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2005

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Articles 5011 - 5040 of 5573

Full-Text Articles in Physical Sciences and Mathematics

Analysis Of Perturbation-Based Testing Methodology As Applied To A Real-Time Control System Problem, Richard A. Stutler Jan 2005

Analysis Of Perturbation-Based Testing Methodology As Applied To A Real-Time Control System Problem, Richard A. Stutler

Theses and Dissertations

Perturbation analysis is a software analysis technique used to study the tail function of a program by inserting an error into an executing program using data state mutation. The impact of this induced error on the output is then measured. This methodology can be used to evaluate the effectiveness of a given test set and in fact can be used as a means to derive a test set which provides coverage for a given program. Previous research has shown that there is a "coupling effect" such that test sets that identify simple errors will also identify more complex errors. Thus …

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Isolation, X-Ray Structures, And Electronic Spectra Of Reactive Intermediates In Friedel−Crafts Acylations, M. G. Davlieva, Sergey V. Lindeman, I. S. Neretin, Jay K. Kochi Jan 2005

Isolation, X-Ray Structures, And Electronic Spectra Of Reactive Intermediates In Friedel−Crafts Acylations, M. G. Davlieva, Sergey V. Lindeman, I. S. Neretin, Jay K. Kochi

Chemistry Faculty Research and Publications

Reactive intermediates in the Friedel−Crafts acylation of aromatic donors are scrutinized upon their successful isolation and X-ray crystallography at very low temperatures. Detailed analyses of the X-ray parameters for the [1:1] complexes of different aliphatic and aromatic-acid chlorides with the Lewis acids antimony pentafluoride and pentachloride, gallium trichloride, titanium and zirconium tetrachlorides provide unexpected insight into the activation mechanism for the formation of the critical acylium carbocations. Likewise, the X-ray-structure examinations of aliphatic and aromatic acylium electrophiles also isolated as crystalline salts point to the origins of their electrophilic reactivity. Although the Wheland intermediates (as acylium adducts to arene donors) …

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Characterization Of The Active Site And Insight Into The Binding Mode Of The Anti-Angiogenesis Agent Fumagillin To The Manganese(Ii)-Loaded Methionyl Aminopeptidase From Escherichia Coli, Ventris M. D'Souza, Robert S. Brown, Brian Bennett, Richard C. Holz Jan 2005

Characterization Of The Active Site And Insight Into The Binding Mode Of The Anti-Angiogenesis Agent Fumagillin To The Manganese(Ii)-Loaded Methionyl Aminopeptidase From Escherichia Coli, Ventris M. D'Souza, Robert S. Brown, Brian Bennett, Richard C. Holz

Physics Faculty Research and Publications

EPR spectra were recorded for methionine aminopeptidase from Escherichia coli (EcMetAP-I) samples (~2.5 mM) to which one and two equivalents of Mn(II) were added (the latter is referred to as [MnMn(EcMetAP-I)]). The spectra for each sample were indistinguishable except that the spectrum of [MnMn(EcMetAP-I)] was twice as intense. The EPR spectrum of [MnMn(EcMetAP-I)] exhibited the characteristic six-line g≈2 EPR signal of mononuclear Mn(II) with A av(55Mn)=9.3 mT (93 G) and exhibited Curie-law temperature dependence. This signal is typical of Mn(II) in a ligand sphere comprising oxygen and/or nitrogen …

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Bell's Jump Process In Discrete Time, Jonathan Barrett, Matthew S. Leifer, Roderich Tumulka Jan 2005

Bell's Jump Process In Discrete Time, Jonathan Barrett, Matthew S. Leifer, Roderich Tumulka

Mathematics, Physics, and Computer Science Faculty Articles and Research

The jump process introduced by J. S. Bell in 1986, for defining a quantum field theory without observers, presupposes that space is discrete whereas time is continuous. In this letter, our interest is to find an analogous process in discrete time. We argue that a genuine analog does not exist, but provide examples of processes in discrete time that could be used as a replacement.

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Point Evaluation And Hardy Space On A Homogeneous Tree, Daniel Alpay, Dan Volok Jan 2005

Point Evaluation And Hardy Space On A Homogeneous Tree, Daniel Alpay, Dan Volok

Mathematics, Physics, and Computer Science Faculty Articles and Research

We consider stationary multiscale systems as defined by Basseville, Benveniste, Nikoukhah and Willsky. We show that there are deep analogies with the discrete time non stationary setting as developed by the first author, Dewilde and Dym. Following these analogies we define a point evaluation with values in a C*–algebra and the corresponding “Hardy space” in which Cauchy’s formula holds. This point evaluation is used to define in this context the counterpart of classical notions such as Blaschke factors.

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The Reno Aerosol Optics Study: An Evaluation Of Aerosol Absorption Measurement Methods, Patrick J. Sheridan, W. Patrick Arnott, John A. Ogren, Elisabeth Andrews, Dean B. Atkinson, David S. Covert, Hans Moosmüller, Andreas Petzold, Beat Schmid, Anthony W. Strawa, Ravi Varma, Aki Virkkula Jan 2005

The Reno Aerosol Optics Study: An Evaluation Of Aerosol Absorption Measurement Methods, Patrick J. Sheridan, W. Patrick Arnott, John A. Ogren, Elisabeth Andrews, Dean B. Atkinson, David S. Covert, Hans Moosmüller, Andreas Petzold, Beat Schmid, Anthony W. Strawa, Ravi Varma, Aki Virkkula

Chemistry Faculty Publications and Presentations

The Reno Aerosol Optics Study (RAOS) was designed and conducted to compare the performance of many existing and new instruments for the in situ measurement of aerosol optical properties with a focus on the determination of aerosol light absorption. For this study, simple test aerosols of black and white particles were generated and combined in external mixtures under low relative humidity conditions and delivered to each measurement system. The aerosol mixing and delivery system was constantly monitored using particle counters and nephelometers to ensure that the same aerosol number concentration and amount reached the different instruments. The aerosol light-scattering measurements …

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A New Cmos Differential Otra Design For The Low Voltage Power Supplies In The Sub-Micron Technologies, Alper Duruk, Hakan Kuntman Jan 2005

A New Cmos Differential Otra Design For The Low Voltage Power Supplies In The Sub-Micron Technologies, Alper Duruk, Hakan Kuntman

Turkish Journal of Electrical Engineering and Computer Sciences

In this study, a new CMOS differential OTRA topology is proposed. This topology can operate with a very low voltage power supply as \pm 0.6V. In this design, CMOS 0.13 \mu m STMicroelectronics technology transistor models are used for the simulations. The designed CMOS OTRA has a transresistance gain (Rm) of 7478 V/I with a 28.1 MHz bandwidth (-3 dB) and a transresistance unity-gain bandwidth of 2 GHz. To demonstrate the performance of the OTRA, designed low pass, high pass and band pass filters employing a single CMOS differential OTRA and passive elements are tested with SPICE simulation program to …

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A Robustness Analysis Procedure For Realistic Missiles, Reşat Özgür Doruk, Erol Kocaoğlan Jan 2005

A Robustness Analysis Procedure For Realistic Missiles, Reşat Özgür Doruk, Erol Kocaoğlan

Turkish Journal of Electrical Engineering and Computer Sciences

This paper presents a robustness analysis procedure for short range realistic missile autopilots. The sensitivity of the autopilots to the aerodynamic parameter uncertainties is investigated through the structured singular value theory where the results are verified through nonlinear simulations. Different types of perturbations are implemented in order to measure the complete performance of the missile.

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A Model For User Profiling Systems With Interacting Agents, Sanem Sariel, Tevfi̇k Akgün Jan 2005

A Model For User Profiling Systems With Interacting Agents, Sanem Sariel, Tevfi̇k Akgün

Turkish Journal of Electrical Engineering and Computer Sciences

Service systems according to users' personal demands and preferences are on their way to provide required services in many application domains. Emulation of interactive model of human societies produces valuable outcomes for such systems. In this work, a system model with interactive agents for multi user service systems is proposed. A novel social interactive agent model using different interaction forms is also included in this proposal. In this model, agents decide how to serve to their users by considering their users' profiles and information from other agents. User clusters are formed by clustering techniques. The Q-learning algorithm is used for …

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Prior Knowledge Input Method In Device Modeling, Serdar Heki̇mhan, Serdar Menekay, N. Serap Şengör Jan 2005

Prior Knowledge Input Method In Device Modeling, Serdar Heki̇mhan, Serdar Menekay, N. Serap Şengör

Turkish Journal of Electrical Engineering and Computer Sciences

The artificial neural networks are being used in modelling electronic elements and devices especially at microwave frequencies where non-linearity and dependence on frequency cannot be neglected. In this paper, instead of using artificial neural networks as a unique modelling device prior knowledge input method based on feed-forward artificial neural network structures as multi-layer perceptrons and wavelet-based neural networks is investigated. The benefits of prior knowledge input method over plain usage of artificial neural networks in modelling BJT is explored by comparing models obtained with and without prior knowledge input. The novelty of the paper is utilizing wavelet-based neural networks as …

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A Survey On The H.264/Avc Standard, Nükhet Özbek, Turhan Tunali Jan 2005

A Survey On The H.264/Avc Standard, Nükhet Özbek, Turhan Tunali

Turkish Journal of Electrical Engineering and Computer Sciences

H.264/AVC is a recently completed video compression standard jointly developed by ITU-T VCEG and ISO/IEC MPEG standards committees. The standard is becoming more popular as it promises much higher compression than that possible with earlier standards. The standard provides flexibilities in coding and organization of data which enable efficient error resilience. The increased coding efficiency offers new application areas and business opportunities. As might be expected, the increases in compression efficiency and flexibility come at the expense of increase in complexity, which is a fact that must be overcome. This paper provides an overview of the technical features of H.264 …

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Control Charts Approach For Scenario Recognition In Video Sequences, Ersi̇n Elbaşi, Long Zuo, Kishan Mehrotra, Chilukuri Mohan, Pramod Varshney Jan 2005

Control Charts Approach For Scenario Recognition In Video Sequences, Ersi̇n Elbaşi, Long Zuo, Kishan Mehrotra, Chilukuri Mohan, Pramod Varshney

Turkish Journal of Electrical Engineering and Computer Sciences

A new approach, based on control charts, is presented for the task of recognition of events and scenarios in video image sequences. For each image in the sequence, low level image processing and feature extraction steps result in feature descriptors for objects of interest detected in the images. Control charts analysis is then explored to classify the nature of the activity depicted by the temporal changes in these features over the image sequence. Scenario recognition with higher accuracy is achieved using this simple approach.

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Color Image Profiling Using Fuzzy Sets, Amine Ait Younes, Isis Truck, Herman Akdag Jan 2005

Color Image Profiling Using Fuzzy Sets, Amine Ait Younes, Isis Truck, Herman Akdag

Turkish Journal of Electrical Engineering and Computer Sciences

In this article, a software for image indexing and retrieval is presented. The classification proposed here is based on the dominant color(s) of the images. The process consists in assigning a colorimetric profile to the image in HLS space (Hue, Lightness, Saturation). First, the definition of hue is done thanks to a fuzzy representation to take into account the non-uniformity of colors distribution. And then, lightness and saturation are represented through linguistic qualifiers also defined in a fuzzy way. Finally, the profile is built through fuzzy functions representing the membership degree of the image to different classes. In order to …

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Final Report For The Development Of The Nasa Technical Report Server (Ntrs), Michael L. Nelson Jan 2005

Final Report For The Development Of The Nasa Technical Report Server (Ntrs), Michael L. Nelson

Computer Science Faculty Publications

The author performed a variety of research, development and consulting tasks for NASA Langley Research Center in the area of digital libraries (DLs) and supporting technologies, such as the Open Archives Initiative Protocol for Metadata Harvesting (OAI-PMH). In particular, the development focused on the NASA Technical Report Server (NTRS) and its transition from a distributed searching model to one that uses the OAI-PMH. The Open Archives Initiative (OAI) is an international consortium focused on furthering the interoperability of DLs through the use of "metadata harvesting". The OAI-PMH version of NTRS went into public production on April 28, 2003. Since that …

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Introduction: Data Communication And Topology Algorithms For Sensor Networks, Stephan Olariu, David Simplot-Ryl, Ivan Stojmenovic Jan 2005

Introduction: Data Communication And Topology Algorithms For Sensor Networks, Stephan Olariu, David Simplot-Ryl, Ivan Stojmenovic

Computer Science Faculty Publications

(First paragraph) We are very proud and honored to have been entrusted to be Guest Editors for this special issue. Papers were sought to comprehensively cover the algorithmic issues in the “hot” area of sensor networking. The concentration was on network layer problems, which can be divided into two groups: data communication problems and topology control problems. We wish to briefly introduce the five papers appearing in this special issue. They cover specific problems such as time division for reduced collision, fault tolerant clustering, self-stabilizing graph optimization algorithms, key pre-distribution for secure communication, and distributed storage based on spanning trees …

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The Effects Of Shilling On Final Bid Prices In Online Auctions, Robert J. Kauffman, Charles A. Wood Jan 2005

The Effects Of Shilling On Final Bid Prices In Online Auctions, Robert J. Kauffman, Charles A. Wood

Research Collection School Of Computing and Information Systems

An increasing number of reports of online auction fraud are of growing concern to auction operators and participants. In this research, we discuss reserve price shilling, where a bidder shills in order to avoid paying auction house fees, rather than to drive up the price of the final bid. We examine the effect that premium bids have upon the final selling price, since they are linked with reserve price shill bids. We use 10,260 eBay auctions during April 2001, and identify 919 auctions involving 322 sellers and 1583 bidders involved in concurrent auctions for the exact same item. We find …

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Technology Competition And Optimal Investment Timing: A Real Options Perspective, Robert J. Kauffman, X. Li Jan 2005

Technology Competition And Optimal Investment Timing: A Real Options Perspective, Robert J. Kauffman, X. Li

Research Collection School Of Computing and Information Systems

Companies often choose to defer irreversible investments to maintain valuable managerial flexibility in an uncertain world. For some technology-intensive projects, technology uncertainty plays a dominant role in affecting investment timing. This article analyzes the investment timing strategy for a firm that is deciding about whether to adopt one or the other of two incompatible and competing technologies.We develop a continuous-time stochastic model that aids in the determination of optimal timing for managerial adoption within the framework of real options theory. The model captures the elements of the decision-making process in such a way so as to provide managerial guidance in …

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A Multi-Agent Approach For Solving Optimization Problems Involving Expensive Resources, Hoong Chuin Lau, H. Wang Jan 2005

A Multi-Agent Approach For Solving Optimization Problems Involving Expensive Resources, Hoong Chuin Lau, H. Wang

Research Collection School Of Computing and Information Systems

In this paper, we propose a multi-agent approach for solving a class of optimization problems involving expensive resources, where monolithic local search schemes perform miserably. More specifically, we study the class of bin-packing problems. Under our proposed Fine-Grained Agent System scheme, rational agents work both collaboratively and selfishly based on local search and mimic physics-motivated systems. We apply our approach to a generalization of bin-packing - the Inventory Routing Problem with Time Windows - which is an important logistics problem, and demonstrate the efficiency and effectiveness of our approach.

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Exploring Bit-Difference For Approximate Knn Search In High-Dimensional Databases, Bin Cui, Heng Tao Shen, Jialie Shen, Kian-Lee Tan Jan 2005

Exploring Bit-Difference For Approximate Knn Search In High-Dimensional Databases, Bin Cui, Heng Tao Shen, Jialie Shen, Kian-Lee Tan

Research Collection School Of Computing and Information Systems

In this paper, we develop a novel index structure to support effcient approximate k-nearest neighbor (KNN) query in high-dimensional databases. In high-dimensional spaces, the computational cost of the distance (e.g., Euclidean distance) between two points contributes a dominant portion of the overall query response time for memory processing. To reduce the distance computation, we first propose a structure (BID) using BIt-Difference to answer approximate KNN query. The BID employs one bit to represent each feature vector of point and the number of bit-difference is used to prune the further points. To facilitate real dataset which is typically skewed, we enhance …

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Self-Assembly Of Ge Quantum Dots On Si(100)- 2×1 By Pulsed Laser Deposition, M. S. Hegazy, H. E. Elsayed-Ali Jan 2005

Self-Assembly Of Ge Quantum Dots On Si(100)- 2×1 By Pulsed Laser Deposition, M. S. Hegazy, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Self-assembled Ge quantum dots are grown on Si(100)- 2×1 by pulsed laser deposition. The growth is studied by in situ reflection high-energy electron diffraction and postdeposition atomic force microscopy. After the completion of the wetting layer, transient hut clusters, faceted by different planes, are observed. When the height of these clusters exceeded a certain value, the facets developed into {305} planes. Some of these huts become {305}-faceted pyramids as the film mean thickness was increased. With further thickness increase, dome clusters developed on the expense of these pyramids. © 2005 American Institute of Physics. [DOI: 10.1063/1.1949285]

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Characterization Of Tio_2 Synthesized In Alcohol By A Sol-Gel Process: The Effects Of Annealing Temperature And Acid Catalyst, Funda Sayilkan, Meltem Asi̇ltürk, Hi̇kmet Sayilkan, Yunus Önal, Murat Akarsu, Ertuğrul Arpaç Jan 2005

Characterization Of Tio_2 Synthesized In Alcohol By A Sol-Gel Process: The Effects Of Annealing Temperature And Acid Catalyst, Funda Sayilkan, Meltem Asi̇ltürk, Hi̇kmet Sayilkan, Yunus Önal, Murat Akarsu, Ertuğrul Arpaç

Turkish Journal of Chemistry

The effects of annealing temperature and hydrolysis catalyst on the crystalline form and crystallite size of TiO_2 prepared by a sol-gel process were investigated. Three types of TiO_2 were synthesized by hydrolysis of titanium(IV)-iso-propoxide with water in n-propanol without catalyst (Type-A) and with HCl as catalyst, where the H^+ /Ti^{4+} mol ratio was 0.54 for Type-B and 0.2 for Type-C. Hydrolysis products were thermally treated at 100, 200, 300, 400 and 500 °C for 1 h after drying at room temperature. Characterization of the particles was carried out using XRD, BET, TG/DTA and SEM analysis. The pore size distributions were …

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Effect Of Humic Substance Photodegradation On Bacterial Growth And Respiration In Lake Water, Alexandre M. Anesio, William Granéli, George R. Aiken, David J. Kieber, Kenneth Mopper Jan 2005

Effect Of Humic Substance Photodegradation On Bacterial Growth And Respiration In Lake Water, Alexandre M. Anesio, William Granéli, George R. Aiken, David J. Kieber, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

This study addresses how humic substance (HS) chemical composition and photoreactivity affect bacterial growth, respiration, and growth efficiency (BGE) in lake water. Aqueous solutions of HSs from diverse aquatic environments representing different dissolved organic matter sources (autochthonous and allochthonous) were exposed to artificial solar UV radiation. These solutions were added to lake water passed through a 0.7-μm pore-size filter (containing grazer-free lake bacteria) followed by dark incubation for 5, 43, and 65 h. For the 5-h incubation, several irradiated HSs inhibited bacterial carbon production (BCP) and this inhibition was highly correlated with H2O2 photoproduction. The H2 …

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Optimization Of Ultraviolet Emission And Chemical Species Generation From A Pulsed Dielectric Barrier Discharge At Atmospheric Pressure, Xinpei Lu, Mounir Laroussi Jan 2005

Optimization Of Ultraviolet Emission And Chemical Species Generation From A Pulsed Dielectric Barrier Discharge At Atmospheric Pressure, Xinpei Lu, Mounir Laroussi

Electrical & Computer Engineering Faculty Publications

One of the attractive features of nonthermal atmospheric pressure plasmas is the ability to achieve enhanced gas phase chemistry without the need for elevated gas temperatures. This attractive characteristic recently led to their extensive use in applications that require low temperatures, such as material processing and biomedical applications. The agents responsible for the efficient plasma reactivity are the ultraviolet (UV) photons and the chemically reactive species. In this paper, in order to optimize the UV radiation and reactive species generation efficiency, the plasma was generated by a dielectric barrier discharge driven by unipolar submicrosecond square pulses. To keep the discharge …

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Human Mental Models Of Humanoid Robots, Sau-Lai Lee, Ivy Yee-Man Lau, Sara Kiesler, Chi-Yue Chiu Jan 2005

Human Mental Models Of Humanoid Robots, Sau-Lai Lee, Ivy Yee-Man Lau, Sara Kiesler, Chi-Yue Chiu

Research Collection School of Social Sciences

Effective communication between a person and a robot may depend on whether there exists a common ground of understanding between the two. In two experiments modelled after human-human studies we examined how people form a mental model of a robot's factual knowledge. Participants estimated the robot's knowledge by extrapolating from their own knowledge and from information about the robot's origin and language. These results suggest that designers of humanoid robots must attend not only to the social cues that robots emit but also to the information people use to create mental models of a robot.

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Crystal Structure Of The Cis-Bis[4-Chloro-N-(Pyrrolidine-1-Carbothioyl)-Benzamido] Copper(Ii) Complex, Nevzat Külcü, Ulrich Flörke, Hakan Arslan Jan 2005

Crystal Structure Of The Cis-Bis[4-Chloro-N-(Pyrrolidine-1-Carbothioyl)-Benzamido] Copper(Ii) Complex, Nevzat Külcü, Ulrich Flörke, Hakan Arslan

Turkish Journal of Chemistry

The crystal and molecular structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) complex was determined by single-crystal X-ray diffraction. The title compound, C_{24}H_{24}N_4O_2 S_2Cl_2Cu, crystalizes in the triclinic space group P-1, with Z = 4 and unit cell parameters a = 8.3877(5) Å, b = 12.7904(8) Å, c = 24.160(2) Å, \alpha = 95.923(1) °, \beta = 96.001(1) °, and \gamma = 95.048(1) °. The copper atom is 4-fold coordinated by 2 S and 2 O atoms and shows a slightly distorted planar quadratic ligand arrangement.

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Diels-Alder Reactions Of New Methoxysubstituted-6-Arylfulvenes, Nüket Öcal, Emi̇ne Bağdatli, Mesut Arslan Jan 2005

Diels-Alder Reactions Of New Methoxysubstituted-6-Arylfulvenes, Nüket Öcal, Emi̇ne Bağdatli, Mesut Arslan

Turkish Journal of Chemistry

Fulvenes 1, 2 and 3 were prepared and their Diels-Alder cycloaddition reactions with maleic anhydride, N-phenylmaleimide and dimethyl acetylenedicarboxylate (DMAD) as dienophiles leading to endo- and exo- [4+2] adducts shown.

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Determination Of Trace Copper By Faas After Solid Phase Extraction And Preconcentration Onto Amberlite Xad-2 Loaded With Nitroso-R Salt, Mohammad Ali Taher, Sayed Ziae Mohammadi Mobarakeh, Ali Reza Mohadesi Jan 2005

Determination Of Trace Copper By Faas After Solid Phase Extraction And Preconcentration Onto Amberlite Xad-2 Loaded With Nitroso-R Salt, Mohammad Ali Taher, Sayed Ziae Mohammadi Mobarakeh, Ali Reza Mohadesi

Turkish Journal of Chemistry

A procedure for the separation and preconcentration of trace amounts of copper is proposed. It is based on the adsorption of copper(II) ions solution onto a column of Amberlite XAD-2 resin loaded with disodium 1-nitroso-2-naphthol-3, 6-disulfonate (nitroso-R salt). Copper is quantitatively retained on the column in the pH range 5.5-7.8 at a flow rate of 2 mL min^{-1}. The copper complex eluted with 5 mL of dimethylformamide (DMF) and copper was measured by flame atomic absorption spectrometry (FAAS) at 324.8 nm. In this case, 0.10 \mu g of copper can be concentrated in the column from 800 mL of aqueous …

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Development And Characterization Of A Cationic Emulsion Formulation As A Potential Pdna Carrier System, Kudret Di̇lşat Barut, Fatma Fi̇li̇z Coşkun Ari, Fi̇li̇z Öner Jan 2005

Development And Characterization Of A Cationic Emulsion Formulation As A Potential Pdna Carrier System, Kudret Di̇lşat Barut, Fatma Fi̇li̇z Coşkun Ari, Fi̇li̇z Öner

Turkish Journal of Chemistry

The development of efficient and stable carriers for the delivery of DNA to the body is becoming an increasingly important issue in the fields of gene therapy and vaccination. The present study was designed to prepare an emulsion-based gene delivery system. Oil-in-water emulsions containing cetyltrimethylammonium bromide (CTAB) as a cationic surfactant and Pluronic F-68 as a nonionic co-surfactant were formulated and their physical characteristics were investigated. The cationic emulsion, referred to as B13d, containing a liquid crystal phase, was found to be stable and suitable for parenteral application. Complex formation between pGL3 plasmid DNA and B13d emulsion achieved at the …

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Potentiometric Studies On The Protonation Constants And Solvation Of Some \Alpha-Amino Acid Benzyl- And T-Butyl- Esters In Ethanol-Water Mixtures, Alev Doğan, Esma Kiliç Jan 2005

Potentiometric Studies On The Protonation Constants And Solvation Of Some \Alpha-Amino Acid Benzyl- And T-Butyl- Esters In Ethanol-Water Mixtures, Alev Doğan, Esma Kiliç

Turkish Journal of Chemistry

To gain more information about the effect of solvent on \alpha -amino acid benzyl- and t-butyl- esters, the stoichiometric protonation constants of 10 esters (glycine benzyl ester, L-alanine benzyl ester, L-valine benzyl ester, L-serine benzyl ester, glycine t-butyl ester, L-alanine t-butyl ester, L-valine t-butyl ester, L-leucine t-butyl ester, L-phenylalanine t-butyl ester and L-isoleucine t-butyl ester) in 20%-80% (v/v) ethanol-water mixtures were determined at an ionic strength of 0.10 M NaCl and at 25.0 \pm 0.1 °C under nitrogen atmosphere. A potentiometric method was used and the calculation of constants was carried out using the PKAS computer program. The logarithm of …

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Synthesis And Characterization Of Novel Hyperbranched Polyimides Based On Silsesquioxane Nanocomposite Networks, Turgay Seçki̇n, Ahmet Gültek, Süleyman Köytepe Jan 2005

Synthesis And Characterization Of Novel Hyperbranched Polyimides Based On Silsesquioxane Nanocomposite Networks, Turgay Seçki̇n, Ahmet Gültek, Süleyman Köytepe

Turkish Journal of Chemistry

A series of nanosized polyimides was successfully prepared by condensation polymerization of an octaamino-functionalized silsesquioxane and a series of commercially available dianhyride monomers. The polymerization of the octaamino silsesquioxane was carried out in 1-methyl-2-pyrrolidone (NMP) at room temperature, giving poly(amic acid) as precursor polymers that were readily converted to the corresponding polyimides by thermal treatment in the subsequent step, which is similar to the conventional 2-stage method. The appropriate molar ratio of the silsesquioxane monomer to a dianhyride was 1:1. These polyimides are readily soluble in polar aprotic solvents such as 1-methyl-2-pyrrolidone, and N,N-dimethylacetamide at room temperature, and show high …

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