Physical Sciences and Mathematics Commons^™

Re-Evaluation Of The Extent And Tectonic History Of The Helena Banks Fault Zone, Offshore South Carolina, Ahmet Postaagasi

Theses and Dissertations

The Helena Banks Fault Zone (HBFZ), first identified in the early 1980’s offshore Charleston, S.C., was originally interpreted to be a major, high-angle, basin-bounding normal fault associated with Mesozoic rifting. Subsequent work suggests that (1) Mesozoic rift basins are not present on the continental shelf of South Carolina, (2) the HBFZ originated as a strike-slip fault within Paleozoic sedimentary rocks of the Suwannee Basin sequence, (3) a mafic intrusion inferred from aeromagnetic data is coincident with a broadly circular zone of highly-complex faulting along the north-eastward continuation of the HBFZ where (4) up to 300 m of local relief can …

Salt Tectonism In The Carolina Trough, Ceren Postaagasi

Theses and Dissertations

The Carolina Trough is a major linear sedimentary basin along the eastern continental margin of North America which formed as a result of tectonic and thermal subsidence during continental rifting in Mesozoic time (Hutchinson et al., 1982). The Carolina Trough is unique along the southeastern U.S. margin where the only known evaporite deposits are found, and this salt basin may reserve large amounts of oil and gas (Carpenter & Amato, 1992). Therefore, analysis of 2D multichannel seismic reflection surveys that were conducted in the Mid-South Atlantic Ocean in 1982 plays an important role in Petroleum industry. In addition, current interpretations …

Organic Acids And Amino Acids In Serpentinization Related Fluids From The Atlantis Massif, Nicholas Camper

Theses and Dissertations

Serpentinization is a low temperature, low pressure process that occurs when water reacts with ultramafic rocks. Fluids that have interacted with serpentinites have elevated concentrations of hydrogen and reduced carbon species that can fuel chemolithoautotrophy. International Ocean Discovery Program Expedition 357 drilled a series of boreholes into the Atlantis Massif with the goal of investigating how serpentinization impacts carbon cycling and sustains life in the subseafloor. Bottom water samples (CTD), fluids flushed from the boreholes during drilling (Rock Drill), and fluids that were trapped in the liners of the cores (Liner fluids) were collected. The changes and distributions of organic …

Investigation Of The Spatial Dependence Of Carrier Dynamics In Semiconductor Optoelectronic Devices, Bobby G. Barker Jr.

Theses and Dissertations

Optoelectronic devices, such as solar cells and photodetectors, rely on separating and transporting charge through semiconductors that have excess electron-hole pairs created by photon absorption. This talk will focus of several different semiconductor materials of various dimensionality, such as lead halide perovskites, wide bandgap SiC, graphene, semiconductor nanowires (NWs), and quantum dots (QDs).

The results of Chapter 2 demonstrate the dependence of the perovskite/hole transport layer on carrier transport of perovskite films for solar cells. Efficient charge separation at the interfaces of the perovskite with the carrier transport layers is crucial for perovskite solar cells to achieve high power conversion …

Goodness Of Fit Via Residual Plots In Item Response Theory, Bryonna Bowen

Theses and Dissertations

Goodness-of-fit criteria developed for the evaluation of item response functions have been examined by many scholars using different theories and criteria. A number of potential graphical analysis approaches, such as residual plots, have been described in literature, but have received little attention from researchers. While many tests of goodness-of-fit are available, those that incorporate the analysis of residuals may be most useful. The unmistakable presence of a pattern in the residual plot for the logistic model item response functions even when we know the model fits raises a red flag up and calls for greater analysis. This study explores different …

Sustainable Soybean Oil And Lignin Derived Monomers And Polymers For Potential Use In Polymeric Materials, Ryan Miskin

Theses and Dissertations

In this thesis project, high oleic soybean oil and lignin derived monomers and polymers are investigated. The properties of these monomers and polymers are characterized and discussed.

Chapter 1 details the potential impact of bio-based resources, monomers, and polymers on the environment. An introduction on polymerization techniques is given, and the overall objectives of my research are discussed.

In Chapter 2, attempts are made at modifying a soybean oil derived thermoplastic polymer into a vitrimer. The synthesis of thermoplastics is reviewed and the vitrimer trials outlined. Different scenarios that arose are examined and discussed.

Chapter 3 outlines the preparation of …

Classifying The Woody Vegetation Community Of Wade Ponds In Colleton County, South Carolina, Wade Biltoft

Theses and Dissertations

Wetland habitats are some of the most biodiverse ecosystems in the world, varying in both physical and biological characteristics. Geographically isolated wetlands are particularly important to the landscape due to their role in the hydrological cycle and as local centers for biodiversity. In parts of the coastal plain of South Carolina, there are geographically isolated wetlands found in concentrated groups with distinctive size, shape, and distribution. Despite their unique appearance and distribution, these wetlands have been scarcely researched or investigated. This project seeks to explore the plant communities that are contained within these ponds in order to understand their composition …

Local Rings And Golod Homomorphisms, Thomas Schnibben

Theses and Dissertations

The Poincaré series of a local ring is the generating function of the Betti numbers for the residue field. The question of when this series represents a rational function is a classical problem in commutative algebra. Golod rings were introduced by Golod in 1962 and are one example of a class of rings that have rational Poincaré series. The idea was generalized to Golod homomorphisms by Levin in 1975.

In this paper we prove two homomorphisms are Golod. The first is a class of ideals such that the natural projection to the quotient ring is a Golod homomorphism. The second …

Semiparametric Statistical Estimation And Inference With Latent Information, Qianqian Wang

Theses and Dissertations

In Chapter 1, we predicted disease risk by transformation models in the presence of missing subgroup identifiers. When a discrete covariate defining subgroup membership is missing for some of the subjects in a study, the distribution of the outcome follows a mixture distribution of the subgroup-specific distributions. Taking into account the uncertain distribution of the group membership and the covariates, we model the relation between the disease onset time and the covariates through transformation models in each sub-population, and develop a nonparametric maximum likelihood based estimation implemented through EM algorithm along with its inference procedure. We further propose methods to …

Bayesian Semiparametric Methods For Analyzing Panel Count Data, Jianhong Wang

Theses and Dissertations

Panel count data commonly arise in epidemiological, social science, medical studies, in which subjects have repeated measurements on the recurrent events of interest at different observation times. Since the subjects are not under continuous monitoring, the exact times of those recurrent events are not observed but the counts of such events within the adjacent observation times are known. Panel count data can be considered as a special type of longitudinal data with a count response variable in the literature. Compared to the frequentist literature, very limited Bayesian approaches have been developed to analyze panel count data. In this dissertation, several …

Special Fiber Rings Of Certain Height Four Gorenstein Ideals, Jaree Hudson

Theses and Dissertations

Let S be a set of four variables, k a field of characteristic not equal to two such that k contains all square roots, and I a height four Gorenstein ideal of k[S] generated by nine quadratics so that I has a Gorenstein-linear resolution. We define a complex X• so that each module of X• is the tensor product of a certain polynomial ring Q in nine variables and a direct sum of indecomposable k[Sym(S)]-modules and the differential maps are Q- and k[Sym(S)]-module homomorphisms. Work with the Macaulay2 software suggests that H0(X•) is the special fiber ring of I and …

Development And Evaluation Of Post-Production Oxygenation Techniques For The Augmentation Of Biochar, Matthew David Huff

Chemistry & Biochemistry Theses & Dissertations

Biochar is the carbon rich solid by-product of biomass pyrolysis. Interest in biochar can be broken down to several main categories: use as a carbon sequestration agent, use as a medium for the removal via adsorption of unwanted materials in wastewater, and as a soil amendment for the increase of cation exchange capacity (CEC). In order to generate a biochar which is stable enough for carbon sequestration, higher temperature pyrolysis must be used in order to ensure a lower O:C ratio in order to increase the half-life of biochar in soil. This dissertation addresses the evaluation of biochars made from …

Offshore Wind Energy: Simulating Local Offshore Wind Turbine, Ian P. Aquino

Mechanical & Aerospace Engineering Theses & Dissertations

Dominion Virginia Energy is looking at the possible creation of an offshore wind plant as a renewable source of electricity to be located off the coast of Virginia Beach. This thesis reports on a computer simulation based on local wind conditions and possible single wind turbine installation.

The National Buoy Data Center keeps records of the local wind conditions gathered in real time and available to the public. These data give a general overview of the wind conditions in Virginia Beach which is used to simulate atmospheric boundary layer (ABL) flow conditions and is subsequently used as input data for …

Regional Sea Level Rise Along The United States Coasts, Alessandra G. Burgos

OES Theses and Dissertations

Over the past several years, there has been several studies focused on reconstructing global mean sea level (GMSL) for the 20th century, along with projecting rates out into the future. Of greater importance for mitigation and adaptation plans, however, is the rate of local or regional sea level (RSL) rise. Ocean dynamics along with changes in Earth’s gravitational field can cause RSL to deviate from the change in GMSL. During the satellite altimeter era covering the past two decades, RSL trends can be four times the global average, with much of this spatial variation due to internal climate variability. Isolating …

Computational Investigation Of Energetic Materials: Influence Of Intramolecular And Intermolecular Interactions On Sensitivity, Ashley Lauren Shoaf

Chemistry & Biochemistry Theses & Dissertations

The development of novel high energy density materials (HEDMs) with superior energetic properties depends on characterizing how and why detonation occurs. Detonation is highly energetic and a nearly instantaneous process, making experimental studies challenging; thus, computational modeling through density functional theory (DFT) and molecular dynamics (MD) can be used to propose weakened, or activated, bonds that break to initiate explosive decomposition, termed trigger bonds. Bond activation is characterized by the Wiberg bond index (WBI), a measure of interatomic electron density. Trigger bonds in HEDMs are commonly found in explosophores, functional groups that contribute to energetic potential such as X-NO_{2 …}

Crab Cavity Requirements For The Jefferson Lab Electron-Ion Collider, Salvador Isaac Sosa Güitrón

Physics Theses & Dissertations

An Electron-Ion Collider (EIC) has been proposed to be the next large facility to explore the dynamics of quarks and gluons inside nuclei. A conceptual design for a Jefferson Lab Electron-Ion Collider (JLEIC) is being developed. It is based on the CEBAF 12 GeV machine as a full energy electron beam injector. Two crucial requirements of JLEIC are high luminosity in the 10³⁴ cm^-2s^-1 range, and full acceptance detection of particles. The full acceptance requirement relies on having the beams collide at a relatively large crossing angle of 50 mrad. Such a large crossing angle, however, …

Applying Machine Learning To Advance Cyber Security: Network Based Intrusion Detection Systems, Hassan Hadi Latheeth Al-Maksousy

Computer Science Theses & Dissertations

Many new devices, such as phones and tablets as well as traditional computer systems, rely on wireless connections to the Internet and are susceptible to attacks. Two important types of attacks are the use of malware and exploiting Internet protocol vulnerabilities in devices and network systems. These attacks form a threat on many levels and therefore any approach to dealing with these nefarious attacks will take several methods to counter. In this research, we utilize machine learning to detect and classify malware, visualize, detect and classify worms, as well as detect deauthentication attacks, a form of Denial of Service (DoS). …

Development Of A 300 Kv Dc High Voltage Photogun And Beam Based Studies Of Alkali Antimonide Photocathodes, Yan Wang

Physics Theses & Dissertations

To advance magnetized gun research in the United States, a compact DC high voltage photogun with inverted-insulator geometry was designed, built, and operated reliably at - 300 kV bias voltage using alkali-antimonide photocathodes. This photogun will provide a magnetized electron beam for the future Jefferson Lab Electron-Ion Collider (JLEIC) cooler. This research describes key electrostatic design features of the photogun and evaluates the performance of the in-house fabricated photocathodes and the quality of the electron beams. The thermal emittance of the electron beam was measured with various conditions: different gun bias voltages, different laser spot sizes, and photocathodes with different …

Human-Intelligence And Machine-Intelligence Decision Governance Formal Ontology, Faisal Mahmud

Engineering Management & Systems Engineering Theses & Dissertations

Since the beginning of the human race, decision making and rational thinking played a pivotal role for mankind to either exist and succeed or fail and become extinct. Self-awareness, cognitive thinking, creativity, and emotional magnitude allowed us to advance civilization and to take further steps toward achieving previously unreachable goals. From the invention of wheels to rockets and telegraph to satellite, all technological ventures went through many upgrades and updates. Recently, increasing computer CPU power and memory capacity contributed to smarter and faster computing appliances that, in turn, have accelerated the integration into and use of artificial intelligence (AI) in …

Approximation Of Quantiles Of Rank Test Statistics Using Almost Sure Limit Theorems, Mark Ledbetter

Mathematics & Statistics Theses & Dissertations

There are many problems in statistics where the analysis is based on asymptotic distributions. In some cases, the asymptotic distribution is in an open form or is intractable. One possible solution is the logarithmic quantile estimation (LQE) method introduced by Thangavelu (2005) for rank tests and Fridline (2010) for the correlation coefficient. LQE is derived from an almost sure version of the central limit theorem using the results of Berkes and Csaki (2001), and it estimates the quantiles of a test statistic using only the data. To date, LQE has been used in only a few applications. We extend the …

Structure Of The Picornavirus Replication Platform: A Potential Drug Target For Inhibiting Virus Replication, Meghan Suzanne Warden

Chemistry & Biochemistry Theses & Dissertations

Picornaviruses are small, positive-stranded RNA viruses, divided into twelve different genera. Members of the Picornaviridae family cause a wide range of human and animal diseases including the common cold, poliomyelitis, foot and mouth disease, and dilated cardiomyopathy. The picornavirus genome is replicated via a highly conserved mechanism involving a presumed cloverleaf structure located at the 5’ noncoding region of the virus genome. The 5’ cloverleaf consists of three stem loops (B, C, and D) and one stem (A), which interact with a variety of virus and host cell proteins during replication. In this dissertation, human rhinovirus serotype 14 (HRV-14) SLB …

A Multi-Criteria And Dynamic Sustainability Assessment Of Crop Rotation Alternatives, Saturnina Fabian Nisperos

Computational Modeling & Simulation Engineering Theses & Dissertations

With the food security challenge faced by nations globally, agriculture sustainability has been a significant consideration for concerned agencies. Sustainability assessments are significant tools in providing support to stakeholders in their crop production planning. Agricultural sustainability assessment, however, is complex and it involves numerous criteria that can be conflicting. Limitations on crop rotation sustainability assessment methods include: non-dynamic assessment; lack of regard to cover crops and to the individual crop production preferences of farmers; and focused only on single-year and single-crop rotation. We sought to address these limitations by developing a multi-criteria and dynamic sustainability assessment model that considers the …

Adaptive Methods For Point Cloud And Mesh Processing, Zinat Afrose

Computational Modeling & Simulation Engineering Theses & Dissertations

Point clouds and 3D meshes are widely used in numerous applications ranging from games to virtual reality to autonomous vehicles. This dissertation proposes several approaches for noise removal and calibration of noisy point cloud data and 3D mesh sharpening methods. Order statistic filters have been proven to be very successful in image processing and other domains as well. Different variations of order statistics filters originally proposed for image processing are extended to point cloud filtering in this dissertation. A brand-new adaptive vector median is proposed in this dissertation for removing noise and outliers from noisy point cloud data.

The major …

Wet And Dry Atmospheric Deposition Of Nutrients And Bioactive Trace Metals To Coastal Waters Of The Mid-Atlantic Bight, Christine Sookhdeo

OES Theses and Dissertations

Atmospheric deposition provides a significant source of nutrients and bioactive trace metals to the surface ocean, including the seasonally oligotrophic waters of the Mid-Atlantic Bight. These atmospherically derived nutrients and trace metals enter the surface ocean via dry deposition of aerosols and wet deposition in rain. To estimate the aeolian input of nutrients and trace metals to coastal waters east of the Delmarva Peninsula, wet and dry atmospheric deposition samples were collected over a one-year time series at the Anheuser-Busch Coastal Research Center, Oyster, Virginia. Weekly composite samples were collected from May 2014 through June 2015. Nutrient species examined were …

Deep Recurrent Learning For Efficient Image Recognition Using Small Data, Mahbubul Alam

Electrical & Computer Engineering Theses & Dissertations

Recognition is fundamental yet open and challenging problem in computer vision. Recognition involves the detection and interpretation of complex shapes of objects or persons from previous encounters or knowledge. Biological systems are considered as the most powerful, robust and generalized recognition models. The recent success of learning based mathematical models known as artificial neural networks, especially deep neural networks, have propelled researchers to utilize such architectures for developing bio-inspired computational recognition models. However, the computational complexity of these models increases proportionally to the challenges posed by the recognition problem, and more importantly, these models require a large amount of data …

On The Composition Of Derivatives, Krzysztof Ciesielski

Faculty & Staff Scholarship

We show that there exists a derivative f : [0, 1] → [0, 1] such that the graph of f ◦ f is dense in [0, 1]2 , so not a Gδ-set. In particular, f ◦ f is everywhere discontinuous, so not of Baire class 1, and hence it is not a derivative.

Lipschitz Restrictions Of Continuous Functions And A Simple Construction Of Ulam-Zahorski C1 Interpolation, Krzysztof Ciesielski

Faculty & Staff Scholarship

We present a simple argument that for every continuous function f : R → R its restriction to some perfect set is Lipschitz. We will use this result to provide an elementary proof of the C 1 free interpolation theorem, that for every continuous function f : R → R there exists a continuously differentiable function g : R → R which agrees with f on an uncountable set. The key novelty of our presentation is that no part of it, including the cited results, requires from the reader any prior familiarity with the Lebesgue measure theory.

Minimal Degrees Of Genocchi-Peano Functions: Calculus Motivated Number Theoretical Estimates, Krzysztof Ciesielski

Faculty & Staff Scholarship

A rational function of the form x α1 1 x α2 2 ⋯x αn n x β1 1 +x β2 2 +⋯+x βn n is a Genocchi-Peano example, GPE, provided it is discontinuous, but its restriction to any hyperplane is continuous. We show that the minimal degree D(n) of a GPE of n-variables equals 2 ⌊ e 2 e2−1 n⌋ + 2i for some i ∈ {0, 1, 2}. We also investigate the minimal degree Db(n) of a bounded GPE of n-variables and note that D(n) ≤ Db(n) ≤ n(n + 1). Finding better bounds for numbers Db(n) remains an …

Environmental Governance And Climate Change Adaptation In The Okavango Delta, Botswana, Jamie Shinn

Faculty & Staff Scholarship

Increased environmental variability as a result of climate change will continue to intensify in coming decades, with particularly acute consequences for those living in already marginal conditions. The impacts of these biophysical changes require new approaches to environmental governance to facilitate successful forms of climate change adaptation for individuals and communities in changing social-ecological systems.

Development Of A Laser-Spark Multicharged Ion System – Application In Shallow Implantation Of Sic By Boron And Barium, Md. Haider Ali Shaim

Electrical & Computer Engineering Theses & Dissertations

A novel multicharged ion source, using laser ablation induced plasma coupled with spark discharge, has been investigated in this work. The designed and demonstrated ion source is cost-effective, compact and versatile. Experiments are described with the intention of demonstrating the practicability of ion implantation via laser ion source.

Multicharged aluminum ions are generated by a ns Q-switched Nd:YAG laser pulse ablation of an aluminum target in an ultrahigh vacuum. The experiments are conducted using laser pulse energies of 45–90 mJ focused on the Al target surface by a lens with an 80-cm focal length to 0.0024 cm² spot area …