Physical Sciences and Mathematics Commons^™

Molecular Dynamics Model Of Carbon Nanotubes In Epon 862/Detda Polymer, Guttormur Arnar Ingvason

Doctoral Dissertations and Master's Theses

The aerospace industry is interested in increasing the strength while reducing the weight of carbon fiber composite materials. Adding single walled carbon nanotubes (SWCNT) to a polymer matrix can achieve that goal by improving delamination properties of the composite. Due to the complexity of polymer molecules and the curing process, few 3-D Molecular Dynamics simulations of a polymer-SWCNT composite have been run. Our model runs on the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS), with a COMPASS (Condensed phase Optimized Molecular Potential for Atomistic Simulations Studies) potential to represent the interactions between the atoms of the polymer and the SWCNT. This …

Extended Book Review: Mathematics In Popular Culture: Essays On Appearances In Film, Fiction, Games, Television And Other Media, Edited By Jessica K. Sklar And Elizabeth S. Sklar; Loving+Hating Mathematics: Challenging The Myths Of Mathematical Life, By Reuben Hersh And Vera John-Steiner; Mathematicians: An Outer View Of The Inner World, By Mariana Cook, Gizem Karaali

Pomona Faculty Publications and Research

I was delighted to have the opportunity to review three books on a topic near and dear to my heart. In recent years it has become a passion of mine to think of and speak about the place of mathematics in the real world, in the world of those who are not doing mathematics for a living. I care about the applications and the implications of mathematics, but more than that, I care about the feelings and the impressions attached to it. Often math anxiety or skepticism comes up; the latter may be due to how frequently others (mis)use statistics, …

Viscosity Dependence Of Faraday Wave Formation Thresholds, Lisa Michelle Slaughter

Physics

This experiment uses an electromagnetic shaker to produce standing wave patterns on the surface of a vertically oscillating sample of silicon liquid. These surface waves, known as Faraday waves, form shapes such as squares, lines, and hexagons. They are known to be dependent upon the frequency and amplitude of the forcing as well as on the viscosity and depth of the liquid in the dish. At a depth of 4mm and for various silicon liquids having kinematic viscosities of 10, 20, and 38 cSt, we determined the acceleration at which patterns form for frequencies between 10 and 60 Hz. For …

Time Variation Of The Broad Hβ And Hα Emission Lines In Active Galactic Nuclei, Bryan R. Scott

Physics

High-quality Keck/LRIS long-slit spectra for a sample of 97 active galaxies selected from the Sloan Digital Sky Survey (redshift between 0.02 & 0.1; Black Hole Mass approximately 10⁷ Solar Masses) were obtained between January 2009 and March 2010 in order to study the black hole (BH) mass scaling relation in the local universe. Typically, the width of the broad Hβ emission line is used to measure the mass of the black hole (MBH). However, signs of variability in the emission line profile are seen for eight objects: While broad Hβ emission lines had previously been observed in spectra from …

Extension Of A High-Order Petrov-Galerkin Implementation Applied To Non-Radiating And Radar Cross Section Geometries, William L. Shoemake

Masters Theses and Doctoral Dissertations

Capabilities of a high-order Petrov-Galerkin solver are expanded to include N-port systems. Tait-Bryan angles are employed to launch electro-magnetic waves in arbitrary directions allowing off axis ports to be driven. The transverse-electric (TE) formulation is added allowing waveguide geometries to be driven directly. A grid convergence study is performed on a coax-driven waveguide system. Physical data are matched to a hybrid-T junction (magic-T) electromagnetic waveguide structure to verify the TE driving formulation along with the Tait-Bryan angles and modified post-processing routines. A simple sphere case is used to exercise the radar cross section (RCS) routines and to examine the benefits …

A Two-Echelon Location-Inventory Model For A Multi-Product Donation-Demand Driven Industry, Milad Khajehnezhad

Theses and Dissertations

This study involves a joint bi-echelon location inventory model for a donation-demand driven industry in which Distribution Centers (DC) and retailers (R) exist. In this model, we confine the variables of interest to include; coverage radius, service level, and multiple products. Each retailer has two classes of product flowing to and from its assigned DC i.e. surpluses and deliveries. The proposed model determines the number of DCs, DC locations, and assignments of retailers to those DCs so that the total annual cost including: facility location costs, transportation costs, and inventory costs are minimized. Due to the complexity of problem, the …

Phylogeographic Inference Of Insular Mule Deer (Odocoileus Hemionus) Divergence In North America's Desert Southwest, Ona Alminas

Theses and Dissertations

Though mule deer (Odocoileus hemionus) persist in robust populations throughout most of their North American distribution, nearly 60% of their historic range in México has declined due to habitat loss and unregulated hunting. Two of the six subspecies inhabiting México's deserts and Baja California peninsula are of conservation concern, occurring on land bridge islands in the Pacific Ocean (O. h. cerrosensis on Cedros Island: threatened) and in the Sea of Cortés (O. h. sheldoni on Tiburón Island: endangered). Focusing on the desert southwest (n=449 deer), we obtained 1,611 bp of mtDNA sequence (control region: 583 bp; cytochrome b gene: 1,028 …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …

Applying Computational Methods To Interpret Experimental Results In Tribology And Enantioselective Catalysis, Michael Garvey

Theses and Dissertations

Computational methods are rapidly becoming a mainstay in the field of chemistry. Advances in computational methods (both theory and implementation), increasing availability of computational resources and the advancement of parallel computing are some of the major forces driving this trend.

It is now possible to perform density functional theory (DFT) calculations with chemical accuracy for model systems that can be interrogated experimentally. This allows computational methods to supplement or complement experimental methods. There are even cases where DFT calculations can give insight into processes and interactions that cannot be interrogated directly by current experimental methods.

This work presents several examples …

An Experimental Investigation Characterizing The Tribological Performance Of Natural And Synthetic Biolubricants Composed Of Carboxylic Acids For Energy Conservation And Sustainability, Carlton Jonathan Reeves

Theses and Dissertations

Over the last several decades the lubrication industry has been striving to bring bio-based lubricants known as biolubricants to prominence. The reasons for the increased environmental initiatives are due to depletion of oil reserves, increases in oil price, stringent government regulations on petroleum-based oils, and most importantly, concerns for protecting the environment. With an estimated, 50% of all lubricants entering the environment and much of these being composed of toxic mineral oils, biolubricants have begun to witness a resurgence. This experimental investigation seeks to develop a new class of ecofriendly biolubricants that are less toxic to the environment, derived from …

The Influence Of Online Word-Of-Mouth On Long Tail Formation, Bin Gu, Qian Tang, Andrew B. Whinston

Research Collection School Of Computing and Information Systems

The long tail phenomenon has been attributed to both supply side and demand side economies. While the cause on the supply side is well-known, research on the demand side has largely focused on the awareness effect of online information that helps consumers discover new and often niche products. This study expands the demand side factors by showing that online information also influences the long tail phenomenon through the informative effect, which affects consumers' evaluation of product quality. We examine the informative effect in the context of online WOM. Two sets of theories suggest opposite directions for the implication of the …

Characterization Of The Hydrogeology And Stress State In The Vicinity Of The Homestake Mine, Lead, Sd, Johnathan Ebenhack

All Theses

Underground workings in fractured rock are common worldwide. They have applications in numerous areas and fields of study. These include mining operations, civil engineering projects like tunnels and underground facilities, and research projects that require underground laboratories such as the physics research being conducted by Sanford Laboratory at the former Homestake mine and Fermi Laboratory near Chicago (Bahcall et al. 2001, Elsworth 2009, Sadoulet et al. 2006, bge science@DUSEL, fnal.gov). These excavations can reach several kilometers in depth including the 3.9 km deep TauTona mine in South Africa, the 3 km deep LaRonde mine in Quebec and the 2.4 km …

Room Generation, Removal, And Recovery In Udk 3.5, Scott Johnson

All Theses

This paper explores algorithms and techniques for creating an extended game world that represents a radical departure from the widely used static content in current use with most games featuring procedurally generated game worlds. Using the Unreal Development Kit 3.5 game engine and focusing on a small set of rooms and doors the research sets to create a game world that is in constant flux and addresses issues of game development limitations on the size of game worlds.

Using Physiology To Predict The Responses Of Ants To Climatic Warming, Sarah E. Diamond, Clint A. Penick, Shannon L. Pelini, Aaron M. Ellison, Nicholas J. Gotelli, Nathan J. Sanders, Robert R. Dunn

College of Arts and Sciences Faculty Publications

Physiological intolerance of high temperatures places limits on organismal responses to the temperature increases associated with global climatic change. Because ants are geographically widespread, ecologically diverse, and thermophilic, they are an ideal system for exploring the extent to which physiological tolerance can predict responses to environmental change. Here, we expand on simple models that use thermal tolerance to predict the responses of ants to climatic warming. We investigated the degree to which changes in the abundance of ants under warming reflect reductions in the thermal niche space for their foraging. In an eastern deciduous forest system in the United States …

Unified Model Of Charge Transport In Insulating Polymeric Materials, Alec Sim

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Charge transport, charging, and subsequent electrostatic discharge due to interactions with the space environment are primary concerns of spacecraft designers. Developing a physical understanding of the interactions of charge with the multitude of materials that spacecraft are composed of is a critical step in understanding and mitigating both short-term and long-term spacecraft degradation. In particular, the study of charge transport in highly insulating materials is critical as they store charge longer, with higher capacity, and with greater destructive capability than other materials.

The Utah State University Materials Physics Group, with the funding of the NASA James Webb Space Telescope project …

Effective Graph-Based Content--Based Image Retrieval Systems For Large-Scale And Small-Scale Image Databases, Ran Chang

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Digital imaging was a great invention in the last century. Since digital cameras became popular in the public, a large amount of digital images emerged in the late of the twentieth century. How to manage the huge amount of images and find desired images among them became an urgent issue during the same period.

Techniques of retrieving a desired image are generally categorized into two basic classes. One relies on text-based key words to retrieve desired images in the image
database. The other one relies on image-based queries to retrieve desired images in the image database. The second technique is …

Demonstration Of A Targeted Proteome Characterization Approach For Examining Specific Metabolic Pathways In Complex Bacterial Systems, Adam Justin Martin

Masters Theses

Multiple Reaction Monitoring (MRM) is a powerful tandem mass spectrometry (MS/MS) tool frequently implemented in proteomic studies to provide targeted analysis of proteins and peptides. The selectivity that MRM delivers is so strong that it provides the quadrupole mass spectrometers (QQQ), on which it is commonly employed, with pertinence to proteomic studies that they would otherwise lack for their relatively low resolution. Additionally, this increased level of selectivity is sufficient enough to supplant complicated fractionation techniques, additional dimensions of chromatography, and 24 hour long MS/MS experiments in simplistic biological samples. But there is a deficiency of evidence to determine the …

Quantitative Trait Loci Associated With Waterlogging Tolerance In A Soft Red Winter Wheat Mapping Population, Diana Carolina Ballesteros Benavides

Graduate Theses and Dissertations

Waterlogging is caused when water stays superficially in the soil for an extended period of time, creating an anaerobic environment which decreases plant growth and grain yield at maturity. Despite the impact of waterlogging on wheat production both globally and in the southeastern U.S., very little is known about the genetic control of waterlogging tolerance in wheat. The objective of this study was to determine the amount of genetic variation for vegetative stage waterlogging tolerance present within a wheat recombinant inbred line (RIL) population and to identify quantitative trait loci (QTL) associated with tolerance and productivity. Experiments were carried out …

Conceptual, Impact-Based Publications Recommendations, Ann Smittu Joseph

Graduate Theses and Dissertations

CiteSeerx is a digital library for scientific publications by computer science researchers. It also functions as a search engine with several features including autonomous citation indexing, automatic metadata extraction, full-text indexing and reference linking. Users are able to retrieve relevant documents from the CiteSeer^x database directly using search queries and will further benefit if the system suggests document recommendations to the user based on their preferences and search history. Therefore, recommender systems were initially developed and continue to evolve to recommend more relevant documents to the CiteSeer^x users. In this thesis, we introduce the Conceptual, Impact-Based Recommender (CIBR), …

Developing A Presumptive Test For Select Synthetic Cannabinoids, Carrie Snyder

Graduate Theses and Dissertations

Synthetic cannabinoids (SC's) began to gain popularity around the world in 2009. Since then, many of the compounds have been outlawed and methods developed to detect them and their metabolites using mass spectrometry. Our work investigated the possibility of developing a colorimetric presumptive test. The SC JWH-019 was synthesized and its ketone targeted as a possible reaction site. Many SC's contain ketones and thus a reaction at this site would be applicable to many of the compounds. Since JWH-019 is costly and time consuming to synthesize, much of the experimental work was done using benzophenone (BP). BP contains a diaryl …

A Bandwidth-Conserving Architecture For Crawling Virtual Worlds, Dipesh Gautam

Graduate Theses and Dissertations

A virtual world is a computer-based simulated environment intended for its users to inhabit via avatars. Content in virtual worlds such as Second Life or OpenSimulator is increasingly presented using three-dimensional (3D) dynamic presentation technologies that challenge traditional search technologies. As 3D environments become both more prevalent and more fragmented, the need for a data crawler and distributed search service will continue to grow. By increasing the visibility of content across virtual world servers in order to better collect and integrate the 3D data we can also improve the crawling and searching efficiency and accuracy by avoiding crawling unchanged regions …

Hydrogeology And Chemical Characterization Of Hydrocarbon In Domestic Water Wells, Rancho Villa Subdivision, Rogers, Arkansas, Janelle Renee Sherman

Graduate Theses and Dissertations

This project is centered on the Rancho Villa community in Rogers, Arkansas where several residents have had hydrocarbon contamination in their domestic water wells. The goal of this project was to understand the hydrogeology in the study area, characterize the contaminant chemically, and determine the source of the contaminant. The hydrogeology of the area was determined from previous theses. Seventeen samples were taken from the wells in the Rancho Villa community; each sample was analyzed for geochemical parameters and by Gas Chromatography/Mass Spectrometry (GC/MS) for organic compounds analysis. Four of the 17 samples had a visible non-aqueous layer of hydrocarbon …

Infrared Spectra Analysis Of Thermally Altered Iron Phyllosilicates And The Implications For Mars, William Thomas Bryan

Graduate Theses and Dissertations

This study looks at two iron-rich phyllosilicates, which may be present on Mars. The minerals, greenalite and hisingerite, are rich in iron-II and iron-III, respectively. Small samples (~0.40 grams) of each mineral were crushed and heated in a Lindberg Tube Oven for approximately twenty-four hours at temperatures selected to mimic lava flows and impact events. Following heating, each sample was placed in a Fourier Transform Infrared (FT-IR) spectrometer to collect the near- and mid-infrared spectra. The spectra allowed for these terrestrial analogs to be analyzed with regards to how their structure breaks down with increasing temperature. The samples' colors were …

Assessment Of The Predictive Reliability Of A Swat Flow Model And The Evaluation Of Runoff Generation And Bmp Effectiveness In A Shale-Gas Impacted Watershed Using A Modeling Approach, Kwasi Asante

Graduate Theses and Dissertations

In order to ensure a harmonious harness of shale-gas resources while ensuring minimal damage to the environment, it is imperative that studies to conduct to inform various aspects of managing the environment. This includes the development of reliable hydrologic models to inform in decisions concerning water and the environment.

The first objective of this study was to evaluate the predictive reliability of the Soil and Water Assessment Tool (SWAT) model based on respective methods of LULC data classification and data type spatial resolution. Results showed that the high-resolution data classified with object-oriented image method does not provide any significant advantage …

Microfluidics Guided By Redox-Magnetohydrodynamics (Mhd) For Lab-On-A-Chip Applications, Vishal Sahore

Graduate Theses and Dissertations

Unique microfluidic control actuated by simply turning off and on microfabricated electrodes in a small-volume system was investigated for lab-on-a-chip applications. This was accomplished using a relatively new pumping technique of redox-magnetohydrodynamics (MHD), which as shown in this dissertation generated the important microfluidic features of flat flow profile and fluid circulation. MHD is driven by the body force, FB = j × B, which is the magnetic part of the Lorentz force equation, and its direction is given by the right hand rule. The ionic current density, j, was generated in an equimolar solution of potassium ferri/ferro cyanide by applying …

Environmental Literacy Of Sixth Grade Students In Arkansas: Implications For Environmental Education Reform, Lisa Suzanne Wood

Graduate Theses and Dissertations

Environmental education must be better integrated into K-12 curriculum to advance environmental literacy. Producing a citizenry that can understand and address the complex environmental issues facing the world today and in the future is essential to sustainable life on this planet.

Using the Middle School Environmental Literacy Survey, 6th grade students across Arkansas were surveyed to obtain a baseline measure of environmental literacy based on the four domains of environmental literacy included in the survey; ecological knowledge, environmental affect, cognitive skills, and behavior. Individual domain scores were combined into a composite environmental literacy score. Results were then compared to the …

Steady-State Switching And Dispersion/Absorption Spectroscopy Of Multistate Atoms Inside An Optical Ring Cavity, Jiteng Sheng

Graduate Theses and Dissertations

This thesis mainly focuses on the experimental investigations of electromagnetically induced transparency (EIT) related phenomena in various systems involving multilevel atoms inside an optical ring cavity. Semiclassical methods, e.g. density-matrix equations, are used through out this thesis to simulate the experimental results. First, the cavity transmission spectrum can be significantly modified when multilevel atoms are placed inside an optical ring cavity. Such coupled atom-cavity systems are well explained by the intracavity dispersion/absorption properties. Specifically, three-level lambda-type, four-level N-type and double-lambda-type atoms inside an optical ring cavity are investigated by examining their cavity transmission spectra. Second, optical multistability (OM) has been …

Towards The Total Synthesis Of Antascomicin B. Efforts To Construct The C1-C21 Fragment, Juliette Rivero-Castro

Graduate Theses and Dissertations

Antascomicin B is a macrolide isolated from a strain of Micromonospora. It possesses structural similarities to FK506 and rapamycin and exhibits potent binding ability to FKBP12. Recent reports suggest that small molecule ligands of FKBP12 possess potent neuroprotective and neurodegenerative properties in mouse models of Parkinson's disease. Our approach to the C1-21 fragment of antascomicin B involves an asymmetric amino-Claisen rearrangement originally developed by Tsunoda et al.35 report the scalability of the preparation and rearrangement of an allylic amide possessing a silyloxy group at the terminal position of the alkene. The Tsunoda-Claisen rearrangement uses inexpensive (S)-α-methylbenzylamine as the chiral …

Monodentate, Bidentate And Photocrosslinkable Thiol Ligands For Improving Aqueous Biocompatible Quantum Dots, Hiroko Takeuchi

Graduate Theses and Dissertations

Water-soluble Quantum Dots (QDs) are highly sensitive fluorescent probes that are often used to study biological species. One of the most common ways to render QDs water-soluble for such applications is to apply hydrophilic thiolated ligands to the QD surface. However, these ligands are labile and can be easily exchanged on the QD surface, which can severely limit their application. As one way to overcome this limitation while maintaining a small colloidal size of QDs, we developed a method to stabilize hydrophilic thiolated ligands on the surface of QDs through the formation of a crosslinked shell using a photocrosslinking approach. …

Tin Sensitization For Electroless Plating, Xingfei Wei

Graduate Theses and Dissertations

The tin sensitization process has been used in electroless plating since 1940s Brenner and Riddell developed the electroless plating for surface metallization method. It was found to be an interesting topic to study tin sensitization for chemically controlling metal deposition on different substrates, because the tin sensitization process had critical effects on the electroless plated metal thin films. Nowadays electroless plating metal deposition is still an important method for depositing metals. It has a few advantages over the vapor deposition and electrodeposition method, such as work in an ambient condition, on nonconductive substrates, and without extra power input. Applying electroless …