Physical Sciences and Mathematics Commons^™

Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia

Journal of Electrochemistry

We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO₄/C are, respectively, 162 mAh·g^-1, 142 mAh·g^-1 and 92 mAh·g^-1 at 0.1C rate. The nano-sized LiFePO₄-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g^-1 even at 30C, while the macroscopic LiFePO₄-c/C (1 μm) exhibits a much poorer discharge …

Aqueous Solution-Evaporation Route Synthesis And Phase Structural Research Of The Li-Rich Cathode Li1.23Ni0.09Co0.12Mn0.56O2 By In-Situ Xrd, Chong-Heng Shen, Shou-Yu Shen, Zhou Lin, Xiao-Mei Zheng, Hang Su, Ling Huang, Jun-Tao Li, Shi-Gang Sun

Journal of Electrochemistry

The Li-rich Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ material was synthesized via aqueous solution-evaporation route. The structure and morphology of the material were characterized by means of XRD and SEM. The results indicated that the single particle of the product was polygonal with the size of 330 nm and the structure was layered solid solution with a certain amount of Li₂MnO₃. Electrochemical tests showed that the first discharge capacity of the Li-rich layered material was 250.8 mAh·g^-1 at 0.1C，the capacity retention was 86.5% after 40 cycles. Through in-situ XRD study a …

Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang

Journal of Electrochemistry

Oncoming large scale electric energy storage (EES) requires battery systems not only to have sufficient storage capacity but also to be cost-effective and environmentally friendly. Li-ion batteries for widespread EES applications may be limited due to the constraint of global lithium resource. From the considerations of available resources and environmental impact, Na-ion batteries have potential advantages as next generation secondary batteries and an alternative to Li-ion batteries. However, in the present state of the art, the Na-storage cathodes reported so far are still deficient both in energy density and power capability, while the carbon and alloy anodes for Na-ion batteries …

Application Of Synchrotron Radiation Based Electrochemical In-Situ Techniques To Study Of Electrode Materials For Lithium-Ion Batteries, Zheng-Liang Gong, Wei Zhang, Dong-Ping Lv, Xiao-Gang Hao, Wen Wen, Zheng Jiang, Yong Yang

Journal of Electrochemistry

Due to its merits of high brightness and high intensity, high level of polarization and wide tunability in energy, etc., synchrotron radiation technique provides an unique platform for analysis of the relationship among composition–structure–performance of materials for lithium ion batteries, especially for in-situ, real time dynamic investigation of the electrochemical reaction mechanism, aging process and failure mechanism during charge-discharge cycling. In this paper, we review the latest developments in application of synchrotron based electrochemical in-situ experimental methods to studies of lithium ion batteries. The paper mainly focuses on the application of electrochemical in-siu XRD and XAFS techniques to the investigations …

Amino Acid Region 1000–1008 Of Factor V Is A Dynamic Regulator For The Emergence Of Procoagulant Activity, Joesph R. Wiencek, Mahesheema Na, Jamila Hirbawi, Michael Kalafatis

Chemistry Faculty Publications

Single chain factor V (fV) circulates as an Mr 330,000 quiescent pro-cofactor. Removal of the B domain and generation of factor Va (fVa) are vital for procoagulant activity. We investigated the role of the basic amino acid region 1000-1008 within the B domain of fV by constructing a recombinant mutant fV molecule with all activation cleavage sites (Arg(709)/Arg(1018)/Arg(1545)) mutated to glutamine (fV(Q3)), a mutant fV molecule with region 1000-1008 deleted (fV(ΔB9)), and a mutant fV molecule containing the same deletion with activation cleavage sites changed to glutamine (fV(ΔB9/Q3)). The recombinant molecules along with wild type fV (fV(WT)) were transiently expressed …

Volatization Of Extraterrestrial Materials As Determined By Zinc Isotopic Analysis, Randal Christopher Paniello

All Theses and Dissertations (ETDs)

None

Primary Care-Based Educational Interventions To Decrease Risk Factors For Metabolic Syndrome For Adults With Major Psychotic And/Or Affective Disorders: A Systematic Review, Cynthia Nover, Sarah S. Jackson

Epidemiology Faculty Publications

Background

Individuals with major psychotic and/or affective disorders are at increased risk for developing metabolic syndrome due to lifestyle- and treatment-related factors. Numerous pharmacological and non-pharmacological interventions have been tested in inpatient and outpatient mental health settings to decrease these risk factors. This review focuses on primary care-based non-pharmacological (educational or behavioral) interventions to decrease metabolic syndrome risk factors in adults with major psychotic and/or affective disorders.

Methods

The authors conducted database searches of PsychINFO, MEDLINE and the Cochrane Database of Systematic Reviews, as well as manual searches and gray literature searches to identify included studies.

Results

The authors were …

Timing And Spectroscopy Requirements For A Plastic Scintillating Fiber Bundle Time-Of-Flight Neutron Spectrometer, Paul A. Clement

Theses and Dissertations

The design parameters of a Time-of-Flight (TOF) neutron spectrometer composed of BCF-12 plastic scintillating fibers were investigated. A GEANT4 transport model was developed for analyzing the interaction of 2.5 MeV neutrons with a 14 x 14 BCF-12 fiber bundle. The bundle simulation demonstrated that 0.359% of all neutrons incident on the bundle will double scatter. The timing and data collection e efficiencies of a Tektronix DPO7104 series digital oscilloscope were examined to determine the signal processing requirements for future fiber bundle measurements. The minimum detectable neutron energy was computed by taking into account the bundle scintillation e efficiency, light collection …

Efficient And Long-Time Accurate Second-Order Methods For The Stokes-Darcy System, Wenbin Chen, Max Gunzburger, Dong Sun, Xiaoming Wan

Mathematics and Statistics Faculty Research & Creative Works

We propose and study two second order in time implicit-explicit methods for the coupled Stokes-Darcy system that governs flows in karst aquifers and other subsurface flow systems. the first method is a combination of a second-order backward differentiation formula and the second order Gear's extrapolation approach. the second is a combination of the second-order Adams-Moulton and second-order Adams-Bashforth methods. Both algorithms only require the solution of decoupled Stokes and Darcy problems at each time-step. Hence, these schemes are very efficient and can be easily implemented using legacy codes. We establish the unconditional and uniform in time stability for both schemes. …

Understanding Human Learning Using A Multiagent Based Unified Learning Model Simulation, Vlad T. Chiriacescu

Department of Computer Science and Engineering: Dissertations, Theses, and Student Research

Within cognitive science, computational modeling based on cognitive architectures has been an important approach to addressing questions of human cognition and learning. Modeling issues such as limited expressivity in representing knowledge and lack of appropriate selection of model structure represent a challenge for existing architectures. Furthermore, latest research shows that the concepts of long-term memory, motivation and working memory are critical cognitive aspects but a unifying cognitive paradigm integrating those concepts hasn’t been previously achieved.

Derived from a synthesis of neuroscience, cognitive science, psychology, and education, the Unified Learning Model (ULM) provides this integration by merging a statistical learning mechanism …

Optimal Allocation Of Distributed Reactive Power Resources Under Network Constraints For System Loss Minimization, L Meegahapola, S Abbott, D Morrow, T Littler, D Flynn

Dr Lasantha G Meegahapola

Abstract-Reactive power control is an important control issue for distribution system operators due to increased penetration of distributed generation. The work presented in this paper utilizes the inherent reactive power capability of the doubly-fed induction generator (DFIG) based wind farms to optimize the system losses while considering the network constraints in the system. The IEEE-30 bus system was modified by installing DFIG based wind farms in the medium voltage (MV) region creating three wind clusters in the network. The steady-state analysis was conducted to illustrate the loss minimization capability of the DFIG based wind farms under different reactive power configurations. …

Frequency Dynamics During High Ccgt And Wind Penetrations, Lasantha Meegahapola, Damian Flynn

Dr Lasantha G Meegahapola

Frequency stability is the paramount concern for secure and reliable operation of a power system. High wind penetration levels are reported in power systems with high thermal generation, and hence its likely to result high wind and combined-cycle gas turbine (CCGT) penetrations during system operation since CCGTs are the most preferable choice for the thermal generation. The doubly-fed induction generators (DFIGs) do not provide any inertial response while the CCGTs have unique frequency response during the system frequency disturbances. Therefore, CCGT turbine response characteristics and the zero inertial response may influence on frequency dynamics of a power network. The main …

Coordinated Utilisation Of Wind Farm Reactive Power Capability For System Loss Optimisation, Lasantha Meegahapola, S Durairaj, D Flynn, B Fox

Dr Lasantha G Meegahapola

Most wind farms currently being installed are based upon doubly fed induction generator (DFIG) or direct-drive synchronous generator (DDSG) technology. Given that one of the impacts of introducing distributed generation is an alteration of steady-state power flows and voltages, both technologies are capable of providing local voltage support. Wind farms may, therefore, be included in optimal power flow (OPF) calculations to minimise fuel cost and/or network losses. The IEEE 30-bus system is considered as a case study, comparing fixed-speed induction generator (FSIG) requirements with DFIG capability. Results are presented for a range of DFIG capability modes, at varying system load …

Rfid-Based Anti-Theft Auto Security System With An Immobilizer, Geeth Jayendra, Sisil Kumarawadu, Lasantha Meegahapola

Dr Lasantha G Meegahapola

This paper presents a novel radio frequency identification (RFID) based vehicle immobilizer system, which features low hacking probability while preserving the safety of the passengers of the hijacked vehicle. The immobilizer uses the active RFID technology where the tag is generated with comparatively large character sets. The receiving unit is intelligently integrated into three control circuits in the vehicle, namely, ignition circuit, power control unit, and automatic gear changing system, enabling it to bring the vehicle speed down to zero in a safe step by step manner. The anti-theft auto security system proposed here was tested under different weather conditions …

A Genetic Algorithm Based Approach To Lv Radial Distribution Feeders Load Reconfiguration, Geeth Jayendra, Sisil Kumarawadu, Lasantha Meegahapola

Dr Lasantha G Meegahapola

No abstract provided.

Spectroscopic And Physico-Chemical Characterization Of Ir(I) And Ru(Iii) Complexes Of 32-Membered Unsymmetrical Dinucleating Macrocyclic Ligand, Mohammad Mansoob Khan Dr

Dr. Mohammad Mansoob Khan

No abstract provided.

U.S. Drought Monitor, December 24, 2013, Matthew Rosencrans

United States Agricultural Commodities in Drought Archive

Drought map of U.S. for December 24, 2013 (12/24/13) plus: U.S. crop areas experiencing drought (map), Approximate percentage of crop located in drought, by state (bar graph), Percent of crop area located in drought, past 52 weeks (line graph) for: Hay, Cattle, Winter wheat.

Table Of Contents, Michele Harmon

Journal of the South Carolina Academy of Science

No abstract provided.

Multi-State Models For Natural History Of Disease, Amy Laird, Rebecca A. Hubbard, Lurdes Y. T. Inoue

UW Biostatistics Working Paper Series

Longitudinal studies are a useful tool for investigating the course of chronic diseases. Many chronic diseases can be characterized by a set of health states. We can improve our understanding of the natural history of the disease by modeling the sequence of visited health states and the duration in each state. However, in most applications, subjects are observed only intermittently. This observation scheme creates a major modeling challenge: the transition times are not known exactly, and in some cases the path through the health states is not known.

In this manuscript we review existing approaches for modeling multi-state longitudinal data. …

Determining The 7li(N,Gamma) Cross Section Via Coulomb Dissociation Of 8li, R. Izsak, A. Horvath, A. Kiss, Z. Seres, A. Galonsky, C. A. Bertulani, Zs Fueloep, T. Baumann, D. Bazin, K. Ieki, C. Bordeanu, N. Carlin, M. Csanád, F. Deák, Paul A. Deyoung, N. Frank, T. Fukuchi, A. Gade, D. Galaviz, C. R. Hoffman, W. A. Peters, H. Schelin, M. Thoennessen, G. I. Veres

Faculty Publications

The applicability of Coulomb dissociation reactions to determine the cross section for the inverse neutron capture reaction was explored using the reaction Li-8(gamma,n)Li-7. A 69.5 MeV/nucleon Li-8 beam was incident on a Pb target, and the outgoing neutron and Li-7 nucleus were measured in coincidence. The deduced (n,gamma) excitation function is consistent with data for the direct capture reaction Li-7(n,gamma) Li-8 and with low-energy effective field theory calculations.

Students' Perceived Utility Of Precision Taught Calculus, Rebecca-Anne Dibbs, David Glassmeyer, Wafa Yacoub

Faculty Articles

The last decade of calculus research has showed students learn best when lecture is supplemented with thoughtful use of technology and group work; however, educators are given little direction of how they are to balance the already full first semester calculus class. Precision teaching is an instructional model that employs formative assessment to provide information on what topics are understood by students as well as indicate troublesome concepts. With this information, the instructor can adjust class time accordingly by incorporating supplemental activities most beneficial to students. The purpose of this interview study was to explore the perceived utility of precision …

A Search For Enhanced Very High Energy Gamma-Ray Emission From The 2013 March Crab Nebula Flare, P. T. Reynolds, Et Al

Physical Sciences Publications

In 2013 March, a flaring episode from the Crab Nebula lasting ~2 weeks was detected by Fermi-LAT (Large Area Telescope on board the Fermi Gamma-ray Space Telescope). The Very Energetic Radiation Imaging Telescope Array System (VERITAS) provides simultaneous observations throughout this period. During the flare, Fermi-LAT detected a 20 fold increase in flux above the average synchrotron flux >100 MeV seen from the Crab Nebula. Simultaneous measurements with VERITAS are consistent with the non-variable long-term average Crab Nebula flux at TeV energies. Assuming a linear correlation between the very high energy flux change >1 TeV and the flux …

C4a-Hydroperoxyflavin Formation In N -Hydroxylating Flavin Monooxygenases Is Mediated By The 2′-Oh Of The Nicotinamide Ribose Of Nadp⁺, Reeder Robinson, Somayesadat Badieyan, Pablo Sobrado

Chemistry Faculty Research & Creative Works

Flavin-dependent monooxygenases must stabilize a C4a-hydroperoxyflavin intermediate to hydroxylate their respective substrates. Formation and decay of the C4a-hydroperoxyflavin were monitored under rapid reaction kinetic conditions in SidA, an N-hydroxylating monooxygenase involved in siderophore biosynthesis. Solvent kinetic isotope effect studies of flavin oxidation indicate that both hydrogen peroxide elimination and water elimination occur via abstraction of hydrogen from the N5 of the flavin. Kinetic isotope effect and density functional theory results are consistent with the transfer of a proton from the 2′-OH of the nicotinamide ribose of nicotinamide adenine dinucleotide phosphate (NADP+) to the C4a-peroxyflavin to form the C4a-hydroperoxyflavin. This represents …

High Resolution X-Ray Diffraction Analysis Of Cb1 Receptor Antagonists As A Means To Explore Binding Affinity, Steven P. Fournet

University of New Orleans Theses and Dissertations

Abstract

Charge density studies have been conducted on ten CB₁ cannabinoid receptor antagonists via high resolution x-ray crystallography. Bond critical point values and various other properties derived from these studies including the electrostatic potential were analyzed in correlation to the affinity of each compound with the CB₁ receptor. Correlation/anti-correlation was found between several properties and K_i. The data was also interpreted by principal component analysis with three principal components accounting for 85% of the data variation. Data mining was limit due to the low sample count and the requirements set for the inclusion of correlated/anti-correlated variables …

Variational Iteration Method For The Burgers' Flow With Fractional Derivatives—New Lagrange Multipliers, Guo-Cheng Wu, Dumitru Baleanu

G.C. Wu

The flow through porous media can be better described by fractional models than the classical ones since they include inherently memory effects caused by obstacles in the structures. The variational iteration method was extended to find approximate solutions of fractional differential equations with the Caputo derivatives, but the Lagrange multipliers of the method were not identified explicitly. In this paper, the Lagrange multiplier is determined in a more accurate way and some new variational iteration formulae are presented.

Social Aggregation In Pea Aphids: Experiment And Random Walk Modeling, Christa Nilsen, John Paige, Olivia Warner, Benjamin Mayhew, Ryan Sutley, Mathew Lam, Andrew J. Bernoff, Chad M. Topaz

Chad M. Topaz

No abstract provided.

A Survey For Very Short-Period Planets In The Kepler Data, Brian Jackson, Christopher C. Stark, Elisabeth R. Adams, John Chambers, Drake Deming

Brian Jackson

We conducted a search for very short-period transiting objects in the publicly available Kepler data set. Our preliminary survey has revealed four planetary candidates, all with orbital periods less than 12 hr. We have analyzed the data for these candidates using photometric models that include transit light curves, ellipsoidal variations, and secondary eclipses to constrain the candidates’ radii, masses, and effective temperatures. Even with masses of only a few Earth masses, the candidates’ short periods mean that they may induce stellar radial velocity signals (a few m s−1) detectable by currently operating facilities. The origins of such short-period planets are …

Ultra-Low Temperature Measurements Of London Penetration Depth In Iron Selenide Telluride Superconductors, Andrei Diaconu

University of New Orleans Theses and Dissertations

The newly discovered iron based superconductors have captivated the attention of the scientific community due to the unusual mechanism behind their superconductivity and their promise as the next generation high temperature superconductors. After a century of superconductor research, the physical mechanism behind high temperature superconductivity is still not understood. These new materials bring renewed hope in elucidating the pairing mechanism responsible with high temperature superconductors and achieving the ultimate goal of the field, room temperature superconductivity. Consequently, a deeper understanding of the intriguing properties of iron based materials is essential.

A great deal about the pairing mechanism of Cooper electron …

Long Term Observations Of B2 1215+30 With Veritas, E. Aliu, S. Archambault, T. Arlen, T. Aune, M. Beilicke, W. Benbow, R. Bird, A. Bouvier, J. H. Buckley, V. Bugaev, A. Cesarini, L. Ciupik, M. P. Connolly, W. Cui, J. Dumm, M. Errando, A. Falcone, S. Federici, Q. Feng, J. P. Finley, P. Fortin, L. Fortson, A. Furniss, N. Galante, L. Gerard, G. H. Gillanders, S. Griffin, J. Grube, G. Gyuk, D. Hanna, J. Holder, G. Hughes, T. B. Humensky, P. Kaaret, M. Kertzman, Y. Khassen, D. Kieda, H. Krawczynski, F. Krennrich, M. J. Lang, A. S. Madhavan, G. Maier, P. Majumdar, S. Mcarthur, A. Mccann, P. Moriarty, R. Mukherjee, D. Nieto, A. O’Faolain De Bhroithe, P. T. Reynolds, Et Al

Physical Sciences Publications

We report on VERITAS observations of the BL Lac object B2 1215+30 between 2008 and 2012. During this period, the source was detected at very high energies (VHEs; E > 100 GeV) by VERITAS with a significance of 8.9σ and showed clear variability on timescales larger than months. In 2011, the source was found to be in a relatively bright state and a power-law fit to the differential photon spectrum yields a spectral index of 3.6 ± 0.4stat ± 0.3syst with an integral flux above 200 GeV of (8.0 ± 0.9stat ± 3.2syst) × 10−12 cm−2 s−1. No short term variability …

A Study On The Integration Of A Novel Absorption Chiller Into A Microscale Combined Cooling, Heating, And Power (Micro-Cchp) System, Scott J. Richard

University of New Orleans Theses and Dissertations

This study explores the application of micro-CCHP systems that utilize a 30 kW gas microturbine and an absorption chiller. Engineering Equation Solver (EES) is used to model a novel single-effect and double-effect water-lithium bromide absorption chiller that integrates the heat recovery unit and cooling tower of a conventional CCHP system into the chiller’s design, reducing the cost and footprint of the system. The results of the EES model are used to perform heat and material balances for the micro-CCHP systems employing the novel integrated chillers, and energy budgets for these systems are developed. While the thermal performance of existing CCHP …