Physical Sciences and Mathematics Commons^™

Speciation Of Chromium By The Combination Of Dispersive Liquid--Liquid Microextraction And Microsample Injection Flame Atomic Absorption Spectrometry, Yunusemre Ünsal, Mustafa Tüzen, Mustafa Soylak

Turkish Journal of Chemistry

A microextraction procedure was established for the speciation of total Cr, Cr(III), and Cr(VI). Sudan blue II was used as a ligand for speciation works. Some factors affecting the recoveries of chromium species, including type of extraction and dispersive solvents, pH, ligand amount, extraction time, and matrix ions, were examined. Optimum values for the dispersive liquid--liquid microextraction method were pH 6, LOD 0.34 \mu g L^{-1}, and preconcentration factor 400. Chromium(III) was quantitatively recovered under optimal conditions, while the recovery of chromium(VI) was below 10%. The relative standard deviation for Cr(III) determinations for the 10-replicate measurement of 0.3 \mu g …

Preparation Of A Lead Sensor Based On Porous Multiwalled Carbon Nanotubes/Thiolated Chitosan Composite Materials, Jun Wan, Ling Xing, Wei Wang

Turkish Journal of Chemistry

Thiolated chitosan (CS--TGA) was prepared using chitosan (CS) and thioglycolic acid (TGA). Then MWCNTs were added to the mixture of CS--TGA and CS to prepare the CS/CS--TGA/MWCNs porous composite by freeze-drying method and this composite was used to modify an indium tin oxide glass electrode. The electrode was used as a sensor for Pb^{2+}. The morphology and structure of the composite were characterized by infrared spectroscopy and scanning electron microscope, and their electrochemical behavior was also studied. Under the optimized experimental conditions, the sensor showed a linear range of 2.0 \times 10^{-9}\sim 2.0 \times 10^{-8} mol L^{-1} for Pb^{2+} with …

Synthesis And X-Ray Powder Diffraction, Electrochemical, And Genotoxic Properties Of A New Azo-Schiff Base And Its Metal Complexes, Mustafa Bal, Gökhan Ceyhan, Bariş Avar, Muhammet Köse, Ahmet Kayraldiz, Mükerrem Kurtoğlu

Turkish Journal of Chemistry

A new, substituted 2-[(E)-{[4-(benzyloxy)phenyl]imino} methyl]-4-[(E)-(4-nitrophenyl)diazenyl]phenol azo-azomethine ligand (mbH) was synthesized from 2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzaldehyde and 4-benzyloxyanilinehydrochloride in ethyl alcohol solution. These mononuclear Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) complexes of the ligand were prepared and their structures were proposed by elemental analysis, and infrared and ultraviolet-visible spectroscopy; the proton NMR spectrum of the mbH ligand was also recorded. The azo-azomethine ligand, mbH, behaves as a bidentate ligand coordinating through the nitrogen atom of the azomethine (--CH=N--) and the oxygen atom of the phenolic group. Elemental analyses indicated that the metal:ligand ratio was 1:2 in the metal chelates. Powder X-ray diffraction parameters suggested …

Selective Synthesis Of Cyclododec-2-En-1-Yl Ethers Via Palladium-Catalyzed Allylic Substitution Reaction: A Kinetic Study, Asen Kolev, Magdalena Mitkova, Stefan Kotov, Encho Balbolov

Turkish Journal of Chemistry

The palladium-catalyzed reaction between isomeric cyclododec-2-en-1-yl acetates and primary aliphatic alcohols was found to result in high yields of the reaction products obtained. The selectivity with respect to cyclododec-2-en-1-yl ethers formed as reaction products ranged from 73% to 93%. The kinetics of the reaction of acetoxycyclododec-2-enes with alcohols was studied within the temperature range of 328--358 K. A kinetic equation best fitting the experimental data was provided.

Study Of The Interaction Between Glucosamine Hydrochloride And Sodium Dodecylsulphate Micelles Using Conductometric, Isothermal Calorimetry, Zeta-Potential Titrations, And Nmr Noesy, Marcos Roberto Abreu Alves, Luciano Sindra Virtuoso, Elson Santiago De Alvarenga, Ângelo Márcio Leite Denadai

Turkish Journal of Chemistry

The aim of this work was to investigate the influence of an anti-inflammatory agent, the bulky counterion named glucosamine (Gl^+), in sodium dodecylsulphate (SDS) in 2 ways: 1) by titration of SDS solutions with different concentrations of Gl^+; and 2) by titration of Gl^+ with SDS solution with concentration close to the critical micellar concentration (cmc) (7.7 mM). In procedure 1, micellisation study by isothermal titration calorimetry (ITC) showed that the increase in Gl^+ concentration reduces the cmc and the micellisation enthalpy. Increasing of the micellisation entropy was also observed, suggesting desolvation of micellar structures as a consequence of electrostatic …

Effect Of Boric Acid On Corrosion And Electrochemical Performance Of Pb-0.08% Ca-1.1% Sn Alloys Containing Cu, As, And Sb Impurities For Manufacture Of Grids Of Lead-Acid Batteries, Said Salih, Ahmed Gad-Allah, Ashraf Abd El-Wahab, Hamid Abd Elrahman

Turkish Journal of Chemistry

The electrochemical performance of lead-acid batteries made of Pb--Ca--Sn alloys with and without 0.1% of each of Cu, As, and Sb individually and combined in 4.0 M H_2SO_4 in the absence and presence of 0.4 M H_3BO_3 was studied. Both impurities and H_3BO_3 were found to reduce the corrosion rate. Cyclic voltammetry revealed that the presence of impurities or H_3BO_3 significantly retarded the formation of large crystal PbSO_4. H_3BO_3 increased the rates of oxygen and hydrogen evolution reactions for all alloys. Impedance measurement was used to quantify the amounts of PbSO_4 and PbO in the initial stage of the oxidation. …

Synthesis And Characterization Of New (E)-N'-(Substituted Benzylidene)-2-(3-(2-Methyl)-4-Oxo-3,4-Dihydroquinazolin-2-Ylthio)Acetohydrazides, Aamer Saeed, Shams-Ul Mahmood, Ulrich Flörke

Turkish Journal of Chemistry

A small library of new azomethine derivatives of 3-aryl-2-thioxo-2,3-dihydroquinazolin-4(1H)-ones was synthesized. The key intermediates 2-thioxo-quinazolinones (3a--e), obtained in 2 steps from the corresponding anilines, were treated with methyl chloroacetate to afford S-substituted esters (4a,d), which were then converted into corresponding acetohydrazides (5a,d). Further, acetohydrazide (5d) was converted to the azomethines derivatives (6a--k) by reacting with a number of suitably substituted benzaldehydes. FTIR, ^1H NMR, ^{13}C NMR, GC-MS, and elemental analyses were used to confirm the assigned structures of the synthesized compounds. Further, compounds 3a, 5, and 6j were also confirmed by X-ray diffraction data.

Calixpenams: Synthesis, Characterization, And Biological Evaluation Of Penicillins V And X Clustered By Calixarene Scaffold, Fazel Nasuhi Pur, Karim Akbari Dilmaghani

Turkish Journal of Chemistry

Four 6-aminopenicillanic acid moieties were grafted at either rim of calix[4]arene, giving 2 novel generations of penicillin, which were named calixpenam. Antibiotic tests showed that they have amplified activity with respect to the corresponding penams against 3 gram-positive nonpenicillinase-producing strains of Streptococcus.

Optimization Of Lifepo_4 Synthesis By Hydrothermal Method, Muhsi̇n Mazman, Ömür Çuhadar, Davut Uzun, Ercan Avci, Emre Bi̇çer, Tevhi̇t Cem Kaypmaz, Ümüt Kadi̇roğlu

Turkish Journal of Chemistry

Optimization of the LiFePO_4 cathode active material synthesis process in the hydrothermal method consists of many factors, including pH, carbon coating, particle size optimization, sintering and hydrothermal synthesis temperature. The main goal of this study is to determine the effect of particle size, pH and carbon coating on capacity and cycle performance. In this study, LiFePO_4 cathode active materials were prepared at different pH (6.5 and 8.5) and temperature (160 and 180 °C) levels using the hydrothermal method. The hydrothermal synthesis products were sintered at 400, 500, 600, and 700 °C with 5% and 7% carbon source. The initial discharge …

Platinum Or Nickel Nanoparticles Decorated On Silica Spheres By Microwave Irradiation Technique, Ayşe Bayrakçeken

Turkish Journal of Chemistry

Supported catalysts are of great interest because of their wide range of application possibilities. In this study, firstly silica spheres were synthesized and then platinum and nickel nanoparticles were incorporated on this silica by microwave irradiation, which is an efficient technique for catalyst preparation. Synthesized silica spheres and catalysts were characterized by BET, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy techniques. Pt or Ni nanoparticles well dispersed over silica support were obtained using microwave irradiation.

Synthesis And Characterization Of New Metallophthalocyanines Containing O_4s_2 Mixed-Donor Substituted Macrocyclic Groups, Meltem Betül Kiliçaslan, Hali̇t Kanteki̇n

Turkish Journal of Chemistry

New phthalocyanine compounds containing mixed-donor substituted macrocyclic groups were synthesized. The complexes of metal phthalocyanines 3--5 were prepared by the reaction of 2 to get dinitrile derivative complexes by means of the corresponding anhydrous metal salts. Structures of the new compounds were characterized by IR, ^1H NMR, ^{13}C NMR, elemental analysis, and MS spectral data.

A Study On The Elementary School Teachers’ Awareness Of Students’ Alternative Conceptions About Change Of States And Dissolution, Chanho Yang, Taehee Noh, Lawrence C. Scharmann, Sukjin Kang

Department of Teaching, Learning, and Teacher Education: Faculty Publications

Knowledge about students’ conceptions is one of the requisite components of pedagogical content knowledge. A keen awareness of students’ alternative conceptions provides teachers with information about prospective difficulties students may incur as they make attempts to learn more accurate scientific representations of critical concepts. In this study, we investigated elementary school teachers’ understanding of their students’ alternative conceptions about change of states and dissolution. The subjects were 152 elementary school teachers and 529 sixth graders in Korea. A conceptions test and the test of the understanding about students’ conceptions were administered in order to examine students’ alternative conceptions and the …

Geology, Mineralogy, Geochemistry, And Depositional Environment Of A Late Miocene/Pliocene Fluviolacustrine Succession, Cappadocian Volcanic Province, Central Anatolia, Turkey, Ersel Göz, Selahatti̇n Kadi̇r, Ali̇ Gürel, Muhsi̇n Eren

Turkish Journal of Earth Sciences

This paper investigates the mineralogy, geochemistry, and depositional environment of Late Miocene/Pliocene fluviolacustrine deposits, including multiple ignimbrite levels and andesitic and basaltic lavas, within the Cappadocian Volcanic Province (CVP) of central Anatolia, Turkey. Palaeosols and calcretes formed within these terrestrial sedimentary rocks under near-surface or surface conditions. The palaeosols are composed predominantly of smectite ± illite with feldspar, quartz, calcite, opal-CT, and amphibole, and the calcretes mainly of calcite with minor feldspar, quartz, and accessory smectite ± palygorskite. The palygorskite occurs on and between the calcite crystals in the calcretes and at the edges of smectite flakes within the palaeosols, …

Affinity Enrichment And Mass Spectrometric Quantitation Of Protein Carbonyls, Suresh Narayanasamy

Theses and Dissertations

The importance of the role of oxidative stress in aging and numerous age-related diseases has become undeniable due to enormous weight of supporting evidence from the field of free radical biology. One of the most prominent oxidative modifications of proteins is the introduction of carbonyl groups. As with oxidative stress, protein carbonylation has been correlated with various disease states and natural aging. While protein carbonyls are relatively stable, reproducible detection and modification site localization are still challenging. This thesis details attempts to improve the analytical methodology used for the identification and quantitation of carbonylated proteins. We have studied the impact …

Making Water Resource Decisions More "Informationally" Efficient: Development Of A Geospatial Water Rights Decision Support System For Kittitas County, Washington, Michael Pease

Geography Faculty Scholarship

In semi-arid river basins like the Yakima River Basin in central Washington State, United States of America, water demand can exceed available supply on an annual basis. More informed decisions about water supply and current allocation have the potential to improve water management. This research created a geospatial water rights database for the Yakima River Basin. The creation of a publicly available decision support system mapping water rights can provide water managers another tool to help achieve this goal. This paper describes the creation of the Decision Support System. In addition it looks at the current utility of the system, …

Rank-Based Two Sample Tests Under A General Alternative, Jamye Curry

Electronic Theses and Dissertations

The problem of testing whether two samples come from the same or different population is a classical one in statistics. In this dissertation, I first study rank based formulation of univariate two-sample distribution-free tests. One form of the test statistic is the average of between-group distances of ranks. The other form of the test statistic is the difference between the average of between-group distances of ranks and the average of within-group distances of ranks. Although they are different in formulation, they are closely related to the two-sample Cramer-von Mises criterion. The first one is a linear transformation of Cramer-von Mises …

For Better Or For Worse: Gender And The Congo Basin Forests, Jennifer M. Bangoura

Capstone Collection

Abstract Gender is increasingly an element of program design in international development and education. Given its inherent significance in cultures around the world, gender shapes and molds the ways in which we perceive the roles and responsibilities of men and women. This study seeks to understand the intersection of gender and natural resource management in the Central Africa region. In this region, where tradition often guides the roles men and women play both at home and in the work place, it is critical to understand the role of gender and how accounting for it in project design can both support, …

On An Extension Of Riordan Array And Its Application In The Construction Of Convolution-Type And Abel-Type Identities, Tian-Xiao He, Leetsch Hsu, Xing Ron Ma

Scholarship

Using the basic fact that any formal power series over the real or complex number field can always be expressed in terms of given polynomials {pn(t)}{pn(t)}, where pn(t)pn(t) is of degree nn, we extend the ordinary Riordan array (resp. Riordan group) to a generalized Riordan array (resp. generalized Riordan group) associated with {pn(t)}{pn(t)}. As new application of the latter, a rather general Vandermonde-type convolution formula and certain of its particular forms are presented. The construction of the Abel type identities using the generalized Riordan arrays is also discussed.

Hyperbolic Expressions Of Polynomial Sequences And Parametric Number Sequences Defined By Linear Recurrence Relations Of Order 2, Tian-Xiao He, Peter Shiue, Tsui-Wei Weng

Scholarship

A sequence of polynomial {an(x)} is called a function sequence of order 2 if it satisfies the linear recurrence relation of order 2: an(x) = p(x)an-1(x) + q(x)an-2(x) with initial conditions a0(x) and a1(x). In this paper we derive a parametric form of an(x) in terms of eθ with q(x) = B constant, inspired by Askey's and Ismail's works shown in [2] [6], and [18], respectively. With this method, we give the hyperbolic expressions of Chebyshev polynomials and Gegenbauer-Humbert Polynomials. The applications of the method to construct corresponding hyperbolic form of several well-known identities are also discussed in this paper.

Is Your Online Data Really Private?, Nathan Pitchaikani

A with Honors Projects

In the present age everyone depends on technology. At least once per day someone uses a machine to help them accomplish their tasks. For example, imagine not using a cell phone for a whole day. These days, machines contain personal information or data about their owner. In most cases this isn’t an issue. However, with technology becoming more advanced day by day, there has become a reason to worry. People are able to illegally enter other people’s computers and steal information. Leading to the point that being able to protect one’s personal data is crucial. Learning how to safeguard one’s …

Evaluation Of Modis Albedo Product (Mcd43a) Over Grassland, Agriculture And Forest Surface Types During Dormant And Snow-Covered Periods, Zhuosen Wang, Crystal B. Schaaf, Alan H. Strahler, Mark Chopping, Miguel O. Román, Yanmin Shuai, Curtis E. Woodcock, David Y. Hollinger, David R. Fitzjarrald

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study assesses the Moderate-resolution Imaging Spectroradiometer (MODIS) BRDF/albedo 8. day standard product and products from the daily Direct Broadcast BRDF/albedo algorithm, and shows that these products agree well with ground-based albedo measurements during the more difficult periods of vegetation dormancy and snow cover. Cropland, grassland, deciduous and coniferous forests are considered. Using an integrated validation strategy, analyses of the representativeness of the surface heterogeneity under both dormant and snow-covered situations are performed to decide whether direct comparisons between ground measurements and 500-m satellite observations can be made or whether finer spatial resolution airborne or spaceborne data are required to …

Modeling Rocket Flight In The Low-Friction Approximation, Logan White

Undergraduate Journal of Mathematical Modeling: One + Two

In a realistic model for rocket dynamics, in the presence of atmospheric drag and altitude-dependent gravity, the exact kinematic equation cannot be integrated in closed form; even when neglecting friction, the exact solution is a combination of elliptic functions of Jacobi type, which are not easy to use in a computational sense. This project provides a precise analysis of the various terms in the full equation (such as gravity, drag, and exhaust momentum), and the numerical ranges for which various approximations are accurate to within 1%. The analysis leads to optimal approximations expressed through elementary functions, which can be implemented …

Fukushima: A Model Study, Melinda Kathryn Mckell

Undergraduate Journal of Mathematical Modeling: One + Two

This article investigates the radiation dispersion modeling system available to Japanese authorities during the response phase of the Fukushima Dai-Ichi incident.

Quantum Harmonic Oscillator With Superoscillating Initial Datum, Roman V. Buniy, Fabrizio Colombo, Irene Sabadini, Daniele C. Struppa

Mathematics, Physics, and Computer Science Faculty Articles and Research

In this paper, we study the evolution of superoscillating initial data for the quantum driven harmonic oscillator. Our main result shows that superoscillations are amplified by the harmonic potential and that the analytic solution develops a singularity in finite time. We also show that for a large class of solutions of the Schrodinger equation, superoscillating behavior at any given time implies superoscillating behavior at any other time.

An Exploration Of “Non-Economic” Damages In Civil Jury Awards, Herbert M. Kritzer, Guangya Liu, Neil Vidmar

Faculty Scholarship

Using three primary data sources plus three supplemental sources discussed in an appendix, this paper examines how well non-economic damages could be predicted by economic damages and at how the ratio of non-economic damages to economic damages changed as the magnitude of the economic damages awarded by juries increased. We found a mixture of consistent and inconsistent patterns across our various datasets. One fairly consistent pattern was the tendency for the ratio of non-economic to economic damages to decline as the amount of economic damages increased. Moreover, the variability of the ratio also tended to decline as the amount of …

The Role Of Ugandan Women In Rural Agriculture And Food Security, Karen Ann Mckenna

Electronic Theses and Dissertations

Women engaged in small-scale rural agriculture in Iganga, Uganda for the purpose of household food security and/or income generation face a number of challenges to creating sustainable livelihoods. This analysis is presented in the form of a case study based on research conducted over the period of one year in Uganda between September 2012 and September 2013. Three conceptual orientations are used to guide the research, including sustainable livelihoods, gender and agricultural development, and food security. Pertinent economic, political, and social contexts are identified for each of these orientations. The author then identifies key challenges that women in Iganga face …

Probing Structure For Photophysical Properties Through Synthesis Of Novel Nucleosides, Brittney Jean Rodgers

Electronic Theses and Dissertations

A brief history of nucleosides and their photophysics provides the background information for the discussion of synthesis, photophysics and incorporation of fluorescent nucleotide analogs during enzymatic DNA synthesis. Through the use of nucleoside starting material, it is possible to synthesize a number of modified nucleotides for use as fluorescent probes in biochemical research. Synthetic endeavors into the synthesis of these and related molecules from nucleobase starting materials are also presented. The synthesis of these molecules involved re-development of the synthetic routes to broaden substrate scope by overcoming the changed reactivity resulting from the presence of additional functionality.

While many highly …

Topological Ramsey Spaces, Associated Ultrafilters, And Their Applications To The Tukey Theory Of Ultrafilters And Dedekind Cuts Of Nonstandard Arithmetic, Timothy Onofre Trujillo

Electronic Theses and Dissertations

This dissertation makes contributions to the areas of combinatorial set theory, the model theory of arithmetic, and the Tukey theory of ultrafilters. The main results are broken into three parts.

In the first part, we identify some new partition relations among finite trees and use them to answer an open question of Dobrinen; namely, "for n < omega, are the notions of Ramsey for Rn and selective for Rn equivalent?" We show that for each n < omega, it is consistent with ZFC that there exists a selective for Rn ultrafilter which is not Ramsey for Rn.

In the second part, we extend results of Blass concerning Dedekind cuts associated to ultrafilter mappings from p-point and weakly-Ramsey ultrafilters to ultrafilter mappings from Ramsey for R1 ultrafilters. Blass associates to each ultrafilter U on a countable set X and each function g …

An Empirical Comparison Of Reuse In Embedded And Nonembedded Systems, Julia F. Varnell-Sarjeant

Electronic Theses and Dissertations

High-quality software, delivered on time and budget, constitutes a critical part of most products and services in modern society. Our government has invested billions of dollars to develop software assets, often to redevelop the same capability many times. Recognizing the waste involved in redeveloping these assets, in 1992 the Department of Defense issued the Software Reuse Initiative.

The vision of the Software Reuse Initiative was "To drive the DoD software community from its current "re-invent the software" cycle to a process-driven, domain-specific, architecture-centric, library-based way of constructing software.'' Twenty years after issuing this initiative, there is evidence of this vision …

Size Dependent Translocation And Fetal Accumulation Of Gold Nanoparticles From Maternal Blood In The Rat, Manuela Semmler-Behnke, Jens Lipka, Alexander Wenk, Martin Schaeffer, Furong Tian, Gunter Schmid, Gunter Oberdorster, Wolfgang Kreyling

Articles

There is evidence that nanoparticles (NP) cross epithelial and endothelial body barriers. We hypothesized that gold (Au) NP, once in the blood circulation of pregnant rats, will cross the placental barrier during pregnancy size-dependently and accumulate in the fetal organism by 1. transcellular transport across the hemochorial placenta, 2. transcellular transport across amniotic membranes 3. transport through ~20 nm wide transtrophoblastic channels in a size dependent manner. The three AuNP sizes used to test this hypothesis are either well below, or of similar size or well above the diameters of the transtrophoblastic channels.