Physical Sciences and Mathematics Commons^™

The Potential For Phosphorus Release From Floodplain Soils: Temporal Variability And Management Strategies, Megan Amanda Reavis

Graduate Theses and Dissertations

Soils may contain large amounts of legacy phosphorus (P) due to past application of excess fertilizers, releasing P during runoff and flood events. As the level of P in soils increases, the release of P from the soils increases, but the temporal fluctuations of this release are not well known. Experiments were conducted to examine 1) the variability of soluble reactive P (SRP) release from the soil throughout a year and 2) the effect of repeated flooding and drying cycles on release rates. Soil cores were collected 7 times throughout a year from 2 sites within the Watershed Research and …

A Geochemical Investigation And Comparison Between Organic-Rich Black Shales And Mississippi Valley-Type Pb-Zn Ores In The Southern Ozarks Region, Bryan Michael Bottoms

Graduate Theses and Dissertations

Mississippi Valley-type (MVT) deposits are base metal sulfide deposits that are important economic sources of both Pb and Zn, accounting for 24% of the global Pb and Zn reserves. They are found all over the world, often hosted in platform carbonates on the flanks of sedimentary basins, and often in proximity to hydrocarbons. They are epigenetic, not related to igneous activity, and thought to be sourced from low temperature, highly saline basinal brines that are expelled from sedimentary basins during compaction and/or in conjunction with an orogenic event. The basinal lithologies responsible for providing the metals for the ores are …

Ab Initio Structural Studies Of Cyclobutylmethyl Cations: Effect Of Fluoroalkyl Groups On The Relative Stability Of The Carbocations, Prakash Reddy, Golam Rasul, G. K. Surya Prakash

Chemistry Faculty Research & Creative Works

Ab initio calculations at MP2/cc-pVTZ level show that the trifluoromethyl group has a strong destabilizing effect on the nonclassical, σ-bridged cyclobutylmethyl cations. The GIAO-MP2 derived ¹³C NMR chemical shifts indicate substantial charge delocalization from the neighboring cyclobutyl ring for carbocations with an α-fluorolkyl group as compared to the 1-cyclobutylethyl cation, and this enhanced charge delocalization in case of the α-(trifluoromethyl)cyclobutylmethyl cation would lead to the ring-opening rearrangement to form the relatively more stable nonclassical primary cyclobutylmethyl cation, in which the carbocation center is farthest from the strongly electron-withdrawing trifluoromethyl group.

The Warning On Saturated Fat: From Defective Experiments To Defective Guidelines, Fabian M. Dayrit

Chemistry Faculty Publications

Coconut oil has been adversely affected by the current dietary guidelines that advocate a lowering of total fat and the replacement of saturated fat with polyunsaturated fat. This recommendation has its origins in the saturated fat-cholesterol-heart disease hypothesis that Ancel Keys first proposed in 1957. This hypothesis became an official recommendation with the publication of the Dietary Guidelines for Americans in 1980 and has been adopted by many other countries and international agencies. The dietary recommendations also warn against coconut oil. Recently, the American Heart Association re-issued this warning in its 2017 Presidential Advisory. However, a critical review of the …

Using Pratt's Importance Measures In Confirmatory Factor Analyses, Amrey D. Wu, Bruno D. Zumbo

Journal of Modern Applied Statistical Methods

When running a confirmatory factor analysis (CFA), users specify and interpret the pattern (loading) matrix. It has been recommended that the structure coefficients, indicating the factors’ correlation with the observed indicators, should also be reported when the factors are correlated (Graham, Guthrie, & Thompson, 2003; Thompson, 1997). The aims of this article are: (1) to note the structure coefficient should be interpreted with caution if the factors are specified to correlate. Because the structure coefficient is a zero-order correlation, it may be partially or entirely a reflection of factor correlations. This is elucidated by the matrix algebra of the structure …

Effectively Comparing Differences In Proportions, Lonnie Turpin Jr.

Journal of Modern Applied Statistical Methods

A single framework of developing and implementing tests about proportions is outlined. It avoids some of the pitfalls of methods commonly put forward in an introductory data analysis course.

Power And Sample Size Estimation For Nonparametric Composite Endpoints: Practical Implementation Using Data Simulations, Paul M. Brown, Justin A. Ezekowitz

Journal of Modern Applied Statistical Methods

Composite endpoints are a popular outcome in controlled studies. However, the required sample size is not easily obtained due to the assortment of outcomes, correlations between them and the way in which the composite is constructed. Data simulations are required. A macro is developed that enables sample size and power estimation.

Parameter Estimation In Weighted Rayleigh Distribution, M. Ajami, S. M. A. Jahanshahi

Journal of Modern Applied Statistical Methods

A weighted model based on the Rayleigh distribution is proposed and the statistical and reliability properties of this model are presented. Some non-Bayesian and Bayesian methods are used to estimate the β parameter of proposed model. The Bayes estimators are obtained under the symmetric (squared error) and the asymmetric (linear exponential) loss functions using non-informative and reciprocal gamma priors. The performance of the estimators is assessed on the basis of their biases and relative risks under the two above-mentioned loss functions. A simulation study is constructed to evaluate the ability of considered estimation methods. The suitability of the proposed model …

Characterizations Of Distributions By Expected Values Of Lower Record Statistics With Spacing, M. Faizan, Ziaul Haque, M. A. Ansari

Journal of Modern Applied Statistical Methods

The characterizations of a certain class of probability distributions are established through conditional expectation of lower record values when the conditioned record value may not be the adjacent one. Some of its important deductions are also discussed.

A Double Ewma Control Chart For The Individuals Based On A Linear Prediction, Rafael Perez Abreu, Jay R. Schaffer

Journal of Modern Applied Statistical Methods

Industrial process use single and double Exponential Weighted Moving Average control charts to detect small shifts in it. Occasionally there is a need to detect small trends instead of shifts, but the effectiveness to detect small trends. A new control chart is proposed to detect a small drift.

Jmasm 46: Algorithm For Comparison Of Robust Regression Methods In Multiple Linear Regression By Weighting Least Square Regression (Sas), Mohamad Shafiq, Wan Muhamad Amir, Nur Syabiha Zafakali

Journal of Modern Applied Statistical Methods

The aim of this study is to compare different robust regression methods in three main models of multiple linear regression and weighting multiple linear regression. An algorithm for weighting multiple linear regression by standard deviation and variance for combining different robust method is given in SAS along with an application.

Study Evaluating The Alterations Caused In An Exploratory Factor Analysis When Multivariate Normal Data Is Dichotomized, Rosilei S. Novak, Jair M. Marques

Journal of Modern Applied Statistical Methods

The relationships resulting from the dichotomization of multivariate normal data is a question that causes concern when using exploratory factor analysis. The relationships in an exploratory factor analysis are examined when multivariate normal data, generated by Monte Carlo methods, is dichotomized.

End Matter, Jmasm Editors

Journal of Modern Applied Statistical Methods

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Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

3d Printing Concrete Structures And Verifying Integrity Of Their G-Code Instructions: Border Wall A Case Study, Jason Breland

Dissertations

Thanks to advances in Additive Manufacturing (AM) technology and continued research by academics and entrepreneurs alike, the ability to “3d print” permanent concrete structures such as homes or offices is now a reality. Generally, AM is the process that allows for a 3d model of an object to be converted into hardware instructions to generate that object layer by layer using a malleable medium such as a plastic. Specifically, large scale concrete AM can now generate a structure, such as a building, layer by layer more quickly and efficiently than traditional construction methods [6, 39]. This innovative, semi-autonomous process promises …

Barrier Properties Of Polymer Nanocomposites With Graphene Oxide And Its Derivatives: Mechanism And Applications In Anticorrosive Coatings, Yidan Guan

Dissertations

Metallic devices made from steel or aluminum are subjected to deterioration by environmental contaminants over time. As one of the corrosion control methods, organic coatings show many advantages due to their low cost, versatility, decoration aesthetics and effective protections. Corrosion protection theories and failure modes of organic coatings are still not fully understood due to complicated interactions in the coating-metal-environment system, however, it is widely agreed that the barrier nature of polymeric materials towards aggressive species, such as oxygen, water, electrolyte, plays a key role. Improved barrier property of polymer nanocomposites (PNCs) with two-dimensional (2D) carbon filler, graphene and graphene …

A Public Humanity: The Application Of Isotopic Analysis To The Intersection Between Body And Law At The Milwaukee County Poor Farm Cemetery, Shannon Kate Freire

Theses and Dissertations

The Milwaukee County Poor Farm Cemetery is an umbrella term used to describe the four cemeteries that were used by Milwaukee County from 1878 through 1974 for the burial of the indigent, unclaimed, institutionalized, and anatomized. Three of these cemeteries remain undisturbed. The primary focus of this research is the twice-excavated Cemetery II (Wisconsin Burial Site 47BMI0076), in use between 1882 and 1925. Archaeological excavations in 1991-1992 and again in 2013 resulted in the recovery of over 2,400 individuals from this cemetery location.

In Wisconsin, legislative efforts to govern indigent burial and dissection mediated competing aspirations between medical education and …

God's Number In The Simultaneously-Possible Turn Metric, Andrew James Gould

Theses and Dissertations

In 2010 it was found that God’s number is 20 in the face turn metric. That is, if the Rubik’s cube hasn’t been disassembled, it can always be solved in 20 twists or fewer, but sometimes requires 20 twists. However, the face turn metric only allows one face to be turned at a time for a total of 18 generators, or 18 possible twists at any time. This dissertation allows opposing, parallel faces to be twisted independent amounts at the same time and still get counted as 1 twist for a total of 45 generators. A new optimal-solving program was …

Reassessment Of The Red Drum Stock In Mississippi Coastal Waters: The Role Of Ages 3-5 Year-Class Fish, Emily Satterfield

Master's Theses

Red Drum, Sciaenops ocellatus, are highly sought after by sport fishermen in Mississippi coastal waters. In 2016, Mississippi anglers made over 180,000 fishing trips targeting Red Drum, making it the second most targeted marine species. The current Fishery Management Plan of the Gulf of Mexico Fishery Management Council, prohibits harvest of Red Drum in federal waters. Monitoring of the stock in Mississippi state waters occurs at sites that are almost exclusively estuarine, using gear types selective for juvenile fish. Additional samples come from the for-hire-industry that typically targets larger Red Drum. This project’s goal was to target age three …

Combined Effects Of Dissolved Oxygen And Temperature On Aerobic Respiration And Respiratory Recovery Responses Of The Spioniform Polychaete, Streblospio Gynobranchiata, In Relation To Body Size, Alyssa Bennett

Master's Theses

Elevated surface temperatures exacerbate the threat of hypoxia within coastal ecosystems. These two primary stressors likely interact as they elicit opposing physiological responses from marine organisms. Metabolic depression is typically associated with hypoxia, while metabolic rates increase with temperature. Moreover, physiological effects of combined stressors may not be additive. In light of increasing pressures from hypoxia, elevated ocean temperatures, and other stressors within coastal regions, studies need to examine effects of multiple stressors on physiology of coastal organisms.

Mass-specific aerobic respiration (V_O2) was characterized as a proxy for metabolic cost of Streblospio gynobranchiata, at combined levels of …

Diagnostics For Choosing Between Stratified Logrank And Stratified Wilcoxon, Jhoanne Marsh C. Gatpatan

Dissertations

Martinez and Naranjo (2010) proposed a pretest for choosing between Logrank or Wilcoxon test in a two - sample case. However, in the presence of covariates, comparing two populations without adjusting for covariates would yield misleading results. In this study, we propose several pretests that will help the analyst decide to use stratified Logrank or stratified Wilcoxon tests in comparing two survival curves after covariates have been taken into account. Power performance of each adaptive test was done through simulations under PH and non-PH cases.

Color-Connected Graphs And Information-Transfer Paths, Stephen Devereaux

Dissertations

The Department of Homeland Security in the United States was created in 2003 in response to weaknesses discovered in the transfer of classied information after the September 11, 2001 terrorist attacks. While information related to national security needs to be protected, there must be procedures in place that permit access between appropriate parties. This two-fold issue can be addressed by assigning information-transfer paths between agencies which may have other agencies as intermediaries while requiring a large enough number of passwords and rewalls that is prohibitive to intruders, yet small enough to manage. Situations such as this can be represented by …

A Deep Learníng-Based Data Minimization Algorithm For Big Genomics Data In Support Of Lot And Secure Smart Health Services, Mohammed Aledhari

Dissertations

In the age of Big Genomics Data, institutes such as the National Human Genome Research Institute (NHGRI),1000-Genomes project, and the international cancer sequencing consortium are faced with the challenge of sharing large volumes of data between internationallydispersed sample collectors, data analyzers, and researchers, a process that up until now has been plagued by unreliable transfers and slow connection speeds. These occur due to the inherent throughput bottlenecks of traditional transfer technologies. One suggested solution is using the cloud as an infrastructure to solve the store and analysis challenges. However, the transfer and share of the genomics datasets between biological laboratories …

First Narrow-Band Search For Continuous Gravitational Waves From Known Pulsars In Advanced Detector Data, Benjamin P. Abbott, Marco Cavaglia, For Full List Of Authors, See Publisher's Website.

Physics Faculty Research & Creative Works

Spinning neutron stars asymmetric with respect to their rotation axis are potential sources of continuous gravitational waves for ground-based interferometric detectors. In the case of known pulsars a fully coherent search, based on matched filtering, which uses the position and rotational parameters obtained from electromagnetic observations, can be carried out. Matched filtering maximizes the signal-to-noise (SNR) ratio, but a large sensitivity loss is expected in case of even a very small mismatch between the assumed and the true signal parameters. For this reason, narrow-band analysis methods have been developed, allowing a fully coherent search for gravitational waves from known pulsars …

Statistical And Clinical Equivalence Of Measurements, Puntipa Wanitjirattikal

Dissertations

This study proposes a test for statistical equivalence of two measurements. Typically, a new measurement process Υ is compared to an existing or standard measurement process Χ. We are assuming that Χ and Υ are measurements on the same scale. The paired t-test may be used to check for significant difference between (Χ, Υ) pairs. However, the paired t-test is intended to detect shift-type relationships of the form Υ=Χ+δ1 and may have low power for scale-type relations of the form Υ=γΧ.

We propose a test that has reasonable power to …

An Lntegrated Approach (Remote Sensing, Hydrogeology, Geotechnical, And Geoinformatics) To Assess And Monitor Fossil Aquifers And Associated Land Deformation Over The Arabian Peninsula, Abdullah Ghurmullah Saeed Othman

Dissertations

Deformational features such as subsidence, sinkholes, fissures, settling and cracks in buildings and structures, and earthquakes are being reported from many of the world’s arid lands, in areas where fossil aquifers are being excessively exploited. Using the Lower Mega Aquifer System (LMAS) in Arabia as a test site, I applied an integrated approach (remote sensing, geodesy, GIS, geology, hydrogeology, and geotechnical) to identify nature, intensity, spatial distribution, and factors controlling the observed deformation in the central (Al-Qassim and Ha'il regions; area: 16×10⁴ km²) and the northern (Wadi As-Sirhan Basin; area: ~10.9×10⁴ km²) Arabia. A four -fold approach was adopted to …

Dynamic Child Growth Prediction: A Comparative Methods Approach, Andrada Ivanescu, Ciprian M. Crainiceanu, William Checkley

Department of Applied Mathematics and Statistics Faculty Scholarship and Creative Works

We introduce a class of dynamic regression models designed to predict the future of growth curves based on their historical dynamics. This class of models incorporates both baseline and time-dependent covariates, start with simple regression models and build up to dynamic function-on-function regressions. We compare the performance of the dynamic prediction models in a variety of signal-to-noise scenarios and provide practical solutions for model selection. We conclude that (a) prediction performance increases substantially when using the entire growth history relative to using only the last and first observation; (b) smoothing incorporated using functional regression approaches increases prediction performance; and (c) …

Hemodynamic Characteristics Of Ruptured And Unruptured Multiple Aneurysms At Mirror And Ipsilateral Locations, Ravi Doddasomayajula, Bong Jae Chung, Fernando Mut, Carlos M. Jimenez, Farid Hamzei-Sichani, Christopher M. Putman, Juan R. Cebral

Department of Applied Mathematics and Statistics Faculty Scholarship and Creative Works

BACKGROUND AND PURPOSE: Different hemodynamic patterns have been associated with aneurysm rupture. The objective was to test whether hemodynamic characteristics of the ruptured aneurysm in patients with multiple aneurysms were different from those in unruptured aneurysms in the same patient.

MATERIALS AND METHODS: Twenty-four mirror and 58 ipsilateral multiple aneurysms with 1 ruptured and the others unruptured were studied. Computational fluid dynamics models were created from 3D angiographies. Case-control studies of mirror and ipsilateral aneurysms were performed with paired Wilcoxon tests.

RESULTS: In mirror pairs, the ruptured aneurysm had more oscillatory wall shear stress (P = .007) than the …

A Multi-Country Assessment Of Factors Related To Smallholder Food Security In Varying Rainfall Conditions, Meredith T. Niles, Molly E. Brown

College of Agriculture and Life Sciences Faculty Publications

Given that smallholder farmers are frequently food insecure and rely significantly on rain-fed agriculture, it is critical to examine climate variability and food insecurity. We utilize data from smallholder farmer surveys from 12 countries with 30 years of rainfall data to examine how rainfall variability and household resources are correlated with food security. We find that on average, households that experienced a drier than average year are 3.81 months food insecure, while households within a normal range of rainfall were 3.67 months food insecure, and wetter than average households were 2.86 months food insecure. Reduced odds of food insecurity is …

Machine Learning To Discover And Optimize Materials, Conrad Waldhar Rosenbrock

Theses and Dissertations

For centuries, scientists have dreamed of creating materials by design. Rather than discovery by accident, bespoke materials could be tailored to fulfill specific technological needs. Quantum theory and computational methods are essentially equal to the task, and computational power is the new bottleneck. Machine learning has the potential to solve that problem by approximating material behavior at multiple length scales. A full end-to-end solution must allow us to approximate the quantum mechanics, microstructure and engineering tasks well enough to be predictive in the real world. In this dissertation, I present algorithms and methodology to address some of these problems at …