Physical Sciences and Mathematics Commons^™

Nano-Structured Materials For Energy Storage Applications, Dongxue Zhao

Doctoral Dissertations

"Hydrogen is a non-polluting and efficient energy carrier. One barrier to utilizing hydrogen is a reliable storage method. NaAlH₄ is the prototypical example of a complex metal hydride with high hydrogen storage capacities (~ 5.5 wt.%) and acceptable reaction temperatures of around 100⁰ when using catalyst. On decomposition of these complex hydrides, such as NaAlH₄, one is left with monohydride NaH. The kinetics of diffusion in the monohydrides is important because reversibility hinges on mass transport and the formation of [AlH₄]^- anions that must structurally coordinate with the alkali metal cation on hydrogen absorption. …

Robotics And The Lessons Of Cyberlaw, Ryan Calo

Articles

Two decades of analysis have produced a rich set of insights as to how the law should apply to the Internet’s peculiar characteristics. But, in the meantime, technology has not stood still. The same public and private institutions that developed the Internet, from the armed forces to search engines, have initiated a significant shift toward developing robotics and artificial intelligence.

This Article is the first to examine what the introduction of a new, equally transformative technology means for cyberlaw and policy. Robotics has a different set of essential qualities than the Internet and accordingly will raise distinct legal issues. Robotics …

Probing The Hydrodesulfurization Properties Of Nickel-Rich Bimetallic Phosphides: Supported Catalysts And Encapsulated Nanoparticles, Samuel J. Danforth

WWU Graduate School Collection

The need for improved hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) catalysts is being driven by increasingly demanding requirements for ultralow sulfur fuels and by the fact that sulfur levels in crude oil have been trending upward over recent decades. Current industrial catalysts are based on molybdenum sulfide (MoS₂) and its highly anisotropic structure severely limits the number of exposed active sites. Transition metal phosphides (e.g. Ni₂P/SiO₂) are a new class of materials with promise to have improved properties relative to sulfided Ni-Mo/Al₂O₃ catalysts. The addition of a second metal can have large …

The First Report Of Lewis Acid Reagents In The Intramolecular Rauhut-Currier Reaction, Andrew T. Krasley, William Paul Malachowski

Chemistry Faculty Research and Scholarship

The first report of Lewis acid use in intramolecular Rauhut-Currier reactions is described. Titanium Lewis acids lead to rapid Rauhut-Currier reactions in the case of two classic substrates. More importantly, titanium and tin Lewis acids were the only successful reagent for a more complex substrate, thereby illustrating the potential for Lewis acid reagents to facilitate challenging intramolecular Rauhut-Currier reactions that fail with traditional reagents.

The Enantioselective Construction Of Tetracyclic Diterpene Skeletons With Friedel-Crafts Alkylation And Palladium-Catalyzed Cycloalkenylation Reactions, Sarah J. Burke, William Paul Malachowski, Sharan K. Mehta, Roselyn Appenteng

Chemistry Faculty Research and Scholarship

Due to the profound extent to which natural products inspire medicinal chemists in drug discovery, there is demand for innovative syntheses of these often complex materials. This article describes the synthesis of tricarbocyclic natural product architectures through an extension of the enantioselective Birch-Cope sequence with intramolecular Friedel-Crafts alkylation reactions. Additionally, palladium-catalyzed enol silane cycloalkenylation of the tricarbocyclic structures afforded the challenging bicyclo[3.2.1]octane C/D ring system found in the gibberellins and the ent-kauranes, two natural products with diverse medicinal value. In the case of the ent-kaurane derivative, an unprecedented alkene rearrangement converted four alkene isomers to one final product.

Modeling The Impact Of Future Climate On Drainage Infrastructures, Tyler J. Baumbach

Electronic Theses and Dissertations

Research has shown a potential 20% increase in future heavy and extreme precipitation events over the Midwestern States. Drainage infrastructures designed using current design conditions may not be able to convey projected runoffs resulting in flooding and damage to infrastructure. The objective of this paper is to determine the effects of future climate variability on culvert selections in a southwest South Dakota watershed. The scope of the study was defined through a comprehensive literature review. Future climate events were based on a 20% increase in current annual precipitation over the Upper White River Subbasin Watershed. A portion of the White …

The Effects Of Chanellization And Channel Restoration On Aquatic Habitat And Biota Of The Pecos River, New Mexico, Darrel J. Mecham

Electronic Theses and Dissertations

River channelization has been shown to negatively impact riverine ecosystems by degrading aquatic habitat conditions, decreasing diversity of both fish and aquatic invertebrate assemblages and impairing fish recruitment. As knowledge of the negative impacts of channelization has increased, so have channel restoration efforts. We evaluated a recent channel restoration project on the Pecos River, New Mexico by comparing abiotic and biotic conditions among five reaches of river, including the restored reach, an unchannelized reach and a channelized reach all prone to streamflow intermittence and an unchannelized reach and channelized reach more perennial in nature. Our first objective was to assess …

Drivers Of Agricultural Land Use Change And Management Decisions In The Dakotas: The Influence Of Climate Change And Other Factors, Moses Luri

Electronic Theses and Dissertations

This thesis conducts a general assessment of the: main drivers of land use change; recent and projected land use patterns; and the evolution of agriculture in the Dakotas. Specifically, it determines the main motives of land use change in the Dakotas by investigating individual and joint effects of external drivers of land use change on farm operators’ decisions and also examines recent and projected agricultural land use patterns in the Dakotas. Farm operators’ perceptions about the evolution of agriculture in the Dakotas based on observed changes in their local area were also analyzed. The study region consists of 37 counties …

Α-Discounting Method For Multi-Criteria Decision Making (Α-D Mcdm), Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

In this book we introduce a new procedure called αDiscounting Method for Multi-Criteria Decision Making (α-D MCDM), which is as an alternative and extension of Saaty’s Analytical Hierarchy Process (AHP). It works for any number of preferences that can be transformed into a system of homogeneous linear equations. A degree of consistency (and implicitly a degree of inconsistency) of a decision-making problem are defined. α-D MCDM is afterwards generalized to a set of preferences that can be transformed into a system of linear and/or non-linear homogeneous and/or nonhomogeneous equations and/or inequalities. Many consistent, weak inconsistent, and strong inconsistent examples are …

Symbolic Neutrosophic Theory, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

Symbolic (or Literal) Neutrosophic Theory is referring to the use of abstract symbols (i.e. the letters T, I, F, or their refined indexed letters T_j, I_k, F_l) in neutrosophics.

In the first chapter we extend the dialectical triad thesis-antithesis-synthesis (dynamics of A and antiA, to get a synthesis) to the neutrosophic tetrad thesis-antithesis-neutrothesis-neutrosynthesis (dynamics of A, antiA, and neutA, in order to get a neutrosynthesis).

In the second chapter we introduce the neutrosophic system and neutrosophic dynamic system. A neutrosophic system is a quasi- or –classical system, in the sense that the neutrosophic …

Mod Functions: A New Approach To Function Theory, Florentin Smarandache, W.B. Vasantha Kandasamy, K. Ilanthenral

Branch Mathematics and Statistics Faculty and Staff Publications

In this book the notion of MOD functions are defined on MOD planes. This new concept of MOD functions behaves in a very different way. Even very simple functions like y = nx has several zeros in MOD planes where as they are nice single line graphs with only (0, 0) as the only zero. Further polynomials in MOD planes do not in general follows the usual or classical laws of differentiation or integration. Even finding roots of MOD polynomials happens to be very difficult as they do not follow the fundamental theorem of algebra, viz a nth degree polynomial …

Probleme De Geometrie Și Trigonometrie, Compilate Și Rezolvate, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

No abstract provided.

Euclid Squares On Infinite Planes, Florentin Smarandache, W.B. Vasantha Kandasamy, K. Ilanthenral

Branch Mathematics and Statistics Faculty and Staff Publications

In this book for the first time the authors study the new type of Euclid squares in various planes like real plane, complex plane, dual number plane, special dual like number plane and special quasi dual number plane. There are six such planes and they behave distinctly. From the study it is revealed that each type of squares behave in a different way depending on the plane. We define several types of algebraic structures on them. Such study is new, innovative and interesting. However for some types of squares; one is not in a position to define product. Further under …

Low Effort Crowdsourcing: Leveraging Peripheral Attention For Crowd Work, Vaish Rajan, Peter Organisciak, Kotaro Hara, Jeffrey P. Bigham, Haoqi Zhang

Research Collection School Of Computing and Information Systems

Crowdsourcing systems leverage short bursts of focusedattention from many contributors to achieve a goal. Byrequiring people’s full attention, existing crowdsourcingsystems fail to leverage people’s cognitive surplus in themany settings for which they may be distracted, performingor waiting to perform another task, or barely payingattention. In this paper, we study opportunities for loweffortcrowdsourcing that enable people to contribute toproblem solving in such settings. We discuss the designspace for low-effort crowdsourcing, and through a seriesof prototypes, demonstrate interaction techniques, mechanisms,and emerging principles for enabling low-effortcrowdsourcing.

Forage Seed Quality: Dormancy, Standards And Quarantine, John G. Hampton

IGC Proceedings (1993-2023)

There are many dimensions to the concept of seed quality. Viable seed which will not germinate when provided with all the requirements for germination is dormant. Forage grasses mostly exhibit non-deep physiological dormancy (PD), while physical dormancy (PY) is common in forage legumes where imbibition is prevented by the seed coat’s impermeability to water (hard seed). Methods for breaking PD and PY to allow germination testing and/or crop establishment are discussed.

In the seed industry seed quality standards are an important feature of quality assurance and may apply for seed production contracts, seed certification, seed sale and seed importing. Standards …

Socio-Cultural Factors Challenging Development Interventions In Cattle Production In The Remote Areas Of Vietnam, Duong-Nam Ha, Pham-Van Hung, Tran-The Cuong, Ninh-Xuan Trung, Tran-Van Long, Laurie Bonney, Peter A. Lane, Guillaume Duteurtre, Stephen Ives

IGC Proceedings (1993-2023)

The northwest highlands of Vietnam are characterized by high altitude, low infrastructure, and low population densities composed of a wide diversity of different ethnic groups. Their socio-cultural characteristics strongly influence their lifestyle and production systems, including agricultural activities. The majority of these people have suffered from slow economic development, with the highest poverty rate in the country. This is a real need for plausible interventions where behavioral changes of smallholders throughout local value chains would be a critical foundation. Our project implemented in this context of development in the Northwest highlands of Vietnam aims to understand the role of socio-cultural …

Genomic Approaches For Dissecting Complex Traits Related To Quality Production Of Range Grasses, Masumi Ebina

IGC Proceedings (1993-2023)

Tropical grasses have been widely used as warm-season forage grasses in the warm temperate zone since the early 20th century because of their high yields; they have also been used as perennial forages in their native tropical areas. Increasing demand for animal production sparked by economic development in tropical countries is requiring breeders to improve native forage grasses in these countries. Considerable efforts have been made to breed accessions with improved characteristics and to develop new cultivars. However, cross-breeding is not common, owing to a lack of genetic information and to complexities related to polyploidy, high sterility rates, outcrossing, and …

Climate Change Impact And Adaptation In Temperate Grassland And Livestock Industries, Afshin Ghahramani, Andrew D. Moore

IGC Proceedings (1993-2023)

Climate is projected to have negative impact on temperate grassland and livestock productions across the globe. Moderately elevated atmospheric CO₂ in the near future is expected to increase plant photosynthetic rates but this is likely to be limited by soil nitrogen deficits. However, in Australia at least it is unlikely that positive effect of elevated CO₂ on plant production be able to offset the negative impacts of climate change. Currently there is a considerable gap between actual and achievable production and profit in Australian grazing systems and many management and genetic improvements for climate adaptation would operate by …

High-Altitude Grassland Management And Improvement Of Pastoral Livelihoods In The Hindu Kush Himalayan Region, Eklabya Sharma

IGC Proceedings (1993-2023)

The Hindu Kush Himalayan (HKH) region is the largest mountain systems in the world, spanning over 4.3 million km2 and covering 3500 km long fragile environment. Grasslands in the HKH region are the source of livelihoods for approximately 25 to 30 million pastoralists and agro-pastoralists. High altitude grasslands play a significant role in storage and regulation of water; storage of carbon in soil and peat lands; permafrost storage; and stabilization of climate, soil, and nutrients. They foster a rich biodiversity with endemic species of fauna and flora; provide clean air and open spaces for recreational purposes, and bolster a rich …

About Sponsors, National Organizing Committee, International Grassland Congress

IGC Proceedings (1993-2023)

No abstract provided.

Reputationpro: The Efficient Approaches To Contextual Transaction Trust Computation In E-Commerce Environments, Haibin Zhang, Yan Wang, Xiuzhen Zhang, Ee Peng Lim

Research Collection School Of Computing and Information Systems

In e-commerce environments, the trustworthiness of a seller is utterly important to potential buyers, especially when a seller is not known to them. Most existing trust evaluation models compute a single value to reflect the general trustworthiness of a seller without taking any transaction context information into account. With such a result as the indication of reputation, a buyer may be easily deceived by a malicious seller in a transaction where the notorious value imbalance problem is involved—in other words, a malicious seller accumulates a high-level reputation by selling cheap products and then deceives buyers by inducing them to purchase …

An Adaptive Gradient Method For Online Auc Maximization, Yi Ding, Peilin Zhao, Steven C. H. Hoi, Yew-Soon Ong

Research Collection School Of Computing and Information Systems

Learning for maximizing AUC performance is an important research problem in machine learning. Unlike traditional batch learning methods for maximizing AUC which often suffer from poor scalability, recent years have witnessed some emerging studies that attempt to maximize AUC by single-pass online learning approaches. Despite their encouraging results reported, the existing online AUC maximization algorithms often adopt simple stochastic gradient descent approaches, which fail to exploit the geometry knowledge of the data observed in the online learning process, and thus could suffer from relatively slow convergence. To overcome the limitation of the existing studies, in this paper, we propose a …

Semi-Universal Portfolios With Transaction Costs, Dingjiang Huang, Yan Zhu, Bin Li, Shuigeng Zhou, Steven C. H. Hoi

Research Collection School Of Computing and Information Systems

Online portfolio selection (PS) has been extensively studied in artificial intelligence and machine learning communities in recent years. An important practical issue of online PS is transaction cost, which is unavoidable and nontrivial in real financial trading markets. Most existing strategies, such as universal portfolio (UP) based strategies, often rebalance their target portfolio vectors at every investment period, and thus the total transaction cost increases rapidly and the final cumulative wealth degrades severely. To overcome the limitation, in this paper we investigate new investment strategies that rebalances its portfolio only at some selected instants. Specifically, we design a novel on-line …

Genetic Differentiation And Phylogeography Of Partially Sympatric Species Complex Rhizophora Mucronata Lam. And R. Stylosa Griff. Using Ssr Markers, Severino G. Salmo Iii, Alison K.S Wee, Koji Takayama, Jasher L. Chua, Takeshi Asakawa, Sankararamasubramanian H. Meenakshisundaram, Onrizal Onrizal, Bayu Adjie, Erwin Riyanto Ardli, Sarawood Saengkaw, Norhaslinda Binti Malekal, Nguyen Xuan Tung, Orlex Baylen Yllano, Mohd Nazre Saleh, Khin Khin Soe, Yoichi Tateichi, Yasuyuki Watano, Shigeyuki Baba, Edward L. Webb, Tadashi Kajita

Environmental Science Faculty Publications

Background

Mangrove forests are ecologically important but globally threatened intertidal plant communities. Effective mangrove conservation requires the determination of species identity, management units, and genetic structure. Here, we investigate the genetic distinctiveness and genetic structure of an iconic but yet taxonomically confusing species complex Rhizophora mucronata and R. stylosa across their distributional range, by employing a suite of 20 informative nuclear SSR markers.

Results

Our results demonstrated the general genetic distinctiveness of R. mucronata and R. stylosa, and potential hybridization or introgression between them. We investigated the population genetics of each species without the putative hybrids, and found strong …

Mod Pseudo Linear Algebras, Florentin Smarandache, W.B. Vasantha Kandasamy, K. Ilanthenral

Branch Mathematics and Statistics Faculty and Staff Publications

In this book authors for the first time elaborately study the notion of MOD vector spaces and MOD pseudo linear algebras. This study is new, innovative and leaves several open conjectures. In the first place as distributive law is not true we can define only MOD pseudo linear algebras. Secondly most of the classical theorems true in case of linear algebras are not true in case of MOD pseudo linear algebras. Finding even eigen values and eigen vectors happens to be a challenging problem. Further the notion of multidimensional MOD pseudo linear algebras are defined using the notion of MOD …

Theory Of Abel Grassmann's Groupoids, Florentin Smarandache, Madad Khan

Branch Mathematics and Statistics Faculty and Staff Publications

It is common knowledge that common models with their limited boundaries of truth and falsehood are not su¢ cient to detect the reality so there is a need to discover other systems which are able to address the daily life problems. In every branch of science problems arise which abound with uncertainties and impaction. Some of these problems are related to human life, some others are subjective while others are objective and classical methods are not su¢ cient to solve such problems because they can not handle various ambiguities involved. To overcome this problem, Zadeh [67] introduced the concept of …

Front Matter [23rd International Grassland Congress Proceedings], National Organizing Committee, International Grassland Congress

IGC Proceedings (1993-2023)

No abstract provided.

Tropical Grasslands--Trends, Perspectives And Future Prospects, Panjab Singh

IGC Proceedings (1993-2023)

This paper attempts a rapid summary of the present day state of tropical grassland and livestock based production systems globally, especially in tropics, in relation to recent trends, future assessment, grassland rehabilitation and management strategies, future perspectives of grassland science and development including policy imperatives.

Development Of Boron-Containing Polyimide Materials And Poly(Arylene Ether)S For Radiation Shielding, Brittani May Collins

Dissertations, Theses, and Masters Projects

No abstract provided.

Enhancing Bug Reports For Mobile Apps, Kevin Patrick Moran

Dissertations, Theses, and Masters Projects

No abstract provided.