Physical Sciences and Mathematics Commons^™

Experimental Studies On The Plasma Bullet Propagation And Its Inhibition, Erdinc Karakas, Mounir Laroussi

Electrical & Computer Engineering Faculty Publications

Plasma bullets generated by atmospheric pressure low temperature plasma jets have recently been an active research topic due to their unique properties and their enhanced plasma chemistry. In this paper, experimental insights into the plasma bullet lifetime and its velocity are reported. Data obtained from intensified charge-coupled device camera and time-resolved optical emission spectroscopy (OES) elucidated the existence of a weakly ionized channel between the plasma bullet and its source (such as the plasma pencil). Factors responsible for the inhibition of the propagation of the bullet, such as low helium mole fraction, the magnitude of the applied voltage, and the …

Plant Isotopes As Indicators Of N Cycling Processes In Agricultural Fields, Eric Thuss

Theses and Dissertations (Comprehensive)

When nitrogen (N) availability exceeds biological demand, excess N, especially nitrate (NO₃), may subsequently pollute ground and surface water. Agricultural practices in Southern Ontario typically supplement soils with organic and inorganic nutrients to aid in crop development, and employ various management techniques to limit nutrient loss. Excess N has several potential fates, which are controlled by the net effects of numerous N cycling reactions in the soil that are often difficult to measure directly. N cycling in soils is controlled in large part by soil moisture, as it affects microbial activity and soil redox conditions. Stable isotope geochemistry …

Microporous Organic Polymers: Synthesis And Post Synthetic Modifications, Phillip Andrew Kerneghan

Theses and Dissertations (Comprehensive)

Microporous solids are an important class of materials that have been studied extensively. Newer to this field are Microporous Organic Polymers (MOPs) which are networks constructed from smaller organic building blocks and exhibit large surface areas, small pore sizes and low densities. It is due to these characteristics that MOPs have attracted attention because of their potential use in applications such as catalysis, chemical separations and gas storage.

In this thesis is described the synthesis of two novel MOPs, the first of which being a network based on benzenediboronic acid and triptycene building blocks linked together by boronate esters. This …

Rethinking Biodiversity Conservation Effectiveness And Evaluation In The National Protected Areas Systems Of Tropical Islands: The Case Of Jamaica And The Dominican Republic, Suzanne Mae Camille Davis

Theses and Dissertations (Comprehensive)

Island conservation theory and practice with regard to conservation of tropical terrestrial biodiversity in protected areas systems has yet to be adequately addressed in conservation literature. This knowledge gap is identified as a key contributor to the adoption of scientific principles for in situ biodiversity conservation, and “universal” conservation and protected area management paradigms that are unsuitable for island contexts and geographical scale. The underlying assumption is that “universal” concepts of biodiversity conservation, protected areas management, and evaluation of their effectiveness are transferable to the ecological and socio-economic contexts of tropical islands. The expected outcome of this knowledge transfer is …

Spatial And Temporal Patterns In Nitrous Oxide Flux From Agricultural Soil In Southern Ontario, Michelle E. Zurbrigg

Theses and Dissertations (Comprehensive)

This research examines spatial and temporal variations in N₂O flux from agricultural clay loam in corn-wheat and corn-oat rotations in southern Ontario. Gas samples are collected by the chamber method following significant precipitation events, thaw events, fertilization events, and otherwise every two weeks over a two-year period. Crop type appears to influence the magnitude of N₂O emisions, whereas N₂O fluxes do not otherwise seem to vary by landscape position. The seasonal pattern of in situ N₂O flux at Strawberry Creek (SC) indicates that the highest N₂O emissions are occuring during …

Carbon Dioxide Exchange In A Permafrost-Dominated Boreal Wetland In The Northwest Territories, Canada, Andrea J. Kenward

Theses and Dissertations (Comprehensive)

Northern boreal wetland complexes are substantial reservoirs for carbon and play a crucial role in both regional and global carbon budgets but they are showing significant signs of impact by climate change. This study examined the carbon dioxide flux of a high boreal wetland during the snowmelt and growing season of 2008 in Scotty Creek Basin, located near Fort Simpson (61°18'N, 121°18'W), Northwest Territories. This basin is not only responding to shifts in atmospheric temperatures, but it is also under additional pressure from increasing permafrost degradation. A dynamic closed-system chamber was used to monitor and quantify mid-day total respiration (R …

Paleolimnological Reconstruction Of Hydrologic Change In The Slave River And Great Slave Lake During The Past Millennium, Matthew Ennis

Theses and Dissertations (Comprehensive)

The Slave River Delta (SRD), NWT, represents a pivotal node in the upper Mackenzie Basin watershed and is a productive northern wetland landscape with a rich natural and cultural heritage. Concerns over environmental consequences of natural and anthropogenic-driven decline in river discharge as well as climate variability have prompted hydroecological sstudies to improve understanding of how this ecosystem functions over time and space. However, long-term natural hydrological variability of the Slave River system is not well documented and needs to be further developed. In order to provide a temperal context for understanding and evaluating the impacts of climate variability and …

Mathematical Modeling And Control Of Nonlinear Oscillators With Shape Memory Alloys, Mohamed Bendame

Theses and Dissertations (Comprehensive)

Shape memory alloys (SMAs) belong to an interesting type of materials that have attracted the attention of scientists and engineers over the last few decades. They have some interesting properties that made them the subject of extensive research to find the best ways to utilize them in different engineering, biomedical, and scientific applications. In this thesis, we develop a mathematical model and analyze the behavior of SMAs by considering a one degree of freedom nonlinear oscillator consisting of a mass connected to a fixed frame through a viscous damping and a shape memory alloy device. Due to the nonlinear and …

Identifying Potential Carbon Flux Responses To Shifting Hydroecological And Climactic Regimes In The Peace-Athabasca Delta, Caleb W. Light

Theses and Dissertations (Comprehensive)

The CO2 flux response of organic carbon stored in lake sediments and littoral peat contained in sensitive, northern wetlands may contribute to accelerating atmospheric CO2 concentrations. Temperature and moisture conditions are important variables that affect the rate and quantity of CO2 released to the atmosphere from organic matter stored in lake sediments and peat. Antecedent hydroecological conditions also influence the direction and magnitude of CO2 fluxes to the atmosphere in a changing environment. To better understand and characterize the role of antecedent conditions on CO2 fluxes, this study combines paleolimnological reconstructions with laboratory incubations of littoral peat and lake sediment …

Isolation And Characterization Of Ligands For The Goldfish Testicular Androgen Receptor From Kraft Mill Chemical Recovery Condensates, Philip David Scott

Theses and Dissertations (Comprehensive)

An investigation of cause was started in the 1990s at a bleached Kraft mill (BKM), located in Saint John NB, Canada. The 5th effect chemical recovery condensates waste stream (derived from wastewater generated during the pulping process) was identified as having the greatest potential for affecting mummichog (Fundulus heteroclitus), compared to the rest of the inmill waste streams. A solid phase extraction (SPE) protocol was utilized to isolate the causative chemicals in the condensate stream. Goldfish testicular androgen receptors (ARs) were exposed to five extracts: filter paper non-polar/polar, solid phase extraction nonpolar/polar, and residual condensates. The filter paper …

Polystyrene-Supported Aluminum Chloride As An Efficient And Reusable Catalyst For Condensation Of Indole With Various Carbonyl Compounds, Bahman Tamami, Amir Nasrolahi Shirazi, Kaveh Parvanak Borujeni

Pharmacy Faculty Articles and Research

Crosslinked polystyrene-supported aluminum chloride (PS-AlCl3) is a stable, recyclable and environmental friendly heterogeneous catalyst for the condensation of indole with aldehydes and ketones to afford diindolylmethanes. In addition, PS-AlCl3 shows satisfactory selectivity in the reaction of mixtures of an aldehyde and a ketone with indole. Although AlCl3 is a water sensitive, corrosive and environmentally harmful compound, PS-AlCl3 is a stable and water-tolerant species. The mild reaction conditions, short reaction times, easy work-up, high to excellent yields, chemoselectivity, reuse of the catalyst for at least ten times without significant change in its catalytic activity, low cost, and easy preparation and handling …

Major Challenges For The Modern Chemistry In Particular And Science In General, Vuk Uskoković

Pharmacy Faculty Articles and Research

In the past few hundred years, science has exerted an enormous influence on the way the world appears to human observers. Despite phenomenal accomplishments of science, science nowadays faces numerous challenges that threaten its continued success. As scientific inventions become embedded within human societies, the challenges are further multiplied. In this critical review, some of the critical challenges for the field of modern chemistry are discussed, including: (a) interlinking theoretical knowledge and experimental approaches; (b) implementing the principles of sustainability at the roots of the chemical design; (c) defining science from a philosophical perspective that acknowledges both pragmatic and realistic …

Computational And Theoretical Aspects Of N-E.C. Graphs, Alexandru Costea

Theses and Dissertations (Comprehensive)

We consider graphs with the n-existentially closed adjacency property. For a positive integer n, a graph is n-existentially closed (or n-e.c.) if for all disjoint sets of vertices A and B with \A∪ B\ = n (one of A or B can be empty), there is a vertex 2 not in A∪B joined to each vertex of A and no vertex of B. Although the n-e.c. property is straightforward to define, it is not obvious from the definition that graphs with the property exist. In 1963, Erdos and Rényi gave …

Financial Securities Under Nonlinear Diffusion Asset Pricing Model, Andrey Vasilyev

Theses and Dissertations (Comprehensive)

In this thesis we investigate two pricing models for valuing financial derivatives. Both models are diffusion processes with a linear drift and nonlinear diffusion coefficient. The forward price process of these models is a martingale under an assumed risk-neutral measure and the transition probability densities are given in analytically closed form. Specifically, we study and calibrate two different families of models that are constructed based on a so-called diffusion canonical transformation. One family follows from the Ornstein-Uhlenbeck diffusion (the UOU family) and the other—from the Cox-Ingersoll-Ross process (the Confluent-U family).

The first part of the thesis considers single-asset and multi-asset …

Littoral Cells, Longshore Transport And Wave Climate: An Examination Of Littoral Transport Along The Western Shore Of Prince Edward County, Ontario, Jayson A. Childs

Theses and Dissertations (Comprehensive)

This study discusses the wave climate and potential littoral transport along the western shore of Prince Edward County approximately two hours east of Toronto along the northern shoreline of Lake Ontario. The limestone headlands and barrier bars of the western coast are exposed toward a southwesterly fetch of approximately 200 km that can produce large offshore wave heights of 2–5 m. The wave model STWAVE was used to transform a standard set of wave conditions developed from recent hindcast data to examine fair weather, storm and extreme conditions for five directions between south and west-northwest along the shore. The resulting …

Limit On Continuous Neutrino Emission From Neutron Stars, Itzhak Goldman, Shmuel Nussinov

Mathematics, Physics, and Computer Science Faculty Articles and Research

The timing data of the binary pulsar PSR1913+16, are used to establish an upper limit on the rate of continuous neutrino emission from neutron stars. Neutrino emission from each of the neutron stars of the binary system, increases the star binding energy and thus translates to a decrease in their masses. This in turn implies an increase with time of the binary period. Using the pulsar data we obtain an upper limit on the allowed rate of mass reduction: vertical bar M vertical bar < 1.1 x 10(-12) yr(-1) M, where M is the total mass of the binary. This constrains exotic nuclear equations of state that predict continuous neutrino emissions. The limit applies also to other channels of energy loss, e. g. axion emission. Continued timing measurements of additional binary pulsars, should yield a stronger limit in the future.

A Time-Symmetric Formulation Of Quantum Mechanics, Yakir Aharonov, Sandu Popescu, Jeff Tollaksen

Mathematics, Physics, and Computer Science Faculty Articles and Research

Quantum mechanics allows one to independently select both the initial and final states of a single system. Such pre- and postselection reveals novel effects that challenge our ideas about what time is and how it flows.

Upper Limits On A Possible Gluon Mass, Shmuel Nussinov, Robert Shrock

Mathematics, Physics, and Computer Science Faculty Articles and Research

We analyze upper limits on a possible gluon mass, mg. We first discuss various ways to modify quantum chromodynamics to include m(g) not equal 0, including a bare mass, a Higgs mechanism, and dynamical breaking of color SU(3)(c). From an examination of experimental data, we infer an upper limit m(g) < O(1) MeV. As part of our analysis, we show that a claim, hitherto unrefuted in the literature, of a much stronger upper limit on m(g), is invalid. We discuss subtleties in interpreting gluon mass limits in view of the fact that at scales below Lambda(QCD), quantum chromodynamics is strongly coupled, perturbation theory is not reliable, and the physics is not accurately described in terms of the Lagrangian degrees of freedom, including gluons. We also point out a fundamental difference in the behavior of quantum chromodynamics with a nonzero gluon mass and a weakly coupled gauge theory with a gauge boson mass.

Entropy And Information Causality In General Probabilistic Theories, Howard Barnum, Jonathan Barrett, Lisa Orloff Clark, Matthew S. Leifer, Robert Spekkens, Nicholas Stepanik, Alex Wilce, Robin Wilke

Mathematics, Physics, and Computer Science Faculty Articles and Research

We investigate the concept of entropy in probabilistic theories more general than quantum mechanics, with particular reference to the notion of information causality (IC) recently proposed by Pawlowski et al (2009 arXiv:0905.2292). We consider two entropic quantities, which we term measurement and mixing entropy. In the context of classical and quantum theory, these coincide, being given by the Shannon and von Neumann entropies, respectively; in general, however, they are very different. In particular, while measurement entropy is easily seen to be concave, mixing entropy need not be. In fact, as we show, mixing entropy is not concave whenever the state …

All-Sky Search For Gravitational-Wave Bursts In The First Joint Ligo-Geo-Virgo Run, J. Abadie, B. P. Abbott, Matthew Benacquista, Teviet Creighton, Mario C. Diaz, R. Grosso, Soumya Mohanty, S. Mukherjee, Malik Rakhmanov, Joseph D. Romano, Robert Stone

Physics and Astronomy Faculty Publications and Presentations

We present results from an all-sky search for unmodeled gravitational-wave bursts in the data collected by the LIGO, GEO 600 and Virgo detectors between November 2006 and October 2007. The search is performed by three different analysis algorithms over the frequency band 50–6000 Hz. Data are analyzed for times with at least two of the four LIGO-Virgo detectors in coincident operation, with a total live time of 266 days. No events produced by the search algorithms survive the selection cuts. We set a frequentist upper limit on the rate of gravitational-wave bursts impinging on our network of detectors. When combined …

A New Technique For Firn Grain-Size Measurement Using Sem Image Analysis, N.E. Spaulding, D.A. Meese, I. Baker, P.A. Mayewski

Dartmouth Scholarship

Firn microstructure is accurately characterized using images obtained from scanning electron microscopy (SEM). Visibly etched grain boundaries within images are used to create a skeleton outline of the microstructure. A pixel-counting utility is applied to the outline to determine grain area. Firn grain sizes calculated using the technique described here are compared to those calculated using the techniques of Gow (1969) and Gay and Weiss (1999) on samples of the same material, and are found to be substantially smaller. The differences in grain size between the techniques are attributed to sampling deficiencies (e.g. the inclusion of pore filler in the …

Remote Access Forensics For Vnc And Rdp On Windows Platform, Paresh Kerai

Theses : Honours

There has been a greater implementation of remote access technologies in recent years. Many organisations are adapting remote technologies such as Virtual Network Computing (VNC) and remote desktop (RDP) applications as customer support application. They use these applications to remotely configure computers and solve computer and network issues of the client on spot. Therefore, the system administrator or the desktop technician does not have to sit on the client computer physically to solve a computer issue. This increase in adaptation of remote applications is of interest to forensic investigators; this is because illegal activities can be performed over the connection. …

Website Accessibility Issues In Western Australian Public Libraries, Vivienne L. Conway

Theses : Honours

Website accessibility is a very real and pressing issue for public libraries internationally. Tim Berners-Lee credited with founding the Web, states "The power of the Web is in its universality. Access by everyone regardless of disability is an essential aspect." (Henry & McGee, 2010). There is wide-spread support for adherence to the Web Content Advisory Guidelines Version 1.0 and 2.0 (WCAG) throughout Federal, State and Local levels of government in Australia. The Guidelines have also been affirmed by the Australian Human Rights Commission, disability advocacy groups such as Vision Australia, and the Australian Library and Information Association. The Australian Government …

Impact Of Higher Education Workplace Relations Requirements On Nteu Membership Density, Tulsi Laxman Panchani

Theses : Honours

The National Tertiary Education Union (NTEU) is the only union working entirely in tertiary education around Australia. The union has over twenty four thousand members comprising of academic and general staff. NTEU maintains membership records at three levels, national, state and branch. The information collected includes gender, age group, employment type and work classification. In late April 2005, Higher Education Workplace Relations Requirements (HEWRRs) legislation was introduced by the Australian government. This legislation imposed restrictions on the interaction between the universities and the union and also curtailed an automatic involvement of the union in the resolution of workplace issues. The …

Effects Of Diesel And Biodiesel Blends On Engine Performance And Efficiency, Christopher Hunt, Donald Johnson, Don Edgar

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Tests were conducted during the summer of 2009 on a John Deere 3203 diesel tractor to determine differences in specific fuel consumption (sfc), power take-off (PTO) torque (Nm), and PTO power (kW), between ultralow sulfur No. 2 Diesel (D2), 20% biodiesel (B20), 50% biodiesel (B50), and100% biodiesel (B100). Four 1-hr tests were conducted with D2, while three 1-hr tests were conducted with B20, B50, and B100. The results indicated that there was no significant (p < 0.05) difference between D2 and B20 for power or torque. Fueling with B50 resulted in significantly lower power and torque than fueling with D2 or B20, but significantly higher power and torque than fueling with B100. There were significant differences between each fuel in sfc; as the biodiesel blend increased, sfc also increased. Based on these data, B20 appears to be the optimal biodiesel blend for this and similar compact utility tractors since fueling with B20 resulted in no significant loss in power or torque (compared to D2) and only a slight increase in fuel consumption.

Environmental Crisis And Religious Rhetoric In Is God Green?, Jen Schneider

Jen Schneider

In the 2006 PBS documentary Is God Green?, Bill Moyers presents the emergence of two key contemporary trends in American political and religious life. The first is the growing popularity of an environmental movement within Christian evangelicalism called 'Creation Care'. Motivated by biblical passages that suggest humans have been 'commissioned' as stewards to care for the earth, or 'God's Body', Creation Care emerged in the late 1970s, gained momentum in the 1990s, and now 'constitutes the "fastest-growing form of Christian ministry"', according to the evangelical publication Christianity Today (Frame 1996:84, see also Psaros 2006:20-32). Is God Green? highlights what …

Karst Geology And Cave Fauna Of Austria: A Concise Review, Erhard Christian, Christoph Spötl

International Journal of Speleology

The state of cave research in Austria is outlined from the geological and zoological perspective. Geologic sections include the setting of karst regions, tectonic and palaeoclimatic control on karst, modern cave environments, and karst hydrology. A chapter on the development of Austrian biospeleology in the 20th century is followed by a survey of terrestrial underground habitats, biogeographic remarks, and an annotated selection of subterranean invertebrates.

Teaching Resources In Speleology And Karst: A Valuable Educational Tool, Jo De Waele

International Journal of Speleology

There is a growing need in the speleological community of tools that make teaching of speleology and karst much easier. Despite the existence of a wide range of major academic textbooks, often the caver community has a difficult access to such material. Therefore, to fill this gap, the Italian Speleological Society, under the umbrella of the Union International de Spéléologie, has prepared a set of lectures, in a presentation format, on several topics including geology, physics, chemistry, hydrogeology, mineralogy, palaeontology, biology, microbiology, history, archaeology, artificial caves, documentation, etc. These lectures constitute the “Teaching Resources in Speleology and Karst”, available online. …

Do Karst Rivers “Deserve” Their Own Biotic Index? A Ten Years Study On Macrozoobenthos In Croatia, Biljana Rađa, Sanja Puljas

International Journal of Speleology

In this study we present the results of a ten year survey of the aquatic macroinvertebrate fauna along four karst rivers: Jadro, Žrnovnica, Grab and Ruda, all of them situated in the Middle Dalmatia region of Croatia, in an attempt to construct the Iliric Biotic Index, which will be more applicable for the water quality analysis than the most frequently applied biotic index in Croatia, the Italian Modification of Extended Biotic Index. The rivers geologically belong to the Dinaric karst, unique geological phenomena in Europe. Benthic macroinvertebrates were collected along each river at 15 sites by standard methods of sampling …

Candoluminescence Of Cave Gypsum, John R. Sweet, John W. Hess, William B. White

International Journal of Speleology

A selection of gypsum specimens from a variety of caves as well as CaSO₄ synthesized in the laboratory emit both a green and yellow candoluminescence when excited by a hydrogen diffusion flame. The green emission is attributed to dehydration of gypsum to bassanite and the yellow emission appears upon further dehydration to anhydrite. The source of the luminescence is ascribed to minor concentrations of Mn²⁺ in the gypsum.