Physical Sciences and Mathematics Commons^™

In Situ Ph Determination Based On The Nmr Analysis Of ¹H-Nmr Signal Intensities And ¹⁹F-Nmr Chemical Shifts, Ming Huang

Masters Theses

"The pH of an NMR sample can be measured directly by NMR experiments of signal intensities, chemical shifts, or relaxation time constants that depend on the pH. The ¹H NMR peak intensities of the pH indicator phenolphthalein change as it changes from the OH-depleted form to the OH-rich form in the range of pH = 11.1 to 12.7. Because this range is rather small, another NMR technique was utilized based on ¹⁹F chemical shifts. The shift of F^- in an aqueous solution of NaF changes in the alkaline range between pH = 11.0 and 14.0 and even …

Family-Based Association Studies Of Autism In Boys Via Facial-Feature Clusters, Luke Andrew Settles

Masters Theses

"Autism spectrum disorder (ASD) refers to a set of developmental disorders with varied attributes. Due to its substantial heterogeneity in terms of behavioral and clinical phenotypes, it is challenging to discern the genetic biomarkers behind ASD, even though the disease is known to be genetic in nature. This serves as a motivation to detect relationships between single nucleotide polymorphisms (SNPs) and a causal autism disease susceptibility locus (DSL) within more homogeneous subgroups. Recently, clinically meaningful subclassifications of ASD have been discovered utilizing facial features of prepubescent boys. Therefore, through the employment of data from 44 prepubertal Caucasian boys with ASD …

Homeomorphic Tetrahedral Tessellation For Biomedical Images, Jing Xu, Andrey N. Chernikov

Computer Science Faculty Publications

We present a novel algorithm for generating three-dimensional unstructured tetrahedral meshes for biomedical images. The method uses an octree as the background grid from which to build the final graded conforming meshes. The algorithm is fast and robust. It produces meshes with high quality since it provides dihedral angle lower bound for the output tetrahedra. Moreover, the mesh boundary is a geometrically and topologically accurate approximation of the object surface in the sense that it allows for guaranteed bounds on the two-sided Hausdorff distance and the homeomorphism between the boundaries of the mesh and the boundaries of the materials. The …

An Investigation Of Acid Rock Drainage In Glacial Streams Through Multivariate Exploratory Analysis And The Biotic Ligand Model In The Cordillera Blanca, Peru., Edward W. Bain

WWU Graduate School Collection

Water chemistry in the Cordillera Blanca, Peru, where glaciers provide crucial freshwater to the arid Andes Mountains, was characterized during the dry season (June-August), 2014. Metal concentrations, anion concentrations, and physical and chemical parameters were assessed at 94 sample sites in seven river valleys. Nonparametric multivariate exploratory statistics were used to compare sample sites.

Compared to other river valleys, high metal concentrations were evident in the Quilcayhuanca valley. Water chemistry and visual signs indicated that acid rock drainage (ARD) is occurring in the Cordillera Blanca, likely due to glacial recession. Hierarchical clustering analysis was performed on the results of a …

Simulation Modeling Of Population Expansion For Introduced Mountain Goats In The Olympic Mountains Of Washington State, Melissa M. Oscarson

WWU Graduate School Collection

Mountain goats (Oreamnos americanus) are not native to the Olympic Peninsula as they are to other regions of Washington State. A total of eleven or twelve animals were translocated from Alaska and British Columbia between 1925 and 1929 then released in the foothills of Mount Storm King. By 1970 these founding goats had colonized the entire Olympic range and concerns about the management of this introduced species developed as damage to alpine soil and vegetation was noted. An aerial census of the Olympic range conducted in July 1983 estimated the mountain goat population at 1,175 (95% CI 840 – 1510). …

Gender Stereotype And Spatial Reasoning: The Milankovitch Cycles, Kristina Gustovich

WWU Graduate School Collection

Stereotype threat, a phenomenon in which learners feel at risk of confirming negative stereotypes about their abilities, is often associated with spatial reasoning abilities in geoscience and has a disproportionately negative effect on women. This study examines how students’ growth or fixed mindsets mediate or amplify the effects of stereotype threat regarding self-perception of their spatial skills and learning how Earth’s cyclical orbital geometry influences its climate.

Undergraduate, introductory-level Geology students at Western Washington University were given a Pre-Test and Post-Test, a spatial reasoning test, and an assessment of their spatial reasoning abilities. Of the 154 participants, 41 had a …

Exploring The Gender Gap In The Conceptual Survey Of Electricity And Magnetism, Rachel Henderson, Gay Stewart, John Stewart, Lynnette Michaluk, Adrienne Traxler

Faculty & Staff Scholarship

The “gender gap” on various physics conceptual evaluations has been extensively studied. Men’s average pretest scores on the Force Concept Inventory and Force and Motion Conceptual Evaluation are 13% higher than women’s, and post-test scores are on average 12% higher than women’s. This study analyzed the gender differences within the Conceptual Survey of Electricity and Magnetism (CSEM) in which the gender gap has been less well studied and is less consistent. In the current study, data collected from 1407 students (77% men, 23% women) in a calculus-based physics course over ten semesters showed that male students outperformed female students on …

Strengthening The Development Of The Short-Rotation Plantations Bioenergy Sector: Policy Insights From Six European Countries, Carlos Parra-Lopez, Martin Holley, Kevin Lindegaard, Samir Sayadi, Gonzalo Esteban-Lopez, Victor Duran-Zuazo, Christoph Knauer, Hans-Georg Von Engelbrechten, Ralf Winterber, Annika Henriksson, Annette Lamley, Anders Nylander, Susanne Paulrud, Pauline Leonard, Patrick Daly, Lukasz Drzewaszewski, Wojciech Rzewuski

Articles

This paper, based on a participatory methodological framework involving expert stakeholders and researchers from six European countries (Germany, Ireland, Poland, Spain, Sweden and UK), analyses the priority issues for the development of short-rotation plantations (SRP), and proposes a series of policy strategies to strengthen this development. The results indicate that there is a lack of awareness of the multifaceted benefits of SRP at the level of farmers, policy makers and public authorities. More research is required to put a value on the multifunctionality of SRP and justify its public support. Small-scale projects using established technologies are also required with energy …

Plithogeny, Plithogenic Set, Logic, Probability, And Statistics, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

In this book we introduce for the first time, as generalization of dialectics and neutrosophy, the philosophical concept called plithogeny. And as its derivatives: the plithogenic set (as generalization of crisp, fuzzy, intuitionistic fuzzy, and neutrosophic sets), plithogenic logic (as generalization of classical, fuzzy, intuitionistic fuzzy, and neutrosophic logics), plithogenic probability (as generalization of classical, imprecise, and neutrosophic probabilities), and plithogenic statistics (as generalization of classical, and neutrosophic statistics).

Plithogeny is the genesis or origination, creation, formation, development, and evolution of new entities from dynamics and organic fusions of contradictory and/or neutrals and/or non-contradictory multiple old entities.

Plithogenic …

Internet Health Information Seeking And The Patient-Physician Relationship: A Systematic Review, Sharon Swee-Lin Tan, Nadee Goonawardene

Research Collection School Of Computing and Information Systems

Background: With online health information becoming increasingly popular among patients, concerns have been raised about the impact of patients' Internet health information-seeking behavior on their relationship with physicians. Therefore, it is pertinent to understand the influence of online health information on the patient-physician relationship. Objective: Our objective was to systematically review existing research on patients' Internet health information seeking and its influence on the patient-physician relationship. Methods: We systematically searched PubMed and key medical informatics, information systems, and communication science journals covering the period of 2000 to 2015. Empirical articles that were in English were included. We analyzed the content …

Phytoplankton Plastid Proteomics: Cracking Open Diatoms To Understand Plastid Biochemistry Under Iron Limitation, Skyler J. Nunn, Phoebe Dreux Chappell, Kristofer Gomes, Anasthasia Bonderenko, Bethany D. Jenkins, Brook L. Nunn

OES Faculty Publications

Diatoms, such as Thalassiosira pseudonana, are important oceanic primary producers, as they sequester carbon dioxide (CO₂) out of the atmosphere, die, and precipitate to the ocean floor. In many areas of the world’s oceans, phytoplankton, such as diatoms, are limited in growth by the availability of iron (Fe). Fe is an essential nutrient for phytoplankton, as it is central in the electron transport chain component of photosynthesis. Through this study, we examined if Fe-limitation makes a significant difference in the proteins expressed within the chloroplast, the power source for diatoms. Here, we utilized a new plastid isolation technique specific …

Modeling Beta-Traces For Beta-Barrels From Cryo-Em Density Maps, Dong Si, Jing He

Computer Science Faculty Publications

Cryo-electron microscopy (cryo-EM) has produced density maps of various resolutions. Although ά-helices can be detected from density maps at 5-8 angstrom resolutions, β-strands are challenging to detect at such density maps due to close-spacing of β-strands. The variety of shapes of β-sheets adds the complexity of β-strands detection from density maps. We propose a new approach to model traces of β-strands for β-barrel density regions that are extracted from cryo-EM density maps. In the test containing eight β-barrels extracted from experimental cryo-EM density maps at 5.5 angstrom-8.25 angstrom resolution, StrandRoller detected about 74.26% of the amino acids in the β-strands …

Impact Of Uri Canonicalization On Memento Count, Mat Kelly, Lulwah M. Alkwai, Michael L. Nelson, Michele C. Weigle, Herbert Van De Sompel

Computer Science Faculty Publications

Quantifying the captures of a URI over time is useful for researchers to identify the extent to which a Web page has been archived. Memento TimeMaps provide a format to list mementos (URI-Ms) for captures along with brief metadata, like Memento-Datetime, for each URI-M. However, when some URI-Ms are dereferenced, they simply provide a redirect to a different URI-M (instead of a unique representation at the datetime), often also present in the TimeMap. This infers that confidently obtaining an accurate count quantifying the number of non-forwarding captures for a URI-R is not possible using a TimeMap alone and that the …

Homeomorphic Tetrahedralization Of Multi-Material Images With Quality And Fidelity Guarantees, Jing Xu, Andrey N. Chernikov

Computer Science Faculty Publications

We present a novel algorithm for generating three-dimensional unstructured tetrahedral meshes of multi-material images. The algorithm produces meshes with high quality since it provides a guaranteed dihedral angle bound of up to 19.47° for the output tetrahedra. In addition, it allows for user-specified guaranteed bounds on the two-sided Hausdorff distance between the boundaries of the mesh and the boundaries of the materials. Moreover, the mesh boundary is proved to be homeomorphic to the object surface. The algorithm is fast and robust, it produces a sufficiently small number of mesh elements that comply with these guarantees, as compared to other software. …

An Effective Computational Method Incorporating Multiple Secondary Structure Predictions In Topology Determination For Cryo-Em Images, Abhishek Biswas, Desh Ranjan, Mohammad Zubair, Stephanie Zeil, Kamal Al Nasr, Jing He

Computer Science Faculty Publications

A key idea in de novo modeling of a medium-resolution density image obtained from cryo-electron microscopy is to compute the optimal mapping between the secondary structure traces observed in the density image and those predicted on the protein sequence. When secondary structures are not determined precisely, either from the image or from the amino acid sequence of the protein, the computational problem becomes more complex. We present an efficient method that addresses the secondary structure placement problem in presence of multiple secondary structure predictions and computes the optimal mapping. We tested the method using 12 simulated images from alpha-proteins and …

Gis Data: Hanover County, Virginia, Shoreline Inventory Report, Marcia Berman, Karinna Nunez, Sharon Killeen, Tamia Rudnicky, Julie Bradshaw, Karen Duhring, Kallie Brown, Jessica Hendricks, David Weiss, Carl Hershner

Data

The 2017 Inventory for Hanover County was generated using on-screen, digitizing techniques in ArcGIS® -ArcMap v10.4.1 while viewing conditions observed in Bing high resolution oblique imagery, Google Earth, and 2013 imagery from the Virginia Base Mapping Program (VBMP).Four GIS shapefiles are developed.The first describes land use and bank conditions (Hanover _lubc_2017). The second portrays the presence of beaches (Hanover _beaches_2017). The third reports shoreline structures that are described as arcs or lines(e.g. riprap)(Hanover _sstru_2017). The final shapefile includes all structures that are represented as points(e.g. piers)(Hanover _astru_2017).The metadata file accompanies the shapefiles and defines attribute accuracy, data development, and any …

Developing A Hydrological Monitoring Program For Ponds In Wapusk National Park, Manitoba, Using Water Isotope Tracers, Stephanie Roy

Theses and Dissertations (Comprehensive)

Northern lake-rich landscapes are vulnerable to increases in surface air temperatures and are changing in dynamic ways. Current meteorological records indicate that some of the greatest warming in the past century has occurred in the Hudson Bay Lowlands (HBL). As the HBL is an extensive wetland consisting of hundreds of thousands of shallow lakes and ponds, it is difficult to anticipate the long-term implications that climate change will have on pond water balance. To develop and implement long-term monitoring of hydrological conditions, sampling of pond water isotope composition has occurred during the past six years in Wapusk National Park (WNP), …

Extensions And Applications Of Mean Length Mortality Estimators For Assessment Of Data-Limited Fisheries, Quang C. Huynh

Dissertations, Theses, and Masters Projects

For data-limited fisheries, length-based mortality estimators are attractive as alternatives to age-structured models due to the simpler data requirements and ease of use of the former. This dissertation develops new extensions of mean length-based mortality estimators and applies them to federally-managed stocks in the southeastern U.S. and U.S. Caribbean.

Chapter 1 presents a review of length-based methods from the literature. Common themes regarding the methodology, assumptions, and diagnostics in these length-based methods are discussed. In Chapter 2, a simulation study evaluates the performance of the length-converted catch curve (LCCC), Beverton-Holt equation (BHE), and Length Based-Spawner Potential Ratio (LB-SPR) over a …

Reconstructing Coastal Forest Retreat And Marsh Migration Response To Historical Sea Level Rise, Nathalie Schieder

Dissertations, Theses, and Masters Projects

Climate change assessments predict that rates of relative sea level rise will increase in the future, leading to enhanced inundation of low-lying coastal regions and a 20 – 50 % decline in salt marsh area by 2100. Global sea level rise began accelerating in the late 19th to early 20th century, and local rates along the U.S. mid-Atlantic coast are twice as fast as global estimates. Frequent flooding and salt stress associated with sea level rise lead to coastal transgression, and the survival of ecosystems depends on their ability to migrate inland faster than they erode and submerge. Here, I …

Investigation Of Local Structures In Cation-Ordered Microwave Dielectric A Solid-State Nmr And First Principle Calculation Study, Rony Gustam Kalfarisi

Dissertations, Theses, and Masters Projects

Solid-state Nuclear Magnetic Resonance (ssNMR) spectroscopy has proven to be a powerful method to probe the local structure and dynamics of a system. In powdered solids, the nuclear spins experience various anisotropic interactions which depend on the molecular orientation. These anisotropic interactions make ssNMR very useful as they give a specific appearance to the resonance lines of the spectra. The position and shape of these resonance lines can be related to local structure and dynamics of the system under study. My research interest has focused around studying local structures and dynamics of quadrupolar nuclei in materials using ssNMR spectroscopy. Li …

Gis Data: Hanover County, Virginia Tidal Marsh Inventory, Marcia Berman, Karinna Nunez, Sharon Killeen, Tamia Rudnicky, Julie Bradshaw, Karen A. Duhring, Kallie Brown, Jessica Hendricks, David Stanhope, David Weiss, Carl Hershner

Data

The 2017 Tidal Marsh Inventory update for Hanover County, Virginia was generated using on-screen digitizing techniques in the most recent version of ArcGIS® - ArcMap while viewing conditions observed in the most recent imagery from the Virginia Base Mapping Program (VBMP). Dominant plant community types were primarily determined during field surveys from shallow-draft boats moving along the shoreline. Land-based surveys were performed in some locations. One shapefile is developed that portrays tidal marsh areas represented as polygons. A metadata file accompanies the shapefile to define attribute accuracy, data development, and any use restrictions that pertain to the data.

Gis Data: City Of Fredericksburg, Virginia Tidal Marsh Inventory, Marcia Berman, Karinna Nunez, Sharon Killeen, Tamia Rudnicky, Julie Bradshaw, Karen Duhring, Kallie Brown, Jessica Hendricks, David Weiss, Carl H. Hershner

Data

The 2017 Tidal Marsh Inventory update for the City of Fredericksburg, Virginiawas generated using on-screen digitizing techniques in the most recent version of ArcGIS® - ArcMap while viewing conditions observed in the most recent imagery from the Virginia Base Mapping Program (VBMP). Dominant plant community types were primarily determined during field surveys from shallow-draft boats moving along the shoreline. Land-based surveys were performed in some locations. One shapefile is developed that portrays tidal marsh areas represented as polygons. A metadata file accompanies the shapefile to define attribute accuracy, data development, and any use restrictions that pertain to the data.

Gis Data: The County Of Chesterfield And The Cities Of Colonial Heights, Petersburg, And Richmond,Virginia Shoreline Management Model, Marcia Berman, Karinna Nunez, Sharon Killeen, Tamia Rudnicky, Julie Bradshaw, Karen Duhring, Kallie Brown, Jessica Hendricks, David Weiss, Carl Hershner

Data

The Shoreline Management Model is a GIS spatial model that determines appropriate shoreline best management practices using available spatial data and decision tree logic. Available shoreline conditions used in the model include the presence or absence of tidal marshes, beaches, and forested riparian buffers, bank vegetation cover, bank height, wave exposure (fetch), nearshore water depth, and proximity of coastal development to the shoreline. The model output for shoreline best management practices is displayed in the locality Comprehensive Map Viewer. One GIS shapefile is developed that describes two arcs or lines representing practices in the upland area and practices at the …

Computational Studies Of Strongly Correlated Quantum Matter, Hao Shi

Dissertations, Theses, and Masters Projects

The study of strongly correlated quantum many-body systems is an outstanding challenge. Highly accurate results are needed for the understanding of practical and fundamental problems in condensed-matter physics, high energy physics, material science, quantum chemistry and so on. Our familiar mean-field or perturbative methods tend to be ineffective. Numerical simulations provide a promising approach for studying such systems. The fundamental difficulty of numerical simulation is that the dimension of the Hilbert space needed to describe interacting systems increases exponentially with the system size. Quantum Monte Carlo (QMC) methods are one of the best approaches to tackle the problem of enormous …

Workload Prediction For Efficient Performance Isolation And System Reliability, Ji Xue

Dissertations, Theses, and Masters Projects

In large-scaled and distributed systems, like multi-tier storage systems and cloud data centers, resource sharing among workloads brings multiple benefits while introducing many performance challenges. The key to effective workload multiplexing is accurate workload prediction. This thesis focuses on how to capture the salient characteristics of the real-world workloads to develop workload prediction methods and to drive scheduling and resource allocation policies, in order to achieve efficient and in-time resource isolation among applications. For a multi-tier storage system, high-priority user work is often multiplexed with low-priority background work. This brings the challenge of how to strike a balance between maintaining …

Ecosystem Services Of Restored Oyster Reefs In A Chesapeake Bay Tributary: Abundance And Foraging Of Estuarine Fishes, Bruce William Pfirrmann

Dissertations, Theses, and Masters Projects

Oyster reef restoration may enhance the production of ecologically or economically important fish species, an ecosystem service, by providing refuge and foraging habitat. Predicting the effects of oyster habitat restoration on fisheries production in Chesapeake Bay requires a better understanding of fish habitat use, trophic dynamics, and the processes leading to production on a habitat-scale. The objective of this thesis was to evaluate the influence of restored subtidal oyster reefs on the abundance and foraging patterns of mobile estuarine fishes. Specifically, I compared the 1) abundance, 2) stomach fullness, 3) diet composition, and 4) daily consumption rate of fishes collected …

Impact Of Climate Variation And Human Adaptation On The Physical Transport Processes And Water Exchange In Chesapeake Bay, Jiabi Du

Dissertations, Theses, and Masters Projects

The efficiencies of water exchanges in both vertical and horizontal directions reflect the overall impact of various physical processes and serve as important indicators of physical control over a variety of ecological and biogeochemical processes. The vertical exchange between surface layers and bottom layers of a waterbody has proved to exert great control over the hypoxic condition, while the horizontal exchange between an estuary and coastal ocean determines the flushing capacity of the estuary and the retention rate of riverine materials. Various processes, such as tidal flushing, tidal mixing, gravitational circulation, and lateral circulation, can affect water exchange. Therefore, water …

Investigating The Charge-Transfer Dynamics Of Single-Molecule Sensitizers, Jenna Tan

Dissertations, Theses, and Masters Projects

Dye-sensitized solar cells (DSSCs) can reduce the cost of photovoltaic electricity generation to meet global energy needs. Optimizing DSSC efficiency requires a detailed understanding of the underlying charge transfer processes at the dye-semiconductor interface. By modifying the sensitizer structure, we gain insight into these charge transfer mechanisms. In this thesis, two hydroxyanthraquinone dyes are compared to investigate the impact of structure on charge-transfer and photobleaching dynamics. A combination of ensemble-averaged and single-molecule spectroscopy approaches are used to interpret the underlying ET kinetics.

Impact Of Climate Change Variables On Nutrient Cycling By Marine Microorganisms In The Southern California Bight And Ross Sea, Antarctica, Jenna Lee Spackeen

Dissertations, Theses, and Masters Projects

Ocean environments are being impacted by climate warming, elevated carbon dioxide (CO2) levels, and shifting nutrient sources and sinks. It is essential to quantify the sensitivity of microorganisms to these effects of global change because they form the base of the marine food web and are an integral component of nutrient cycling on the planet. their role in photosynthesis, nutrient uptake, and transfer of organic matter into higher trophic levels or to the deep ocean via the biological pump render microorganisms key in ecosystem structure and function and in regulating the global climate. The goal of this dissertation research was …

Investigating The Role Of The Written Curriculum On Lesson Planning For First-Year Elementary Mathematics Teachers, Anna Kron

Honors Program Theses

While studies have previously explored aspects of lesson planning from the perspective of experienced teachers, there is a lack of research investigating how this process is different for brand new educators. The researcher, a preservice elementary teacher studying at the University of Northern Iowa, wanted to learn more about the available resources and how she would utilize them when planning for mathematics instruction in her first elementary classroom. At the completion of this project, the researcher hoped to have a better understanding of the process first-year elementary teachers experience when transforming written textbook materials into a mathematics lesson plan. The …