Physical Sciences and Mathematics Commons^™

Supramolecular Coordination Networks Of S- And F-Block Metals Featuring The 1,8-Naphthalimide Tecton, Andrew Paul Leitner

Theses and Dissertations

The reactions of (S)-2-(1,8-naphthalimido)propanoic acid (HLala), and (S)-2-(1,8- naphthalimido)-3-hydroxypropanoic acid (HLser), protonated forms of ligands that contain a carboxylate donor group, an enantiopure chiral center and a 1,8-naphthalimide π...π stacking supramolecular tecton and in the case of HLser an alcohol functional group, with the appropriate alkali metal hydroxide followed by a variety of crystallization methods leads to the formation of crystalline K(Lala)(MeOH) (1), K(Lala)(H2O) (2), Na(Lala)(H2O) (3), KLser (4), CsLser (5) and CsLala (6). Each of these new complexes has a solid state structure based on six-coordinate metals linked into homochiral helical rod SBU central cores. In addition to the …

Fast Methods For Variable-Coefficient Peridynamic And Non-Local Diffusion Models, Che Wang

Theses and Dissertations

In previous studies, scientists developed the classical solid mechanic theory. The model has been widely used in scientific research and practical production. The main assumption of the classical theory of solid mechanics is that all internal forces act through zero distance. Because of this assumption, the mathematical model always leads to partial differential equations, which meet with problems when describing the spontaneous formation of discontinuities and other singularities. A peridynamic model was proposed as a reformation of solid mechanics [40, 41, 43, 44, 45], which leads to a non-local framework that does not explicitly involve the notion of deformation gradients, …

A Survey Of The Kinetic Monte Carlo Algorithm As Applied To A Multicellular System, Michael Richard Laughlin

Theses and Dissertations

We explore the origins and implementation of the Kinetic Monte Carlo method on a system of cells suspended in a liquid media. The situation presented herein has applications in the emerging field of biofabrication, which may have lasting impacts in medical science. The theory behind the method is explained in detail, starting with its emergence in the 1960s, and two major improvements to the scaling of the method are presented, along with a restriction to a special case. Finally, we give the results of several simulations.

Comparing The Geography Of Environmental Justice Guidelines, Fish Consumption Waterbodies, And Land Use/Land Cover In South Carolina, Matthew James Neet

Theses and Dissertations

Environmental justice (EJ) grew out of the Civil Rights movement of the 1960s, as well as grass roots organizations during the 1980s and early 1990s. However, it was not until President William J. Clinton signed Executive Order (EO) 12898 in 1994 that EJ became an official governmental policy. With this directive, federal agencies made EJ part of their daily operations. EO 12898 had two overriding goals, the fair treatment and meaningful involvement of all populations. As part of these goals, minority, low-income, and native populations would be analyzed for any disproportionate and adverse impacts on human or environmental health. Despite …

Modeling, Simulation, And Applications Of Fractional Partial Differential Equations, Wilson Cheung

Theses and Dissertations

The Black-Scholes model is commonly used to track the price of European options with respect to maturity in many financial markets. This model degenerates into a partial differential equation that relates the European-style option price to the underlying price and time of expiry. Black-Scholes assumes that underlying prices satisfy a geometric Brownian motion.

After the U.S. stock market crash of 1987, this assumption becomes inaccurate as it fails to represent the behavior of S&P 500 European vanilla option prices. Specifically, under the measure of moneyness, the volatility smirk does not flatten out and the resulting conditional return distribution does not …

Next-Generation Scientists Get A Taste Of Their Future Careers, Patrick M. Edwards, Linda A. George, Matthew Mctammany

Environmental Science and Management Faculty Publications and Presentations

Article provides an overview of the middle and high school poster session that took place during the 2014 Joint Aquatic Sciences Meeting (JASM) in Portland, Oregon. The poster session provided the students with opportunity to participate in the research process and prepare their posters.

Needs Assessment: A Report On Seven Focus Groups In Ohio, Kevin O'Brien, Daniel Baracskay, Wendy Kellogg, Michael Mcgoun, Claudette Robey, Michael Tevesz, Kirstin Toth

Michael J. Tevesz

A series of seven focus groups were conducted in various locations throughout northern Ohio to identify and assess coastal resources management training needs across the Ohio Great Lakes basin. The focus groups were comprised of a cross-section of professionals who make decisions affecting watershed areas or Lake Erie coastal areas. Six of the focus groups included decision-makers considered previous and potential users of coastal resources management training (non-providers). A seventh focus group included decision-makers who provide training in coastal resources management (providers).

Spectroscopic And Functional Characterization Of The Nitric Oxide Adducts Of The Fe(Iii) And Fe(Ii) States Of The Co-Sensing Transcription Factor, Cooa, From Carboxydothermus Hydrogenoformans, Robert Clark, Edra Jani, Arathi Francis, Elise Laroche, Isabel Malone

Robert Clark

CooA is a carbon monoxide (CO) sensing transcription factor that is found in several bacteria and regulates CO metabolism. CO binding to CooA’s heme groups initiates a conformation change that activates protein DNA binding. This study investigates the reaction of Fe(III) Carboxydothermus hydrogenoformansCooA (Ch CooA) with nitric oxide (NO). Previously, Clark and coworkers reported Fe(II) Ch CooA bound NO to form a 6-coordinate (6-C) Fe(II)-NO adduct that was active for DNA binding in vivo and in vitro. This is in contrast to the best studied CooA homolog from R. rubrum (Rr) that was exquisitely specific for CO and formed an …

The Effect Of Latency On User Performance In Warcraft Iii, Nathan Sledon, Eric Girard, Seth Borg, Mark Claypool, Emmanuel Agu

Emmanuel O. Agu

Variable latency on the Internet is a well-known problem for interactive applications. With the increase in interactive network games comes the increased importance of understanding the effects of latency on user performance. Classes of network games such as First Person Shooters (FPS) and Read Time Strategy (RTS) differ in their user interaction model and hence susceptibility to variable latency. While previous work has measured the effects of latency on FPS games, there has been no systematic investigation of the effects of latency on RTS games. In this work, we design and conduct user studies that measure the impact of latency …

Low Delay Marking For Tcp In Wireless Ad Hoc Networks, Choong-Soo Lee, Mingzhe Li, Emmanuel Agu, Mark Claypool, Robert Kinicki

Emmanuel O. Agu

End-hosts on wireless ad hoc networks typically use TCP as their transport layer protocol. Being designed for wired networks, TCP can perform poorly over wireless networks. Work that has proposed ways to improve TCP performance over wireless networks has concentrated primarily on improving TCP throughput only. Emerging applications, such as interactive multimedia and network games, require reduced delay at least as much as increased throughput. In this paper, we propose LDM1, an IP layer queue marking mechanism that estimates the number of hops and flows at each wireless node to computes the optimal marking probability. We present simulation results and …

Full Isolation Number Of Matrices: Some Extremal Results, David Tate, David Brown

David C. Brown

A set of nonzero entries of a (0,1)-matrix is an isolated set if no two entries belong to the same row, no two entries belong to the same column, and no two entries belong to a submatrix of the form [1 1; 1 1]. The isolation number of a matrix is the maximum size over all isolated sets. The isolation number of a matrix is a well-known and well-used lower bound for the matrix's Boolean rank. We will discuss the isolation number of the adjacency matrix of various graphs and develop some extremal results for n x n matrices with …

Use Of Cryoelectronics To Reduce Power Losses, Christopher Hawley, Steve Gower, Dominic Cuiuri

Dominic Cuiuri

The operational characteristics of power electronics operating at ambient temperatures are well known. Less well known are the characteristics of these devices when operating at cryogenic temperatures. This emerging field is known as cryoelectronics. The primary driver for operation at reduced temperatures is the promise of a resultant reduction in device operation losses. The operating characteristics of Metal Oxide Silicon Field Effect Transistors (MOSFETs) and Insulated Gate Bipolar Transistors (IGBTs) at Liquid Nitrogen (LN) temperature have been experimentally analysed. The results have been used to evaluate the viability of using cryoelectronics in medium - high power applications, considering trade-offs between …

Time-Partitioned Index Design For Adaptive Multi-Route Data Stream Systems Utilizing Heavy Hitter Algorithms, Karen Works, Elke Rundensteiner, Emmanuel Agu

Emmanuel O. Agu

Adaptive multi-route query processing (AMR) is a recently emerging paradigm for processing stream queries in highly fluctuating environments. AMR dynamically routes batches of tuples to operators in the query network based on routing criteria and up-to-date system statistics. In the context of AMR systems, indexing, a core technology for efficient stream processing, has received little attention. Indexing in AMR systems is demanding as indices must adapt to serve continuously evolving query paths while maintaining index content under high volumes of data. Our proposed Adaptive Multi-Route Index (AMRI) employs a bitmap time-partitioned design that while being versatile in serving a diverse …

Harmonic Allocation Following Iec Guidelines Using The Voltage Droop Concept, V. Gosbell, Robert Barr

Robert Barr

Present IEC guidelines are difficult to apply to realistic cases because of the data load, the number of assumptions required and the computational complexity. A new approach is given based on the concept of voltage droop, to be detailed in a companion paper. The benefits of the approach are a simple calculation with minimal data and no required assumptions. It applies to radial or meshed distribution systems where feeders are sufficiently short that line capacitance can be ignored. The approach can be applied at the installation (MV or LV) and the equipment level and can be used to give reference …

New Exactly Solvable Hamiltonians - Shape Invariance And Self-Similarity, David Barclay, Ranabir Dutt, Asim Gangopadhyaya, Avinash Khare, A. Pagnamenta, Uday Sukhatne

Asim Gangopadhyaya

We discuss in some detail the self-similar potentials of Shabat and Spiridonov which are reflectionless and have an infinite number of bound states. We demonstrate that these self-similar potentials are in fact shape invariant potentials within the formalism of supersymmetric quantum mechanics. In particular, using a scaling ansatz for the change of parameters, we obtain a large class of new, reflectionless, shape invariant potentials of which the Shabat-Spiridonov ones are a special case. These new potentials can be viewed as q-deformations of the single soliton solution corresponding to the Rosen-Morse potential. Explicit expressions for the energy eigenvalues, eigenfunctions and transmission …

Performance Enhancement Of Tfrc In Wireless Networks, Mingzhe Li, Emmanuel Agu, Mark Claypool, Robert Kinicki

Emmanuel O. Agu

The TCP-Friendly Rate Control (TFRC) is used as a streaming media transport protocol. Using the TCP congestion response function and current network conditions, TFRC adjusts its transmission rate to yield the maximum TCP-Friendly throughput when sharing capacity with TCP flows. Since TFRC was designed for wired networks, it does not achieve the maximum TCP-Friendly throughput in multihop ad hoc wireless networks. The reduced wireless spatial channel reuse due to hidden terminals in multihop wireless networks induces TFRC throughput reductions. Specifically, TFRC is unaware of MAC layer transmission delays due to collisions, retransmissions and MAC layer congestion. This paper illustrates that …

Nilgai Antelope In Northern Mexico As A Possible Carrier For Cattle Fever Ticks And Babesia Bovis And Babesia Bigemina., E Cardenas-Canales, J. Alfonso Ortega-Santos, Tyler A. Campbell, Zeferino Garcia-Vaquez, Antonio Cantu-Covarrubias, Julio Figueroa-Millian, Randy W. Deyoung, David G. Hewitt, Fred Bryant

Fred B. Bryant

Of 20 blood samples from nilgais from Me´ xico, five were polymerase chain reaction-positive for Babesia bigemina and one for Babesia bovis. Positive samples had the expected 170 (B. bigemina) and 291 (B. bovis) base pairs and were identical to Gen-Bank B. bigemina accession S45366 and B. bovis M38218.

Generation Of A Complete Set Of Additive Shape-Invariant Potentials From An Euler Equation, Jonathan Bougie, Asim Gangopadhyaya, Jeffrey Mallow

Asim Gangopadhyaya

In supersymmetric quantum mechanics, shape invariance is a sufficient condition for solvability. We show that all conventional additive shape-invariant superpotentials that are independent of ħ can be generated from two partial differential equations. One of these is equivalent to the one-dimensional Euler equation expressing momentum conservation for inviscid fluid flow, and it is closed by the other. We solve these equations, generate the set of all conventional shape-invariant superpotentials, and show that there are no others in this category. We then develop an algorithm for generating all additive shape-invariant superpotentials including those that depend on ħ explicitly.

Supersymmetry And The Tunneling Problem In An Asymmetric Double Well, Asim Gangopadhyaya, Prasanta Panigrahi, Uday Sukhatne

Asim Gangopadhyaya

The techniques of supersymmetric quantum mechanics are applied to the calculation of the energy difference between the ground state and the first excited state of an asymmetric double well. This splitting, originating from the tunneling effect, is computed via a systematic, rapidly converging perturbation expansion. Perturbative calculations to any order can be easily carried out using a logarithmic perturbation theory. Our approach yield substantially better results than alternative widely used semiclassical analyses.

Mechanism Of Redox- And Co-Sensing By The Heme Protein, Cooa: Cryoradiolysis Studies, Robert Clark, Deanna Kalafut

Robert Clark

Gas-sensing heme proteins participate in a variety of signal-transduction mechanisms across a broad range of biological systems. This class of proteins functions by undergoing an allosteric conformational change in response to the binding of a small gas molecule to a heme group. CooA, which is a redox- and CO-sensing transcription factor that is found in several bacteria, regulates gene expression that enables growth on CO as a sole energy source. In the current study, we have employed the technique of gamma-irradiation / cryoreduction spectroscopy (cryoradiolysis) to investigate facile changes that occur to the heme coordination structure of CooA during activation. …

Holocene Climatic Change And Past Irish Societal Response, David Brown, M. Baillie, J. Palmer, Christian Turney

David C. Brown

No abstract provided.

Discovering A Research Agenda For Using Design Rationale In Software Maintenance, Janet Burge, David Brown

David C. Brown

Design Rationale consists of the reasons behind decisions made while designing. This information would be particularly useful during software maintenance. In this paper, we describe a study performed to investigate the content, structure, and use of design rationale during maintenance. The major goal of this study was to discover an agenda for further research into the use of design rationale for software maintenance.

Measuring The Performance Gains From Directional Antennas In An Unplanned 802.11b Mesh Network, Jason Wilson, Patrick Gemme, Emmanuel Agu

Emmanuel O. Agu

Wireless mesh networks are becoming increasingly popular. Most proposed mesh algorithms are evaluated using simulation. Simulations frequently oversimplify real world scenarios and can lead to results that are significantly different. Thus, although it is more difficult to run controlled experiments in already deployed real-world networks, it is important to understand how proposed improvements perform under these realistic scenarios. Several authors have suggested the use of directional antennas, but their merits have only comprehensively evaluated in simulators. Roofnet is an unplanned 802.11b wireless mesh network deployed by MIT and is constructed primarily of omni-directional antennas. We use measurements to evaluate performance …

Inferring Unobservable Learning Variables From Students’ Help Seeking Behavior, Ivon Arroyo

Ivon Arroyo

Results of an evaluation of students’ attitudes and their relationship to student behaviors within a tutoring system are presented. Starting from a correlation analysis that integrates survey-collected student attitudes, learning variables, and behaviors while using the tutor, we constructed a Bayesian Network that infers attitudes and perceptions towards help and the tutoring system.

Coastal Resources Management Training Needs Assessment: Strategies And Opportunities, Kevin O'Brien, Claudette Robey, Wendy Kellogg, Michael Tevesz

Michael J. Tevesz

The Old Woman Creek National Estuarine Research Reserve (OWC), Ohio Department of Natural Resources-Coastal Management Program (ODNRCMP), and Ohio Sea Grant College Program engaged the Great Lakes Environmental Finance Center (GLEFC) to aid them in developing a coastal resources management training initiative for Ohio coastal decision-makers. Coastal decision-maker professionals are expected to formulate effective strategies and apply interdisciplinary approaches to solving problems and policy issues that affect the environments of coastal regions. There are a number of professionals in a variety of occupations who make decisions regarding coastal and environmental policy issues. These individuals include those within the coastal resources …

Silica-Bound Copper(Ii) Triazacyclononane As A Phosphate Esterase: Effect Of Linker Length And Surface Hydrophobicity, Brett Bodsgard, Robert Clark, Anthony Ehrbar, Judith Burstyn

Robert Clark

A series of silica-bound Cu(II) triazacyclononane materials was prepared to study the effect of linker length and surface hydrophobicity on the hydrolysis of phosphate esters. The general synthetic approach for these heterogeneous reagents was rhodium-catalyzed hydrosilation between an alkenyl-modified triazacyclononane and hydride-modified silica followed by metallation with a Cu(II) salt. Elemental analysis confirmed that organic functionalization of the silica gel was successful and provided an estimate of the surface concentration of triazacyclononane. EPR spectra were consistent with square pyramidal Cu(II), indicating that Cu(II) ions were bound to the immobilized macrocycles. The hydrolytic efficacies of these heterogeneous reagents were tested with …

Magnet Traveling Through A Conducting Pipe: A Variation On The Analytical Approach, Benjamin Irvine, Matthew Kemnetz, Asim Gangopadhyaya, Thomas Ruubel

Asim Gangopadhyaya

We present an analytical study of magnetic damping. In particular, we investigate the dynamics of a cylindrical neodymium magnet as it moves through a conducting tube. Owing to the very high degree of uniformity of the magnetization for neodymium magnets, we are able to provide completely analytical results for the electromotive force generated in the pipe and the consequent retarding force. Our analytical expressions are shown to have excellent agreement with experimental observations.

Noncentral Potentials And Spherical Harmonics Using Supersymmetry And Shape Invariance, Ranabir Dutt, Asim Gangopadhyaya, Uday Sukhatne

Asim Gangopadhyaya

It is shown that the operator methods of supersymmetric quantum mechanics and the concept of shape invariance can profitably be used to derive properties of spherical harmonics in a simple way. The same operator techniques can also be applied to several problems with noncentral vector and scalar potentials. As examples, we analyze the bound state spectra of an electron in a Coulomb plus an Aharonov – Bohm field and/or in the magnetic field of a Dirac monopole.

Isomer Distribution Of Succinylcyclohexenyl, Acetylcyclohexenyl And Acetylcyclopentenyl Enamines, A. Cook, Sarah Folk

A. Gilbert Cook

The isomeric distributions of some cyclohexenyl enamines substituted by succinyl or acetyl groups at either the 2- or 6-positions are reported as are the isomeric distributions of similarly substituted cyclopentenyl enamines. Correlation between the C-13 NMR chemical shifts in these enamines and isomer distribution is shown. Density functional molecular modeling is used to demonstrate resonance and electrostatic effects on isomeric distributions.

Mobile Mud Dynamics In The East China Sea Elucidated Using 210pb, 137cs, 7be, And 234th As Tracers, Jinlong Wang, Jinzhou Du, Mark Baskaran, Jing Zhang

Environmental Science and Geology Faculty Research Publications

“Mobile mud” (MM), which has fine grain size distribution (>90% clay + silt, and <5% sand) and high porosity (≥0.50), plays an important role in the biogeochemical cycles in the estuarine areas and the inshore shelf. A suite of MM samples from the coastal area of the East China Sea (ECS) was collected in spring and summer of 2011 to observe their spatial and temporal distribution, grain size, and radionuclides concentrations. The MM thickness ranged from 0.5 to 11 cm (average: 2.2 cm (May) and 3.9 cm (August)). The thick mud layer is mainly distributed along the coast, with an area of 2.2 × 104 km2 in May and 1.5 × 104 km2 in August, with corresponding masses of 8.8 × 108 and 7.8 × 108 t, respectively. The estimated masses of MM are considerably larger than the annual sediment discharge mass of the Changjiang River. The distribution of 137Cs inventories in MM indicates that 137Cs can be effectively utilized as a transport tracer of MM in the river‐dominated estuaries and coastal areas. The higher inventories of 7Be in MM in the river mouth in spring are attributed to higher depositional flux and higher sediment discharge. The ratio of the MM inventory of 234Thex/production in the overlying water column of >2.5 in south inshore indicates that the sediment focusing resulted in the increased mass flux. The residence time of MM is estimated as 3–6 years both by mass balance of MM and 210Pbex in MM.