Physical Sciences and Mathematics Commons^™

Improved Identification Of Sulfidic Soil Materials By A Modified Incubation Method, Leigh Sullivan, Nicholas Ward, Richard Bush, Edward Burton

Associate Professor Edward D Burton

This study examines the acidification behaviour and rate of sulfidic-sulfur oxidation in the incubation method that is currently used in soil taxonomies to identify sulfidic materials, for some clayey textured soil materials. ‘Sulfidic’ in these taxonomies identifies that a soil material is capable of becoming extremely acidic (i.e. pH < 4) as a result of oxidation of sulfide minerals contained in that soil material. As well as examining incubation slabs of acid sulfate soil materials with the standard 10 mm thickness, the utility of thinner (i.e. 2 mm thick) incubation slabs of these soil materials for identification of sulfidic soil materials …

Fe And S K-Edge Xas Determination Of Iron-Sulfur Species Present In A Range Of Acid Sulfate Soils: Effects Of Particle Size And Concentration On Quantitative Xanes Determinations, Kate Morgan, Edward Burton, Perran Cook, Mark Raven, Robert Fitzpatrick, Richard Bush, Leigh Sullivan, Rosalie Hocking

Associate Professor Edward D Burton

Acid sulfate soils (ASS) are soils and soft sediments in which sulfuric acid may be produced from iron sulfides or have been produced leaving iron oxyhydroxysulfates in amounts that have a long lasting effect on soil characteristics. If soil material is exposed to rotting vegetation or other reducing material, the Fe-oxyhydroxysulfates can be bacterially reduced to sulfides including disulfides (pyrite and marcasite), and Monosulfidic Black Ooze (MBO) a poorly characterised material known to be a mixture of iron sulfides (especially mackinawite) and organic matter. The chemistry of these environments is strongly affected by Fe and S cycling processes and herein …

Reductive Transformation Of Iron And Sulfur In Schwertmannite-Rich Accumulations Associated With Acidified Coastal Lowlands, Edward Burton, Richard Bush, Leigh Sullivan, David Mitchell

Associate Professor Edward D Burton

We examined the transformations of Fe and S associated with schwertmannite (Fe8O8(OH)6SO4) reduction in acidified coastal lowlands. This was achieved by conducting a 91 day diffusive-flux column experiment, which involved waterlogging of natural schwertmannite- and organic-rich soil material. This experiment was complemented by short-term batch experiments utilizing synthetic schwertmannite. Waterlogging readily induced bacterial reduction of schwertmannite-derived Fe(III), producing abundant pore-water FeII, SO4 and alkalinity. Production of alkalinity increased pH from pH 3.4 to pH 6.5 within the initial 14 days, facilitating the precipitation of siderite (FeCO3). Interactions between schwertmannite and FeII at pH 6.5 were found, for the first time, …

A Sequential Extraction Procedure For Acid-Sulfate Soils: Partitioning Of Iron, Salirian Claff, Leigh Sullivan, Edward Burton, Richard Bush

Associate Professor Edward D Burton

A new sequential extraction scheme for acid sulfate soil materials has been evaluated for iron partitioning in a range of synthetic iron-bearing minerals and natural acid sulfate soil materials. This sequential extraction procedure employs six steps to quantify (1) exchangeable (magnesium chloride extractable), (2) acid (hydrochloric acid) soluble, (3) reactive organic-bound (pyrophosphate extractable), (4) crystalline oxide (citrate buffered dithionite (CBD)) extractable, (5) pyrite-bound (nitric acid extractable) and (6) residual (acid/peroxide digestible) forms of iron. Given its intended use for acid sulfate soil materials that frequently contain pyrite, a primary aim of this new sequential extraction procedure was to differentiate iron …

Autonomous Fmcw Radar Survey Of Antarctic Shear Zone, Gary Koh, James H. Lever, Steven A. Arcone, Hans-Peter Marshall, Laura E. Ray

CGISS Publications and Presentations

Radar survey of the Antarctic shear zone was conducted using an ultra-wideband (2-10 GHz) frequency modulated continuous wave (FMCW) radar. The radar was mounted on a sled and pulled by a robot that was specifically designed to operate in a harsh polar environment. Our FMCW radar had good penetration through Antarctic snow and we observed snow stratigraphy to a depth of 20 m. The radar images also revealed multiple crevasses in the shear zone. Our results demonstrate that autonomous survey using high frequency radar is feasible and safe approach for detecting hidden crevasses.

2d Ground-Penetrating Radar Avo Response To A 3d Dielectric Permittivity Anomaly, John H. Bradford

CGISS Publications and Presentations

To evaluate the amplitude vs offset response of GPR to small distributions of hydrocarbon contamination, I acquired multi-offset 450 MHz GPR data in TE and TM modes over a buried rectangular tank filled with gasoline saturated sand. All dimensions of the tank were less than one wavelength at the characteristic antenna frequency. The permittivity ratio at the moist sand/gasoline sand boundary, estimated by fitting the Fresnel equations to the observed amplitudes and by Brewster's Angle analysis, differed from that obtained through migration velocity analysis by no more than 12%. 2D FDTD modeling reproduced amplitude characteristics for 3 o f 4 …

How To Implement A Content Management System, Jonathan M. Smith

Library Faculty Publications & Presentations

Web content management systems (CMS) are increasingly becoming the preferred solution for library websites and intranets. This session will describe the entire process of implementing CMS; from requirements gathering to post-launch evaluation. We will take a look at several popular open source CMS, and discuss the technical requirements for hosting these systems. Project management principles will be applied to the process, and usability testing methods will be discussed as part of the design and evaluation phases.

Enhanced Web Search Engines With Query-Concept Bipartite Graphs, Yan Chen

Computer Science Dissertations

With rapid growth of information on the Web, Web search engines have gained great momentum for exploiting valuable Web resources. Although keywords-based Web search engines provide relevant search results in response to users’ queries, future enhancement is still needed. Three important issues include (1) search results can be diverse because ambiguous keywords in queries can be interpreted to different meanings; (2) indentifying keywords in long queries is difficult for search engines; and (3) generating query-specific Web page summaries is desirable for Web search results’ previews. Based on clickthrough data, this thesis proposes a query-concept bipartite graph for representing queries’ relations, …

Long-Lived Time-Dependent Remnants During Cosmological Symmetry Breaking: From Inflation To The Electroweak Scale, Marcelo Gleiser, Noah Graham, Nikitas Stamatopoulos

Dartmouth Scholarship

Through a detailed numerical investigation in three spatial dimensions, we demonstrate that long-lived time-dependent field configurations emerge dynamically during symmetry breaking in an expanding de Sitter spacetime. We investigate two situations: a single scalar field with a double-well potential and an SU(2) non-Abelian Higgs model. For the single scalar, we show that large-amplitude oscillon configurations emerge spontaneously and persist to contribute about 1.2% of the energy density of the Universe. We also show that for a range of parameters, oscillon lifetimes are enhanced by the expansion and that this effect is a result of parametric resonance. For the SU(2) case, …

Scattering Amplitudes From Unitarity-Based Reduction Algorithm At The Integrand-Level, P. Mastrolia, Giovanni Ossola, T. Reiter, F. Tramontano

Publications and Research

Samurai is a tool for the automated numerical evaluation of one-loop corrections to any scattering amplitudes within the dimensional-regularization scheme. It is based on the decomposition of the integrand according to the OPP-approach, extended to accommodate an implementation of the generalized d-dimensional unitarity-cuts technique, and uses a polynomial interpolation exploiting the Discrete Fourier Transform. samurai can process integrands written either as numerator of Feynman diagrams or as product of tree-level amplitudes. We discuss some applications, among which the 6- and 8-photon scattering in QED, and the 6-quark scattering in QCD. samurai has been implemented as a Fortran90 library, publicly available, …

Functional, Degradable Polyester Materials Synthesized From Poly(Epsilon-Caprolactone-Co-2-Oxepane-1,5-Dione): An Investigation Into The Derivatization, Self Assembly, And Degradation Behavior Of Poly(Epsilon-Caprolactone)-Based Materials, Rhiannon K. Iha

Arts & Sciences Electronic Theses and Dissertations

Biocompatible, degradable polymers possessing a high degree of complexity are an extremely desirable target for many applications. In order to further develop the range and utility of materials made from aliphatic polyesters, poly(epsilon-caprolactone-co-2-oxepane-1,5-dione) (P(CL-co-OPD)) was used as a polymeric precursor for the construction of a series of functional polyester-based materials. By taking advantage of the electrophilic ketone moieties characteristic of the OPD repeat unit, small molecule and polymer grafts were attached to the PCL backbone through the formation of both hydrazone and ketoxime ether linkages. This work has focused on both the synthesis and characterization of functional, degradable polyesters, including …

Insights Into Particle Formation And Remineralization Using The Short-Lived Radionuclide, Thorium-234, Kanchan Maiti, Claudia R. Benitez-Nelson, Ken O. Buesseler

Faculty Publications

[1] Simple mass balance models are applied to a high resolution 234Th profile from the northwest Pacific to examine the magnitude, rate, and depth distribution of particle remineralization processes below the euphotic zone (Ez). Here, excess 234Th (234Th > 238U) below the Ez is attributed to fragmentation processes that result in the conversion of sinking to non‐sinking particles. By considering particulate organic carbon (POC) to 234Th ratios on particles, we show that POC flux attenuation is larger than for 234Th, which we attribute to bacterial and zooplankton consumption of sinking POC. Three case studies are used to demonstrate how different combinations …

Spin Obit Interaction, Ronald Lovett

Topics in Quantum Mechanics

No abstract provided.

Transition Metal Dopants Essential For Producing Ferromagnetism In Metal Oxide Nanoparticles, Lydia M. Johnson, Aaron Thurber, Joshua Anghel, Maryam Sabetian, Mark H. Engelhard, Dmitri A. Tenne, Charles B. Hanna, Alex Punnoose

Physics Faculty Publications and Presentations

Recent claims that ferromagnetism can be produced in nanoparticles of metal oxides without the presence of transition metal dopants have been challenged in this work by investigating 62 high quality well-characterized nanoparticle samples of both undoped and Fe doped (0-10% Fe) ZnO. The undoped ZnO nanoparticles showed zero or negligible magnetization, without any dependence on the nanoparticle size. However, chemically synthesized Zn_1-xFe_xO nanoparticles showed clear ferromagnetism, varying systematically with Fe concentration. Furthermore, the magnetic properties of Zn_1-xFe_xO nanoparticles showed strong dependence on the reaction media used to prepare the samples. The zeta …

Is Competition Making A Comeback? Discovering Methods To Keep Female Adolescents Engaged In Stem: A Phenomenological Approach, Kathryn B. Notter

College of Education and Human Sciences: Dissertations, Theses, and Student Research

The decreasing number of women who are graduating in the Science, Technology, Engineering and Mathematics (STEM) fields continues to be a major concern. Despite national support in the form of grants provided by National Science Foundation, National Center for Information and Technology and legislation passed such as the Deficit Reduction Act of 2005 that encourages women to enter the STEM fields, the number of women actually graduating in these fields is surprisingly low. This research study focuses on a robotics competition and its ability to engage female adolescents in STEM curricula. Data have been collected to help explain why young …

The Analysis Of Palaeobotanical Remains From Native American Sites In The Tennessee Region Of The Upper Cumberland Plateau., Chase W. Beck

Electronic Theses and Dissertations

Sediment samples were collected from 3 rock shelter sites and one natural pond on the Upper Cumberland Plateau. Samples were processed to quantitatively and qualitatively evaluate pollen and charcoal abundance as well as other palaeobotanicals. The analysis was to determine when prehistoric Native Americans began controlled burns to enhance resources acquisition. Samples were also analyzed for the presence of pollen to determine vegetation changes that may accompany the use of controlled burns and to determine the onset of horticulture. The Upper Cumberland Plateau is often considered a marginal area used only seasonally by Native Americans; however, management practices may have …

Cyanoscorpionates And Transition Metal Complexes., Donald Martin Johnson

Electronic Theses and Dissertations

The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.

Non-Classical Symmetry Solutions To The Fitzhugh Nagumo Equation., Arash Mehraban

Electronic Theses and Dissertations

In Reaction-Diffusion systems, some parameters can influence the behavior of other parameters in that system. Thus reaction diffusion equations are often used to model the behavior of biological phenomena. The Fitzhugh Nagumo partial differential equation is a reaction diffusion equation that arises both in population genetics and in modeling the transmission of action potentials in the nervous system. In this paper we are interested in finding solutions to this equation. Using Lie groups in particular, we would like to find symmetries of the Fitzhugh Nagumo equation that reduce this non-linear PDE to an Ordinary Differential Equation. In order to accomplish …

Early Stopping Of A Neural Network Via The Receiver Operating Curve., Daoping Yu

Electronic Theses and Dissertations

This thesis presents the area under the ROC (Receiver Operating Characteristics) curve, or abbreviated AUC, as an alternate measure for evaluating the predictive performance of ANNs (Artificial Neural Networks) classifiers. Conventionally, neural networks are trained to have total error converge to zero which may give rise to over-fitting problems. To ensure that they do not over fit the training data and then fail to generalize well in new data, it appears effective to stop training as early as possible once getting AUC sufficiently large via integrating ROC/AUC analysis into the training process. In order to reduce learning costs involving the …

Virtual Manipulatives In The Classroom And Resulting Articles And Lesson Plans, Cheryl Juliana

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Upon coming across mathematical manipulatives generated and produced by Utah State University, as a math teacher, I conducted a classroom teaching experiment in three pre-algebra classes with students of various achievement levels. After teaching the entire year using no manipulatives in the classroom, I tested my students with a general, end-of-year, core criterion, or cumulative test. Their scores were noted. The students in the study group were then given opportunities to try several manipulatives offered on the "National Library of Virtual Manipulatives," both as a class, and alone, and then retested. The following paper gives the parameters of the study, …

A Study Of Improving The Parallel Performance Of Vasp., Matthew Brandon Baker

Electronic Theses and Dissertations

This thesis involves a case study in the use of parallelism to improve the performance of an application for computational research on molecules. The application, VASP, was migrated from a machine with 4 nodes and 16 single-threaded processors to a machine with 60 nodes and 120 dual-threaded processors. When initially migrated, VASP's performance deteriorated after about 17 processing elements (PEs), due to network contention. Subsequent modifications that restrict communication amongst VASP processes, together with additional support for threading, allowed VASP to scale up to 112 PEs, the maximum number that was tested. Other performance-enhancing optimizations that were attempted included replacing …

Spousal Concordance In Academic Achievements And Intelligence And Family-Based Association Studies Identified Novel Loci Associated With Intelligence., Yue Pan

Electronic Theses and Dissertations

Assortative Mating, the tendency for mate selection to occur on the basis of similar traits, plays an essential role in understanding the genetic variation on academic achievements and intelligence (IQ). It is an important mechanism explaining spousal concordance. We used principal component analysis (PCA) for spousal correlation. There is a significant positive correlation between spouses by the new variable PC1 (correlation coefficient=0.515, p<0.0001). We further research the genetic factor that affects IQ by using the same data. We performed a low density genome-wide association (GWA) analysis with a family-based association test to identify genetic variants that associated with intelligence as measured by WAIS full-score IQ (FSIQ). NTM at 11q25 (rs411280, p=0.000764) and NR3C2 at 4q31.23 (rs3846329, p=0.000675) were 2 novel genes that haven't been associated with IQ from other studies. This study may serve as a resource for replication in other populations and a foundation for future investigations.

A Comparative Study Between The Standards Of Learning And In-Class Grades., Randetta Lynn Fuller

Electronic Theses and Dissertations

We examined the Standards of Learning mathematics scores and in-class grades for a rural Virginia county public school system. We looked at third, fourth, fifth, sixth, and seventh grades as well as Algebra I, Algebra II, and Geometry classes. The purpose of this was to determine whether or not there is a strong correlation between the Standards of Learning and the students' in-class grades. Had a strong enough correlation between the Standards of Learning and in-class grades been found we would have used only the in-class grades to predict the Standard of Learning test scores. However, we found that the …

Acoustical Analysis Of A Horn-Loaded Compression Drivers Using Numerical Analysis, Daniel Ross Tengelsen

Theses and Dissertations

Two numerical techniques, the boundary-element method (BEM) and the finite-difference method (FDM), are used for simulating the radiation from horn-loaded compression drivers and from an infinitely-baffled, finite-length pipe. While computations of the horn-loaded compression driver are in steady state, transient analysis of the finite-length pipe is studied as a precursor to transient analysis within the horn-loaded compression driver. BEM numerical simulations show promise for the development of new designs. Numerical simulations serve as a good tool for time and cost-effective prototyping as poor designs are detected before they are built.

Use A Mobile Phone To Control Zigbee Enabled Harex Dynamic Natural Light Leds, Gang-Ryung Uh

Gang-Ryung Uh

Short-Range Smectic Order In Bent-Core Nematic Liquid Crystals, S. H. Hong, R. Verduzco, J. C. Williams, R. J. Twieg, E. Dimasi, R. Pindak, Antal Jakli, J. T. Gleeson, Samuel Sprunt

Antal Jakli

Small angle X-ray diffraction from the uniaxial nematic phase of certain bent-core liquid crystals is shown to be consistent with the presence of molecular clusters possessing short-range tilted smectic (smectic-C) order. Persistence of these clusters throughout the nematic phase, and even into the isotropic state, likely accounts for the unusual macroscopic behavior previously reported in bent-core nematics, including an anomalously large flexoelectric effect (similar to 1000 times that of conventional calamitic nematics), very large orientational and flow viscosities (similar to 10 100 and similar to 100 1000 times, respectively, typical values for calamitics), and an extraordinary flow birefringence observed in …

Interview With Crystal Benson, Green Building Services, 2010 (Audio), Crystal Benson

All Sustainability History Project Oral Histories

Interview of Crystal M. Benson by Alex Woolery at Green Building Services Portland, Oregon on August 12th, 2010.

The interview index is available for download.

Thinking Outside The Curve, Part Ii: Modeling Fetal-Infant Mortality, Richard Charnigo, Lorie W. Chesnut, Tony Lobianco, Russell S. Kirby

Statistics Faculty Publications

BACKGROUND: Greater epidemiologic understanding of the relationships among fetal-infant mortality and its prognostic factors, including birthweight, could have vast public health implications. A key step toward that understanding is a realistic and tractable framework for analyzing birthweight distributions and fetal-infant mortality. The present paper is the second of a two-part series that introduces such a framework.

METHODS: We propose estimating birthweight-specific mortality within each component of a normal mixture model representing a birthweight distribution, the number of components having been determined from the data rather than fixed a priori.

RESULTS: We address a number of methodological issues related to our …

Synthesis And Characterization Of An Oligothiophene-Ruthenium Complex And Synthesis And Optical Properties Of Oligothiophene-Ruthenium Complexes Bound To Cdse Nanoparticles, Nathan A. Bair

Theses and Dissertations

Oligothiophenes are of increasing interest in organic based electronic devices in part due to their high electron and hole mobilities. In an organic photovoltaic (OPV) device, the electronic properties of oligothiophenes make them advantageous as charge transfer junctions. To serve as charge transfer junctions, oligothiophenes must be functionalized to bind to the donor and acceptor parts of the device. The donor and acceptor parts are different materials and the synthesis of asymmetric oligothiophenes is of great interest. Previous researchers in our lab synthesized four asymmetric oligothiophenes, two with two thiophene subunits and two with four. Each set of oligothiophenes contained …

Backflip: A Principled Approach To Online Attribute Verification, Devlin R. Daley

Theses and Dissertations

As traditional interactions in the real-word move online, services that require verified personal information from web users will increase. We propose an architecture for the verification of web user attributes without the use of cryptographic-based credentials. In this architecture, service providers are delegated a user's ability to directly contact a certifying party and retrieve attribute data. We demonstrate that this approach is simple for both developers and users, can be applied to existing Internet facilities and sufficiently secure for typical web use cases.