Physical Sciences and Mathematics Commons^™

Kinetics Of The Electrical Discharge Pumped Oxygen-Iodine Laser, Matthew A. Lange

Theses and Dissertations

A systematic study of microwave discharges at 2.45 GHz has been performed through the pressure range of sustainable electric discharges in pure oxygen flows of 2 to 10 Torr. A corresponding study of 13.56 MHz has also been performed at pressures of 2, 4, and 7 Torr. Optical emissions from O2(a 1Δ), O2(b 1Σ), and O-atoms have been measured from the center of a μ-wave discharge. Discharge residence times from 0.1 to 5 ms have been reported. The O2(b 1Σ) emissions, with a spectral resolution of 0.01 nm, have been used to measure the temperature of the gas, which typically …

Characterization And Discrimination Of Large Caliber Gun Blast And Flash Signatures, Bryan J. Steward

Theses and Dissertations

Two hundred and one firings of three 152 mm howitzer munitions were observed to characterize firing signatures of a large caliber gun. Muzzle blast expansion was observed with high-speed (1600 Hz) optical imagery. The trajectory of the blast front was well approximated by a modified point-blast model described by constant rate of energy deposition. Visible and near-infrared (450 - 850 nm) spectra of secondary combustion were acquired at 0.75 nm spectral resolution and depict strong contaminant emissions including Li, Na, K, Cu, and Ca. The O2 (X-b) absorption band is evident in the blue wing of the potassium D lines …

Multi- Autonomous Vehicle Insertion-Extraction System (Mavies), Jamie C. Macbeth, Manal Habib, Armen Mkrtchyan, Missy Cummings

Computer Science: Faculty Publications

MAVIES (Multi-Autonomous Vehicle Insertion-Extraction System) is the culmination of a year-long multi-stakeholder e ort between UTRC and the Humans and Automation Lab at MIT to design a human inter- face for insertion and extraction missions with multiple UAVs and option- ally piloted rotorcraft. The design process is a successful application of the Hybrid Cognitive Task Analysis (hCTA) process that tracks dozens of tasks, decision-making processes and their associated situation aware- ness requirements to determine the proper allocation of responsibilities between the human operator and the automated mission planner.

This paper discusses the various accomplishments through several phases of a disciplined …

Interstaple Dithiol Cross-Linking In Au 25(Sr) 18 Nanomolecules: A Combined Mass Spectrometric And Computational Study, Vijay Reddy Jupally, Rajesh Kota, Eric Van Dornshuld, Daniell L. Mattern, Gregory S. Tschumper, De En Jiang, Amala Dass

Chemistry Faculty Research & Creative Works

A systematic study of cross-linking chemistry of the Au 25(SR) 18 nanomolecule by dithiols of varying chain length, HS-(CH₂)_n-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated Au₂₅ has six [RSAuSRAuSR] staple motifs on its surface, and MALDI mass spectrometry data of the ligand exchanged clusters show that propane (C3) and butane (C4) dithiols have ideal chain lengths for interstaple cross-linking and that up to six C3 or C4 dithiols can be facilely exchanged onto the cluster surface. Propanedithiol predominately exchanges with two monothiols at a time, making cross-linking bridges, …

The Massachusetts Environmental Industry: Facing The Challenges Of Maturity, Betty J. Diener, David Terkla, Erick Cooke

David G. Terkla

For most of the past 20 years, the environmental industry has been a very significant one, both in Massachusetts and across the country. Some have placed it alongside the electronics, computer hardware, software, biotechnology, fiber optics, and composite materials industries as part of the high-technology sector that has diversified and strengthened the state’s economy. Nationally, environmental industry employment exceeded that of several major manufacturing industries, including chemicals, paper, and aerospace. In the late 1990s, however, the momentum of the environmental movement began to wane. A decline in both employment and sales suggests that many of the most pressing environmental concerns …

Starting Radial Subdiffusion From A Central Point Through A Diverging Medium (A Sphere): Heat-Balance Integral Method, Jordan Hristov

Jordan Hristov

The work presents an integral solution of the time-fractional subdiffusion equation as alternative approach to those employing hypergeometric functions. The integral solution suggests a preliminary defined profile with unknown coefficients and the concept of penetration (boundary layer) well known from the heat diffusion and hydrodynamics. The profile satisfies the boundary conditions imposed at the boundary of the boundary layer that allows its coefficients to be expressed through the boundary layer depth as unique parameter describing the profile. The technique is demonstrated by a solution of a time fractional radial equation concerning anomalous diffusion from a central point source in a …

Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mikhail Khenner

Dewetting of pulsed-laser irradiated, thin (< 20 nm), optically reflective metallic bilayers on an optically transparent substrate with a reflective support layer is studied within the lubrication equations model. A steady-state bilayer film thickness (h) dependent temperature profile is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Large thermocapillary forces are observed along the plane of the liquid-liquid and liquid-gas interfaces due to this h-dependent temperature, which, in turn, is strongly influenced by the h-dependent laser light reflection and absorption. Consequently the dewetting is a result of the competition between thermocapillary and intermolecular forces. A linear analysis of the dewetting length scales established that the non-isothermal calculations better predict the experimental results as compared to the isothermal case within the bounding Hamaker coefficients. Subsequently, a computational non-linear dynamics study of the dewetting pathway was performed for Ag/Co and Co/Ag bilayer systems to predict the morphology evolution. We found that the systems evolve towards formation of different morphologies, including core-shell, embedded, or stacked nanostructure morphologies.

On The Radio And Optical Luminosity Evolution Of Quasars, Jack Singal, V. Petrosian, A. Lawrence, L. Stawarz

Physics Faculty Publications

We calculate simultaneously the radio and optical luminosity evolutions of quasars, and the distribution in radio loudness R defined as the ratio of radio and optical luminosities, using a flux-limited data set containing 636 quasars with radio and optical fluxes from White et al. We first note that when dealing with multi-variate data it is imperative to first determine the true correlations among the variables, not those introduced by the observational selection effects, before obtaining the individual distributions of the variables. We use the methods developed by Efron and Petrosian which are designed to obtain unbiased correlations, distributions, and evolution …

Optical Polarization And Spectral Variability In The M87 Jet, Eric S. Perlman, Mihai Cara, Matthew Bourque, Raymond C. Simons

Aerospace, Physics, and Space Science Faculty Publications

During the last decade, M87's jet has been the site of an extraordinary variability event, with one knot (HST-1) increasing by over a factor 100 in brightness. Variability has also been seen on timescales of months in the nuclear flux. Here we discuss the optical-UV polarization and spectral variability of these components, which show vastly different behavior. HST-1 shows a highly significant correlation between flux and polarization, with P increasing from 20% at minimum to >40% at maximum, while the orientation of its electric vector stayed constant. HST-1's optical-UV spectrum is very hard (αUV-O 0.5, F ν ∞ ν-α), and …

A Search For The Transit Of Hd 168443b: Improved Orbital Parameters And Photometry, G. Pilyavsky, S. Mahadevan, S. R. Kane, A. W. Howard, D. R. Ciardi, C. De Pree, D. Dragomir, D. A. Fischer, G. W. Henry, Eric L.N. Jensen, G. Laughlin, H. Marlowe, M. Rabus, K. Von Braun, J. T. Wright, X. X. Wang

Physics & Astronomy Faculty Works

The discovery of transiting planets around bright stars holds the potential to greatly enhance our understanding of planetary atmospheres. In this work we present the search for transits of HD 168443b, a massive planet orbiting the bright star HD 168443 (V = 6.92) with a period of 58.11 days. The high eccentricity of the planetary orbit (e = 0.53) significantly enhances the a priori transit probability beyond that expected for a circular orbit, making HD168443 a candidate for our ongoing Transit Ephemeris Refinement and Monitoring Survey. Using additional radial velocities from Keck High Resolution Echelle Spectrometer, we refined the orbital …

Ubvri Photometric Analysis Of The Solar-Type Eclipsing Binary Tyc 3034-299-1, Ronald G. Samec, Adam Jaso, Jesse White, Danny R. Faulkner, Nicholas Blum, Walter Van Hamme

Department of Physics

TYC 3034-0299-1 (CV_n) is a magnetically active, contact binary, ROTSE variable. UBVR_cI_c light curves are presented along with a period study and a simultaneous UBVRI light curve solution. Our light curves show eclipse amplitudes of 0.72 and 0.62 mags (V) in the primary and secondary eclipses. Modeled results include a dark spot region, found at longitude 51°, a 24% Roche lobe fill-out, and a mass ratio of 0.48. A total eclipse is found to occur in the secondary eclipse making TYC 3034-0299-1 a W-type (less massive star is hotter) W UMa variable.

Socially Responsible Investment In A Changing World, Desheng Wu

Electronic Thesis and Dissertation Repository

Socially responsible investment funds make up a growing segment of the investment world. This work considers the impact of including SRI in an investor portfolio both normally and during crisis times. Regimes are identified using Markov switching models. This study is based on return data of four indices, namely, the MSCI World Index, S&P 500, Eurostoxx 50, and the socially responsible index - Advanced Sustainable Performance Index (ASPI). The approaches used are portfolio optimization, GARCH and Markov switching models. Our work shows that a socially responsible index is a good asset to keep in a portfolio. Our simulation results suggest …

Hyperspectral Data Processing In A High Performance Computing Environment: A Parallel Best Band Selection Algorithm, Stefan Robila, Gerald Busardo

Department of Computer Science Faculty Scholarship and Creative Works

Hyperspectral data are characterized by a richness of information unique among various visual representations of a scene by representing the information in a collection of grayscale images with each image corresponding to a narrow interval in the electromagnetic spectrum. Such detail allows for precise identification of materials in the scene and promises to support advances in imaging beyond the visible range. However, hyperspectral data are considerably large and cumbersome to process and efficient computing solutions based on high performance computing are needed. In this paper we first provide an overview of hyperspectral data and the current state of the art …

Ordered Phases In Ruthenium Binary Alloys From High-Throughput First-Principles Calculations, Gus L. W. Hart, Lance J. Nelson, Michal Jahnátek, Ohad Levy, Roman V. Chepulskii, J. Xue, Stephano Curtarolo

Faculty Publications

Despite the increasing importance of ruthenium in numerous technological applications, e.g., catalysis and electronic devices, experimental and computational data on its binary alloys are sparse. In particular, data are scant on those binary systems believed to be phase-separating. We performed a comprehensive study of ruthenium binary systems with the 28 transition metals, using high-throughput first-principles calculations. These computations predict novel unsuspected compounds in 7 of the 16 binary systems previously believed to be phase-separating and in two of the three systems reported with only a high-temperature σ phase. They also predict a few unreported compounds in five additional systems and …

Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mathematics Faculty Publications

Dewetting of pulsed-laser irradiated, thin (< 20 nm), optically reflective metallic bilayers on an optically transparent substrate with a reflective support layer is studied within the lubrication equations model. A steady-state bilayer film thickness (h) dependent temperature profile is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Large thermocapillary forces are observed along the plane of the liquid-liquid and liquid-gas interfaces due to this h-dependent temperature, which, in turn, is strongly influenced by the h-dependent laser light reflection and absorption. Consequently the dewetting is a result of the competition between thermocapillary and intermolecular forces. A linear analysis of the dewetting length scales established that the non-isothermal calculations better predict the experimental results as compared to the isothermal case within the bounding Hamaker coefficients. Subsequently, a computational non-linear dynamics study of the dewetting pathway was performed for Ag/Co and Co/Ag bilayer systems to predict the morphology evolution. We found that the systems evolve towards formation of different morphologies, including core-shell, embedded, or stacked nanostructure morphologies.

Determining Magnetic Nanoparticle Size Distributions From Thermomagnetic Measurements, R. Dipietro, H. Johnson, S. Bennett, T. Nummy, L. Lewis, D. Heiman

Laura H. Lewis

Thermomagnetic measurements are used to obtain the size distribution and anisotropy of magnetic nanoparticles. An analytical transformation method is described which utilizes temperature-dependent zero-field cooling (ZFC) magnetization data to provide a quantitative measurement of the average diameter and relative abundance of superparamagnetic nanoparticles. Applying this method to self-assembled MnAs nanoparticles in MnAs-GaAs composite films reveals a log-normal size distribution and reduced anisotropy for nanoparticles compared to bulk materials. This analytical technique holds promise for rapid assessment of the size distribution of an ensemble of superparamagnetic nanoparticles.

Determining Magnetic Nanoparticle Size Distributions From Thermomagnetic Measurements., R. S. Dipietro, H. G. Johnson, S. P. Bennett, T. J. Nummy, L. H. Lewis, D. Heiman

Laura H. Lewis

Thermomagnetic measurements are used to obtain the size distribution and anisotropy of magnetic nanoparticles. An analytical transformation method is described which utilizes temperature-dependent zero-field cooling magnetization data to provide a quantitative measurement of the average diameter and relative abundance of superparamagnetic nanoparticles. Applying this method to self-assembled MnAs nanoparticles in MnAs–GaAs composite films reveals a log-normal size distribution and reduced anisotropy for nanoparticles compared to bulk materials. This analytical technique holds promise for rapid assessment of the size distribution of an ensemble of superparamagnetic nanoparticles.

Magnetic Signature Of Symmetry Reduction In Epitaxial La₀.₆₇Sr₀.₃₃Mno₃ Films, Radhika Barua, L. Lewis, D. Heiman

Laura H. Lewis

The magnetic properties of epitaxially grown La0.67Sr0.33MnO3 perovskite thin films were investigated to elucidate an unexpected broken symmetry between orthogonal [100] and [010] inplane directions, resulting from the magnetostructural coupling between the film and the cubic SrTiO3 (001) substrate. The films were synthesized by molecular beam epitaxy with either complete or zero A-site cation disorder. Magnetization measured in [100] and [010] directions shows differences that signal a reduction of the in-plane cubic symmetry only for T < 290 K. The magnetization asymmetry is more robust in the film with complete A-site disorder. These results are attributed to a dominant Mn3+ character …

Universal Properties Of Linear Magnetoresistance In Strongly Disordered Mnas-Gaas Composite Semiconductors, H. G. Johnson, S. P. Bennett, R. Barua, L. H. Lewis, D. Heiman

Laura H. Lewis

Linear magnetoresistance (LMR) occurs in semiconductors as a consequence of strong electrical disorder and is characterized by nonsaturating magnetoresistance that is proportional to the applied magnetic field. By investigating a disordered MnAs-GaAs composite material, it is found that the magnitude of the LMR is numerically equal to the carrier mobility over a wide range and is independent of carrier density. This behavior is complementary to the Hall effect that is independent of the mobility and dependent on the carrier density. Moreover, the LMR appears to be insensitive to the details of the disorder and points to a universal explanation of …

Determining Magnetic Nanoparticle Size Distributions From Thermomagnetic Measurements., R. S. Dipietro, H. G. Johnson, S. P. Bennett, T. J. Nummy, L. H. Lewis, D. Heiman

Donald Heiman

Thermomagnetic measurements are used to obtain the size distribution and anisotropy of magnetic nanoparticles. An analytical transformation method is described which utilizes temperature-dependent zero-field cooling magnetization data to provide a quantitative measurement of the average diameter and relative abundance of superparamagnetic nanoparticles. Applying this method to self-assembled MnAs nanoparticles in MnAs–GaAs composite films reveals a log-normal size distribution and reduced anisotropy for nanoparticles compared to bulk materials. This analytical technique holds promise for rapid assessment of the size distribution of an ensemble of superparamagnetic nanoparticles.

Magnetotransport Properties Of Mn-Si-C Based Nanostructures, Sungmu Kang, Greg A. Brewer, Battogtokh Jugdersuren, Robert Dipietro, Don Heiman, Andrew C. Buechele, David A. Mckeown, Ian L. Pegg, John Philip

Donald Heiman

Boron-incorporated Mn5SiC nanowires were grown using chemical vapor deposition method. The nanowire cluster exhibits magnetic hysteresis loops at room temperature and the strength of the magnetic behavior depends on the concentration of the boron incorporation. Mn5SiC nanowire-based devices exhibit spin dependent transport properties which shows significant changes with boron content. Large magnetoresistance is observed in lightly boron-incorporated nanowire devices and it decreases with increase in boron content.

Magnetic Signature Of Symmetry Reduction In Epitaxial La₀.₆₇Sr₀.₃₃Mno₃ Films, Radhika Barua, L. H. Lewis, D. Heiman

Donald Heiman

The magnetic properties of epitaxially grown La0.67Sr0.33MnO3 perovskite thin films were investigated to elucidate an unexpected broken symmetry between orthogonal [100] and [010] inplane directions, resulting from the magnetostructural coupling between the film and the cubic SrTiO3 (001) substrate. The films were synthesized by molecular beam epitaxy with either complete or zero A-site cation disorder. Magnetization measured in [100] and [010] directions shows differences that signal a reduction of the in-plane cubic symmetry only for T < 290 K. The magnetization asymmetry is more robust in the film with complete A-site disorder. These results are attributed to a dominant Mn3+ character …

Universal Properties Of Linear Magnetoresistance In Strongly Disordered Mnas-Gaas Composite Semiconductors, H. Johnson, S. Bennett, R. Barua, L. Lewis, D. Heiman

Donald Heiman

Linear magnetoresistance (LMR) occurs in semiconductors as a consequence of strong electrical disorder and is characterized by nonsaturating magnetoresistance that is proportional to the applied magnetic field. By investigating a disordered MnAs-GaAs composite material, it is found that the magnitude of the LMR is numerically equal to the carrier mobility over a wide range and is independent of carrier density. This behavior is complementary to the Hall effect that is independent of the mobility and dependent on the carrier density. Moreover, the LMR appears to be insensitive to the details of the disorder and points to a universal explanation of …

Large Low Field Magnetoresistance In La₀.₆₇Sr₀.₃₃Mno₃ Nanowire Devices, Battogtokh Jugdersuren, Sungmu Kang, Robert S. Dipietro, Don Heiman, David Mckeown, Ian L. Pegg, John Philip

Donald Heiman

Large low field magnetoresistance (LFMR) of about 28% is observed in La0.67Sr0.33MnO3 nanowires with 80 nm in diameter at T = 300 K. A gradual decrease in the LFMR has been found with increase in wire diameter. The LFMR drops to zero for wires above 280 nm in diameter. The nanowires are grown by means of electrospinning process and exhibit distorted orthorhombic crystal structure. The large LFMR is considered as a grain boundary effect as observed in several perovskite systems. The large LFMR observed in these manganites with reduced dimensions may be useful for room temperature device applications.

Analytic Derivative Couplings Between Configuration-Interaction-Singles States With Built-In Electron-Translation Factors For Translational Invariance, Shervin Fatehi, Ethan Alguire, Yihan Shao, Joseph Subotnik

Chemistry Faculty Publications and Presentations

We present a method for analytically calculating the derivative couplings between a pair of configuration-interaction-singles (CIS) excited states obtained in an atom-centered basis. Our theory is exact and has been derived using two completely independent approaches: one inspired by the Hellmann-Feynman theorem and the other following from direct differentiation. (The former is new, while the latter is in the spirit of existing approaches in the literature.) Our expression for the derivative couplings incorporates all Pulay effects associated with the use of an atom-centered basis, and the computational cost is minimal, roughly comparable to that of a single CIS energy gradient. …

Design And Synthesis Of Cationic Steroid Antimicrobial Compounds, Synthesis Of Glycolipids Recognized By Natural Killer T Cells And Development Of Tlr-1, Tlr-6 Heterodimer Binders And Studies Of Their Immunology Activities, Yanshu Feng

Theses and Dissertations

Cationic steroid antimicrobial agents (CSAs) are a family of bile acid derivatives. These compounds are amphiphilic and mimic endogenous antimicrobial peptides. The antimicrobial activities of CSA-13 have been investigated and due to portent bactericidal activities and low toxicity, a large amount of CSA-13 is demanded for clinic trails and other antimicrobial applications. During our studies, we optimized the synthetic route of CSA-13, so that it can be prepared at the kilogram, even in tons scale. We investigated three routes and one of them is suitable for industry, because only recrystallization is needed in the synthesis. Natural killer T cells (NKT …

Large Coercivity In Nanostructured Rare-Earth-Free Mnxga Films, Don Heiman, Tom Nummy, Steve Bennett, Tom Cardinal

Donald Heiman

The magnetic hysteresis of MnxGa films exhibit remarkably large coercive fields as high as HC=2.5 T when fabricated with nanoscale particles of a suitable size and orientation. This coercivity is an order of magnitude larger than in well-ordered epitaxial film counterparts and bulk materials. The enhanced coercivity is attributed to the combination of large magnetocrystalline anisotropy and ~50-100 nm size nanoparticles. The large coercivity is also replicated in the electrical properties through the anomalous Hall effect. The magnitude of the coercivity approaches that found in rare-earth magnets, making them attractive for rare-earth-free magnet applications.

Testing The Limits Of Hyperspectral Airborne Remote Sensing By Mapping Eelgrass In Elkhorn Slough, Kelley J. Bostrom

Master's Theses

Seagrass ecosystems are a valuable resource, but vulnerable to changing conditions in the coastal ocean. Quantification of seagrass density and distribution from aerial imagery can be applied as a tool in resource management and ecosystem health and stability monitoring. This study investigates analytical methods for mapping eelgrass beds in an optically complex shallow, turbid estuary. Hyperspectral imagery (HSI) of Elkhorn Slough, CA was collected by the Spectroscopic Aerial Mapper with Onboard Navigation (SAMSON) instrument. In-situ data of water column and benthic optical properties and Hydrolight Radiative Transfer model were used to create a spectral library describing the reflectance of Elkhorn …

Satellite Evidence For A Large Source Of Formic Acid From Boreal And Tropical Forests, T Stavrakou, J F. Muller, J Peeters, A Razavi, L Clarisse, C Clerbaux, P Coheur, D Hurtmans, M De Maziere, C Vigouroux, Nicholas Deutscher, David Griffith, Nicholas Jones, Clare Paton-Walsh

Faculty of Science - Papers (Archive)

Formic acid contributes significantly to acid rain in remote environments1, 2. Direct sources of formic acid include human activities, biomass burning and plant leaves. Aside from these direct sources, sunlight-induced oxidation of non-methane hydrocarbons (largely of biogenic origin) is probably the largest source3, 4. However, model simulations substantially underpredict atmospheric formic acid levels5, 6, 7, indicating that not all sources have been included in the models. Here, we use satellite measurements of formic acid concentrations to constrain model simulations of the global formic acid budget. According to our simulations, 100–120 Tg of formic acid is produced annually, which is two …

Collisional Reactivation Of Rift Margin Fracture Zones, Taiwan And The Taconic Allochthon, David C. Mirakian

Master's Theses

Chapter I. Transverse Topographic Development due to the Reactivation of a Partially-Subducted Fracture Zone: The Southwest Hsüehshan Range, Central Taiwan

Abstract — The southwest flank of the Hsüehshan Range is defined by a topographic break which cuts across regionally mapped structures in central Taiwan. The mountain front trends ~345°, slightly oblique to the Sanyi-Puli seismic zone which has been previously interpreted as a reactivated continental margin fracture zone. Structural data collected along the length of the topographic break reveal two populations of cross-cutting faults with distinct fault-zone materials and a series of southwest-plunging folds. Paleostress axes were reconstructed using the …