Physical Sciences and Mathematics Commons^™

Measurement Of The Prompt J/Psi Pair Production Cross Section In Pp Collisions At Sqrt(S) = 8 Tev With Cms, Grant Valentine Riley

Doctoral Dissertations

The cross section for the prompt production of J/ψ [J/Psi] meson pairs in proton-proton collisions at √ s[sqrt(s)] = 8 TeV at the LHC from a sample corresponding to an integrated luminosity of 20.2±0.5 fb−1 [inverse femtobarns] has been measured with the CMS detector. It provides unique insight into particle production and proton structure in proton-proton (pp) collisions. The two J/ψ mesons are fully reconstructed in their µ +µ −[mu+ mu-] decay. An acceptance region is defined by the individual J/ψ transverse momentum pT J/ψ [J/Psi pT] and rapidity |y J/ψ| [J/Psi Rapidity]. The total fiducial cross section assuming unpolarized …

Development Of High-Performing Polydimethylsiloxane-Based Membranes For Carbon Dioxide Separation, Tao Hong

Doctoral Dissertations

Membrane separation is highlighted as one of the most promising approaches to mitigate the excessive CO₂ [carbon dioxide] emission, due to its significant reduction of energy cost compared with many conventional separation techniques. Unfortunately, the separation performance of current membranes does not meet the practical CO₂/N₂ [nitrogen] separation requirements. And due to the huge volume of industrial flue gas, membranes with exceptionally high permeability are needed for practical reasons.

Currently, the separation mechanism of most polymeric membranes is based on size-sieving. However, this method is not sufficient for CO₂/N₂ separations due to the …

An Exploration Of Basic Processes For Aqueous Electrochemical Production Of Hydrogen From Biomass Derived Molecules, Brian Fane

Doctoral Dissertations

Polymer electrolyte membrane fuel cells(PEMFCs) are energy conversion devices with significant potential. The factors preventing them from becoming widespread concern production and distribution of hydrogen. Developing an efficient hydrogen infrastructure with an approachable rollout plan is an essential step towards the future of fuel cells. Water electrolysis is limited by the thermodynamics of the process, which leads to high electrical consumption and significant materials challenges. Alternative methods for cleanly generating hydrogen while using a lower cell voltage are required. PEM based electrolyzers can operate with a "depolarized anode", whereby they become significantly less power hungry.

This thesis explores two techniques …

Design And Synthesis Of Analogs Of Myo-Inositol, Serine, And Cysteine To Enable Chemical Biology Studies, Tanei J. Ricks

Doctoral Dissertations

Phosphorylated myo-inositol compounds including inositol phosphates (InsPs) as well as the phosphatidylinositol polyphosphate lipids (PIP_ns) are critical biomolecules that regulate many of the most important biological processes and pathways. They are aberrant in many disease states due to their regulatory function. The same is true of the phospholipid phosphatidylserine (PS) which can serve as a marker to begin apoptosis. However, the full scope of activities of these structures is not clear, particularly since techniques that enable global detection and analysis of the production of these compounds spatially and temporally are lacking. With all of these obstacles in …

Search For The Decays Of 113ba, Yongchi Xiao

Doctoral Dissertations

The search for new alpha-emitters in the region above tin-100 was carried out in Japan Atomic Energy Agency (JAEA) tandem accelerator in Tokai, Japan. This work aimed to discover barium-113 produced via the fusion-evaporation reaction nickel-58(nickel-58,3n)barium-113 and observation through its alpha-decay chain from barium-113 to xenon-109 to tellurium-105 and tin-101. In the proof of principle experiment in March 2014, the alpha-decay chain of xenon-109 was observed with Double-sided Silicon Strip Detector (DSSD) and digital electronics at JAEA Recoil Mass Separator (RMS). The first discovery-oriented barium-113 experiment was carried out in December 2014 searching for its alpha-decay, ground-state to ground-state beta-decay …

Multiscale Modeling Approach To Understand Active Sites In Non-Conventional Catalyst Layers For Fuel Cell Applications, Diana Constanza Orozco Gallo

Doctoral Dissertations

Fuel cells development required stable, active and more abundant catalytic materials. Oxygen reduction reaction (ORR) is the key process to enhance better activity and reduce the fabrication costs. Pt-based has proven to be the best catalyst for ORR and greater efforts has been made in terms of reducing the Pt content in the electrodes, reduce electrode thickness and enhance better catalytic activities. To overcome many of the challenges present, the catalyst layer studies are the great importance in the fuel cell community. Understanding catalyst layer with new catalytic materials, and configurations requires the development of methodological approach to relate structure, …

From Pyrochlore To The Tripod Kagome Lattice: Magnetism Of New Compound Family A2re3sb3o14 (A = Mg, Zn; Re = Pr, Nd, Gd, Tb, Dy, Ho, Er, Yb), Zhiling Dun

Doctoral Dissertations

Geometrical frustration refers to the inability of a complex system to satisfy all its competing interactions within an underlying topological constrained lattice. The two-dimensional kagome lattice is one of the most frustrated lattices and has been a favorite in the theoretical condensed matter community. However, the large variety of exotic states predicted in kagome lattices lies in contrast to a paucity of experimental systems, making new kagome lattice compounds highly desired.

In this dissertation, I shall provide a systematic study of the structural and magnetic properties of a new compounds family, A2RE3Sb3O14 (A = Mg, Zn; RE = Pr, Nd, …

Development And Implementation Of Redox-Active Olefin Polymerization Catalysts, William Curtis Anderson Jr.

Doctoral Dissertations

Investigating homogeneous polymerization catalysts has been a thriving area of chemistry in the academic realm for several decades now, and has helped drive the development of a range of materials, from designer plastics to cheap commodity polymers. Billions of pounds of these materials are produced every year, which ensures that continuing research in the area will be necessary to improve current processes and enable more economic use of our resources.

This dissertation showcases the Long group’s research in homogeneous polymerization catalysis and our impact on the field thus far. We show that intelligent design of redox-active catalysts allows for a …

Impact Of Soil Water Content On Bermudagrass Athletic Field Performance, Kyley Hampton Dickson

Doctoral Dissertations

Soil water content (SWC) influences the consistency and performance of athletic fields. Two studies were conducted at the University of Tennessee Center for Athletic Field Safety (Knoxville, TN) to determine SWC impact on the performance of hybrid bermudagrass [Cynodon dactylon (L.) Pers. x C. transvaalensis, Burtt-Davy, ‘Tifway’] on silt loam (cohesive) and sand root zone conforming to United States Golf Association (USGA) specifications (noncohesive) root zones. Soil water content treatments for the cohesive soil averaged 0.10 m³/m³ (+/- 0.035), 0.17 m³/m³ (+/- 0.035), 0.26 m³/m³ (+/- 0.035), and 0.35 …

Transport Of Water And Ions Through Single-Walled Armchair Carbon Nanotubes: A Molecular Dynamics Study, Michelle Patricia Aranha

Doctoral Dissertations

The narrow hydrophobic interior of a carbon nanotube (CNT) poses a barrier to the transport of water and ions, and yet, unexpectedly, numerous experimental and simulation studies have confirmed fast water transport rates comparable to those seen in biological aquaporin channels. These outstanding features of high water permeability and high solute rejection of even dissolved ions that would typically require a lot of energy for separation in commercial processes makes carbon nanotubes an exciting candidate for desalination membranes. Extending ion exclusion beyond simple mechanical sieving by the inclusion of electrostatics via added functionality to the nanotube bears promise to not …

Analysis Of Primary Stripper Foils At The Spallation Neutron Source By An Electron Beam Foil Test Stand, Eric Paul Barrowclough

Doctoral Dissertations

Diamond films are used at the Spallation Neutron Source (SNS) as the primary charge exchange foils (i.e., stripper foils) of the accelerated 1 GeV (Gigaelectron volts) hydride ions. The most common type of film used is a nanocrystalline diamond film, typically 17 mm x 45 mm (millimeter) with an aerial density of 350 μg/cm² (microgram per square centimeter). The diamond film is deposited on a corrugated silicon substrate using plasma-assisted chemical vapor deposition. After the growth of the diamond film, 30 mm of the silicon substrate is etched away, leaving a freestanding diamond foil with a silicon handle that …

Exploration Of Equal Tune Transverse Coupling In The Spallation Neutron Source Accumulator Ring, Robert Edward Potts Iii

Doctoral Dissertations

The development of hadron machines is one of the main areas of focus in accelerator technology and is specifically called out as a priority in the high energy physics 10-year plan[70]. The trend for future accelerators is to move towards very high-intensity high-power accelerators to be used as proton drivers for secondary particles, target stations, and high-energy accelerators. These accelerators require lower beam losses and more stringent beam controls to maintain typical loss levels and meet specific final beam distributions.

This study focuses on the recently documented coupling resonance in the Spallation Neutron Source (SNS) accumulator ring. It was previously …

Optimal Layout For A Component Grid, Michael W. Ebert

Computer Science and Software Engineering

Several puzzle games include a specific type of optimization problem: given components that produce and consume different resources and a grid of squares, find the optimal way to place the components to maximize output. I developed a method to evaluate potential solutions quickly and automated the solving of the problem using a genetic algorithm.

Noteit Ios App, Waylin W. Wang, Gurjeevan Bains

Computer Science and Software Engineering

Miscommunication is a common struggle that many students face in today’s world, despite the significant technological progress that we have made. With NoteIt, we aimed to solve this issue, by allowing students to join groups based off of the courses that they are enrolled in during the current quarter. Within the app, they can send and receive messages and events from everyone else in the group, or post private reminders to themselves. Communication can range from assignment clarification to exam preparation tips. Overall the development of the application went relatively well, despite some roadblocks along the way. We were satisfied …

Minerva 2017, The Honors College

Minerva

This issue of Minerva includes a feature on Honors College research collaboratives; an article on Honors students studying abroad in Singapore and Chile; an article reflecting upon the 15-year anniversary of the Honors College and the importance of mentorship; and articles on Honors students Isaiah Mansour and Aliya Uteova.

Unit Root Test For Panel Data Ar(1) Time Series Model With Linear Time Trend And Augmentation Term: A Bayesian Approach, Jitendra Kumar, Anoop Chaturvedi, Umme Afifa, Shafat Yousuf, Saurabh Kumar

Journal of Modern Applied Statistical Methods

The univariate time series models, in the case of unit root hypothesis, are more biased towards the acceptance of the Unit Root Hypothesis especially in a short time span. However, the panel data time series model is more appropriate in such situation. The Bayesian analysis of unit root testing for a panel data time series model is considered. An autoregressive panel data AR(1) model with linear time trend and augmentation term has been considered and derived the posterior odds ratio for testing the presence of unit root hypothesis under appropriate prior assumptions. A simulation study and real data analysis are …

'Parallel Universe' Or 'Proven Future'? The Language Of Dependent Means T-Test Interpretations, Anthony M. Gould, Jean-Etienne Joullié

Journal of Modern Applied Statistical Methods

Of the three kinds of two-mean comparisons which judge a test statistic against a critical value taken from a Student t-distribution, one – the repeated measures or dependent-means application – is distinctive because it is meant to assess the value of a parameter which is not part of the natural order. This absence forces a choice between two interpretations of a significant test result and the meaning of the test hypothesis. The parallel universe view advances a conditional, backward-looking conclusion. The more practical proven future interpretation is a non-conditional proposition about what will happen if an intervention is (now) applied …

Quasi-Geostrophic, Two-Layer Model, Mykhailo Rudko

Supplementary Data and Tools

This is a finite-difference, two-layer, quasi-geosotrophic model. The governing equations are the conservation of potential vorticity in each layer with added viscous terms and forcing (Pedlosky, 1987). This model simulates the dynamics of mesoscale currents. The nonlinear term is discretized with Arakawa energy, enstrophy and symmetry conserving scheme. Doubly-periodic boundary conditions are applied. To compile, please, type "make all".

Evaluating Spatial Variability In Sediment And Phosphorus Concentration-Discharge Relationships Using Bayesian Inference And Self-Organizing Maps, Kristen L. Underwood, Donna M. Rizzo, Andrew W. Schroth, Mandar M. Dewoolkar

College of Engineering and Mathematical Sciences Faculty Publications

Given the variable biogeochemical, physical, and hydrological processes driving fluvial sediment and nutrient export, the water science and management communities need data-driven methods to identify regions prone to production and transport under variable hydrometeorological conditions. We use Bayesian analysis to segment concentration-discharge linear regression models for total suspended solids (TSS) and particulate and dissolved phosphorus (PP, DP) using 22 years of monitoring data from 18 Lake Champlain watersheds. Bayesian inference was leveraged to estimate segmented regression model parameters and identify threshold position. The identified threshold positions demonstrated a considerable range below and above the median discharge—which has been used previously …

Catastrophic Failure Of Nacre Under Pure Shear Stresses Of Torsion, Saleh Alghamdi, Ting Tan, Christopher Hale-Sills, Floyd Vilmont, Tian Xia, Jie Yang, Dryver Huston, Mandar Dewoolkar

College of Engineering and Mathematical Sciences Faculty Publications

Nacre, a composite made from biogenic aragonite and proteins, exhibits excellent strength and toughness. Here, we show that nacreous sections can exhibit complete brittle fracture along the tablet interfaces at the proportional limit under pure shear stresses of torsion. We quantitatively separate the initial tablet sliding primarily resisted by nanoscale aragonite pillars from the following sliding resisted by various microscale toughening mechanisms. We postulate that the ductility of nacre can be limited by eliminating tablet interactions during crack propagations. Our findings should help pursuing further insights of layered materials by using torsion.

Mining Drives Extensive Deforestation In The Brazilian Amazon, Laura J. Sonter, Diego Herrera, Damian J. Barrett, Gillian L. Galford, Chris J. Moran, Britaldo S. Soares-Filho

Rubenstein School of Environment and Natural Resources Faculty Publications

Mining poses significant and potentially underestimated risks to tropical forests worldwide. In Brazil's Amazon, mining drives deforestation far beyond operational lease boundaries, yet the full extent of these impacts is unknown and thus neglected in environmental licensing. Here we quantify mining-induced deforestation and investigate the aspects of mining operations, which most likely contribute. We find mining significantly increased Amazon forest loss up to 70 km beyond mining lease boundaries, causing 11,670 km2 of deforestation between 2005 and 2015. This extent represents 9% of all Amazon forest loss during this time and 12 times more deforestation than occurred within mining leases …

Vibronically Coherent Ultrafast Triplet-Pair Formation And Subsequent Thermally Activated Dissociation Control Efficient Endothermic Singlet Fission, Hannah L. Stern, Alexandre Cheminal, Shane R. Yost, Katharina Broch, Sam L. Bayliss, Kai Chen, Maxim Tabachnyk, Karl J. Thorley, Neil Greenham, Justin Hodgkiss, John E. Anthony, Martin Head-Gordon, Andrew J. Musser, Akshay Rao, Richard H. Friend

Chemistry Faculty Publications

Singlet exciton fission (SF), the conversion of one spin-singlet exciton (S₁) into two spin-triplet excitons (T₁), could provide a means to overcome the Shockley–Queisser limit in photovoltaics. SF as measured by the decay of S₁ has been shown to occur efficiently and independently of temperature, even when the energy of S₁ is as much as 200 meV less than that of 2T₁. Here we study films of triisopropylsilyltetracene using transient optical spectroscopy and show that the triplet pair state (TT), which has been proposed to mediate singlet fission, forms on ultrafast timescales …

Three-Dimensional Vapor Intrusion Modeling Approach That Combines Wind And Stack Effects On Indoor, Atmospheric, And Subsurface Domains, Elham Shirazi, Kelly G. Pennell

Civil Engineering Faculty Publications

Vapor intrusion (IV) exposure risks are difficult to characterize due to the role of atmospheric, building and subsurface processes. This study presents a three-dimensional VI model that extends the common subsurface fate and transport equations to incorporate wind and stack effects on indoor air pressure, building air exchange rate (AER) and indoor contaminant concentration to improve VI exposure risk estimates. The model incorporates three modeling programs: (1) COMSOL Multiphysics to model subsurface fate and transport processes, (2) CFD0 to model atmospheric air flow around the building, and (3) CONTAM to model indoor air quality. The combined VI model predicts AER …

Numerical Studies Of Iron Based Superconductors Using Spin-Fermion Models, Christopher Brian Bishop

Doctoral Dissertations

The iron pnictide and iron chalchogenide superconductors are studied numerically using classical Monte Carlo techniques to reproduce experimental data and make predictions about the nature of the relevant interactions. The focus will be using Spin-Fermion models in a classical approximation to explore the phase diagram and calculate important physical properties of these materials over a wide range of temperatures.

Popularity Prediction, Andrew Furgiuele

Computer Science

With the rise in popularity of the Internet, data describing unique types of items has been collected into easy to access sources. Using this newly acquired data, is it possible to predict if an item will become a bestseller while another fade away with time? Popularity prediction is a problem that has attracted a great deal of research recently, and for good reason. The ability to predict an items future rise to popularity or fall to obscurity is a possibly priceless skill and sought out in many different industries such as sales, investments, and marketing. This report enumerates and analyzes …

The Firece Green Fire: Vol. 8 Issue 11, Wofford College Environmental Studies Program

The Fierce Green Fire

No abstract provided.

Canines For Disabled Kids, Erin Jerrett, Margarita Mnatsakanyan, Colleen Reynolds, Yin Wang

School of Professional Studies

Canines for Disabled Kids have been working on behalf of children and their families to educate communities and promote service dog partnerships for almost twenty years. Their advocacy with local legislatures, business owners, and community leaders highlighted the difficulties encountered when differentiating service dogs from emotional support/comfort dogs. Service dogs are entitled to access by the Americans with Disabilities Act (ADA), while emotional support/comfort dogs are not protected under the federal statute or to the same rights. Canines for Disabled Kids proposed a study to obtain a current count of licensed service dogs in the Commonwealth and investigate the feasibility …

Progression Magazine, 2017 Winter, Coastal Carolina University

Progression Magazine

Magazine of the College of Science at Coastal Carolina University.

Comparison Of Ecosystem Processes In A Woodland And Prairie Pond With Different Hydroperiods, Daniel J. Hornbach, Mark C. Hove, Mira W. Ensley-Field, Matthew R. Glasenapp, Ian A. Goodbar, J. Douglas Harman, Benjamin D. Huber, Emily A. Kangas, Kira X. Liu, Molly Stark-Ragsdale, Long K. Tran

Faculty Publications

Shallow lakes and ponds constitute a significant number of water bodies worldwide. Many are heterotrophic, indicating that they are likely net contributors to global carbon cycling. Climate change is likely to have important impacts on these waterbodies. In this study, we examined two small Minnesota ponds; a permanent woodland pond and a temporary prairie pond. The woodland pond had lower levels of phosphorus and phytoplankton than the prairie pond. Using the open water oxygen method, we found the prairie pond typically had a higher level of gross primary production (GPP) and respiration (R) than the woodland pond, although the differences …

Estimating The Contribution Of Dynamical Ejecta In The Kilonova Associated With Gw170817, B. P. Abbott, R. Abbott, T. D. Abbott, F. Acernese, K. Ackley, C. Adams, T. Adams, Marc Favata, Shaon Ghosh, Rodica Martin

Department of Physics and Astronomy Faculty Scholarship and Creative Works

The source of the gravitational-wave (GW) signal GW170817, very likely a binary neutron star merger, was also observed electromagnetically, providing the first multi-messenger observations of this type. The two-week-long electromagnetic (EM) counterpart had a signature indicative of an r-process-induced optical transient known as a kilonova. This Letter examines how the mass of the dynamical ejecta can be estimated without a direct electromagnetic observation of the kilonova, using GW measurements and a phenomenological model calibrated to numerical simulations of mergers with dynamical ejecta. Specifically, we apply the model to the binary masses inferred from the GW measurements, and use the resulting …