Physical Sciences and Mathematics Commons^™

Synthesis And Characterization Of Catalysts For The Selective Transformation Of Biomass-Derived Materials, Isaac Tyrone Ghampson

Electronic Theses and Dissertations

The experimental work in this thesis focuses on generating catalysts for two intermediate processes related to the thermal conversion of lignocellulosic biomass: the synthesis and characterization of mesoporous silica supported cobalt catalysts for the Fischer-Tropsch reaction, and an exploration of the reactivity of bulk and supported molybdenum-based nitride catalysts for the hydrodeoxygenation (HDO) of guaiacol, a lignin model compound. The first section of the work details the synthesis of a series of silicasupported cobalt Fischer-Tropsch catalysts with pore diameters ranging from 2-23 nm. Detailed X-ray diffraction measurements were used to determine the composition and particle diameters of the metal fraction, …

A Review On Convolutions Of Gamma Random Variables, Baha-Eldin Khaledi, Subhash C. Kochar

Mathematics and Statistics Faculty Publications and Presentations

Due to its wide range of applications, the topic of the distribution theory of convolutions of Gamma random variables has attracted the attention of many researchers. In this paper we review some of the latest developments on this problem.

Achieving Laser Wavelength Stability For Use In Neutral Atom Quantum Computing, Jennifer H. Rushing

Physics

Quantum computing may still be decades away from realization but the pieces necessary for the construction of the first quantum chip are beginning to come together. One piece still eluding researchers is the ability to address individual atoms within a scalable quantum chip structure. The resolution to this issue may be found in any one of several promising implementations, including the use of neutral atoms trapped in 2D optical lattices. One method of constructing such lattices, which has been shown to be computationally viable, employs the diffraction pattern just behind a circular aperture. Laser wavelength stability plays a crucial role …

Astronomical Spectroscopy At The Cal Poly Observatory, Christopher James Almich

Physics

Embarking on the first ever astronomical spectroscopy project at the Cal Poly Observatory, I have tested the capabilities of our equipment. Our spectrograph, in conjunction with a telescope and CCD camera, is capable of making fairly precise measurements of absorption and emission lines with sub-nanometer precision. In my research I obtained a spectrum of Jupiter and was able to confidently identify a number of Fraunhofer solar absorption lines.

Groundwater Chemistry Of The Weaber Plain: Preliminary Results, Adam Lillicrap, Paul Raper, Richard J. George Dr, D L. Bennett

Resource management technical reports

In 2008, the Ord Irrigation Expansion Project was approved by the Western Australian Government to develop irrigated agriculture on the Weaber Plain. Construction of the M2 supply channel connecting the ORIA and the Weaber Plain, and the final period of irrigation design, environmental management and related approval processes, commenced later in 2009. This process followed a protracted period of public and private industry planning and environmental assessment (Kinhill 2000). This report summarises an analysis of groundwater salinity trends on the Ivanhoe and Weaber plains and the preliminary results of an intensive water-quality sampling program carried out in 2010 as part …

Surface Water Characteristics Of The Weaber Plain And Lower Keep River Catchments: Data Review And Preliminary Results, D L. Bennett, Richard J. George Dr

Resource management technical reports

In 2008, the Ord Irrigation Expansion Project was approved by the Western Australian Government to develop irrigated agriculture on the Weaber Plain.

An important concern is the effect the Weaber Plain agricultural development may have on the water quality of the downstream Border Creek and Keep River

This report assembles and reviews all available physico-chemical water quality data for the lower Keep River and Border Creek systems and presents data from the initial year of a targeted baseline monitoring program (June 2010 – June 2013).

New Theories And Methods For Technology Adoption Research, Robert J. Kauffman, Angsana A. Techatassanasoontorn

Research Collection School Of Computing and Information Systems

This special issue includes six articles on different aspects of technology adoption that represent the development and application of different theoretical and methodological approaches to the business problems that they treat. In terms of theory, three of the articles use behavioral and organizational theories, including adaptive structuration theory, management fashion theory, the unified theory of technology acceptance, the technology acceptance model, and diffusion of innovation theory. The other two are based on economic theory, including network effects theory, and economic growth theory. The methods used are also dramatically different in each of the studies. Three studies use field research and …

Assessing The Impact Of Recommendation Agents On On-Line Consumer Unplanned Purchase Behavior, R. Eric Hostler, Victoria Y. Yoon, Zhiling Guo, Tor Guimaraes, Guisseppi Forgionne

Research Collection School Of Computing and Information Systems

Recommendation agents (RAs) have been used by many Internet businesses such as Amazon and Netflix. However, few authors have studied how consumer behavior is affected by those that make suggestions to online consumers based on their recent shopping behavior. Fewer still have examined the role that RAs play in influencing impulse purchasing decisions online. Our study developed a theoretical model to illustrate the impact of RAs on online consumer behavior. The model was tested through an online shopping simulation which used a collaborative filtering based product RA. Particular attention was paid to the effects of an RA on consumer behavior; …

Data-Intensive Computing For Bioinformatics Using Virtualization Technologies And Hpc Infrastructures, Pengfei Xuan

All Theses

The bioinformatics applications often involve many computational components and massive data sets, which are very difficult to be deployed on a single computing machine. In this thesis, we designed a data-intensive computing platform for bioinformatics applications using virtualization technologies and high performance computing (HPC) infrastructures with the concept of multi-tier architecture, which can seamlessly integrate the web user interface (presentation tier), scientific workflow (logic tier) and computing infrastructure (data/computing tier). We demonstrated our platform on two bioinformatics projects. First, we redesigned and deployed the cotton marker database (CMD) (http://www.cottonmarker.org), a centralized web portal in the cotton research community, using the …

Randomization Tests For Quantifying Species Importance To Ecosystem Function, Nicholas J. Gotelli, Werner Ulrich, Fernando T. Maestre

College of Arts and Sciences Faculty Publications

1. Quantifying the contribution of different species to ecosystem function is an important challenge. We introduce simple randomization tests (and software) for quantifying the average effect of species on ecosystem variables measured in multiple plots with and without the presence of a particular species. These randomization tests formalize the analysis of uncontrolled 'natural experiments' and quantify species effects in standardized deviation units. 2.We tested the method with data on ecosystem function in biological soil crust assemblages of lichens in semi-arid gypsum outcrops in central Spain. In sixty-three 50cm×50cm sample plots, we measured the presence and percentage cover of 17 species …

An Embedded Atom Method Investigation Into The Lattice Dynamics Of Metallic Surfaces, Richard B. Wilson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The explosion in electronic devices over the last half century is a result of the successful development and application of theories that explain the physical properties of solids. For example, the theory of lattice vibrations developed in the first half of the 20^th century has had a huge impact on our ability to understand and design devices. The idea that atoms vibrate together in grouped vibrational modes, called phonons, has enabled scientists to quantify the impact that atomic motion has on mechanical, thermal, electrical, and optical properties. This has aided the creation of all sorts of useful technology ranging …

Accelerating Production Of Slow-Growing Intermountain West Native Plants By Modifying Their Microclimate, Sam A. Miller

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Water shortages are a recurring problem in the western US. As much as 70% of yearly municipal water consumption may be used to irrigate urban landscapes. Significant water savings can be realized by installing low water landscapes, where turfgrass is replaced by low water trees, shrubs, grasses, and perennials. Intermountain West (IMW) native trees and shrubs are excellent candidates for low water landscaping. However, due to their slow initial growth, many native trees and shrubs are simply unavailable to consumers, as they are not cost effective for nursery growers to produce. In an effort to accelerate the yearly growth rates …

The Interrelationship Between The Bio- And Sequence Stratigraphy Of The Middle Cambrian Spence Shale Of Northern Utah And Southern Idaho, Eva Lyon

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This project was undertaken with the objective of discerning the relationship between sea level change and changes in the fauna of the Spence Shale. A combination of field and lab work was employed to undertake this research. The Spence Shale is rich in fossils from the earliest period of visible life on this planet. It provides a unique window onto the evolution of life and changes in the Earth at this time. It is important to study this relationship between sea level and life changes as these conditions are constantly changing, particularly in this day and age. A better understanding …

Surfactant Induced Reservoir Wettability Alteration: Recent Theoretical And Experimental Advances In Enhanced Oil Recovery, Yefei Wang, Huaimin Xu, Weizhao Yu, Baojun Bai, Xinwang Song, Jichao Zhang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Reservoir wettability plays an important role in various oil recovery processes. The origin and evolution of reservoir wettability were critically reviewed to better understand the complexity of wettability due to interactions in crude oil-brine-rock system, with introduction of different wetting states and their influence on fluid distribution in pore spaces. The effect of wettability on oil recovery of waterflooding was then summarized from past and recent research to emphasize the importance of wettability in oil displacement by brine. The mechanism of wettability alteration by different surfactants in both carbonate and sandstone reservoirs was analyzed, concerning their distinct surface chemistry, and …

Visualizing The Spatial Localization Of Active Matrix Metalloproteinases (Mmps) Using Maldi Imaging Ms, Sasirekha Muruganantham

Graduate Theses and Dissertations

Biomaterial implantation induces the foreign body response (FBR). Development of longer-term implants relies on the thorough understanding of the FBR. The progression of the FBR is regulated by a number of biomolecules including cytokines, chemokines, and matrix metalloproteinases (MMPs). The nature of the FBR requires the spatial and temporal regulation of these mediators. MMPs are an extremely large and diverse group of enzymes that play key roles in regulating the FBR. Precise spatiotemporal regulation of MMPs defines their proteolytic activities. The aim of this project is to develop a new bioanalytical method to visualize the localization of active MMPs at …

The Design, Synthesis And Application Of A Novel Class Of N-Heterocyclic Carbene Catalysts, Abigail Lynn Hubbard

Graduate Theses and Dissertations

A copper carbenoid representative of a novel class of N-heterocyclic carbene (NHC) catalysts has been synthesized. This compound was characterized by X-ray crystallography and was found to confirm the rationale of our synthetic design: The C2-symmetric structure places four stereocenters in close proximity (<5Å) to the reactive site of the carbene via a trans-annular gearing effect. The copper carbenoid was found to catalyze the hydrosilylation of prochiral ketones with superb selectivity in high yield.

Perception Of Aquifer Depletion And The Effects Of Land Use Change Across The Madaba Plain, Jordan, Mohammad Salem

Graduate Theses and Dissertations

In Jordan, demand for water for agricultural purposes has put a high strain on aquifer resources. Water mining, erosion, and desertification have all increased as global temperatures rise. This along with fragmentation of the landscape have altered the environment in a profound way. The Madaba Plain was chosen for this study due to the agricultural activities that take place there, as well as the proximity to a number of population centers. The purpose of the study is to examine how fragmentation of irrigated landscape has affected the aquifers underneath, while taking into account perceptions of risk of the local population. …

High Performance Geospatial Analysis On Emerging Parallel Architectures, Seth Warn

Graduate Theses and Dissertations

Geographic information systems (GIS) are performing increasingly sophisticated analyses on growing data sets. These analyses demand high performance. At the same time, modern computing platforms increasingly derive their performance from several forms of parallelism. This dissertation explores the available parallelism in several GIS-applied algorithms: viewshed calculation, image feature transform, and feature analysis. It presents implementations of these algorithms that exploit parallel processing to reduce execution time, and analyzes the effectiveness of the implementations in their use of parallel processing.

Analyzing Spring Freeze Impacts On Deciduous Forest Productivity Using Modis Satellite Imagery, Karl Lintvedt

Graduate Theses and Dissertations

The impacts of an April 2007 spring freeze event on the productivity of deciduous broadleaf forest were analyzed using geographic information system (GIS) tools. Forest productivity was modeled using the Enhanced Vegetation Index (EVI), as recorded by the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite sensor. Measures of spatial autocorrelation were used to quantify the degree of spatial congruence between a map depicting the severity of the freeze event, and maps modeling forest productivity throughout the year. The results show a geographic correlation between the unseasonably low minimum temperatures sustained during the freeze and the unusually low forest productivity that followed. …

Studies Toward The Development Of A Microelectrode Array For Detection Of Dopamine Through Redox Cycling, Anupama Aggarwal

Graduate Theses and Dissertations

Redox cycling is an electrochemical technique that cycles the reversible redox species between its oxidative states repeatedly on generator and collector electrodes. Two or more individually-addressable microelectrodes located close to each other allow redox cycling to be possible. Electrochemical behavior of a biologically important molecule, dopamine is examined under redox cycling conditions. To our knowledge, this is the first report on detection of physiological concentration of dopamine in presence of up to 100 times excess ascorbate with the use of redox cycling, without the involvement of polymer coating such as Nafion®.

Microfabrication was used to produce different geometries (parallel bands …

Dynamics And Catalytic Resolution Of Selected Chiral Organolithiums, Timothy Kum Beng

Graduate Theses and Dissertations

One of the most important developments of the last decade has been the emergence of new methods to dynamically resolve racemic organolithiums using stoichiometric amounts of the chiral ligand. When this concept is implemented successfully, it obviates the need for covalently attached chiral auxiliary based methods, asymmetric deprotonation, and asymmetric synthesis of a precursor stannane as ways to access enantioenriched organolithium compounds for use in asymmetric synthesis. Since certain electrophiles consume the chiral ligand, it is desirable to render this process catalytic in the chiral ligand.

As part of a larger study on the amenability of chiral organolithiums to a …

Subcritical Water Hydrolysis Of Whey Proteins, Ashley Dawn Espinoza

Graduate Theses and Dissertations

Hydrolyzing food by-products is a unique approach to potentially increase by-product value and reduce waste. An abundant by-product of cheese production, whey, contains all essential amino acids and some distinctive peptides with functional and nutraceutical properties. Typically, proteins from whey are tailored for specific uses by chemical or enzymatic hydrolysis; however, subcritical water hydrolysis is a novel alternative used successfully to hydrolyze various substrates. Nevertheless, minimal research exists on: (1) the hydrolysis of whey protein; (2) the incorporation of additives; (3) the hydrolysis of whole whey; and (4) the production of volatiles when using subcritical water hydrolysis.

Therefore, whey protein …

Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins

Graduate Theses and Dissertations

Disinfection by-products (DBPs) form as an unintended result of drinking water disinfection, from chemical reactions between disinfectants (e.g., free chlorine) and naturally occurring dissolved organic matter (DOM). At present, 11 DBPs are regulated in treated drinking waters due to potential adverse health effects, including four trihalomethanes (THMs). Despite nearly 40 years of DBP research, compliance with DBP regulations remains a challenge for many drinking water treatment plants (DWTPs), including the four DWTPs located on the Beaver Lake Reservoir in Northwest Arkansas. Due to the high net negative surface charge on DOM, anion exchange is one potentially viable method for removing …

Water Quality Trends For Section 319 Priority Watersheds In Northwest Arkansas, 1997-2010, Bryan William Bailey

Graduate Theses and Dissertations

Northwest Arkansas contains two Section 319 Priority Watersheds that the Arkansas Natural Resources Commission (ANRC) has identified as being impacted by point and nonpoint sources of pollution (i.e., phosphorus, nitrogen, and sediment), and the Arkansas Water Resources Center (AWRC) has monitored the water quality at several sites within these watersheds. Water-quality data has been collected over the last decade within the Illinois River Watershed (HUC #11110103) and the Upper White River Basin (Beaver Reservoir HUC# 11010001), each watershed containing three sampling sites. The Illinois River Watershed sites are located on the Illinois River, Osage Creek, and Ballard Creek, and the …

Nitrogen Retention And Denitrification In Reservoirs, Erin Grantz

Graduate Theses and Dissertations

Studies coupling direct measurements of micro-scale nitrogen (N) cycle processes with ecosystem-scale flux estimates are needed to determine N retention hotspots within river networks, where up to 50% of terrestrial loading to aquatic systems is retained. This study examined the role of denitrification, a microbially-mediated reactive N removal pathway, in ecosystem-scale N retention in 3 small (< 1 km2), shallow flood-control reservoirs. Annual reservoir N retention was estimated through mass balance modeling of system inputs and outputs. Annual denitrification rates were estimated by combining multiple measurements of seasonal, habitat-specific dinitrogen gas (N2) fluxes. Annual reservoir N retention ranged from 14 - 19 g m-2 in the reservoirs, while reactive N removal through denitrification was 13 - 25 g m-2. Denitrification efficiency, or the portion of the retained N load that was denitrified, was high relative to other lentic systems and was > 100% at 2 sites. Previous lentic denitrification studies may have underestimated denitrification efficiency by not considering water column denitrification, which was 50% of total denitrification at one study reservoir. However, not all potential inputs, most importantly biological N2 fixation, were included in this …

Geospatial Tools And Techniques For Watershed Management Using Swat 2009, Naresh Pai

Graduate Theses and Dissertations

In this study, geospatial tools and techniques were developed to support specific aspects of watershed pollution management, such as quantifying land-use change (LUC) impacts, prioritizing subwatersheds, and communicating field-scale impacts, using the soil and water assessment tool 2009 (SWAT 2009) model.

For the land-use change objective, a geospatial tool titled SWAT2009_LUC was developed that enables SWAT modelers to prepare specific input files for simulating concurrent land-use changes during the SWAT 2009 model simulations. Testing of the tool for the Illinois River Drainage Area in Arkansas (IRDAA) watershed showed that the tool accurately represented temporal land-uses within the model. Model simulations …

Field-Based Constraints On The Origin Of The Benton Uplift, Ouachita Mountains, Rachel Victoria Keng

Graduate Theses and Dissertations

The Ouachita Mountains are an east-west trending fold-and-thrust belt exposed in west central Arkansas and southeastern Oklahoma. The Mississippian-Pennsylvanian Ouachita orogeny occurred when the Sabine arc terrane collided during south-facing subduction, during closure of the Cambrian passive margin of the North American plate. Deep-water Paleozoic strata were incorporated into an accretionary wedge as the Sabine terrane approached the North American plate. Folds and thrust faults in the Ouachita Mountains generally verge north due to tectonic transport of an accretionary wedge from south to north. Structures in the Benton and Broken Bow Uplifts (located in the core of the wedge) locally …

Defining, Executing And Visualizing Representative Workflows In A Retail Domain, May Zeineldin

Graduate Theses and Dissertations

Our lives are filled with routine activities that we do more or less on auto-pilot such as driving to work and cooking. This thesis explores a workflow representation as a way to represent such activities of daily living. The domain of a retail store environment is used. Workflows are initially expressed in a structured English representation, then translated into a Petri net notation and implemented in mix of Petri nets, Lua, and C so that the resulting workflows can be displayed as the actions of collections of avatarbots (avatars controlled by programs) in a 3D virtual world, Second Life. One …

Vireo@Trecvid 2011: Instance Search, Semantic Indexing, Multimedia Event Detection And Known-Item Search, Chong-Wah Ngo, Shi-Ai Zhu, Wei Zhang, Chun-Chet Tan, Ting Yao, Lei Pang, Hung-Khoon Tan

Research Collection School Of Computing and Information Systems

The vireo group participated in four tasks: instance search, semantic indexing, multimedia event detection and known-item search. In this paper,we will present our approaches and discuss the evaluation results.

Understanding And Protecting Privacy: Formal Semantics And Principled Audit Mechanisms, Anupam Datta, Jeremiah Blocki, Nicolas Christin, Henry Deyoung, Deepak Garg, Limin Jia, Dilsun Kaynar, Arunesh Sinha

Research Collection School Of Computing and Information Systems

Privacy has become a significant concern in modern society as personal information about individuals is increasingly collected, used, and shared, often using digital technologies, by a wide range of organizations. Certain information handling practices of organizations that monitor individuals’ activities on the Web, data aggregation companies that compile massive databases of personal information, cell phone companies that collect and use location data about individuals, online social networks and search engines—while enabling useful services—have aroused much indignation and protest in the name of privacy. Similarly, as healthcare organizations are embracing electronic health record systems and patient portals to enable patients, employees, …