Physical Sciences and Mathematics Commons^™

High-Energy Product Exchange-Spring Fept/Fe Cluster Nanocomposite Permanent Magnets, X. Rui, Jeffrey E. Shield, Zhiguang Sun, Lanping Yue, Yinfan Xu, David J. Sellmyer, Z. Liu, D.J. Miller

David Sellmyer Publications

In this paper, we report on the production of Fe cluster/FePt matrix nanocomposite permanent magnets. Monodispersed Fe clusters with sizes below 10 nm were formed by gas aggregation techniques. These Fe clusters were imbedded in an FePt matrix by alternate deposition from two sources. Specimens with a range of Fe cluster phase content from 0 to 30 vol% were produced by controlling deposition times from each source. As-deposited FePt formed in the A1 structure; thus, post-deposition heat treatment was necessary to form the hard magnetic L1₀ FePt compound. A single-step heat treatment at 600 °C for 10 min leads …

Cooling Of The Quasi-Persistent Neutron Star X-Ray Transients Ks 1731-260 And Mxb 1659-29, Edward M. Cackett, Rudy Wijnands, Manuel Linares, Jon M. Miller, Jeroen Homan, Walter H. G. Lewin

Physics and Astronomy Faculty Research Publications

We present Chandra and XMM-Newton X-ray observations that monitor the neutron star cooling of the quasi-persistent neutron star X-ray transients KS 1731-260 and MXB 1659-29 for approximately 4 yr after these sources returned to quiescence from prolonged outbursts. In both sources the outbursts were long enough to significantly heat the neutron star crust out of thermal equilibrium with the core. We analyse the X-ray spectra by fitting absorbed neutron star atmosphere models to the observations. The results of our analysis strengthen the preliminary findings of Wijnands et al. that in both sources the neutron star crust cools down very rapidly …

Multiobjective Optimization Problems With Equilibrium Constraints, Boris S. Mordukhovich

Mathematics Research Reports

The paper is devoted to new applications of advanced tools of modern variational analysis and generalized differentiation to the study of broad classes of multiobjective optimization problems subject to equilibrium constraints in both finite-dimensional and infinite-dimensional settings. Performance criteria in multiobjectivejvector optimization are defined by general preference relationships satisfying natural requirements, while equilibrium constraints are described by parameterized generalized equations/variational conditions in the sense of Robinson. Such problems are intrinsically nonsmooth and are handled in this paper via appropriate normal/coderivativejsubdifferential constructions that exhibit full calculi. Most of the results obtained are new even in finite dimensions, while the case of …

Chemistry & Biochemistry Newsletter, Department Of Chemistry & Biochemistry, South Dakota State University

Chemistry & Biochemistry Newsletter: 2002-2015

Inside:

Page 2-3 Grad students attend International Summer School in Green Chemistry

Page 3 Alumni News

Page 4 Alum receives brigadier general stars

Page 5 New Grad Students

Page 6 Tanaka endows undergraduate scholarship; Midwest Seeds becomes internship partner

Page 7 The 2006/2007 Burris Lecturer leader in drug discovery

Page 8 New Faculty; Perfecting the formula for the future of SDSU chemistry

An Elliptic Equation With No Monotonicity Condition On The Nonlinearity, Gregory S. Spradlin

Greg S. Spradlin Ph.D.

An elliptic PDE is studied which is a perturbation of an autonomous equation. The existence of a nontrivial solution is proven via variational methods. The domain of the equation is unbounded, which imposes a lack of compactness on the variational problem. In addition, a popular monotonicity condition on the nonlinearity is not assumed. In an earlier paper with this assumption, a solution was obtained using a simple application of topological (Brouwer) degree. Here, a more subtle degree theory argument must be used.

Analiza Możliwości Ograniczenia Emisji Zanieczyszczeń Powietrza Z Instalacji Spalania Odpadów Medycznych W Tarnowie, Robert Oleniacz

Robert Oleniacz

The paper presents initial research of effects of some factors on the amount of gaseous pollutants formation during medical waste incineration in a two-stage starved air fluidised bed reactor. In the research was included the impact of such factors as oxygen contents in flue gases, frequency of waste loading, momentary mass flow of waste and temperature in the secondary combustion chambers. Measurements showed that the waste incineration in large amount periodically caused excessive emissions incomplete combustion products (CO, HC), especially during wrong operation of the combustion system. The work demonstrated that the essential importance for CO and HC formation reducing …

Development Of Genetic Algorithm For Solving Scheduling Tasks In Fms With Coloured Petri Nets, Liana Napalkova, Galina Merkuryeva, Miquel Angel Piera

Liana Napalkova

The paper describes the algorithm, which is developed to solve scheduling tasks in Flexible Manufacturing Systems. The algorithm is a combination of Genetic Algorithm and Coloured Petri Nets. It is proposed to use Coloured Petri Nets to tackle the encoding problem in Genetic Algorithm. The objective is to minimize the total make-span subject to different constraints obtained in Flexible Manufacturing Systems.

Anaerobic Catalytic Oxidation Of Hydrocarbons In Moving Heat Waves. Case Simulation: Propane Oxidative Dehydrogenation In A Packed Adiabatic V-Ti Oxide Catalyst Bed, Andrey N. Zagoruiko

Andrey N Zagoruiko

The model simulation study has shown that the anaerobic process of oxidative dehydrogenation of propane under periodic alteration of feeding between propane and air may be realized in adiabatic catalyst beds in stable continuous cyclic mode in two-reactor scheme. In case of appropriate choice of process parameters (cycle duration, feeding flow rates) the process appears to be autothermal, i.e. it does not require any inlet gas preheating for stable operation. Compared to similar steady-state adiabatic process, the proposed process is characterized with much lower maximum catalyst temperatures, giving the way to process pure propane without diluting it with inert gases, …

Why Don't People Read The Manual?, David G. Novick, Karen Ward

David G. Novick

Few users of computer applications seek help from the documentation. This paper reports the results of an empirical study of why this is so and examines how, in real work, users solve their usability problems. Based on in-depth interviews with 25 subjects representing a varied cross-section of users, we find that users do avoid using both paper and online help systems. Few users have paper manuals for the most heavily used applications, but none complained about their lack. Online help is more likely to be consulted than paper manuals, but users are equally likely to report that they solve their …

Phase Field Theory Of Surface- And Size-Induced Microstructures, Valery I. Levitas, D.W. Lee, D. L. Preston

Valery I. Levitas

New surface- and size-induced microstructures are found as analytic solutions to a phase field theory of first-order phase transformations. A recently developed exact stability criterion, based on most destabilizing fluctuations, is used to analyze the stability and physical interpretation of each microstructure. Conditions for barrierless surface nucleation, i.e. relationship between surface energy, driving force for the transformation and sample size, are found. If they are met, some of these microstructures are destroyed resulting in the barrierless transformation to alternative phases.

Semicrystalline Thermoplastic Elastomeric Polyolefins: Advances Through Catalyst Development And Macromolecular Design, Atsushi Hotta, Eric W. Cochran, Janne Ruokolainen, Vikram Khann, Glenn H. Fredrickson, Edward J. Kramer, Yong-Woo Shin, Fumihiko Shimizu, Anna E. Cherian, Phillip D. Hustad, Jeffrey M. Rose, Geoffrey W. Coates

Eric W. Cochran

We report the design, synthesis, morphology, phase behavior, and mechanical properties of semicrystalline, polyolefin-based block copolymers. By using living, stereoselective insertion polymerization catalysts, syndiotactic polypropylene-block-poly(ethylene-co-propylene)-block-syndiotactic polypropylene and isotactic poly propylene-block-regioirregular poly propylene-block- isotactic polypropylene triblock copolymers were synthesized. The volume fraction and composition of the blocks, as well as the overall size of the macromolecules, were controlled by sequential synthesis of each block of the polymers. These triblock copolymers, with semicrystalline end-blocks and mid-segments with low glass-transition temperatures, show significant potential as thermoplastic elastomers. They have low Young's moduli, large strains at break, and better than 90% elastic recovery at …

Hydrogen And Deuterium Exchange On Pt(111) And Its Poisoning By Carbon Monoxide Studied By Surface Sensitive High-Pressure Techniques, Max Montano, Kaitlin M. Bratlie, Miquel Salmeron, Gabor A. Somorjai

Kaitlin M. Bratlie

Catalytic hydrogen/deuterium exchange on a platinum (111) single crystal and its poisoning with carbon monoxide was studied using scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), sum frequency generation vibrational spectroscopy (SFG), and mass spectrometry under reaction conditions at pressures in the mTorr to atmospheric range. At 298 K and in the presence of 200 mTorr of hydrogen and 20 mTorr of deuterium the surface is catalytically active, producing HD with activation energy of 5.3 kcal/mol. Addition of 5 mTorr of CO stops the reaction completely. In situ STM images reveal an ordered surface structure of chemisorbed CO. At 353 …

Occlusion Of Grubbs' Catalysts In Active Membranes Of Polydimethylsiloxane:  Catalysis In Water And New Functional Group Selectivities, Martin T. Mwangi, M. Brett Runge, Ned B. Bowden

Martin M. Thuo

The Grubbs' first and second generation catalysts were occluded into cross-linked slabs of polydimethylsiloxane with volumes from 1 mm3 to 1 cm3 by swelling the polymer with catalyst and methylene chloride. Methylene chloride was evaporated under vacuum to yield occluded catalysts where their solvent was polydimethylsiloxane. These occluded catalysts were reacted with alkenes dissolved in H2O or H2O/MeOH mixtures that diffused into the polydimethylsiloxane to react by ring-closing metathesis and cross metathesis. Control experiments revealed that the catalysts remained occluded and metathesis did not occur in the solvent. Occlusion of these catalysts allowed commercially available Grubbs' catalysts to be used …

Remarks On The Combinatorial Intersection Cohomology Of Fans, Tom Braden

Tom Braden

No abstract provided.

Sum Frequency Generation Vibrational Spectroscopic And High-Pressure Scanning Tunneling Microscopic Studies Of Benzene Hydrogenation On Pt(111), Kaitlin M. Bratlie, Max O. Montano, Lucio D. Flores, Matti Paajanen, Gabor A. Somorjai

Kaitlin M. Bratlie

Sum frequency generation (SFG) vibrational spectroscopy and high-pressure scanning tunneling microscopy (HP-STM) have been used in combination for the first time to study a catalytic reaction. These techniques have been able to identify surface intermediates in situ during benzene hydrogenation on a Pt(111) single-crystal surface at Torr pressures.

Probing The Reaction Mechanism Of The D-Ala-D-Ala Dipeptidase, Vanx, By Using Stopped-Flow Kinetic And Rapid-Freeze Quench Epr Studies On The Co(Ii)-Substituted Enzyme, Megan L. Matthews, Gopalraj Periyannan, Christine E. Hajdin, Tara K. Sidgel, Brian Bennett, Michael W. Crowder

Physics Faculty Research and Publications

In an effort to probe the reaction mechanism of VanX, the D-ala-D-ala dipeptidase required for high-level vancomycin resistance in bacteria, stopped-flow kinetic and rapid-freeze quench EPR studies were conducted on the Co(II)-substituted enzyme when reacted with d-ala-d-ala. The intensity of the Co(II) ligand field band at 550 nm decreased (ε₅₅₀ = 140 to 18 M^-1 cm^-1) when VanX was reacted with substrate, suggesting that the coordination number of the metal increases from 5 to 6 upon substrate binding. The stopped-flow trace was fitted to a kinetic mechanism that suggests the presence of an intermediate whose breakdown …

A Simple Electric Field Probe In A Gauss's Law Laboratory, Daniel O. Ludwigsen, Gregory N. Hassold

Physics Publications

Early in our calculus-based introductory course, students are introduced to electric fields and sometimes struggle with the abstraction of a vector field. They have less familiarity with the phenomena associated with electric fields, and the connection between phenomena and mathematical formalism is weaker. Our very next topic is Gauss's law.

Solution Methods For The P-Median Problem: An Annotated Bibliography, Josh Reese

Mathematics Faculty Research

The p-median problem is a graph theory problem that was originally designed for, and has been extensively applied to, facility location. In this bibliography, we summarize the literature on solution methods for the uncapacitated and capacitated p-median problem on a graph or network.

Oregon Ballast Water Task Force Report On Ballast Water Management In Oregon, Christina Simkanin, Mark Sytsma

Center for Lakes and Reservoirs Publications and Presentations

This report provides information and analysis on the current ballast water regulations at international, federal, regional and state levels; ballast water discharge trends in Oregon; the shipping industry’s compliance with Oregon law; and current and emerging issues affecting Oregon’s ballast water legislation. The report also provides recommendations for strengthening Oregon’s management of shipping-related pathways of invasive species introduction.

Geogram 2006, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Santa Clara Magazine, Volume 48 Number 2, Fall 2006, Santa Clara University

Santa Clara Magazine

8 - TRUTH, LEGEND, AND JESSE JAMES By Ron Hansen M.A. '95. Jesse James' exploits made him a legend even in his own time. Now the author of the novel The Assassination of Jesse James by the Coward Robert Ford reveals what it takes to get beyond coloring book heroes and villains to understanding a charming psychopath and his killer. Plus insights into the making of the forthcoming film starring Brad Pitt and Casey Affleck.

14 - VIOLENCE IN THE MOVIES By Jim Shepard. Movies keep giving us more motion, more mayhem-which is exactly what we want. But what price …

Indiana Wildlife Disease News; Volume 1, Issue 4, October 2006

Indiana Wildlife Disease News

Epizootic hemorrhagic disease (EHD) is an acute, infectious, often fatal viral disease of some wild ruminants. Epizootic Hemorrhagic Disease Confirmed in Free-ranging Deer From West-Central Indiana. Bluetongue is an insect-borne, viral disease primarily of sheep, occasionally goats and deer and, very rarely, cattle. The Indiana State Department of Health (ISDH) has had a sophisticated disease surveillance system in place since 2000 to monitor mosquitoes and birds that can potentially carry West Nile virus (WNV). Testing for chronic wasting disease (CWD) in Indiana’s deer herd will continue this fall. Chronic Wasting Disease Herd Certification Petitions and Request for Comments. For updates …

Wissensmanagement Profitiert Von Semantiktechnologien, Pascal Hitzler, Rudi Studer

Computer Science and Engineering Faculty Publications

In der Forschung um das Semantic Web werden Technologien entwickelt, die auf breites Interesse in vielen Anwendungsgebieten stoßen. So z.B. im Wissensmanagement und im Ubiquitous Computing.

2006 (Fall), University Of Dayton. Department Of Mathematics

Colloquia

Abstracts of the talks givn at the 2006 Fall Colloquium.

Allometric Extension For Multivariate Regression Models, Thaddeus Tarpey, Christopher T. Ivey

Mathematics and Statistics Faculty Publications

In multivariate regression, interest lies on how the response vector depends on a set of covariates. A multivariate regression model is proposed where the covariates explain variation in the response only in the direction of the first principal component axis. This model is not only parsimonious, but it provides an easy interpretation in allometric growth studies where the first principal component of the log-transformed data corresponds to constants of allometric growth. The proposed model naturally generalizes the two–group allometric extension model to the situation where groups differ according to a set of covariates. A bootstrap test for the model is …

Classifying Surface Roughness With Ctfm Ultrasonic Sensing, Phillip J. Mckerrow, B. J. Kristiansen

Faculty of Informatics - Papers (Archive)

Roughness is a characteristic of a surface that is a function of its geometry. Ultrasonic sensing in air provides range, area, and angle information because the surface geometry determines the characteristics of the echo. The authors introduce the “spatial-angle-filter model” to explain the impact of surface roughness on the echo. On the basis of this model, they design a set of features for use in classifying surfaces. The quality of the features and the classification is measured with the Mahalanobis distance. The resultant system is able to achieve 99.73% classification of a set of 12 surfaces using five features.

Viewpoints Merging Via Incrementally Elicited Ranked Structures, Aditya K. Ghose, Q. Lin

Faculty of Informatics - Papers (Archive)

Handling inconsistent requirements specifications remains a difficult challenge for the requirements engineering community. This paper seeks to apply techniques developed in the belief merging literature within AI to this problem. The application is non-trivial, since many belief merging operations cannot be directly applied, but must be modified to make them usable in practical settings. We address the problem of merging state model viewpoints, and improve on previous work by Chechik and Easterbrook. We develop a variant of the belief merging framework developed by Meyer et al, which we refer to as the framework of incrementally elicited ranked structures. We show …

Co-Evolution Of I* Models And 3apl Agents, Aneesh Krishna, Y. Guan, Aditya K. Ghose

Faculty of Informatics - Papers (Archive)

Agent-Oriented Conceptual Modelling (AOCM), as exemplified by the i* notation [9], represents an interesting approach to modelling early phase requirements that is particularly effective in capturing organisational contexts, stakeholder intentions and rationale. Our objective in this paper is to define means for executing i* models by translating these into set of interacting agents implemented in the 3APL language. We also propose a hybrid modelling, or co-evolution, approach in which i* models and 3APL agent programs are concurrently maintained and updated, while maintaining some modicum of loose coupling via consistency constraints. This paper explores how these two otherwise disparate approaches might …

Co-Evolution Of Agent Oriented Conceptual Models And Use Case Diagrams, Moshiur Bhuiyan, M. M. Zahidul Islam, Aneesh Krishna, Aditya K. Ghose

Faculty of Informatics - Papers (Archive)

Agent--oriented conceptual modeling notations such as i* represents an interesting approach for modeling early phase requirements which includes organizational contexts, stakeholder intentions and rationale. On the other hand Use Case diagram is used for capturing functional requirements of the system. The integration of i* model and Use Case diagram closes the gap of capturing organizational requirements and system requirements. But in both contexts the requirements might change at any time. Any change made in one model must be reflected in the other. This paper proposes a methodology supporting the co-evolution of these two otherwise disparate approaches in a synergistic fashion.

The Planet, 2006, Fall, Shawn C. Query, Huxley College Of The Environment, Western Washington University

The Planet

No abstract provided.