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2005

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Articles 4471 - 4500 of 5573

Full-Text Articles in Physical Sciences and Mathematics

Hydrologic Properties Of Coal Beds In The Powder River Basin, Montana I. Geophysical Log Analysis, Roger H. Morin Jan 2005

Hydrologic Properties Of Coal Beds In The Powder River Basin, Montana I. Geophysical Log Analysis, Roger H. Morin

United States Geological Survey: Staff Publications

As part of a multidisciplinary investigation designed to assess the implications of coal-bed methane development on water resources for the Powder River Basin of southeasternMontana, six wells were drilled through Paleocene-age coal beds along a 31 km east–west transect within the TongueRiver drainage basin.Analysis of geophysical logs obtained in thesewells provides insight into the hydrostratigraphic characteristics of the coal and interbedded siliciclastic rocks and their possible interaction with the local stress field.Natural gamma and electrical resistivity logswere effective in distinguishing individual coal beds. Full-waveformsonic logswere used to determine elastic properties of the coal and an attendant estimate of aquifer storage …

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Negative Correlation Between Porosity And Hydraulic Conductivity In Sand-And-Gravel Aquifers At Cape Cod, Massachusetts, Usa, Roger H. Morin Jan 2005

Negative Correlation Between Porosity And Hydraulic Conductivity In Sand-And-Gravel Aquifers At Cape Cod, Massachusetts, Usa, Roger H. Morin

United States Geological Survey: Staff Publications

Although it may be intuitive to think of the hydraulic conductivity K of unconsolidated, coarse-grained sediments as increasing monotonically with increasing porosity ɸ , studies have documented a negative correlation between these two parameters under certain grain-size distributions and packing arrangements. This is confirmed at two sites on Cape Cod, Massachusetts, USA, where groundwater investigations were conducted in sand-and-gravel aquifers specifically to examine the interdependency of several aquifer properties using measurements from four geophysical well logs. Along with K and ɸ , the electrical resistivity R0 and the natural gamma activity γ of saturated deposits were determined as functions …

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Population Structure Of Columbia Spotted Frogs (Rana Luteiventris) Is Strongly Affected By The Landscape, W. Chris Funk, Michael S. Blouin, Paul Stephen Corn, Bryce A. Maxell, David S. Pilliod, Stephen Amish, Fred W. Allendorf Jan 2005

Population Structure Of Columbia Spotted Frogs (Rana Luteiventris) Is Strongly Affected By The Landscape, W. Chris Funk, Michael S. Blouin, Paul Stephen Corn, Bryce A. Maxell, David S. Pilliod, Stephen Amish, Fred W. Allendorf

United States Geological Survey: Staff Publications

Landscape features such as mountains, rivers, and ecological gradients may strongly affect patterns of dispersal and gene flow among populations and thereby shape population dynamics and evolutionary trajectories. The landscape may have a particularly strong effect on patterns of dispersal and gene flow in amphibians because amphibians are thought to have poor dispersal abilities. We examined genetic variation at six microsatellite loci in Columbia spotted frogs (Rana luteiventris) from 28 breeding ponds in western Montana and Idaho, USA, in order to investigate the effects of landscape structure on patterns of gene flow. We were particularly interested in addressing …

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Combining Structure-Based Drug Design And Pharmacophores, Renate Griffith, T. T. T. Luu, James A. Garner, Paul A. Keller Jan 2005

Combining Structure-Based Drug Design And Pharmacophores, Renate Griffith, T. T. T. Luu, James A. Garner, Paul A. Keller

Faculty of Science - Papers (Archive)

Development towards integrated computer-aided drug design methodologies is presented by utilising crystal structure complexes to produce structure-based pharmacophores. These novel pharmacophores represent the ligand features that are involved in interactions with the target protein, as well as the space around the ligand occupied by the protein. The protein-ligand complexes can also yield information about all interactions that ligands could potentially form with the binding site, as well as about the size of the binding cavity. Together, these describe a 'superligand', which can also be viewed as a pharmacophore. Various types of novel pharmacophores are discussed and compared, using HIV-1 Reverse …

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A Convenient And Efficient Synthesis Of (S)-Lysine And (S)-Arginine Homologues Via Olefin Cross-Metathesis, Timothy P. Boyle, John B. Bremner, Jonathan A. Coates, Paul A. Keller, Stephen G. Pyne Jan 2005

A Convenient And Efficient Synthesis Of (S)-Lysine And (S)-Arginine Homologues Via Olefin Cross-Metathesis, Timothy P. Boyle, John B. Bremner, Jonathan A. Coates, Paul A. Keller, Stephen G. Pyne

Faculty of Science - Papers (Archive)

A convenient five step synthesis of (S)-homolysine, incorporating a key olefin cross-metathesis step in the chain extension methodology, has been developed, together with a six step related synthesis of a new homologue of arginine, (S)-bishomoarginine.

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Force-Velocity Correlations In A Dense, Collisional, Granular Flow, Emily Gardel, Ellen Keene, Sonia Dragulin, Nalini Easwar, Narayanan Menon Jan 2005

Force-Velocity Correlations In A Dense, Collisional, Granular Flow, Emily Gardel, Ellen Keene, Sonia Dragulin, Nalini Easwar, Narayanan Menon

Physics: Faculty Publications

We report measurements in a 2-dimensional, gravity-driven, collisional, granular flow of the normal force delivered to the wall and of particle velocity at several points in the flow. The wall force and the flow velocity are negatively correlated. This correlation falls off only slowly when the wall force is correlated against the flow velocity at various locations across the channel, but dies away on the scale of a few particle diameters upstream or downstream. The data support a picture of short-lived chains of frequently colliding particles that extend transverse to the flow direction, making transient load-bearing bridges that cause bulk …

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Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. J. Long, O. O. Famodu, M. Murakami, Jason R. Hattrick-Simpers, G. W. Rubloff, M. Stukowski, K. Rajan Jan 2005

Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. J. Long, O. O. Famodu, M. Murakami, Jason R. Hattrick-Simpers, G. W. Rubloff, M. Stukowski, K. Rajan

Faculty Publications

We discuss techniques for managing and visualizing x-ray diffraction spectrum data for thin film composition spreads which map large fractions of ternary compositional phase diagrams. An in-house x-ray microdiffractometer is used to obtain spectra from over 500 different compositions on an individual spread. The MATLAB software is used to quickly organize the data and create various plots from which one can quickly grasp different information regarding structural and phase changes across the composition spreads. Such exercises are valuable in rapidly assessing the “overall” picture of the structural evolution across phase diagrams before focusing in on specific composition regions for detailed …

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Interphase Exchange Coupling In Fe/Sm-Co Bilayers With Gradient Fe Thickness, Ming-Hui Yu, Jason R. Hattrick-Simpers, Ichiro Takeuchi, Jing Li, Z. L. Wang, J. P. Liu, S. E. Lofland, Somdev Tyagi, J. W. Freeland, D. Giubertoni, M. Bersani, M. Anderle Jan 2005

Interphase Exchange Coupling In Fe/Sm-Co Bilayers With Gradient Fe Thickness, Ming-Hui Yu, Jason R. Hattrick-Simpers, Ichiro Takeuchi, Jing Li, Z. L. Wang, J. P. Liu, S. E. Lofland, Somdev Tyagi, J. W. Freeland, D. Giubertoni, M. Bersani, M. Anderle

Faculty Publications

We have fabricated Fe∕Sm–Co bilayers with gradient Fe thicknesses in order to systematically study the dependence of exchange coupling on the thickness of the Fe layer. The Fe layer was deposited at two different temperatures (150 and 300°C) to study the effect of deposition temperature on the exchange coupling. Magneto-optical Kerr effect and x-ray magnetic circular dichroism (XMCD) have been employed as nondestructive rapid characterization tools to map the magnetic properties of the gradient samples. Systematic enhancement in exchange coupling between the soft layer and the hard layer is observed as the soft layer thickness is decreased. Separate exchange couplings …

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Shoreline Evolution Chesapeake Bay And Piankatank River Shorelines Mathews County, Va, C. Scott Hardaway Jr., Donna A. Milligan, Lyle M. Varnell, Christine A. Wilcox, George R. Thomas Jan 2005

Shoreline Evolution Chesapeake Bay And Piankatank River Shorelines Mathews County, Va, C. Scott Hardaway Jr., Donna A. Milligan, Lyle M. Varnell, Christine A. Wilcox, George R. Thomas

Reports

Shoreline evolution is the change in shore position through time. In fact, it is the material resistance of the coastal geologic underpinnings against the impinging hydrodynamic (and aerodynamic) forces. Along the shores of Chesapeake Bay, it is a process-response system. The processes at work include winds, waves, tides and currents, which shape and modify coastlines by eroding, transporting and depositing sediments. The shore line is commonly plotted and measured to provide a rate of change but it is as important to understand the geomorphic patterns of change. Shore analysis provides the basis to know how a particular coast has changed …

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Isotopic Tracers As Evidence Of Denitrification In The Karlsruhe Aquifer, Eben J. Spencer Jan 2005

Isotopic Tracers As Evidence Of Denitrification In The Karlsruhe Aquifer, Eben J. Spencer

Theses and Dissertations

The Karlsruhe Aquifer of north-central North Dakota has experienced considerable nitrate contamination sparking an investigation by the North Dakota State Water Commission. Certain portions of the aquifer have experienced nitrate-N concentrations of up to seven times the drinking water standard. Although contamination is evident it is possible the NO₃¯ is naturally being eliminated by denitrification, whereby bacteria reduce NO₃¯ to nitrogen gas. Evidence of denitrification may be illustrated by accelerated reduction of NO₃¯ relative to the conservative tracer Cl¯ coupled with an increase in the heavy isotopes of 15N and 18O within the NO₃¯ ion. Such an increase is not …

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Punishment And Rehabilitation Views Of Social Work Majors And Non-Social Work Students: An Exploratory Study, Eric G. Lambert, Sudershan Pasupuleti, Reva I. Allen Jan 2005

Punishment And Rehabilitation Views Of Social Work Majors And Non-Social Work Students: An Exploratory Study, Eric G. Lambert, Sudershan Pasupuleti, Reva I. Allen

Journal of the South Carolina Academy of Science

No abstract provided.

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Estimation Of Bound Carbonyls In Pmma-R-Ps Copolymers Adsorbed On Silica, Pavan K. Challa, Bing Zhang, Frank D. Blum Jan 2005

Estimation Of Bound Carbonyls In Pmma-R-Ps Copolymers Adsorbed On Silica, Pavan K. Challa, Bing Zhang, Frank D. Blum

Chemistry Faculty Research & Creative Works

The adsorption of random copolymers on solid surfaces is essential for developing good properties in composite materials. A good control and understanding of interfaces allows tuning of the properties of the individual components. Interfacial polymers are important in many industrial applications such as photoresists, protective coatings, metal insulator and semi-conductor insulator junctions, metal-filled polymer composites and polymer-lined metal containers for protective food packaging. The effect of the drying process,1 configuration and tacticity,2 molecular mass, density of surface hydroxyls,3 and adsorbed amounts4 have already been studied for interfacial polymers. The thermal characterization for polystyrene,5 PMMA11 and PMMA-r- PS6 copolymers adsorbed on …

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Auditory Brainstem Responses In The Eastern Screech Owl: An Estimate Of Auditory Thresholds, Elizabeth F. Brittan-Powell, Bernard Lohr, Dana L. Hahn, Robert J. Dooling Jan 2005

Auditory Brainstem Responses In The Eastern Screech Owl: An Estimate Of Auditory Thresholds, Elizabeth F. Brittan-Powell, Bernard Lohr, Dana L. Hahn, Robert J. Dooling

United States Geological Survey: Staff Publications

The auditory brainstem response (ABR), a measure of neural synchrony, was used to estimate auditory sensitivity in the eastern screech owl (Megascops asio). The typical screech owl ABR waveform showed two to three prominent peaks occurring within 5 ms of stimulus onset. As sound pressure levels increased, the ABR peak amplitude increased and latency decreased. With an increasing stimulus presentation rate, ABR peak amplitude decreased and latency increased. Generally, changes in the ABR waveform to stimulus intensity and repetition rate are consistent with the pattern found in several avian families. The ABR audiogram shows that screech owls hear best between …

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Comparison Of Individual And Pooled Sampling Methods For Detecting Bacterial Pathogens Of Fish, Sonia Mumford, Chris Patterson, Joy Evered, Ray Brunson, Jay Levine, Jim Winton Jan 2005

Comparison Of Individual And Pooled Sampling Methods For Detecting Bacterial Pathogens Of Fish, Sonia Mumford, Chris Patterson, Joy Evered, Ray Brunson, Jay Levine, Jim Winton

United States Geological Survey: Staff Publications

Examination of finfish populations for viral and bacterial pathogens is an important component of fish disease control programs worldwide. Two methods are commonly used for collecting tissue samples for bacteriological culture, the currently accepted standards for detection of bacterial fish pathogens. The method specified in the Office International des Epizooties Manual of Diagnostic Tests for Aquatic Animals permits combining renal and splenic tissues from as many as 5 fish into pooled samples. The American Fisheries Society (AFS) Blue Book/US Fish and Wildlife Service (USFWS) Inspection Manual specifies the use of a bacteriological loop for collecting samples from the kidney of …

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Dielectric Properties And Maxwell-Wagner Relaxation Of Compounds Acu3ti4o12 (A=Ca,Bi2/3,Y2/3,La2/3), Jianjun Liu, Chun-Gang Duan, Wai-Ning Mei, Robert W. Smith, John R. Hardy Jan 2005

Dielectric Properties And Maxwell-Wagner Relaxation Of Compounds Acu3ti4o12 (A=Ca,Bi2/3,Y2/3,La2/3), Jianjun Liu, Chun-Gang Duan, Wai-Ning Mei, Robert W. Smith, John R. Hardy

Physics Faculty Publications

We have studied the frequency and temperature dependences of permittivity and impedance of the compounds ACu3Ti4O12 A=Ca, Bi2/3, Y2/3, La2/3 in the ranges of 10−1–106 Hz and −150–200 °C. All compounds investigated display similar dielectric properties. Specifically, they all have a Debye-like relaxation and their dielectric constants are independent of frequency and temperature over a wide range. They all have two electrical responses in impedance formalism, indicating that there are two distinct contributions. We attribute them to grains and grain boundaries in the ceramic samples and explain the dielectric behaviors by Maxwell-Wagner relaxation arising at the interfaces between grains and …

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High Gain / Broadband Oxide Glasses For Next Generation Raman Amplifiers, Clara Rivero Jan 2005

High Gain / Broadband Oxide Glasses For Next Generation Raman Amplifiers, Clara Rivero

Electronic Theses and Dissertations

Interest in Raman amplification has undergone a revival due to the rapidly increasing bandwidth requirements for communications transmission, both for long haul and local area networks, and recent developments in the telecom fiber industry and diode laser technology. In contrast to rare earth doped fiber amplifiers, for which the range of wavelengths is fixed and limited, Raman gain bandwidths are larger and the operating wavelength is fixed only by the pump wavelength and the bandwidth of the Raman active medium. In this context, glasses are the material of choice for this application due to their relatively broad spectral response, and …

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Measurement And Characterization Of Microwave Transient Electromagnetic Fields Generated From Laser/Matter Interaction, Nicholas Barbieri Jan 2005

Measurement And Characterization Of Microwave Transient Electromagnetic Fields Generated From Laser/Matter Interaction, Nicholas Barbieri

Electronic Theses and Dissertations

From past experiments conducted with high intensity lasers, it has been known for some time that laser matter interactions result in the emission of short, transient electromagnetic pulses. Previous investigations into laser generated electromagnetic pulses provide basic information regarding frequencies where such pulses may be present, along with the time duration of the pulses. Such investigations have also demonstrated a number of measurement techniques in which basic information on the pulses may be obtained. The purpose of this current investigation is to obtain a more thorough description and understands of electromagnetic pulses generated for laser matter interaction. To this end, …

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Synthesis Of Alkylthiol-Containing Fluorene Derivatives For Gold Nanoparticle Functionalization, Sriram Mukundarajan Jan 2005

Synthesis Of Alkylthiol-Containing Fluorene Derivatives For Gold Nanoparticle Functionalization, Sriram Mukundarajan

Electronic Theses and Dissertations

A novel synthetic methodology has been developed for attaching fluorene derivatives, containing different types of electron donating and accepting groups at the 2 and 7 positions, to gold nanoparticles of different sizes by exploiting the affinity of the thiol functional group for gold. The distance between the dye and nanoparticles was varied by introducing two alkyl chains containing different number of carbon atoms at the 9 position on the fluorene ring system. The methodology that was developed gave enough scope for performing Radiative Decay Engineering (RDE) studies, in order to investigate the impact of gold nanoparticles on the singlet oxygen …

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Design Of A Dynamic Focusing Microscope Objective For Oct Imaging, Supraja Murali Jan 2005

Design Of A Dynamic Focusing Microscope Objective For Oct Imaging, Supraja Murali

Electronic Theses and Dissertations

Optical Coherence Tomography (OCT) is a novel optical imaging technique that has assumed significant importance in bio-medical imaging in the last two decades because it is non-invasive and provides accurate, high resolution images of three dimensional cross-sections of body tissue, exceeding the capabilities of the current predominant imaging technique –ultrasound. In this thesis, high resolution OCT is investigated for in vivo detection of abnormal skin pathology for the early diagnosis of cancer. The technology presented is based on a dynamic focusing microscopic imaging probe conceived for skin imaging and the detection of abnormalities in the epithelium. A novel method for …

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Qos In Cognitive Packet Networks: Adaptive Routing, Flow And Congestion Control, Pu Su Jan 2005

Qos In Cognitive Packet Networks: Adaptive Routing, Flow And Congestion Control, Pu Su

Electronic Theses and Dissertations

With the emergence of various applications that have different Quality of Service (QoS) requirements, the capability of a network to support QoS becomes more and more important and necessary. This dissertation explores QoS in Cognitive Packet Networks (CPN) by using adaptive routing, flow and congestion control. We present a detailed description and analysis of our proposed routing algorithms based on single and multiple QoS constraints. An online estimation of packet loss rate over a path is introduced. We implement and evaluate the adaptive routing scheme in an experimental CPN test-bed. Our experiments support our claims that the users can achieve …

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Phase Synchronization In Three-Dimensional Lattices And Globally Coupled Populations Of Nonidentical Rossler Oscillators, Limin Qi Jan 2005

Phase Synchronization In Three-Dimensional Lattices And Globally Coupled Populations Of Nonidentical Rossler Oscillators, Limin Qi

Electronic Theses and Dissertations

A study on phase synchronization in large populations of nonlinear dynamical systems is presented in this thesis. Using the well-known Rossler system as a prototypical model, phase synchronization in one oscillator with periodic external forcing and in two-coupled nonidentical oscillators was explored at first. The study was further extended to consider three-dimensional lattices and globally coupled populations of nonidentical oscillators, in which the mathematical formulation that represents phase synchronization in the generalized N-coupled Rossler system was derived and several computer programs that perform numerical simulations were developed. The results show the effects of coupling dimension, coupling strength, population size, and …

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A Solvable Model For Gravity Driven Granular Dynamics, J. J. P. Veerman Jan 2005

A Solvable Model For Gravity Driven Granular Dynamics, J. J. P. Veerman

Mathematics and Statistics Faculty Publications and Presentations

We discuss a toy model to study the dynamics of individual particles in avalanches. The model describes a particle launched from an inclined infinite staircase. The particle is not allowed to bounce when it collides with the staircase. During the collision, the particle loses some energy, and after that slides on to the end of the step it landed on. The process then repeats itself. The dynamics of this no-bounce model can essentially be completely understood. Partial versions of some results were stated and argued in previous work. Here we give a full description together with all the proofs. We …

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Infrared Response Of Charge-Coupled Devices, Matthias Loch, Ralf Widenhorn, Erik Bodegom Jan 2005

Infrared Response Of Charge-Coupled Devices, Matthias Loch, Ralf Widenhorn, Erik Bodegom

Physics Faculty Publications and Presentations

With a band gap of silicon of 1.1eV, the largest wavelength that can excite electrons from the valence to the conduction band is roughly 1100nm. As a consequence, in, for instance, a charge-coupled device, the quantum efficiency (QE) for wavelengths larger than 1100nm is assumed to be zero. We found that there is a response at those longer wavelengths and that the response decreases with increasing wavelength. The QE increases with increasing chip temperature which suggests a thermally activated process. Impurities in the silicon provide the energy levels in the band gap, from which electrons can be excited either thermally …

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The Ultrasonic/Shear-Force Microscope: A Metrology Tool For Surface Science And Technology, Andres H. La Rosa, Nan Li, K. Asante Jan 2005

The Ultrasonic/Shear-Force Microscope: A Metrology Tool For Surface Science And Technology, Andres H. La Rosa, Nan Li, K. Asante

Physics Faculty Publications and Presentations

This paper describes recent results obtained with the Ultrasonic/Shear-Force Microscope (SUNM), an analytical tool suitable for investigating the quite different dynamic displayed by fluid-like films when subjected to mesoscopic confinement and while in intimate contact with two sliding solid boundaries. The SUNM uses two sensory modules to concurrently but independently monitor the effects that fluid-mediated interactions exert on two sliding bodies: the microscope’s sharp probe (attached to a piezoelectric sensor) and the analyzed sample (attached to an ultrasonic transducer). This dual capability allows correlating the fluid-like film’s viscoelastic properties with changes in the probe’s resonance frequency and the generation of …

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Investigation Of Polymerization Rate In An Acrylamide-Based Photopolymer Using Raman Spectroscopy, Raghavendra Jallapuram, Izabela Naydenova, Hugh Byrne, Suzanne Martin, Robert Howard, Vincent Toal Jan 2005

Investigation Of Polymerization Rate In An Acrylamide-Based Photopolymer Using Raman Spectroscopy, Raghavendra Jallapuram, Izabela Naydenova, Hugh Byrne, Suzanne Martin, Robert Howard, Vincent Toal

Conference Papers

Diffusion models predict that polymerization and diffusion rates are the key factors that control the dynamics and the final properties of a holographic grating recorded in a photopolymerizable material. Diffusion rates during the initial phase of holographic recording have already been studied and reported. We now report the investigation of the polymerization rate in an acrylamide-based photopolymer using Raman spectroscopy. The polymerization rate constant was estimated by monitoring the intensity of the characteristic Raman peaks at 1284 cm-1 corresponding to the bending mode of CH vinyl bond in acrylamide and 1609 cm-1 corresponding to the carbon-carbon double bond (C=C) in …

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A Compact Electronic Speckle Pattern Interferometry System Using A Photopolymer Reflection Holographic Optical Element, Guntaka Tulasi Sridhar Reddy, Raghavendra Jallapuram, Vincent Toal, Izabela Naydenova, Suzanne Martin, Svetlana Mintova Jan 2005

A Compact Electronic Speckle Pattern Interferometry System Using A Photopolymer Reflection Holographic Optical Element, Guntaka Tulasi Sridhar Reddy, Raghavendra Jallapuram, Vincent Toal, Izabela Naydenova, Suzanne Martin, Svetlana Mintova

Conference Papers

A simple and compact electronic speckle pattern interferometry system using a reflection holographic optical element is presented. The reflection holographic optical element is recorded on an acrylamide based photopolymer formulated and prepared at the Centre for Industrial & Engineering Optics. Light intensity of 40mW/cm2 with an exposure time of 60 seconds was used in fabricating the holographic optical element. The vibration mode patterns of a 4 cm diameter thin circular sheet of brass metal attached to a 4 cm diameter paper cone loud speaker are presented.

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Simple Electronic Speckle Pattern Shearing Interferometer With A Holographic Grating As A Shearing Element, Emilia Mihaylova, Izabela Naydenova, Suzanne Martin, Vincent Toal Jan 2005

Simple Electronic Speckle Pattern Shearing Interferometer With A Holographic Grating As A Shearing Element, Emilia Mihaylova, Izabela Naydenova, Suzanne Martin, Vincent Toal

Conference Papers

An optical set-up for electronic speckle pattern shearing interferometry (ESPSI) using a photopolymer diffractive optical element as a shearing element, is presented. A laser beam illuminates the object at an angle to the normal to the object surface. The holographic diffraction grating is placed in front of the object. The zero and the first order of diffraction form the image and the sheared image of the object. The images are imaged onto the CCD camera, whose optical axis coincides with the normal to the object surface. The field of view is limited only by the dimensions of the photopolymer plate. …

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Correlation Of Spectroscopic And Biochemical Assays Postionising Radiation Exposure In Human Skin Cell Analogues, Aidan Meade, Hugh Byrne, Fiona Lyng Jan 2005

Correlation Of Spectroscopic And Biochemical Assays Postionising Radiation Exposure In Human Skin Cell Analogues, Aidan Meade, Hugh Byrne, Fiona Lyng

Conference papers

Raman spectroscopy, as an evaluation of the products of ionising radiation exposure in biological systems, has been utilised mainly in the evaluation of the impact of exposure in tissue, cellular constituents and live animals. It has also been recently demonstrated that Raman spectroscopy can demonstrate key spectroscopic changes in the live cell associated with significant apoptotic and necrotic chemical damage. The present preliminary work utilises Raman spectroscopy at 514.5 nm to evaluate the results of exposure to -rays in HaCaT cells from a Co-60 therapy source, in tandem with other biological assays. The results demonstrate that a number of spectral …

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Electroabsorption Studies Of Structurally Modified Fullerene Thin Films, Gerald Farrell, Gordon Chambers, Hugh Byrne Jan 2005

Electroabsorption Studies Of Structurally Modified Fullerene Thin Films, Gerald Farrell, Gordon Chambers, Hugh Byrne

Conference papers

Ultraviolet (UV/Vis) and Electroabsorption (EA) spectroscopy is used to examine and differentiate between intermolecular and intra molecular excited state species in fullerene films. Charge Transfer (CT) states are identified at 2.4 eV and 2.7 eV and dipole moments are calculated. Thermal annealing of C60 films is monitored in situ using absorption spectroscopy and electroabsorption spectroscopy. Recorded spectra display both some temperature dependent and partially irreversible effects, indicating the occurrence of an annealing process. EA shows that the CT states associated with the transferring an electron from the HOMO of one molecule located at the (0,0,0) position to the LUMO of …

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The Potential Of Vibrational Spectroscopy In The Early Detection Of Cervical Cancer: An Exciting Emerging Field, Eoghan O'Faolain, Mary Hunter, Joe Byrne, Peter Kelehan, Hugh Byrne, Fiona Lyng Jan 2005

The Potential Of Vibrational Spectroscopy In The Early Detection Of Cervical Cancer: An Exciting Emerging Field, Eoghan O'Faolain, Mary Hunter, Joe Byrne, Peter Kelehan, Hugh Byrne, Fiona Lyng

Conference papers

The application of vibrational spectroscopy to disease diagnosis is a relatively new, rapidly evolving scientific field. Techniques such as Raman and infrared spectroscopy have shown great promise in this regard over the past number of years. This study directly compared Raman spectroscopy and synchrotron infrared (SR-IR) spectroscopy on parallel cervical cancer samples. Both frozen and dewaxed formalin fixed paraffin preserved tissue sections were examined. Both tissue types produced good quality Raman and SR-IR spectra, although the lesser processed, frozen tissue sections displayed the most detailed spectra. Spectroscopy was shown capable of discriminating between different cell types in normal cervical tissue. …

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