Physical Sciences and Mathematics Commons^™

The Electrochemical Study Of Simulated Spent Nuclear Fuel (Simfuel) Corrosion Under Permanent Disposal Conditions, Ziyan Zhu

Electronic Thesis and Dissertation Repository

The safety assessment of spent nuclear fuel under permanent disposal conditions requires examination of the corrosion of the spent fuel waste form (UO₂) inside a failed waste container. The objective of this research project was to develop a detailed mechanism of the UO₂ corrosion process when exposed to groundwater. The redox conditions within a failed container in a deep geologic repository will be complex. The oxidant, H₂O₂, produced by the α-radiolysis of groundwater, will be the main driving force for fuel corrosion. However, the efficiency of fuel dissolution will be determined by the …

Lunchtime Keynote Address: The Pamunkey As Partners In Resilience, Robert Gray, Ashley Spivey

Virginia Coastal Policy Center Annual Conference

No abstract provided.

Building Resilience For Our Green & Gray Infrastructure, Carl Hershner, Lance Gregory, Curtis Smith, Angela King

Virginia Coastal Policy Center Annual Conference

No abstract provided.

Introduction/Welcome/Announcements, Kathryn Rowe, Davison M. Douglas, Elizabeth Armistead Andrews

Virginia Coastal Policy Center Annual Conference

No abstract provided.

Visualization, Feature Selection, Machine Learning: Identifying The Responsible Group For Extreme Acts Of Violence, Mahdi Hashemi, Margeret A. Hall

Interdisciplinary Informatics Faculty Publications

The toll of human casualties and psychological impacts on societies make any study on violent extremism worthwhile, let alone attempting to detect patterns among them. This paper is an effort to predict which violent extremist organization (VEO), among 14 currently active ones throughout the world, is responsible for a violent act based on 14 features, including its human and structural tolls, its target type and value, intelligence, and weapons utilized in the attack. Three main steps in our paper include: 1) the visualization of the violent acts through linear and non-linear dimensionality reduction techniques; 2) sequential forward feature selection based …

The Firece Green Fire: Vol. 9 Issue 9, Wofford College Environmental Studies Program

The Fierce Green Fire

No abstract provided.

Multi-Robot Coordination And Scheduling For Deactivation & Decommissioning, Sebastian A. Zanlongo

FIU Electronic Theses and Dissertations

Large quantities of high-level radioactive waste were generated during WWII. This waste is being stored in facilities such as double-shell tanks in Washington, and the Waste Isolation Pilot Plant in New Mexico. Due to the dangerous nature of radioactive waste, these facilities must undergo periodic inspections to ensure that leaks are detected quickly. In this work, we provide a set of methodologies to aid in the monitoring and inspection of these hazardous facilities. This allows inspection of dangerous regions without a human operator, and for the inspection of locations where a person would not be physically able to enter.

First, …

An Introduction To Quantile-Quantile Plots For The Experimental Physicist, Allen Andersen, Jr Dennison

Journal Articles

No abstract provided.

A Cost Benefit Analysis Of Using A Battery Energy Storage System (Bess) Represented By A Unit Commitment Model, Nemanja Mihailovic

USF Tampa Graduate Theses and Dissertations

This thesis aims to provide a general overview of a cost and benefit analysis of incorporating a battery energy storage system within unit commitment model.

The deregulation of the electricity market in the U.S. has only been around for the last two decades. With renewable energy and energy storage systems becoming less expensive, a decentralized market scheme is becoming more popular and plausible. The scope of this work is to provide a fundamental understanding of unit commitment and a cost analysis of applying a battery energy storage system to an already established power system.

A battery energy storage system (BESS) …

Analysis And New Applications Of Metal Organic Frameworks (Mof): Thermal Conductivity Of A Perovskite-Type Mof And Incorporation Of A Lewis Pair Into A Mof., Wilarachchige D C B Gunatilleke

USF Tampa Graduate Theses and Dissertations

Metal organic frameworks have gained much attention due to their tunable pore sizes and very high surface areas. With the discovery many of these type materials the need has raised to look into new applications of theses porous frameworks. This thesis focuses on the synthesis of a new perovskite-type metal organic framework and measurement of its thermal conductivity in search of its applicability as a thermoelectric material. The second part of this work focuses on the synthesis of a metal organic framework incorporated with a Lewis pair for the first time. The optimum loading amount of the Lewis pair into …

Elevation And Azimuth-Aided Channel Estimation Scheme For Airborne Hyperspectral Data Transmission, Vahid Vahidi, Ebrahim Saberinia

Electrical & Computer Engineering Faculty Research

A channel-estimation (CE) scheme is proposed to estimate the complex amplitude, Doppler shift, angle-of-departure, and angle-of-arrival of the channel taps for sparse and doubly selective channels for hyperspectral image transmission from unmanned aircraft vehicles (UAVs) to ground stations. The proposed method is dubbed as compressed-sensing joint parameter estimation (CS-JPE) and finds the channel parameters matrix by employing a compressed-sensing (CS)-based method. Afterward, a modified version of the joint parameter estimation (JPE) is proposed as CS-JPE and is dubbed as M-CS-JPE, which employs the elevation-azimuth angles of the line-of-sight channel tap to estimate the channel parameters with higher accuracy and lower …

Automatic Extraction Of Narrative Structure From Long Form Text, Joshua Daniel Eisenberg

FIU Electronic Theses and Dissertations

Automatic understanding of stories is a long-time goal of artificial intelligence and natural language processing research communities. Stories literally explain the human experience. Understanding our stories promotes the understanding of both individuals and groups of people; various cultures, societies, families, organizations, governments, and corporations, to name a few. People use stories to share information. Stories are told –by narrators– in linguistic bundles of words called narratives.

My work has given computers awareness of narrative structure. Specifically, where are the boundaries of a narrative in a text. This is the task of determining where a narrative begins and ends, a …

Interaction Between Gravitational Radiation And Electromagnetic Radiation, Preston Jones, Douglas Singleton

Publications

In this review paper we investigate the connection between gravity and electromagnetism from Faraday to the present day. The particular focus is on the connection between gravitational and electromagnetic radiation. We discuss electromagnetic radiation produced when a gravitational wave passes through a magnetic field. We then discuss the interaction of electromagnetic radiation with gravitational waves via Feynman diagrams of the process graviton + graviton → photon + photon. Finally we review recent work on the vacuum production of counterpart electromagnetic radiation by gravitational waves.

Integrating Towed Underwater Video With Multibeam Acoustics For Mapping Benthic Habitat And Assessing Reef Fish Communities On The West Florida Shelf, Alexander Ross Ilich

USF Tampa Graduate Theses and Dissertations

Using a towed underwater video camera system, benthic habitats were classified along transects in a popular offshore fishing area on the West Florida Shelf (WFS) known as “The Elbow.” Additionally, high resolution multibeam bathymetry and co-registered backscatter data were collected for the entire study area. Using these data, full coverage geologic and biotic habitat maps were developed using both unsupervised and supervised statistical classification methodologies. The unsupervised methodology used was k-means clustering, and the supervised methodology used a random forest algorithm. The two methods produced broadly similar results; however, the supervised methodology outperformed the unsupervised methodology. The results of the …

Measuring And Modeling Evolution Of Cryoconite Holes In The Mcmurdo Dry Valleys, Antarctica, Felix Jacob Zamora

Dissertations and Theses

Cryoconite holes are vertical columns of meltwater within the shallow subsurface of glaciers. In the McMurdo Dry Valleys (MDV) of Antarctica cryoconite holes are a source of meltwater and harbor microbial communities in an otherwise arid environment with low biologic activity. The holes form as sediments on the ice surface, which are darker than the surrounding ice, are preferentially heated by solar radiation. The warm sediments melt the underlying ice and migrate downwards. An ice lid forms, isolating them from the below-freezing atmosphere enabling them to remain thawed. In this study, field observations, laboratory experiments, and numerical modeling are used …

Fast Radio Burst Energetics And Detectability From High Redshifts, Bing Zhang

Physics & Astronomy Faculty Research

We estimate the upper limit redshifts of known fast radio bursts (FRBs) using the dispersion measure (DM)-redshift (z) relation and derive the upper limit peak luminosity L p and energy E of FRBs within the observational band. The average z upper limits range from 0.17 to 3.10, the average L p upper limits range from 1.24 × 1042 erg s−1 to 7.80 × 1044 erg s−1, and the average E upper limits range from 6.91 × 1039 erg to 1.94 × 1042 erg. FRB 160102 with DM = 2596.1 ± 0.3 pc cm−3 likely has a redshift greater than 3. …

Quantification Of Cloud Condensation Nuclei Effects On The Microphysical Structure Of Continental Thunderstorms Using Polarimetric Radar Observations, Kun-Yuan Lee

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Aerosols serving as cloud condensation nuclei (CCN) are crucial to the microphysical structure of thunderstorms. They can also alter the rate of cloud microphysical processes, the moisture profile and the local temperature as a result of latent heating/cooling in the early stage of thunderstorm development. Continental thunderstorms are characterized by high complexity and are highly influenced by environmental conditions. The purpose of this study is to determine the influences of CCN concentration on the microphysics of continental thunderstorms, using a sample of storms from northwestern Oklahoma. The Weather Surveillance Radar-1988 Doppler (WSR-88D) at Vance Air Force Base (KVNX) was upgraded …

Groundwater Recharge Response To Reduced Irrigation Pumping In Western Nebraska, Justin Philip Gibson

School of Natural Resources: Dissertations, Theses, and Student Research

Given current and continued investment in irrigation scheduling technologies, a need exists to better estimate the longevity and magnitude of water savings at watershed level to avoid the paradox of irrigation efficiency. This paradox occurs within a watershed as not all irrigation inefficiencies lead to the system losing water. For example, irrigation pumping rates in excess of crop water demand may lead to enhanced groundwater recharge or surface runoff that migrates to a stream. Thus, increases in efficiency may not lead to similar magnitudes of water savings. I hypothesize that water savings longevities are short given previous work demonstrating rapid …

Examining Patterns In Nest Predation Using Artificial Nests, Victoria L. Simonsen

School of Natural Resources: Dissertations, Theses, and Student Research

The use of artificial nests to study the predation of avian nests has faced disregard by ecologists due to inconsistencies found between the survival rates of real and artificial nests across studies and reviews. The negative perception of artificial nests providing an inconsistent assessment of survival has thus fostered the perception that artificial nests are a secondary option to be used to overcome logistical hurdles associated with achieving sufficient sample sizes in systems where study species are rare or elusive, or as merely a preliminary method to study predation across gradients. We argue that the greatest mistake ecologists have made …

A Multidecade Experiment Shows That Fertilization By Salmon Carcasses Enhanced Tree Growth In The Riparian Zone, Thomas P. Quinn, Helfield M. James, Catherine S. Austin, Rachel A. Hovel, Andrew Godard Bunn

Environmental Sciences Faculty and Staff Publications

As they return to spawn and die in their natal streams, anadromous, semelparous fishes such as Pacific salmon import marine‐derived nutrients to otherwise nutrient‐poor freshwater and riparian ecosystems. Diverse organisms exploit this resource, and previous studies have indicated that riparian tree growth may be enhanced by such marine‐derived nutrients. However, these studies were largely inferential and did not account for all factors affecting tree growth. As an experimental test of the contribution of carcasses to tree growth, for 20 yr, we systematically deposited all sockeye salmon (Oncorhynchus nerka) carcasses (217,055 individual salmon) in the riparian zone on one …

Interactions Between Spermine-Derivatized Tentacle Porphyrins And The Human Telomeric Dna G-Quadruplex, Navin C. Sabharwal , '14, Jessica Chen , '17, Joo Hyun Lee , '17, C. M. A. Gangemi, A. D'Urso, Liliya A. Yatsunyk

Chemistry & Biochemistry Faculty Works

G-rich DNA sequences have the potential to fold into non-canonical G-Quadruplex (GQ) structures implicated in aging and human diseases, notably cancers. Because stabilization of GQs at telomeres and oncogene promoters may prevent cancer, there is an interest in developing small molecules that selectively target GQs. Herein, we investigate the interactions of meso-tetrakis-(4-carboxysperminephenyl)porphyrin (TCPPSpm4) and its Zn(II) derivative (ZnTCPPSpm4) with human telomeric DNA (Tel22) via UV-Vis, circular dichroism (CD), and fluorescence spectroscopies, resonance light scattering (RLS), and fluorescence resonance energy transfer (FRET) assays. UV-Vis titrations reveal binding constants of 4.7 × 10⁶ and 1.4 × 10⁷ M⁻¹ and binding stoichiometry of …

The Dpg-Star Method, Leszek Demkowicz, Jay Gopalakrishnan, Brendan Keith

Portland Institute for Computational Science Publications

This article introduces the DPG-star (from now on, denoted DPG*) finite element method. It is a method that is in some sense dual to the discontinuous Petrov– Galerkin (DPG) method. The DPG methodology can be viewed as a means to solve an overdetermined discretization of a boundary value problem. In the same vein, the DPG* methodology is a means to solve an underdetermined discretization. These two viewpoints are developed by embedding the same operator equation into two different saddle-point problems. The analyses of the two problems have many common elements. Comparison to othermethods in the literature round out the newly …

The Importance Of Culture In Predicting Environmental Behavior In Middle School Students On Hawai‘I Island, Rachelle K. Gould, Daniel H. Krymkowski, Nicole M. Ardoin

Rubenstein School of Environment and Natural Resources Faculty Publications

Researchers have investigated the factors that influence environmental behavior for decades. Two often-investigated phenomena, connectedness to nature and self-efficacy, often correlate with environmental behavior, yet researchers rarely analyze those correlations along with underlying cultural factors. We suggest that this is a substantial oversight and hypothesize that cultural factors affect environmental behavior, particularly through an interplay with the connectedness to nature and self-efficacy constructs. To test this hypothesis, we surveyed eighth-grade students on the island of Hawai‘i. The instrument included items to assess connectedness to nature and self-efficacy (both frequently measured in environmental behavior studies) and multiple measures of behavior. Most …

Crystal Structure Of The 13-(E)-(2-Aminobenzylidene)-Parthenolide, Shobanbabu Bommagani, Narsihma R. Penthala, Sean Parkin, Peter A. Crooks

Chemistry Faculty Publications

The title compound, C₂₁H₂₅NO₃ [systematic name: (1aR,4E,7aS,8E,10aS,10bR)-8-(2-amino­benzyl­idene)-1a,5-dimethyl-2,3,6,7,7a,8,10a,10b-octa­hydro­oxireno[2′,3′:9,10]cyclo­deca­[1,2-b]furan-9(1aH)-one], was synthesized by the reaction of parthenolide [systematic name (1aR,7aS,10aS,10bS,E)-1a,5-dimethyl-8-methyl­ene-2,3,6,7,7a,8,10a,10b-octa­hydro­oxireno[2′,3′:9,10]cyclo­deca­[1,2-b]furan-9(1aH)-one] with 2-iodo­aniline via Heck reaction conditions. The mol­ecule is composed of fused ten-, five- (lactone), and three-membered (epoxide) rings. The lactone ring shows a flattened envelope-type conformation (r.m.s. deviation from planarity = 0.0477 Å), and bears a 2-amino­benzyl­idene substituent that is disordered over two conformations [occupancy …

Blood Transfusions In Preterm Infants: Changes On Perfusion Index And Intermittent Hypoxemia, Katrina T. Ibonia, Henrietta S. Bada, Philip M. Westgate, Enrique Gomez Pomar, Prasad Bhandary, Abhijit R. Patwardhan, Elie G. Abu Jawdeh

Pediatrics Faculty Publications

BACKGROUND

Red blood cell (RBC) transfusion decreases intermittent hypoxemia (IH) events beyond the first week of life. This benefit may be related to improved perfusion to the respiratory control network. Perfusion index (PI) is a perfusion measure provided by the pulse oximeter. We hypothesized that the benefit in IH after RBC transfusion is associated with an increase in PI. In addition, we assessed the value of PI and clinical measures in predicting the effect of RBC transfusion on IH.

STUDY DESIGN AND METHODS

We prospectively enrolled infants less than 30 weeks' gestation age. PI and oxygen saturation (SpO₂) …

Studying The [O Iii]Λ5007 Å Emission-Line Width In A Sample Of ∼ 80 Local Active Galaxies: A Surrogate For Σ⋆?, Vardha Nicola Bennert, Donald Loveland, Edward Donohue, Maren Cosens, Sean Lewis, S. Komossa, Tommaso Treu, Matthew A. Malkan, Nathan Milgram, Kelsi Flatland, Matthew W. Auger, Daesong Park, Mariana S. Lazarova

Physics

For a sample of ∼ 80 local (0.02 ≤ z" role="presentation">z ≤ 0.1) Seyfert-1 galaxies with high-quality long-slit Keck spectra and spatially resolved stellar-velocity dispersion (σ_⋆) measurements, we study the profile of the [O iii]λ5007 Å emission line to test the validity of using its width as a surrogate for σ_⋆. Such an approach has often been used in the literature, since it is difficult to measure σ_⋆ for type-1 active galactic nuclei (AGNs) due to the AGN continuum outshining the stellar-absorption lines. Fitting the [O iii] line with a single Gaussian or Gauss–Hermite …

Preface, Weixing Song

Conference on Applied Statistics in Agriculture

Preface

Ecosystem Based Fisheries Management (Ebfm) Risk Assessment Of The Western Australian Sea Cucumber Fishery, F J. Webster, Anthony M. Hart

WA Marine Stewardship Council report series

This report provides a comprehensive overview of the commercial Western Australian Sea Cucumber Fishery (SCF) and the outcomes from the 2016 ecological risk assessment for this fishery. Two key species, sandfish (Holothuria scabra) and redfish (Actinopyga echinites), are targeted by the commercial SCF through hand collection by diving and wading primarily in shallow waters of northern WA.

Climate Change Implications For Irrigation And Groundwater In The Republican River Basin, Usa, Gengxin Ou, Francisco Munoz-Arriola, Daniel R. Uden, Derrel Martin, Craig R. Allen, Nancy Shank

School of Natural Resources: Faculty Publications

This study investigates the influence of climate change on groundwater availability, and thereby, irrigation across political boundaries within the US High Plains aquifer. A regression model is developed to predict changes in irrigation according to predicted changes in precipitation and temperature from a downscaled dataset of 32 general circulation models (GCMs). Precipitation recharge changes are calculated with precipitation recharge curves developed for prognostic representations of precipitation across the Nebraska-Colorado-Kansas area and within the Republican River Basin focal landscape. Irrigation-recharge changes are scaled with changes in irrigation. The groundwater responses to climate forcings are then simulated under new pumping and recharge …

Early Warnings For State Transitions, Caleb P. Roberts, Dirac Twidwell, Jessica L. Burnett, Victoria M. Donovan, Carissa L. Wonkka, Christine L. Bielski, Ahjond S. Garmestani, David G. Angeler, Tarsha Eason, Brady W. Allred, Matthew O. Jones, David E. Naugle, Shana M. Sundstrom, Craig R. Allen

School of Natural Resources: Faculty Publications

New concepts have emerged in theoretical ecology with the intent to quantify complexities in ecological change that are unaccounted for in state-and-transition models and to provide applied ecologists with statistical early warning metrics able to predict and prevent state transitions. With its rich history of furthering ecological theory and its robust and broad-scale monitoring frameworks, the rangeland discipline is poised to empirically assess these newly proposed ideas while also serving as early adopters of novel statistical metrics that provide advanced warning of a pending shift to an alternative ecological regime. We review multivariate early warning and regime shift detection metrics, …