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2018

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Articles 2851 - 2880 of 13646

Full-Text Articles in Physical Sciences and Mathematics

Focusvr: Effective And Usable Vr Display Power Management, Kiat Wee Tan, Eduardo Cuervo, Rajesh Krishna Balan Sep 2018

Focusvr: Effective And Usable Vr Display Power Management, Kiat Wee Tan, Eduardo Cuervo, Rajesh Krishna Balan

Research Collection School Of Computing and Information Systems

In this paper, we present the design and implementation of FocusVR, a system for effectively and efficiently reducing the power consumption of Virtual Reality (VR) devices by smartly dimming their displays. These devices are becoming increasingly common with large companies such as Facebook (Oculus Rift), and HTC and Valve (Vive), recently releasing high quality VR devices to the consumer market. However, these devices require increasingly higher screen resolutions and refresh rates to be effective, and this in turn, leads to high display power consumption costs. We show how the use of smart dimming techniques, vignettes and color mapping, can significantly …


Self-Supervised Feature Learning For Semantic Segmentation Of Overhead Imagery, Suriya Singh, Anil Batra, Guansong Pang, Lorenzo Torresani, Saikat Basu, Manohar Paluri, C. V. Jawahar Sep 2018

Self-Supervised Feature Learning For Semantic Segmentation Of Overhead Imagery, Suriya Singh, Anil Batra, Guansong Pang, Lorenzo Torresani, Saikat Basu, Manohar Paluri, C. V. Jawahar

Research Collection School Of Computing and Information Systems

Overhead imageries play a crucial role in many applications such as urban planning, crop yield forecasting, mapping, and policy making. Semantic segmentation could enable automatic, efficient, and large-scale understanding of overhead imageries for these applications. However, semantic segmentation of overhead imageries is a challenging task, primarily due to the large domain gap from existing research in ground imageries, unavailability of large-scale dataset with pixel-level annotations, and inherent complexity in the task. Readily available vast amount of unlabeled overhead imageries share more common structures and patterns compared to the ground imageries, therefore, its large-scale analysis could benefit from unsupervised feature learning …


Underwater Adhesive Using Solid–Liquid Polymer Mixes, Alin Cristian Chipara, T. Tsafack, P. S. Owuor, J. Yeon, C. E. Junkermeier, A. C. T. Van Duin, S. Bhowmick, S. A. S. Asif, S. Radhakrishnan, Mircea Chipara Sep 2018

Underwater Adhesive Using Solid–Liquid Polymer Mixes, Alin Cristian Chipara, T. Tsafack, P. S. Owuor, J. Yeon, C. E. Junkermeier, A. C. T. Van Duin, S. Bhowmick, S. A. S. Asif, S. Radhakrishnan, Mircea Chipara

Physics and Astronomy Faculty Publications and Presentations

Instantaneous adhesion between different materials is a requirement for several applications ranging from electronics to biomedicine. Approaches such as surface patterning, chemical cross-linking, surface modification, and chemical synthesis have been adopted to generate temporary adhesion between various materials and surfaces. Because of the lack of curing times, temporary adhesives are instantaneous, a useful property for specific applications that need quick bonding. However, to this day, temporary adhesives have been mainly demonstrated under dry conditions and do not work well in submerged or humid environments. Furthermore, most rely on chemical bonds resulting from strong interactions with the substrate such as acrylate …


Iron Oxide Nanomagnets In Polymer Matrices – Synthesis And Characterization, Shenjie Qiu Sep 2018

Iron Oxide Nanomagnets In Polymer Matrices – Synthesis And Characterization, Shenjie Qiu

Dissertations, Theses, and Capstone Projects

Magneto-responsive polymer-iron oxide materials have been fabricated by coating various polymers on iron oxide nanoparticles (NPs). The stability of magneto-responsive polymer-iron oxide materials relies on the selection of appropriate coating anchors, such as catechols and silanes. This dissertation describes two robust polymer coating systems on iron oxide NPs. One system focuses on thermo-responsive nitrated catechol-N-isopropylacrylamide polymers with binding enhancement factors (EnF) of ~40 and ~20 towards iron oxide NPs and a boronic acid compared to the polymers without the nitro group. The second system involves coating of poly(vinyl alcohol) (PVA) on iron oxide NPs via a silane anchor …


Identifying Weak Interdomain Interactions That Stabilize The Supertertiary Structure Of The N-Terminal Tandem Pdz Domains Of Psd-95, Inna S. Yanez Orozco, Frank A. Mindlin, Junyan Ma, Bo Wang, Brie Levesque, Matheu Spencer, Soheila Rezaei Adariani, George Hamilton, Feng Ding, Mark E. Bowen, Hugo Sanabria Sep 2018

Identifying Weak Interdomain Interactions That Stabilize The Supertertiary Structure Of The N-Terminal Tandem Pdz Domains Of Psd-95, Inna S. Yanez Orozco, Frank A. Mindlin, Junyan Ma, Bo Wang, Brie Levesque, Matheu Spencer, Soheila Rezaei Adariani, George Hamilton, Feng Ding, Mark E. Bowen, Hugo Sanabria

Publications

Previous studies of the N-terminal PDZ tandem from PSD-95 produced divergent models and failed to identify interdomain contacts stabilizing the structure. We used ensemble and single-molecule FRET along with replica-exchange molecular dynamics to fully characterize the energy landscape. Simulations and experiments identified two conformations: an open-like conformation with a small contact interface stabilized by salt bridges, and a closed-like conformation with a larger contact interface stabilized by surface-exposed hydrophobic residues. Both interfaces were confirmed experimentally. Proximity of interdomain contacts to the binding pockets may explain the observed coupling between conformation and binding. The low-energy barrier between conformations allows submillisecond dynamics, …


Tunnel Diode Resonator For Precision Magnetic Susceptibility Measurements In A Mk Temperature Range And Large Dc Magnetic Fields, Hyunsoo Kim, M. A. Tanatar, R. Prozorov Sep 2018

Tunnel Diode Resonator For Precision Magnetic Susceptibility Measurements In A Mk Temperature Range And Large Dc Magnetic Fields, Hyunsoo Kim, M. A. Tanatar, R. Prozorov

Physics Faculty Research & Creative Works

Precision radio-frequency measurements of the magnetic susceptibility using the tunnel diode resonator (TDR) technique are used to study the delicate effects in magnetic and superconducting materials. High resolution (in ppb range) measurements are particularly important for studies of the London and Campbell penetration depths in a superconductor and for the investigation of magnetic transitions in (anti)ferromagnets. Due to the small rf magnetic-excitation in a mOe range, the TDR is especially useful at low-temperatures in a mK range, if Joule heating generated in the TDR circuitry is efficiently removed and the circuit is stabilized with sub-mK precision. Unfortunately, the circuit has …


Entity-Grounded Image Captioning, Annika Lindh, Robert J. Ross, John D. Kelleher Sep 2018

Entity-Grounded Image Captioning, Annika Lindh, Robert J. Ross, John D. Kelleher

Conference papers

An urgent limitation in current Image Captioning models is their tendency to produce generic captions that avoid the interesting detail which makes each image unique. To address this limitation, we propose an approach that enforces a stronger alignment between image regions and specific segments of text. The model architecture is composed of a visual region proposer, a region-order planner and a region-guided caption generator. The region-guided caption generator incorporates a novel information gate which allows visual and textual input of different frequencies and dimensionalities in a Recurrent Neural Network.


Evaluation And Quantification Of Diffractive Plenoptic Camera Algorithm Performance, Jack A. Shepherd Iii Sep 2018

Evaluation And Quantification Of Diffractive Plenoptic Camera Algorithm Performance, Jack A. Shepherd Iii

Theses and Dissertations

A diffractive plenoptic camera is a novel approach to the traditional plenoptic camera which replaces the main optic with a Fresnel zone plate making the camera sensitive to wavelength instead of range. However, algorithms are necessary to reconstruct the image produced by plenoptic cameras. While many algorithms exist for traditional plenoptic cameras, their ability to create spectral images in a diffractive plenoptic camera is unknown. This paper evaluates digital refocusing, super resolution, and 3D deconvolution through a Richardson-Lucy algorithm as well as a new Gaussian smoothing algorithm. All of the algorithms worked well near the Fresnel zone plate design wavelength, …


Saw: Wristband-Based Authentication For Desktop Computers, Shrirang Mare, Reza Rawassizadeh, Ronald Peterson, David Kotz Sep 2018

Saw: Wristband-Based Authentication For Desktop Computers, Shrirang Mare, Reza Rawassizadeh, Ronald Peterson, David Kotz

Dartmouth Scholarship

Token-based proximity authentication methods that authenticate users based on physical proximity are effortless, but lack explicit user intentionality, which may result in accidental logins. For example, a user may get logged in when she is near a computer or just passing by, even if she does not intend to use that computer. Lack of user intentionality in proximity-based methods makes them less suitable for multi-user shared computer environments, despite their desired usability benefits over passwords. \par We present an authentication method for desktops called Seamless Authentication using Wristbands (SAW), which addresses the lack of intentionality limitation of proximity-based methods. SAW …


Detection And Monitoring Of Repetitions Using An Mhealth-Enabled Resistance Band, Curtis L. Peterson, Emily V. Wechsler, Ryan J. Halter, George G. Boateng, Patrick O. Proctor, David F. Kotz, Summer B. Cook, John A. Batsis Sep 2018

Detection And Monitoring Of Repetitions Using An Mhealth-Enabled Resistance Band, Curtis L. Peterson, Emily V. Wechsler, Ryan J. Halter, George G. Boateng, Patrick O. Proctor, David F. Kotz, Summer B. Cook, John A. Batsis

Dartmouth Scholarship

Sarcopenia is defined as an age-related loss of muscle mass and strength which impairs physical function leading to disability and frailty. Resistance exercises are effective treatments for sarcopenia and are critical in mitigating weight-loss induced sarcopenia in older adults attempting to lose weight. Yet, adherence to home-based regimens, which is a cornerstone to lifestyle therapies, is poor and cannot be ascertained by clinicians as no objective methods exist to determine patient compliance outside of a supervised setting. Our group developed a Bluetooth connected resistance band that tests the ability to detect exercise repetitions. We recruited 6 patients aged 65 years …


Assembling Of Niox/Mwcnts-Gc Anodic Nanocatalyst For Water Electrolysis Applications, Yaser M. Asal Mr., Islam M. Al-Akraa Dr, Saher D. Khamis Eng Sep 2018

Assembling Of Niox/Mwcnts-Gc Anodic Nanocatalyst For Water Electrolysis Applications, Yaser M. Asal Mr., Islam M. Al-Akraa Dr, Saher D. Khamis Eng

Chemical Engineering

Glassy carbon (GC) electrode is intended to be modified with nickel oxide (NiOx) and multiwalled carbon nanotubes (MWCNTs) in the anodic reaction of water electrolysis. NiOx deposition time is optimized and a 5 min was enough to attain the maximum activity. A further modification of the catalyst with MWCNTs could greatly enhance its stability during continuous electrolysis. As an outcome, an energy amount of 21.7 kWh/KgO2 is minimized. Several electrochemical and materials characterization setups will be utilized to test the catalyst activity and to know its geometry and structure.


Question 1: Plastic Straws; Question 2: Casino Sevens, Larry Weinstein Sep 2018

Question 1: Plastic Straws; Question 2: Casino Sevens, Larry Weinstein

Physics Faculty Publications

The article offers questions on 1) the impact that American plastic straws have on the environment, and 2) the probable longest streak of consecutive sevens in casino craps games in the entire history of Las Vegas, Nevada.


Photoproduction Of K+ K- Meson Pairs On The Proton, S. Lombardo, M. Battaglieri, A. Celentano, A. D'Angelo, R. De Vita, A. Filippi, D. I. Glazier, M. Khachatryan, A. Klein, Y. Prok, The Clas Collaboration Sep 2018

Photoproduction Of K+ K- Meson Pairs On The Proton, S. Lombardo, M. Battaglieri, A. Celentano, A. D'Angelo, R. De Vita, A. Filippi, D. I. Glazier, M. Khachatryan, A. Klein, Y. Prok, The Clas Collaboration

Physics Faculty Publications

The exclusive reaction γp → pK+K was studied in the photon energy range 3.0–3.8 GeV and momentum transfer range 0.6 < −t< 1.3 GeV2. Data were collected with the CLAS detector at the Thomas Jefferson National Accelerator Facility. In this kinematic range the integrated luminosity was approximately 20 pb−1. The reaction was isolated by detecting the K+ and the proton in CLAS, and reconstructing the K via the missing-mass technique. Moments of the dikaon decay angular distributions were extracted from the experimental data. Besides the dominant contribution of the ϕ meson in the P wave, …


Insights Into Barrier-Island Stability Derived From Transgressive/Regressive State Changes Of Parramore Island, Virginia, Jessica L. Raff, Justin L. Shawler, Daniel J. Ciarletta, Emily A. Hein, Jorge Lorenzo Trueba, Christopher J. Hein Sep 2018

Insights Into Barrier-Island Stability Derived From Transgressive/Regressive State Changes Of Parramore Island, Virginia, Jessica L. Raff, Justin L. Shawler, Daniel J. Ciarletta, Emily A. Hein, Jorge Lorenzo Trueba, Christopher J. Hein

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Barrier islands and their associated backbarrier ecosystems front much of the U.S. Atlantic and Gulf coasts, yet threshold conditions associated with their relative stability (i.e., state changes between progradation, erosion, and landward migration) in the face of sea-level rise remain poorly understood. The barrier islands along Virginia's Eastern Shore are among the largest undeveloped barrier systems in the U.S., providing an ideal natural laboratory to explore the sensitivity of barrier islands to environmental change. Details about the developmental history of Parramore Island, one of the longest (12 km) and widest (1.0–1.9 km) of these islands, provide insight into the timescales …


Assessing The Relationship Between Groundwater Nitrate Concentrations And Environmental Variables Through Repeat Sampling And Statistical Machine Learning: Dutch Flats, Nebraska, Martin Wells Sep 2018

Assessing The Relationship Between Groundwater Nitrate Concentrations And Environmental Variables Through Repeat Sampling And Statistical Machine Learning: Dutch Flats, Nebraska, Martin Wells

Department of Biological Systems Engineering: Dissertations and Theses

Nitrate-contaminated aquifers are common in landscapes dominated by agricultural land use. Health concerns related to consuming nitrate-contaminated groundwater are well documented and continued research aimed at decreasing concentrations is critical. A 1990s U.S. Geological Survey (USGS) study focused on groundwater characteristics in the Dutch Flats area of western Nebraska. Agricultural-related practices were determined to largely influence groundwater recharge and nitrate concentrations ([NO3-]). Since the conclusion of the USGS study, a transition to more efficient irrigation technology has been observed in this region. The emphasis of this 2016 study was to resample several well nests examined in 1998 …


2018 September - Tennessee Monthly Climate Report, Tennessee Climate Office, East Tennessee State University Sep 2018

2018 September - Tennessee Monthly Climate Report, Tennessee Climate Office, East Tennessee State University

Tennessee Climate Office Monthly Report

No abstract provided.


Vertical Vs. Adiabatic Ionization Energies In Solution And Gas-Phase: Probing Ionization-Induced Reorganization In Conformationally-Mobile Bichromophoric Actuators Using Photoelectron Spectroscopy, Electrochemistry And Theory, Maxim Vadimovich Ivanov, Denan Wang, Depeng Zhang, Rajendra Rathore, Scott A. Reid Sep 2018

Vertical Vs. Adiabatic Ionization Energies In Solution And Gas-Phase: Probing Ionization-Induced Reorganization In Conformationally-Mobile Bichromophoric Actuators Using Photoelectron Spectroscopy, Electrochemistry And Theory, Maxim Vadimovich Ivanov, Denan Wang, Depeng Zhang, Rajendra Rathore, Scott A. Reid

Chemistry Faculty Research and Publications

Ionization-induced structural and conformational reorganization in various π-stacked dimers and covalently linked bichromophores is relevant to many processes in biological systems and functional materials. In this work, we examine the role of structural, conformational, and solvent reorganization in a set of conformationally mobile bichromophoric donors, using a combination of gas-phase photoelectron spectroscopy, solution-phase electrochemistry, and density functional theory (DFT) calculations. Photoelectron spectral analysis yields both adiabatic and vertical ionization energies (AIE/VIE), which are compared with measured (adiabatic) solution-phase oxidation potentials (Eox). Importantly, we find a strong correlation of Eox with AIE, but not VIE, reflecting variations …


Bilock: User Authentication Via Dental Occlusion Biometrics, Yongpan Zou, Meng Zhao, Zimu Zhou, Jiawei Lin, Mo Li, Kaishun Wu Sep 2018

Bilock: User Authentication Via Dental Occlusion Biometrics, Yongpan Zou, Meng Zhao, Zimu Zhou, Jiawei Lin, Mo Li, Kaishun Wu

Research Collection School Of Computing and Information Systems

User authentication on smart devices is indispensable to keep data privacy and security. It is especially significant for emerging wearable devices such as smartwatches considering data sensitivity in them. However, conventional authentication methods are not applicable for wearables due to constraints of size and hardware, which makes present wearable devices lack convenient, secure and low-cost authentication schemes. To tackle this problem, we reveal a novel biometric authentication mechanism which makes use of sounds of human dental occlusion (i.e., tooth click). We demonstrate its feasibility by comprehensive measurement study, and design a prototype-BiLock with two Android platforms. Extensive real-world experiments have …


Jobcomposer: Career Path Optimization Via Multicriteria Utility Learning, Richard J. Oentaryo, Xavier Jayaraj Siddarth Ashok, Ee-Peng Lim, Philips Kokoh Prasetyo Sep 2018

Jobcomposer: Career Path Optimization Via Multicriteria Utility Learning, Richard J. Oentaryo, Xavier Jayaraj Siddarth Ashok, Ee-Peng Lim, Philips Kokoh Prasetyo

Research Collection School Of Computing and Information Systems

With online professional network platforms (OPNs, e.g., LinkedIn, Xing, etc.)becoming popular on the web, people are now turning to these platforms tocreate and share their professional profiles, to connect with others who sharesimilar professional aspirations and to explore new career opportunities. Theseplatforms however do not offer a long-term roadmap to guide career progressionand improve workforce employability. The career trajectories of OPN users canserve as a reference but they are not always optimal. A career plan can also bedevised through consultation with career coaches, whose knowledge may howeverbe limited to a few industries. To address the above limitations, we present anovel …


Assessing Carbon Pollution Standards: Electric Power Generation Pathways And Their Water Impacts, Kustini Lim-Wavde, Haibo Zhai, Robert John Kauffman, Edward S. Rubin Sep 2018

Assessing Carbon Pollution Standards: Electric Power Generation Pathways And Their Water Impacts, Kustini Lim-Wavde, Haibo Zhai, Robert John Kauffman, Edward S. Rubin

Research Collection School Of Computing and Information Systems

Highlights•Without carbon regulations, CO2 emissions and water use are highly affected by fuel prices.•Carbon regulations reduce both CO2 emissions and water use.•Without incentives, carbon capture is not competitive with cheap natural gas and renewables.•A stringent constraint on water withdrawal lowers the fleet share of once-through cooling.AbstractThis study evaluates transition pathways in electricity generation and their future water impacts. Scenarios that do or do not comply with the carbon pollution standards – based on the U.S. New Source Performance Standards and Clean Power Plan – are evaluated. Using the Electric Reliability Council of Texas region as an illustration, the scenarios with …


Neural-Machine-Translation-Based Commit Message Generation: How Far Are We?, Zhongxin Liu, Xin Xia, Ahmed E. Hassan, David Lo, Zhenchang Xing, Xinyu Wang Sep 2018

Neural-Machine-Translation-Based Commit Message Generation: How Far Are We?, Zhongxin Liu, Xin Xia, Ahmed E. Hassan, David Lo, Zhenchang Xing, Xinyu Wang

Research Collection School Of Computing and Information Systems

Commit messages can be regarded as the documentation of software changes. These messages describe the content and purposes of changes, hence are useful for program comprehension and software maintenance. However, due to the lack of time and direct motivation, commit messages sometimes are neglected by developers. To address this problem, Jiang et al. proposed an approach (we refer to it as NMT), which leverages a neural machine translation algorithm to automatically generate short commit messages from code. The reported performance of their approach is promising, however, they did not explore why their approach performs well. Thus, in this paper, we …


A Strategic Value Appropriation Path For Cloud Computing, Abhishek Kathuria, Arti Mann, Jiban Khuntia, Robert J. Kauffman Sep 2018

A Strategic Value Appropriation Path For Cloud Computing, Abhishek Kathuria, Arti Mann, Jiban Khuntia, Robert J. Kauffman

Research Collection School Of Computing and Information Systems

Cloud-based information management is one of the leading competitive differentiation strategies for firms. With the increasing criticality of information management in value creation and process support, establishing an integrated capability with cloud computing is vital for organizational success in the changing landscape of business competition. These issues have received scant attention, however. We draw on the resource-based view, dynamic capability hierarchy concepts, and the perspective of operand and operant resources to suggest a cloud value appropriation model for firms. We argue that, to appropriate business value from cloud computing, the firm needs to effectively deploy cloud computing and leverage cloud …


Wasserstein Divergence For Gans, J. Wu, Zhiwu Huang, J. Thoma, D. Acharya, Gool L. Van Sep 2018

Wasserstein Divergence For Gans, J. Wu, Zhiwu Huang, J. Thoma, D. Acharya, Gool L. Van

Research Collection School Of Computing and Information Systems

In many domains of computer vision, generative adversarial networks (GANs) have achieved great success, among which the family of Wasserstein GANs (WGANs) is considered to be state-of-the-art due to the theoretical contributions and competitive qualitative performance. However, it is very challenging to approximate the k-Lipschitz constraint required by the Wasserstein-1 metric (W-met). In this paper, we propose a novel Wasserstein divergence (W-div), which is a relaxed version of W-met and does not require the k-Lipschitz constraint. As a concrete application, we introduce a Wasserstein divergence objective for GANs (WGAN-div), which can faithfully approximate W-div through optimization. Under various settings, including …


A Vector Field Design Approach To Animated Transitions, Yong Wang, Daniel Archambault, Carlos E. Scheidegger, Huamin Qu Sep 2018

A Vector Field Design Approach To Animated Transitions, Yong Wang, Daniel Archambault, Carlos E. Scheidegger, Huamin Qu

Research Collection School Of Computing and Information Systems

Animated transitions can be effective in explaining and exploring a small number of visualizations where there are drastic changes in the scene over a short interval of time. This is especially true if data elements cannot be visually distinguished by other means. Current research in animated transitions has mainly focused on linear transitions (all elements follow straight line paths) or enhancing coordinated motion through bundling of linear trajectories. In this paper, we introduce animated transition design, a technique to build smooth, non-linear transitions for clustered data with either minimal or no user involvement. The technique is flexible and simple to …


Secondary Frequency Stochastic Optimal Control In Independent Microgrids With Virtual Synchronous Generator-Controlled Energy Storage Systems, Ting Yang, Yajian Zhang, Zhaoxia Wang, Haibo Pen Sep 2018

Secondary Frequency Stochastic Optimal Control In Independent Microgrids With Virtual Synchronous Generator-Controlled Energy Storage Systems, Ting Yang, Yajian Zhang, Zhaoxia Wang, Haibo Pen

Research Collection School Of Computing and Information Systems

With the increasing proportion of renewable energy in microgrids (MGs), its stochastic fluctuation of output power has posed challenges to system safety and operation, especially frequency stability. Virtual synchronous generator (VSG) technology, as one effectivemethod, was used to smoothen frequency fluctuation and improve the system's dynamic performance,which can simulate the inertia and damping of the traditional synchronous generator. This study outlines the integration of VSG-controlled energy storage systems (ESSs) and traditional synchronous generators so they jointly participate in secondary frequency regulation in an independent MG. Firstly, a new uncertain state-space model for secondary frequency control is established, considering the measurement …


A Two-Stage Mechanism For Ordinal Peer Assessment, Zhize Li, Le Zhang, Zhixuan Fang, Jian Li Sep 2018

A Two-Stage Mechanism For Ordinal Peer Assessment, Zhize Li, Le Zhang, Zhixuan Fang, Jian Li

Research Collection School Of Computing and Information Systems

Peer assessment is a major method for evaluating the performance of employee, accessing the contributions of individuals within a group, making social decisions and many other scenarios. The idea is to ask the individuals of the same group to assess the performance of the others. Scores or rankings are then determined based on these evaluations. However, peer assessment can be biased and manipulated, especially when there is a conflict of interests. In this paper, we consider the problem of eliciting the underlying ordering (i.e. ground truth) of n strategic agents with respect to their performances, e.g., quality of work, contributions, …


Three-Dimensional Carbon Nanotube Yarn Based Solid State Solar Cells With Multiple Sensitizers Exhibit High Energy Conversion Efficiency, Glenn Grissom, Jared Jaksik, Monica Mcentee, Erin M. Durke, Sayeeda Tj Aishee, Margaret Cua, Okenwa Okoli, Ahmed Touhami, H. Justin Moore, M. Jasim Uddin Sep 2018

Three-Dimensional Carbon Nanotube Yarn Based Solid State Solar Cells With Multiple Sensitizers Exhibit High Energy Conversion Efficiency, Glenn Grissom, Jared Jaksik, Monica Mcentee, Erin M. Durke, Sayeeda Tj Aishee, Margaret Cua, Okenwa Okoli, Ahmed Touhami, H. Justin Moore, M. Jasim Uddin

Chemistry Faculty Publications and Presentations

Fiber-type dye sensitized solar cells that are non-metallic, flexible, and thread-like in structure have many potential military and functional textile applications. With the use of quantum dots (QD), exciton transfer facilitators (Phenyl-C61-butyric acid methyl ester-PCBM) and Poly(3-hexylthiophene-2,5-diyl-P3HT), and careful preparation of the TiO2 oxide layer deposited on the carbon fiber working electrode, an optimized efficiency of 7.6% was obtained. Carbon nanotube yarn (CNTY) was used to prepare both the working and counter electrodes of the fabricated cells. TiCl4 annealing of the TiO2 layer was carried out and the resulting oxide layer morphology was found to be very uniform. The quantum …


Conformational Analysis Of A Taddol-Based Phosphoramidite P,N Ligand In A Palladium(Ii) Η3-Π-Allyl Complex, Tülay A. Ateşin, Abdurrahman Atesin, Oscar Rodriguez, Diego Rivera, Lohany Y. Garcia Sep 2018

Conformational Analysis Of A Taddol-Based Phosphoramidite P,N Ligand In A Palladium(Ii) Η3-Π-Allyl Complex, Tülay A. Ateşin, Abdurrahman Atesin, Oscar Rodriguez, Diego Rivera, Lohany Y. Garcia

Chemistry Faculty Publications and Presentations

Highlights

  • Two lowest energy conformers differ in allyl conformation, conformer with exo allyl having lower energy.
  • Lowest energy conformer has “chair” conformation of 7-membered ring and “edge-on/face-on/face-on/edge-on” array of pH groups.
  • Next lowest energy conformer with exo allyl has alternating “edge-on/face-on” arrangement and “twist” 7-membered ring.
  • Changes in “chair/twist” conformations with different substrates is possible due to 2.4 kcal/mol energy difference.
  • These results explain stereochemical outcome of the reaction, and will guide design of new catalysts.

Abstract

The most stable conformations of a TADDOL-based phosphoramidite P,N ligand coordinated to a palladium(II) η3-π-allyl fragment have been investigated using …


Higher-Level Consistencies: Where, When, And How Much, Robert J. Woodward Sep 2018

Higher-Level Consistencies: Where, When, And How Much, Robert J. Woodward

Department of Computer Science and Engineering: Dissertations, Theses, and Student Research

Determining whether or not a Constraint Satisfaction Problem (CSP) has a solution is NP-complete. CSPs are solved by inference (i.e., enforcing consistency), conditioning (i.e., doing search), or, more commonly, by interleaving the two mechanisms. The most common consistency property enforced during search is Generalized Arc Consistency (GAC). In recent years, new algorithms that enforce consistency properties stronger than GAC have been proposed and shown to be necessary to solve difficult problem instances.

We frame the question of balancing the cost and the pruning effectiveness of consistency algorithms as the question of determining where, when, and how much of a higher-level …


Asymmetric Relativistic Fermi Gas Model For Quasielastic Lepton-Nucleus Scattering, M. B. Barbaro, A. De Pace, T. W. Donnelly, J. A. Caballero, G. D. Megias, J. W. Van Orden Sep 2018

Asymmetric Relativistic Fermi Gas Model For Quasielastic Lepton-Nucleus Scattering, M. B. Barbaro, A. De Pace, T. W. Donnelly, J. A. Caballero, G. D. Megias, J. W. Van Orden

Physics Faculty Publications

We develop an asymmetric relativistic Fermi gas model for the study of the electroweak nuclear response in the quasielastic region. The model takes into account the differences between neutron and proton densities in asymmetric (N> Z) nuclei, as well as differences in the neutron and proton separation energies. We present numerical results for both neutral and charged-current processes, focusing on nuclei of interest for ongoing and future neutrino oscillation experiments. We point out some important differences with respect to the commonly employed symmetric Fermi gas model.