Physical Sciences and Mathematics Commons^™

Synthesis, Crystal Structure And Antifungal/Antibacterial Activity Of Some Novel Highly Functionalized Benzoylaminocarbothioyl Pyrrolidines, H. Ali̇ Döndaş, Yahya Nural, Ni̇zami̇ Duran, Colin Kilner

Turkish Journal of Chemistry

A series of novel highly functionalized benzoylaminocarbothioyl pyrrolidines were prepared from benzoylisothiocyanate and substituted pyrrolidines in excellent yield. The crystal structure of the novel 1-benzoylaminocarbothioyl-5-(naphthyl)- pyrrolidine-2,3,4-tricarboxylicacid trimethyl ester (3a) was determined by X-ray crystal structure analysis. The synthesized compounds were characterized and screened for their in vitro antibacterial and antifungal activities and toxicity. The prepared compounds were tested against the standard strains: Escherichia coli (ATCC 25922), Enterobacter cloacae (ATCC 13047), Enterococcus faecalis (ATCC 29212), Pseudomonas aeruginosa (ATCC 27853), Staphylococcus aureus (ATCC 29213) and Staphylococcus epidermidis (ATCC 12228) and the yeasts Candida albicans (ATCC 90028), Candida krusei (ATCC 6258), Candida parapsilosis …

Synthesis Of Vic-Dioxime Derivatives With Hydrazone Side Groups And Their Metal Complexes, İlknur Babahan, Hüseyi̇n Anil, Nursabah Sarikavakli

Turkish Journal of Chemistry

Two novel vic-dioxime (L^1H_2, L^2H_2) compounds bearing hydrazone side groups and their transition metal complexes Ni(II), Co(II), Cu(II), and Zn(II) were synthesized. The vic-dioxime ligands bearing hydrazone side groups were synthesized by reacting anti-glyoximehydrazine (GH_2) with 4-nitroacetophenone and 4-methylacetophenenone, respectively. Ligands form mononuclear complexes [(LH)_2M] with a metal to ligand ratio of 1:2 with M=Co(II)(H_2O)_2, Ni(II), and Cu(II). Zn(II) forms complexes [(LH)(H_2O)(Cl)Zn] with a metal to ligand ratio of 1:1. The Co(II) complexes of the ligands are proposed to be octahedral with water molecules as axial ligands, the Ni(II) and Cu(II) complexes are proposed to be square planar, and the …

Electrochemical Copolymerization Of Thiophene Containing Pseudo-Polyether Cages With Pyrrole, Ati̇lla Ci̇haner, Ahmet M. Önal

Turkish Journal of Chemistry

Conducting copolymers were synthesized via the electrochemical oxidation of pyrrole (Py) in the presence of the monomer 1,12-bis(2-thienyl)-2,5,8,11-tetraoxadodecane (I). The presence of monomer I in the electrolytic solution greatly changed the CV behavior of Py during its potensiodynamic polymerization. The electroactivity of poly(I-co-Py) increased with the increasing amount of I in the comonomer mixture. Copolymer films were prepared via constant potential electrolysis in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF_6) dissolved in acetonitrile. The spectroelectrochemical properties of the films were investigated using UV-VIS spectroscopy.

Infrared Laser Desorption/Ionization Mass Spectrometry: Fundamental And Applications, Mark Little

LSU Doctoral Dissertations

This dissertation on infrared laser desorption/ionization mass spectrometry encompasses fundamental studies of the desorption/ionization process and direct-from-gel laser desorption/ionization applications. Understanding of the fundamentals behind desorption and ionization can lead to improvements in the technique and to new applications. Experiments aimed at advancing this goal are wavelength studies and two-laser infrared/ultraviolet matrix-assisted laser desorption/ionization experiments. The direct-from-gel laser desorption/ionization application in which infrared laser desorption/ionization of analytes directly ionized after gel electrophoretic separation will also be presented. Protein and peptide standards were used as test analytes and the infrared lasers used were a 10.6 micrometers carbon-dioxide laser and a mid-IR …

Low-Temperature Infrared Spectroscopy Of H2 In Solid C60, Hugh O.H. Churchill

Honors Papers

Diffuse reflectance infrared spectroscopy is used to measure the quantum dynamics of molecular hydrogentrapped within a C60 lattice at temperatures as low as 10 K. Crystal field effects in conjunction with rotational translational coupling lead to a rich spectrum with multiply split peaks that are more than an order of magnitude sharper than at room temperature. The induced redshifts in the vibrational-rotational mode frequencies are explained using a simple model in which the state dependence of the H2 polarizability leads to changes in the C60-H2 interaction potential.

Effects Of Diesel-Fuel And Copper Contaminants On Benthic Microalgae, Soraya Silva

LSU Doctoral Dissertations

Salt marshes are dynamic, highly productive habitats and serve as nursery grounds for many commercially and economically important species. Benthic microalgae (BMA) are considered an important food source for benthos and provide the principal source of nutrition that fuels secondary production. Estuarine sediments around the world are a repository for many contaminants from anthropogenic sources. In particular, hydrocarbons and metals are ubiquitous contaminants in coastal systems. The primary goal of this study was to study the effects of diesel fuel and copper, alone and in combination, on the BMA assemblage from a coastal salt marsh. To achieve this objective, salt …

Factors Influencing The Participation In Environmental Stewardship Programs: A Case Study Of The Agricultural And Forestry Sectors In Louisiana, Carrie Castille Mendoza

LSU Doctoral Dissertations

Considerable research has been conducted to evaluate the adoption of agricultural best management practices and their overall impact on improving environmental quality. However, limited studies have been conducted to evaluate the behavioral factors that influence the adoption of these practices in the context of educational programs The goal of this study is to determine the factors that influence farmer conservation behavior that might lead to an increased probability of improving agriculture and forestry watersheds. A conceptual model was developed to identify the: 1) identify landowner participation in watershed conservation projects, and 2) determine the factors influencing agriculture and forestry landowners …

Water Rights In Wilderness: The Influence Of Reserved Rights Language On Protection Of Wilderness Water In Arizona And Colorado, Kathryn M. Mutz, David Bower, Katie Stone, Melissa Boness, Alexis Kazan Nelson, Kathryn Bostwick, Katie Umekubo, Eric Potyondy, Rebecca Mehring, Carol Hoskins, Meredith Roberts, University Of Colorado Boulder. Natural Resources Law Center

Books, Reports, and Studies

1 v. (various pagings) : ill. (some color), color maps ; 29 cm

Executive summary -- Introduction -- Background and scope -- Compilation and analysis of water rights data -- Protection of wilderness water : federal agency response to statutory language -- Final observations -- Appendix A. Legislative history of Arizona and Colorado wilderness legislation -- Appendix B. State water law : Arizona and Colorado -- Appendix C. Study methods -- Appendix D. Agency policies.

Unconfined Versus Confined Speleogenetic Settings: Variations Of Solution Porosity, Alexander Klimchouk

International Journal of Speleology

Speleogenesis in confined settings generates cave morphologies that differ much from those formed in unconfined settings. Caves developed in unconfined settings are characterised by broadly dendritic patterns of channels due to highly competing development. In contrast, caves originated under confined conditions tend to form two- or three-dimensional mazes with densely packed conduits. This paper illustrates variations of solution (channel) porosity resulted from speleogenesis in unconfined and confined settings by the analysis of morphometric parameters of typical cave patterns. Two samples of typical cave systems formed in the respective settings are compared. The sample that represents unconfined speleogenesis consists of solely …

Synthesis, Crystal Growth, Magnetic And Transport Properties Of Ln-M-X (Ln=Lanthanide, M=Transition Metal, X=In, Ga) Compounds, Willa Maria Williams

LSU Doctoral Dissertations

ABSTRACT This dissertation focuses on the structural stability, magnetic and transport properties of ternary lanthanide compounds grown using indium and gallium flux. Single crystals of TbRhIn5 were synthesized using indium flux. TbRhIn5 is isostructural to the well known LnnMIn3n+2 (n = 1, 2, ∞; Ln = La, Ce; M = Rh, Ir) and adopts the HoCoGa5 structure type and crystallizes in the space group P4/mmm, Z = 1. Lattice parameters are a = 4.6000(6) Å and c = 7.4370(11) Å, V = 157.29(6) Å3. A sharp antiferromagnetic transition is observed at TN = 48 K for TbRhIn5. Single crystals of …

Development Of Project Management Application Suite For Improved Communication & Project Development, Sheree Wiedeman

Regis University Student Publications (comprehensive collection)

The purpose of this project was to provide the client with a project management solution that provided for better communication between ITS and the community, while providing a place for projects to be proposed and stored, ensuring projects are not lost. This goal was achieved through a process of determining the client's business needs, examining their existing systems, preparing a formal project plan, and designing and implementing a solution. The result was a solution that provided the community a location to improve communication on project status on a 24x7 basis. Through the design of a custom project management solution, all …

A Server Consolidation Solution, Richard J. Swain

Regis University Student Publications (comprehensive collection)

Advances in server architecture has enabled corporations the ability to strategically redesign their data centers in order to realign the system infrastructure to business needs. The architectural design of physically and logically consolidating servers into fewer and smaller hardware platforms can reduce data center overhead costs, while adding quality of service. In order for the organization to take advantage of the architectural opportunity a server consolidation project was proposed that utilized blade technology coupled with the virtualization of servers. Physical consolidation reduced the data center facility requirements, while server virtualization reduced the number of required hardware platforms. With the constant …

Assessing Trace Evidence Left By Secure Deletion Programs, Paul Burke, Philip Craiger

Publications

Secure deletion programs purport to permanently erase files from digital media. These programs are used by businesses and individuals to remove sensitive information from media, and by criminals to remove evidence of the tools or fruits of illegal activities. This paper focuses on the trace evidence left by secure deletion programs. In particular, five Windows-based secure deletion programs are tested to determine if they leave identifiable signatures after deleting a file. The results show that the majority of the programs leave identifiable signatures. Moreover, some of the programs do not completely erase file metadata, which enables forensic investigators to extract …

Research-Based Web Design & Usability Guidelines [2006 Edition], Michael O. Leavitt, Ben Shneiderman, Robert W. Bailey, Carol Barnum, John Bosley, Barbara Chaparro, Joseph Dumas, Melody Y. Ivory, Bonnie John, Hal Miller-Jacobs, Sanjay J. Koyani, James R. Lewis, Stanley Page, Judith Ramey, Janice (Ginny) Redish, Jean Scholtz, Steve Wigginton, Cari A. Wolfson, Larry E. Wood, Don Zimmerman

Publications

The new edition of the U.S. Department of Health and Human Services’ (HHS) Research-Based Web Design and Usability Guidelines. These guidelines reflect HHS’ commitment to identifying innovative, research-based approaches that result in highly responsive and easy-to-use Web sites for the public.

These guidelines help move us in that direction by providing practical, yet authoritative, guidance on a broad range of Web design and communication issues. Having access to the best available research helps to ensure we make the right decisions the first time around and reduces the possibility of errors and costly mistakes.

Transfer Of Training From Flight Training Devices To Flight For Ab-Initio Pilots, Nickolas D. Macchiarella, Pamela K. Arban, Shawn M. Doherty

Publications

The application of flight simulation to meet pilot training needs continues to evolve. Flight simulations built with powerful and inexpensive computers are making high fidelity simulation available as a medium for training ab-initio pilots at Pilot Schools and Training Centers. The researchers conducted an 18-month study that applied an experimental flight-training curriculum comprised of 60% flight training device (FTD) flight and 40% airplane flight to certify Private Pilots under Federal Aviation Regulation (FAR) Part 142. The results from the research provided data to ascertain the effective transfer for each flight-training task. Ab-initio student pilots practiced each task to standard in …

Cool White Dwarfs In The Sloan Digital Sky Survey, Mukremin Kilic, Jeffrey A. Munn, Hugh C. Harris, James W. Liebert, Ted Von Hippel, Kurtis A. Williams, Travis S. Metcalfe, D. E. Winget, Stephen E. Levine

Publications

A reduced proper motion diagram utilizing Sloan Digital Sky Survey (SDSS) photometry and astrometry and USNO-B plate astrometry is used to separate cool white dwarf candidates from metal-weak, high-velocity, mainsequence Population II stars (subdwarfs) in the SDSS Data Release 2 imaging area. Follow-up spectroscopy using the Hobby-Eberly Telescope, the MMT, and the McDonald 2.7 m telescope is used to demonstrate that the white dwarf and subdwarf loci separate cleanly in the reduced proper motion diagram and that the contamination by subdwarfs is small near the cool white dwarf locus. This enables large, statistically complete samples of white dwarfs, particularly the …

Book Review: The Amateur Astronomer's Introduction To The Celestial Sphere, T. D. Oswalt

Publications

This document is Dr. Oswalt’s review of The Amateur Astronomer's Introduction to the Celestial Sphere by William Millar. Cambridge, 2006 299p, 052167123X $40.00, 9780521671231 $40.00.

Observations Of Triboelectric Charging Effects On Langmuir-Type Probes In Dusty Plasma, Aroh Barjatya, Charles M. Swenson

Publications

Investigation of Earth’s mesosphere using sounding rockets equipped with a myriad of instruments has been a highly active field in the last 2 decades. This paper presents data from three separate instruments: an RF impedance probe, a DC fixed bias Langmuir probe, and an electric field probe, that were flown on a mesospheric sounding rocket flight investigating the presence of charged dust within and/or around a sporadic metal layer. The combined data set indicates a case of payload surface charging, the causes of which are investigated within this paper. A generic circuit model is developed to analyze payload charging and …

Review: Stability Of Bases And Frames Of Reproducing Kernels In Model Spaces, Stephan Ramon Garcia

Pomona Faculty Publications and Research

No abstract provided.

Kernels Of Directed Graph Laplacians, John S. Caughman Iv, J. J. P. Veerman

Mathematics and Statistics Faculty Publications and Presentations

Let G denote a directed graph with adjacency matrix Q and in- degree matrix D. We consider the Kirchhoff matrix L = D − Q, sometimes referred to as the directed Laplacian. A classical result of Kirchhoff asserts that when G is undirected, the multiplicity of the eigenvalue 0 equals the number of connected components of G. This fact has a meaningful generalization to directed graphs, as was observed by Chebotarev and Agaev in 2005. Since this result has many important applications in the sciences, we offer an independent and self-contained proof of their theorem, showing in this paper …

Analyzing Dna Microarrays With Undergraduate Statisticians, Johanna S. Hardin, Laura Hoopes, Ryan Murphy '06

Pomona Faculty Publications and Research

With advances in technology, biologists have been saddled with high dimensional data that need modern statistical methodology for analysis. DNA microarrays are able to simultaneously measure thousands of genes (and the activity of those genes) in a single sample. Biologists use microarrays to trace connections between pathways or to identify all genes that respond to a signal. The statistical tools we usually teach our undergraduates are inadequate for analyzing thousands of measurements on tens of samples. The project materials include readings on microarrays as well as computer lab activities. The topics covered include image analysis, filtering and normalization techniques, and …

Conjugation And Clark Operators, Stephan Ramon Garcia

Pomona Faculty Publications and Research

No abstract provided.

Yeast Through The Ages: A Statistical Analysis Of Genetic Changes In Aging Yeast, Alison Wise '05, Johanna S. Hardin, Laura Hoopes

Pomona Faculty Publications and Research

Microarray technology allows for the expression levels of thousands of genes in a cell to be measured simultaneously. The technology provides great potential in the fields of biology and medicine, as the analysis of data obtained from microarray experiments gives insight into the roles of specific genes and the associated changes across experimental conditions (e.g., aging, mutation, radiation therapy, drug dosage). The application of statistical tools to microarray data can help make sense of the experiment and thereby advance genetic, biological, and medical research. Likewise, microarrays provide an exciting means through which to explore statistical techniques.

Intrinsic Linking And Knotting Of Graphs In Arbitrary 3–Manifolds, Erica Flapan, Hugh Howards, Don Lawrence, Blake Mellor

Pomona Faculty Publications and Research

We prove that a graph is intrinsically linked in an arbitrary 3–manifold M if and only if it is intrinsically linked in S³. Also, assuming the Poincaré Conjecture, we prove that a graph is intrinsically knotted in M if and only if it is intrinsically knotted in S³.

Super Solutions Of The Dynamical Yang-Baxter Equation, Gizem Karaali

Pomona Faculty Publications and Research

Solutions of the classical dynamical Yang-Baxter equation on a Lie superalgebra are called super dynamical r−matrices. A super dynamical r−matrix r satisfies the zero weight condition if

[h ⊗ 1 + 1 ⊗ h, r(λ)] = 0 for all h ∈ ɧ, λ ∈ ɧ ∗ .

In this paper we classify super dynamical r−matrices with zero weight.

What I Learned At The Maa Digital Library Workshop, Gizem Karaali

Pomona Faculty Publications and Research

Toward the end of July 2006, an item appeared briefly on the MAA website. This was the call for participants for the MAA Digital Library Workshop. Curious surfers like me clicked on it to find the description of this workshop, which was to be held over the course of a weekend in October 2006 in Washington, DC. The announcement included a cryptic sentence of the form “The primary aims of the workshop are to provide an overview of the two MAA digital libraries and of the National Science Digital Library, and to prepare participants to offer a short workshop on …

Implications Of Mass Education On Chemistry Higher Education, Christine O'Connor

Conference Papers

The following paper discusses the implications of government policy on widening of participation at third level institutes. The increase in ‘non-traditional’ students has been widely recognised on an international scale; however some inequality issues still exist. The ‘struggles’ associated with widening of participation and creating a ‘new’ student type is discussed in particular reference to chemistry education. A change in mindset of staff on their pedagogical approach to cater for a diverse student body with a broad range of learner types is required. This must be supported from a departmental and institutional level. A look at the literature to investigate …

Effect Of A Finite Number Of Electrons On The Physical Properties Of Two Dimensional Parabolic Quantum Dot, Berna Gülveren, Ülfet Atav, Mehmet Tomak

Turkish Journal of Physics

The effect of number of particles on the physical properties of a two dimensional parabolic quantum dot system is investigated numerically at finite temperature. The Thomas-Fermi equation is solved self consistently with Poisson equation. The changes induced by electron-electron interaction are also analyzed. It is shown that the numerical procedure that is applied to solve the problem is very efficient at all temperatures.

Ibm-2 Calculations Of Selected Even-Even Ruthenium Nuclei, İlyas İnci̇, Nuretti̇n Türkan

Turkish Journal of Physics

In this study, we have employed the Interacting Boson Model-2 (IBM-2) to determine the most appropriate Hamiltonian for the study of ruthenium nuclei in the region A \cong 100. Using the best fit values of parameters to construct the Hamiltonian, we have estimated energy levels and multipole mixing ratios (\delta (E2/M1)) for some doubly-even Ru nuclei. The results are compared with previous experimental and theoretical data and it is observed that they are in good agreement.

Ibm-2 Calculations Of Selected Even-Even Palladium Nuclei, İlyas İnci̇, Nuretti̇n Türkan

Turkish Journal of Physics

In this study, we have employed the Interacting Boson Model-2 (IBM-2) to determine the most appropriate Hamiltonian for the study of palladium nuclei. Using the best fit values of parameters to construct the Hamiltonian, we have estimated energy levels and multipole mixing ratios (\delta (E2/M1)) for some doubly-even Pd nuclei. The results are compared with previous experimental and theoretical data and it is observed that they are in good agreement.