Physical Sciences and Mathematics Commons^™

Electrically Conductive Polyaniline Sensitized Defective-Tio2 For Improved Visible Light Photocatalytic And Photoelectrochemical Performance: A Synergistic Effect, M O. Ansari, Mohammad Mansoob Khan Dr, S A. Ansari, M H. Cho

Dr. Mohammad Mansoob Khan

Sulfonated polyaniline@pure-TiO2 (s-Pani@p-TiO2) and polyaniline@defective-TiO2 (s-Pani@m-TiO2) nanocomposites were prepared by the in-situ oxidative polymerization of aniline in the presence of TiO2 (p-TiO2 and m-TiO2) nanoparticles followed by sulfonation with fuming sulfuric acid. Defect-induced TiO2 (m-TiO2) nanoparticles were obtained by an electron beam (EB) treatment of commercial TiO2 (p-TiO2) nanoparticles. The resulting s-Pani@p-TiO2 and s-Pani@m-TiO2 nanocomposites were characterized by UV-visible diffuse absorbance spectroscopy, photoluminescence spectroscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Polyaniline (Pani) was dispersed uniformly over the defective m-TiO2 surface with intimate contact on the interface to act cooperatively with the defects introduced deliberately to achieve remarkably …

Large-Scale And High-Resolution 3-D Cave Mapping By Terrestrial Laser Scanning: A Case Study Of The Domica Cave, Slovakia, Michal Gallay, Ján Kaňuk, Zdenko Hochmuth, John D. Meneely, Jaroslav Hofierka, Vladimír Sedlák

International Journal of Speleology

Mapping and modelling the complicated geometry of caves is a challenging task that has traditionally been undertaken by tacheometric surveying methods. These methods are excellent for capturing the general shape of a cave system but they are not suitable for high-speed, high-resolution mapping of complex surfaces found in this environment. Terrestrial laser scanning (TLS) technologies can acquire millions of points represented by 3-D coordinates, at very high spatial densities on complex multifaceted surfaces within minutes. In the last few years, advances in measurement speed, reduction in size / cost and increased portability of this technology has revolutionised the collection of …

Visible Light Responsive Systems Based On Metastable-State Photoacids, Yi Liao

Chemistry and Chemical Engineering Faculty Publications

Proton transfer is one of the most fundamental processes in nature. Metastable-state photoacids can reversibly generate a large proton concentration under visible light with moderate intensity. which provides a general approach to control various proton transfer processes. Several applications of mPAHs have been demonstrated recently including control of acid-catalyzed reactions, volume-change of hydrogels, polymer conductivity, bacteria killing, odorant release, and color change of materials. They have also been utilized to control supramolecular assemblies, molecular switches, microbial fuel cells and cationic sensors. In this talk, the mechanism, structure design, and applications of metastable-state photoacids are introduced. Recent development of different types …

X-Ray Structure Of A Mammalian Stearoyl-Coa Desaturase, Yonghong Bai, Jason G. Mccoy, Elena J. Levin, Pablo Sobrado, Kanagalaghatta R. Rajashankar, Brian G. Fox, Ming Zhou

Chemistry Faculty Research & Creative Works

Stearoyl-CoA desaturase (SCD) is conserved in all eukaryotes and introduces the first double bond into saturated fatty acyl-CoAs. Because the monounsaturated products of SCD are key precursors of membrane phospholipids, cholesterol esters and triglycerides, SCD is pivotal in fatty acid metabolism. Humans have two SCD homologues (SCD1 and SCD5), while mice have four (SCD1-SCD4). SCD1-deficient mice do not become obese or diabetic when fed a high-fat diet because of improved lipid metabolic profiles and insulin sensitivity^5,6. Thus, SCD1 is a pharmacological target in the treatment of obesity, diabetes and other metabolic diseases⁷. SCD1 is an integral …

Schneefernerhaus As A Mountain Research Station For Clouds And Turbulence, S. Risius, H. Xu, F. Di Lorenzo, H. Xi, H. Siebert, R. A. Shaw, E. Bodenschatz

Michigan Tech Publications

Cloud measurements are usually carried out with airborne campaigns, which are expensive and are limited by temporal duration and weather conditions. Ground-based measurements at high-altitude research stations therefore play a complementary role in cloud study. Using the meteorological data (wind speed, direction, temperature, humidity, visibility, etc.) collected by the German Weather Service (DWD) from 2000 to 2012 and turbulence measurements recorded by multiple ultrasonic sensors (sampled at 10 Hz) in 2010, we show that the Umweltforschungsstation Schneefernerhaus (UFS) located just below the peak of Zugspitze in the German Alps, at a height of 2650 m, is a well-suited station for …

High-Resolution Measurement Of Cloud Microphysics And Turbulence At A Mountaintop Station, H. Siebert, R. A. Shaw, J. Ditas, T. Schmeissner, S. P. Malinowski, E. Bodenschatz, H. Xu

Michigan Tech Publications

Mountain research stations are advantageous not only for long-term sampling of cloud properties but also for measurements that are prohibitively difficult to perform on airborne platforms due to the large true air speed or adverse factors such as weight and complexity of the equipment necessary. Some cloud-turbulence measurements, especially Lagrangian in nature, fall into this category. We report results from simultaneous, high-resolution and collocated measurements of cloud microphysical and turbulence properties during several warm cloud events at the Umweltforschungsstation Schneefernerhaus (UFS) on Zugspitze in the German Alps. The data gathered were found to be representative of observations made with similar …

Applications Of Green Chemistry In Asymmetric Transfer Hydrogenation And Chiral Separations, Ruoqiu Wu

Seton Hall University Dissertations and Theses (ETDs)

Green chemistry has been applied to all aspects of the life cycle of chemically related products, including design, usage, manufacturing, analysis, and disposal. In this thesis, I focus on the green chemistry applications in organic synthesis and analytical chemistry. More specifically, allylic and chiral alcohols are abundant in natural sources such as in essential oils, and widely utilized as starting materials. They are also major components in food, fragrance, biocides and the pharmaceutical compounds. In this thesis, I report the first Ru-catalysed asymmetric transfer hydrogenation (ATH) of prochiral allylic alcohols. This reaction provides chiral secondary alcohols in excellent enantioselectivities and …

Curved Noncommutative Tori As Leibniz Quantum Compact Metric Space, Frédéric Latrémolière

Mathematics Preprint Series

We prove that curved noncommutative tori are Leibniz quantum compact metric spaces and that they form a continuous family over the group of invertible matrices with entries in the commutant of the quantum tori in the regular representation, when this group is endowed with a natural length function.

Biomass Burning Emissions And Potential Air Quality Impacts Of Volatile Organic Compounds And Other Trace Gases From Temperate Fuels Common In The United States, J. B. Gilman, B. M. Lerner, W. C. Kuster, P. D. Goldan, C. Warneke, P. R. Veres, J. M. Roberts, J. A. De Gouw, I. R. Burling, Robert Yokelson

Chemistry and Biochemistry Faculty Publications

A comprehensive suite of instruments was used to quantify the emissions of over 200 organic gases, including methane and volatile organic compounds (VOCs), and 9 inorganic gases from 56 laboratory burns of 18 different biomass fuel types common in the southeastern, southwestern, or northern United States. A gas chromatograph-mass spectrometer (GC-MS) provided extensive chemical detail of discrete air samples collected during a laboratory burn and was complemented by real-time measurements of organic and inorganic species via an open-path Fourier transform infrared spectrometer (OP-FTIR) and 3 different chemical ionization-mass spectrometers. These measurements were conducted in February 2009 at the U.S. Department …

Anomalous High-Energy Waterfall-Like Electronic Structure In 5 D Transition Metal Oxide Sr2Iro4 With A Strong Spin-Orbit Coupling, Yan Liu, Li Yu, Xiaowen Jia, Jianzhou Zhao, Hongming Weng, Yingying Peng, Chaoyu Chen, Zhuojin Xie, Daixiang Mou, Junfeng He, Xu Liu, Ya Feng, Hemian Yi, Lin Zhao, Guodong Liu, Shaolong He, Xiaoli Dong, Jun Zhang, Zuyan Xu, Chuangtian Chen, Gang Cao, Xi Dai, Zhong Fang, X. J. Zhou

Physics and Astronomy Faculty Publications

The low energy electronic structure of Sr₂IrO₄ has been well studied and understood in terms of an effective J_eff= 1/2 Mott insulator model. However, little work has been done in studying its high energy electronic behaviors. Here we report a new observation of the anomalous high energy electronic structure in Sr₂IrO₄. By taking high-resolution angle-resolved photoemission measurements on Sr₂IrO₄ over a wide energy range, we have revealed for the first time that the high energy electronic structures show unusual nearly-vertical bands that extend over a large energy range. …

Simulation Of Groundwater Flow And Analysis Of The Effects Of Water-Management Options In The North Platte Natural Resources District, Nebraska, Steven M. Peterson, Amanda T. Flynn, Joseph Vrabel, Derek W. Ryter

United States Geological Survey: Water Reports and Publications

The North Platte Natural Resources District (NPNRD) has been actively collecting data and studying groundwater resources because of concerns about the future availability of the highly inter-connected surface-water and groundwater resources. This report, prepared by the U.S. Geological Survey in cooperation with the North Platte Natural Resources District, describes a groundwater-flow model of the North Platte River valley from Bridgeport, Nebraska, extending west to 6 miles into Wyoming. The model was built to improve the understanding of the interaction of surface-water and groundwater resources, and as an optimization tool, the model is able to analyze the effects of water-management options …

Characterizing Demographicparameters Across Environmental Gradients: A Case Study With Ontario Moose, Garrett M. Street, Tal Avgar, Arthur R. Rodgers, John M. Fryxell

Wildland Resources Faculty Publications

Population-level demographic characteristics as estimated by standard logistic growth models (i.e., carrying capacity and intrinsic growth rate) should vary with changes in habitat quality and availability of resources. However, few published studies have tested this hypothesis by comparing population growth rates across broad bioclimatic gradients, and fewer still the carrying capacities of those populations. We used time series data on moose (Alces alces) population densities based on aerial census and hunter harvest data for 34 management units across Ontario to estimate local carrying capacities and intrinsic growth rates. These population parameters were then regressed against associated habitat covariates for each …

Dendrochronological Analysis Of The Crowe Barn

Historic Structures

Dating historical structures using dendrochronology. The Historical Structures collection consists of reports that are the result of dendochronological analysis of timbers from structures in Pennsylvania and Ohio. Contributors: Wiesenberg, Nicholas

Development Of A Small Animal Conformal Irradiator With Dual Energy X-Ray Computed Tomography Imaging For Kilovoltage Dosimetry, Michael D. Jensen

Electronic Thesis and Dissertation Repository

External beam radiotherapy has become technically sophisticated with image guided radiation therapy (IGRT) and intensity modulated radiation therapy (IMRT). These technologies allow for precise delivery of radiation to geometric targets in cancer patients. However, many questions remain on how to best define targets based on biological information, such as functional imaging, and how to combine radiation with other cancer therapies. To help answer these questions, small animal preclinical studies are needed to generate data to inform clinical trials. However, the precise radiation delivery capabilities of IGRT and IMRT have not been available in the preclinical labs. To enable translational experiments …

Quantization Of Two Types Of Multisymplectic Manifolds, Baran Serajelahi

Electronic Thesis and Dissertation Repository

This thesis is concerned with quantization of two types of multisymplectic manifolds that have multisymplectic forms coming from a Kahler form. In chapter 2 we show that in both cases they can be quantized using Berezin-Toeplitz quantization and that the quantizations have reasonable semiclassical properties.

In the last chapter of this work, we obtain two additional results. The first concerns the deformation quantization of the (2n-1)-plectic structure that we examine in chapter 2, we make the first step toward the definition of a star product on the Nambu-Poisson algebra (C^{\infty}(M),{.,...,.}). The second result concerns the algebraic properties of the generalized …

U.S. Drought Monitor, August 11, 2015, Brian Fuchs

United States Agricultural Commodities in Drought Archive

Drought map of U.S. for August 11, 2015 (8/11/15) plus: U.S. crop areas experiencing drought (map), Approximate percentage of crop located in drought, by state (bar graph), Percent of crop area located in drought, past 52 weeks (line graph) for: Corn, Soybeans, Hay, Cattle, Winter wheat.

Software Design For An Intelligent Attitude Determination And Control System, Matthew Russell, Jeremy Straub

Jeremy Straub

Space exploration and satellite missions often carry equipment that must be accurately pointed towards distant targets, therefore making an effective attitude determination and control system (ADCS) a vital component of almost every spacecraft. However, the effectiveness of the ADCS could decrease drastically if components shift during launch, degrade in efficiency over the course of the mission, or simply fail. Prior work [0] has presented a concept for a adaptive ADCS which can respond to changing spacecraft conditions and environmental factors. This poster presents an implementation for a lazy learning ADCS is presented that uses past maneuver data to construct and …

Testing A Novel Cryptosystem For Use In Securing Small Satellite Communications, Samuel Jackson, Scott Kerlin, Jeremy Straub

Jeremy Straub

Cryptography in the domain of Small Satellites is a topic of growing importance. While large satellites are likely to have the hardware requirements to run common cryptographic algorithms, small satellites are extremely limited in both hardware capabilities, which limits the speed and security of cryptosystems implemented in software, and available physical space, which limits the ability to include cryptosystems implemented in hardware. However, small satellites are growing in popularity, and as such securing communications becomes a necessity for some. The Department of Defense is exploring the possibility of using CubeSats, a type of small satellite, in their operations, as are …

Improving Satellite Security Through Incremental Anomaly Detection On Large, Static Datasets, Connor Hamlet, Matthew Russell, Jeremy Straub, Scott Kerlin

Jeremy Straub

Anomaly detection is a widely used technique to detect system intrusions. Anomaly detection in Intrusion Detection and Prevent Systems (IDPS) works by establishing a baseline of normal behavior and classifying points that are at a farther distance away as outliers. The result is an “anomaly score”, or how much a point is an outlier. Recent work has been performed which has examined use of anomaly detection in data streams [1]. We propose a new incremental anomaly detection algorithm which is up to 57,000x faster than the non-incremental version while slightly sacrificing the accuracy of results. We conclude that our method …

Does The Stellar Disc Flattening Depend On The Galaxy Type, A. V. Mosenkov, N. Ya. Sotnikova, V. P. Reshetnikov, D. V. Bizyaev, Stefan Kautsch

Chemistry and Physics Faculty Articles

We analyse the dependence of the stellar disc flatness on the galaxy morphological type using 2D decomposition of galaxies from the reliable subsample of the Edge-on Galaxies in SDSS catalogue. Combining these data with the retrieved models of the edge-on galaxies from the Two Micron All Sky Survey and the Spitzer Survey of Stellar Structure in Galaxies catalogue, we make the following conclusions.

1. The disc relative thickness z₀/h in the near- and mid-infrared passbands correlates weakly with morphological type and does not correlate with the bulge-to-total luminosity ratio B/T in all studied bands.

2. Applying a 1D photometric …

Hexaniobate Nanopeapods: In Situ Deposition Of Magnetic-Noble Metal Nanoparticles Inside Preformed Nanoscrolls, Sarah P. Gauthier

University of New Orleans Theses and Dissertations

An in situ deposition procedure was developed for the nanopeapod (NPP) formation of NiAu nanoparticles inside preformed acid-exchanged hexaniobate nanoscrolls (HNB). Metal salt precursors of Ni(acac)₂ and HAuCl₄∙3H₂O were reduced in solution under mild synthetic conditions in the presence of the preformed acid-exchanged hexaniobate nanoscrolls. Two of the surfactants used for the formation of the nanoparticles were oleylamine and triphenylphosphine oxide (TTPO). Reaction conditions were studied and modified to produce well-defined NiAu@HNB NPP systems, with monodispersed particles evenly filling and orienting within the nanoscrolls. The synthetic parameters studied were both time and temperature, with the …

Numerical Solutions Of Generalized Burgers' Equations For Some Incompressible Non-Newtonian Fluids, Yupeng Shu

University of New Orleans Theses and Dissertations

The author presents some generalized Burgers' equations for incompressible and isothermal flow of viscous non-Newtonian fluids based on the Cross model, the Carreau model, and the Power-Law model and some simple assumptions on the flows. The author numerically solves the traveling wave equations for the Cross model, the Carreau model, the Power-Law model by using industrial data. The author proves existence and uniqueness of solutions to the traveling wave equations of each of the three models. The author also provides numerical estimates of the shock thickness as well as maximum strain $\varepsilon_{11}$ for each of the fluids.

Inhibition Of The Dape-Encoded N-Succinyl- ʟ, ʟ-Diaminopimelic Acid Desuccinylase From Neisseria Meningitidis By ʟ-Captopril, Anna Starus, Boguslaw Nocek, Brian Bennett, James A. Larrabee, Daniel L. Shaw, Wisath Sae-Lee, Marie T. Russo, Danuta M. Gillner, Magdalena Makowska-Grzyska, Andzrej Joachimiak, Richard C. Holz

Physics Faculty Research and Publications

Binding of the competitive inhibitor ʟ-captopril to the dapE-encoded N-succinyl-ʟ, ʟ-diaminopimelic acid desuccinylase from Neisseria meningitidis (NmDapE) was examined by kinetic, spectroscopic, and crystallographic methods. ʟ-Captopril, an angiotensin-converting enzyme (ACE) inhibitor, was previously shown to be a potent inhibitor of the DapE from Haemophilus influenzae (HiDapE) with an IC₅₀ of 3.3 μM and a measured K_i of 1.8 μM and displayed a dose-responsive antibiotic activity toward Escherichia coli. ʟ-Captopril is also a competitive inhibitor of NmDapE with a K_i of 2.8 μM. To examine the nature of the interaction …

Api-Based Acquisition Of Evidence From Cloud Storage Providers, Andres E. Barreto

University of New Orleans Theses and Dissertations

Cloud computing and cloud storage services, in particular, pose a new challenge to digital forensic investigations. Currently, evidence acquisition for such services still follows the traditional approach of collecting artifacts on a client device. In this work, we show that such an approach not only requires upfront substantial investment in reverse engineering each service, but is also inherently incomplete as it misses prior versions of the artifacts, as well as cloud-only artifacts that do not have standard serialized representations on the client.

In this work, we introduce the concept of API-based evidence acquisition for cloud services, which addresses these concerns …

Creating Volatility Support For Freebsd, Elyse Bond

University of New Orleans Theses and Dissertations

Digital forensics is the investigation and recovery of data from digital hardware. The field has grown in recent years to include support for operating systems such as Windows, Linux and Mac OS X. However, little to no support has been provided for less well known systems such as the FreeBSD operating system.

The project presented in this paper focuses on creating the foundational support for FreeBSD via Volatility, a leading forensic tool in the digital forensic community. The kernel and source code for FreeBSD were studied to understand how to recover various data from analysis of a given system’s memory …

From Copper Zinc Tin Sulfur To Perovskites: Fabrication And Characterization Of New Generation Of Solar Cells, Sarah Wozny

University of New Orleans Theses and Dissertations

In 2013, the worldwide production of renewable electricity accounted for 22.1% of the total energy production with 0.9% coming from solar photovoltaics (PVs). Recently, there has been a growing interest for Cu₂ZnSnS₄ (CZTS) quaternary semiconductor due to the abundance and low cost of its precursors. Moreover, this chalcopyrite material has an ideal direct band gap around 1.5 eV, high absorption coefficient (α >10⁴ cm^-1) and high conductivity, making it suitable for nanostructured and dye-sensitized solar cell (DSSC) applications. Here, CZTS nanoparticles have been synthesized by pulsed laser deposition (PLD) and simultaneously deposited in the …

Rational Design Of Materials For The Protection Of Outdoor Metalworks, Natasja Alexandria Swartz

Dissertations and Theses

Protective coatings are commonly used to protect culturally significant works, such as outdoor sculptures and architectural elements. Given the valuable nature of such metalworks, there is a surprising lack of environmentally sustainable coatings available for their conservation. High performance clear coatings are not developed or thoroughly tested for compatibility and longevity on outdoor sculptures. This can make the implementation of both methods and materials, no matter how promising in a lab, a significant hurdle for the conservation science community. This dissertation work initially aims to replace high-VOC formulations such as acrylic lacquers and waxes currently used as protective coatings for …

Penalized Functional Regression For Next-Generation Sequencing Studies, Olga A. Vsevolozhskaya

Olga A. Vsevolozhskaya

Recent technological advances equipped researchers with capabilities that go beyond traditional genotyping of loci known to be polymorphic in a general population. Genetic sequences of study participants can now be assessed directly. This capability removed technology-driven bias toward scoring predominantly common polymorphisms and let researchers reveal a wealth of rare and sample-specific variants. While the relative contributions of rare and common polymorphisms to trait variation are being debated, researchers are faced with the need for new statistical tools for simultaneous evaluation of all variants within a region. Several research groups demonstrated flexibility and good statistical power of the functional linear …

Kepler 453 B - The 10th Kepler Transiting Circumbinary Planet, William F. Welsh, Darin Ragozzine

Aerospace, Physics, and Space Science Faculty Publications

We present the discovery of Kepler-453 b, a 6.2 RƟ planet in a low-eccentricity, 240.5 day orbit about an eclipsing binary. The binary itself consists of a 0.94 and 0.195 M☉ pair of stars with an orbital period of 27.32 days. The plane of the planetʼs orbit is rapidly precessing, and its inclination only becomes sufficiently aligned with the primary star in the latter portion of the Kepler data. Thus three transits are present in the second half of the light curve, but none of the three conjunctions that occurred during the first half of the light curve produced observable …

Concerns About Least Squares Estimation For The Three-Parameter Weibull Distribution: Case Study Of Statistical Software, William V. Harper, Thomas R. James

Mathematics Faculty Scholarship

Least Squares estimation of the 2-parameter Weibull distribution is straightforward; however, there are multiple methods for least squares estimation of the 3-parameter Weibull. The third parameter for the 3-parameter Weibull distribution shifts the origin from 0 to some generally positive value sometimes called the location, threshold, or minimum life. The different methods used by the packages result in fairly major differences in the estimated parameters between the statistical packages. This may have implications for those needing to estimate or apply the results of a 3-parameter Weibull distribution that is used frequently in practice. The results are analyzed in detail based …