appearance constraints, objects are labeled consistently across cameras (zooms). Finally, we demonstrate a new machine learning paradigm, TemporalBoost, that can recognize events in video. One aspect of any machine learning algorithm is in the feature set used. The approach taken here is to build a large set of activity features, though TemporalBoost itself is able to work with any feature set …

Structural Study Of Disease Related Proteins, Ayse Sinem Ozyurt

Electronic Theses and Dissertations

The availability of complete sequences for the genomes of many organisms changes the researcher's attention from genome sequencing to finding the function of gene products, the proteins. The three dimensional (3D) structure of a protein is helpful to understand its function, because tertiary structure is more conserved in evolution than sequence. The 3D structures can be found quickly by using high-throughput (HT) methods for protein expression, purification, characterization and structure determination. This process is very challenging in every step. Therefore we selected nearly 200 cancer related proteins as targets to see the difficulties in trying to determine the web predicted …

A Solvent-Free Baeyer–Villiger Lactonization For The Undergraduate Organic Laboratory: Synthesis Of Γ-T-Butyl-Ε-Caprolactone, John J. Esteb, James N. Hohman, Diana E. Schladaminger, Anne M. Wilson

Scholarship and Professional Work - LAS

We present an experiment involving the Baeyer–Villiger oxidation reactionfor a first-year organic chemistry class. The Baeyer–Villiger reactionprovides an efficient method to convert ketones to esters or lactones. Most organictextbooks cover the Baeyer–Villiger reaction but owing to a lack of suitableexperiments, students seldom get to explore the reaction in the undergraduateteaching laboratory. In this experiment, m-chloroperoxybenzoic acid(m-CPBA) and4-tert-butylcyclohexanone are mixed together for 30 minutes under solvent-freeconditions to produce γ-t-butyl-ε-caprolactone in 95%yield. The solvent-free nature of this procedure greatly limits the quantityof waste generated by students and keeps costs low by removing the need for solvent.