Physical Sciences and Mathematics Commons^™

Voices Of Bangladeshi Environmental Youth Leaders: A Narrative Study, Paige Pappianne

Antioch University Dissertations & Theses

Can environmental youth leaders affect meaningful positive change in the global fight to reign in climate change? While the academic literature contains a vast array of youth leadership materials, there is a gap in the research of the effect environmental youth leadership programs have at the community level, and specifically how these effects can contribute to environmental sustainability of that community, region, or country. This mixed methods qualitative study narrows this gap by employing grounded theory and narrative analysis to determine how five Bangladeshi environmental youth leaders understand their role in influencing their school and communities’ efforts to adapt to …

Emergence: Developing Worldview In The Environmental Humanities, Rhonda D. Davis

Antioch University Dissertations & Theses

While the environment has long played a role in humanistic expressions and investigations, the need for a more integrated look at the human-environment relationship has become ever more pressing. More than ever, humanities scholars are recognizing their ability to mobilize critical and creative action to address pressing socioeconomic, sociopolitical, and socioenvironmental problems. Teaching and engaging students through interdisciplinary methods, connecting students and communities, developing a sense of agency and responsibility for planetary sustainability has become a visible focus in higher education. My study aimed to understand how an environmental humanities class affects, if at all, the way students construct worldview. …

Habitat Characteristics And Nesting Ecology Of Golden Eagles In Arizona, Michele J. Losee

Antioch University Dissertations & Theses

Golden Eagles (Aquila chrysaetos) have a broad range globally and in general are well-studied. However, Arizona’s Golden Eagle population remained essentially unstudied until 2011, when Arizona Game and Fish Department (AZGFD) began nest surveys for cliff nesting Golden Eagles throughout the state. As a result of this data collection, the natural history of Arizona’s Golden Eagles is finally revealing itself. This dissertation outlined a reliable description of their nesting phenology that provides a framework for timing surveys and a baseline to monitor the effects of climate change on Golden Eagles. The mean date for egg-laying was February 14 and pairs …

Targeted Short-Term Nutrient Reduction To Manage Ventenata Dubia An Invasive Winter Annual Grass: Soil And Plant Responses, Jaren F. Lamm

EWU Masters Thesis Collection

Invasive winter annual grasses, IWAGs, have degraded extensive ecosystems around the world and continue to invade new ones yearly. IWAGs readily form large monocultures or near monocultures, thus management and restoration goals largely focus on maintaining or increasing plant diversity in impacted ecosystems. Unfortunately, common management methods also reduce native plant diversity and harm the soil microbiome. These effects require additional measures to be taken, like reseeding, and plant diversity is still usually well below remnant targets. Early season short-term nutrient reduction to manage IWAGs is largely unexplored and would potentially decrease IWAG abundance, active earlier than most plants, but …

Exposing Students To Stem Careers Through Hands-On Activities With Drones And Robots, Vukica M. Jovanović, George Mcleod, Thomas E. Alberts, Cynthia Tomovic, Otilia Popescu, Tysha Batts, Ms. Mary Louise Sandy

Engineering Technology Faculty Publications

Autonomous robots have been used in a variety of ways from collecting specimen in hazardous environments to space exploration. These robots can be found in various manufacturing systems as Autonomous Guided Vehicles (AGVs) to transport parts and assemblies throughout the manufacturing system. They have also been used as a vehicle to convey design thinking and other STEM-related concepts in mechanical engineering/mechanical engineering technology, electrical engineering/electrical engineering technology, computer science, and computer engineering. Various outreach events have included robotics based activities that engage students in building and programming autonomous robots for the purpose of achieving a specific task. These events are …

Comparison Of Observed And Simulated Drop Size Distributions From Large Eddy Simulations With Bin Microphysics, Mikael K. White, Patrick Y. Chuang, Orlando Ayala, Lian-Ping Wang, Graham Feingold

Engineering Technology Faculty Publications

Two case studies of marine stratocumulus (one nocturnal and drizzling, the other daytime and nonprecipitating) are simulated by the UCLA large-eddy simulation model with bin microphysics for comparison with aircraft in situ observations. A high-bin-resolution variant of the microphysics is implemented for closer comparison with cloud drop size distribution (DSD) observations and a turbulent collision–coalescence kernel to evaluate the role of turbulence on drizzle formation. Simulations agree well with observational constraints, reproducing observed thermodynamic profiles (i.e., liquid water potential temperature and total moisture mixing ratio) as well as liquid water path. Cloud drop number concentration and liquid water content profiles …

Reliability Estimation Of Reciprocating Seals Based On Multivariate Dependence Analysis And It's Experimental Validation, Chao Zhang, Rentong Chen, Shaoping Wang, Yujie Qian, Mileta M. Tomovic

Engineering Technology Faculty Publications

Accurate reliability estimation for reciprocating seals is of great significance due to their wide use in numerous engineering applications. This work proposes a reliability estimation method for reciprocating seals based on multivariate dependence analysis of different performance indicators. Degradation behavior corresponding to each performance indicator is first described by the Wiener process. Dependence among different performance indicators is then captured using D-vine copula, and a weight-based copula selection method is utilized to determine the optimal bivariate copula for each dependence relationship. A two-stage Bayesian method is used to estimate the parameters in the proposed model. Finally, a reciprocating seal degradation …

Spin Response Function For Spin Transparency Mode Of Rhic, V. S. Morozov, P. Adams, Y. S. Derbenev, Y. Filatov, H. Huang, A. M. Kondratenko, M. A. Kondratenko, F. Lin, F. Méot, V. Ptitsyn, W. B. Schmidke, Y. Zhang

Engineering Technology Faculty Publications

In the Spin Transparency (ST) mode of RHIC, the axes of its Siberian snakes are parallel. The spin tune in the ST mode is zero and the spin motion becomes degenerate: any spin direction repeats every particle turn. In contrast, the lattice of a conventional collider determines a unique stable periodic spin direction, so that the collider operates in the Preferred Spin (PS) mode. Contributions of perturbing magnetic fields to the spin resonance strengths in the PS mode are usually calculated using the spin response function. However, in that form, it is not applicable in the ST mode. This paper …

Geology Of Southeastern Nebraska, Robert Matthew Joeckel, Dana Divine, Leslie M. Howard, Kathleen Cameron, Michele M. Waszgis

Conservation and Survey Division

No abstract provided.

Maps Showing The Physical Hydrogeology And Changes In Saturated Thickness (Predevelopment To Spring 2016 And Spring 2011 To Spring 2016) In The Middle Republican Natural Resources District, Southwestern Nebraska., Jesse T. Korus Dr., Leslie M. Howard

Conservation and Survey Division

This report accompanies fourteen new maps summarizing the hydrogeology and changes in saturated thickness in the Middle Republican Natural Resources District (MRNRD). The purpose of these maps is to assist the MRNRD in their groundwater management programs and in planning and installing an observation well network. Maps include:

• base of the principal aquifer;

• water table surfaces for predevelopment, Spring 2011, and Spring 2016;

• saturated thicknesses for predevelopment, Spring 2011, and Spring 2016;

• changes in saturated thickness (both in absolute magnitude and in percent) from predevelopment to Spring 2016 and from Spring 2011 to Spring 2016;

• …

New Perspectives On The Schrödinger-Pauli Theory Of Electrons: Part I, Viraht Sahni

Publications and Research

Schrödinger-Pauli (SP) theory is a description of electrons in the presence of a static electromagnetic field in which the interaction of the magnetic field with both the orbital and spin moments is explicitly considered. The theory is described from the new perspective of the individual electron via its equation of motion or ‘Quantal Newtonian’ first law. The law is in terms of ‘classical’ fields whose sources are quantum mechanical expectation values of Hermitian operators taken with respect to the system wave function. The law states that each electron experiences an external and an internal field, the sum of which vanish. …

Modeling The Effects Of Climate Variability On Hydrology And Stream Temperatures In The North Fork Of The Stillaguamish River, Kyra Freeman

WWU Graduate School Collection

The Stillaguamish River in northwest Washington State, USA, provides water resources to local agriculture, industry and First Nations Tribes, and provides crucial habitat for several endangered species of salmonids. The watershed experiences a mild maritime climate and high relief, with rain and snowmelt dominating the streamflow. In anticipation of shifts in snowpack, streamflow, and stream temperature, I use projected global climate scenarios and numerical models to examine future climatic variability on streamflow and stream temperatures in the snow-melt dominated North Fork of the Stillaguamish River. I calibrated the physically based Distributed Hydrology Soil Vegetation Model (DHSVM) and River Basin Model …

Everyone Can Grow! Winter Programming Using An Indoor Horticulture Environmental Education Program To Benefit Military Veterans, Rachel Elam

WWU Graduate School Collection

Working with plants has numerous physical, mental health and well-being benefits for people, and military veteran farming programs have been started to provide these benefits. However, these programs lack activities outside of the Washington State growing season which is approximately May to October. Since these programs are largely meant as ways for veterans to engage in community and peer support, the gap over winter is unacceptable for the purposes of supporting mental health. This project produced a winter environmental education curriculum for military vets, titled Everyone can Grow! (ECG!), and is designed to provide peer support and psychological …

Quantifying The Magnitude And Spatial Variability Of Bedrock Erosion Beneath The Sisters Glacier, Washington, Using Cosmogenic 3he Concentrations, Sarah W. Francis

WWU Graduate School Collection

Cosmogenic ³He analyses provide a tool to infer spatial variation of cirque-glacial bedrock erosion. ³He accumulates in bedrock exposed at the surface as a result of cosmic ray bombardment; the concentration of cosmogenic ³He increases with exposure time as well as proximity to the surface. The Twin Sisters range, North Cascades, WA is an ideal location to use cosmogenic ³He to infer cirque-glacial erosion depths and rates, due to the dunite bedrock and the detailed record of Holocene glaciation from the nearby Mount Baker. We used field mapping, lidar data and aerial imagery to identify bedrock …

Multifunctional Microgels For Nanoparticle-Based Detection Methodologies, Alyson Silva

WWU Graduate School Collection

In this study, pH-responsive microgel particles, comprised of 2-vinyl pyridine (P2VP) and styrene (PS), are explored as scaffolds to assemble metallic nanoparticles (NPs) for ultrasensitive detection strategies. Microgel particles serve as size-tunable scaffolds to assemble metal (silver or gold) NPs for surface-enhanced Raman scattering (SERS) vibrational spectroscopy. The high sensitivity of SERS arises from the enormous enhancement of the Raman scattering cross sections of molecules adsorbed to roughened metal surfaces, such as metal NPs. Using a sterically stabilized latex of random copolymers of PS and P2VP (PSxP2VPy), this polymer is capable of transitioning to a microgel state through acid-base titration. …

Synthesis Of A Stimulus Responsive Phosphine Ligand And Metal Binding Studies, Gabriel Bourne

WWU Graduate School Collection

Cations have been shown to modify a variety of properties of transition metals, including bite angle, isomerization, substrate control, and catalytic activation. Herein describes the synthesis of a novel stimulus responsive phosphine ligand. Ligand binding studies by NMR salt titration show a preference in the order of Na⁺ > Li⁺ > K⁺. Platinum dimethyl and dichloride complexes with the phosphine ligand were also synthesized. Isomerization of the platinum chloride complex between cis and trans is reported.

Synthesis Of An Archazolid Based Enzyme Inhibitor, Cooper A. Vincent

WWU Graduate School Collection

The archazolids are a family of natural products that display powerful growth inhibitory activity against a number of human cancer cell lines. This activity has been linked to inhibition of the vacuolar-type ATPase (V-ATPase) and more recently cyclooxygenase (COX) enzymes. Using the archazolid structure as a starting point, several simplified analogues have been prepared and assayed for their V-ATPase and COX inhibitory activity. These simplified analogues were prepared using a novel Suzuki coupling with yields over 80%. They were assayed to investigate both their V-ATPase and COX inhibitory activity. In our assays there was no COX inhibition, while there was …

Not Just Nature, Sarah Kellogg

WWU Graduate School Collection

This field project, entitled Not Just Nature, consists of three parts: the first being a curriculum by the same name. This curriculum, an arts-based workshop series, has been/is being developed to open conversations to interrogate the colonial and white supremacist concepts of nature that have been created in the United States through a variety of means.

The second part of this project is using self as a site of research/critical autoethnography. No field is apolitical, and the creator/researcher will always bring pieces of themselves and their identities to whatever processes they participate in. Thus, throughout my graduate experience I have …

The Atomic And Electronic Structure And Tunability Of Ruddlesden-Popper Phases For Photovoltaic Applications, Britt A. Tyler

WWU Graduate School Collection

There is an increasing need for alternative energy sources that reduce the global reliance on fossil fuels. Since their demonstration in 2009, perovskite solar cells (based on compounds with the formula ABX₃, such as CH₃NH₃PbI₃) have become an extremely promising and active research area. Still, there are obstacles to the widespread use of these technologies, including their instability and the environmental impacts of lead. It is therefore important to find ways to modify and tune the structure and properties of perovskites to optimize their stability and photovoltaic performance. This research explores a …

Increased Hydrologic Variability Near The Paleocene-Eocene Boundary (Piceance Creek Basin, Colorado, U.S.A.)), Anna Lesko

WWU Graduate School Collection

The Paleocene Eocene Thermal Maximum (PETM) was a rapid global warming event that occurred approximately 56 million years ago and represents the largest and most abrupt warming event of the Cenozoic Era. The PETM caused mean annual temperatures to increase at least 5°C globally above the already warm, greenhouse climate state of the early Paleogene. The warming and associated perturbation of the carbon cycle had numerous consequences for paleoenvironments and paleobiologic systems. This study investigates the hydrologic response to the PETM within the interior of North America and presents a new d¹³C bulk organic record. This study generates …

Progress Towards The Substrate-Bound Structure Of Streptococcus Pneumoniae Sortase A, Nicholas M. Horvath

WWU Graduate School Collection

Sortases are cysteine transpeptidases found primarily on the cell surface of Gram-positive bacteria. Sortase-mediated ligations have become an attractive option for protein modification chemistry, enabling the synthesis of a wide range of non-natural polypeptide derivatives. Attempts at understanding how these enzymes recognize and bind substrates are integral to furthering their usefulness in protein engineering and, potentially, treatment of bacterial diseases. However, the variable substrate specificity and activity between homologs of these enzymes is not yet fully understood. Of specific interest to us is sortase A from Streptococcus pneumoniae (SrtA_pneu), as it demonstrates a broad substrate tolerance not …

Validation Of Predicted Tsunami Inundation For The Inland Coast Of The Salish Sea Associated With Cascadia Subduction Zone Earthquakes, Paige Morkner

WWU Graduate School Collection

The Cascadia subduction zone is understood to produce large, Mw 9.0, earthquakes every 300-1000 years. As a result of large ruptures along the fault, Washington, Oregon and Northern California, are susceptible large tsunamis along the coast. Hazard modeling and mapping along the Cascadia subduction zone has concluded that large tsunamis are able to travel through the Strait of Juan de Fuca and inundate coastal regions of the Salish Sea and Puget Sound. However, to improve modeling efforts, field validation of models is required. Tsunamis can move material from the near shore and beach and deposit in low-laying coastal marshes and …

Dendroclimatology Of Yellow Cedar (Callitropsis Nootkatensis) And Late Holocene Temperature Variability On The Western Slopes Of The North Cascades In Washington State, Christopher A. (Chrisopher Anthony) Trinies

WWU Graduate School Collection

Subalpine tree growth in the Washington Cascades is often limited by both growing season temperatures and persistence of the winter snowpack, making paleoclimate inferences on temperature alone difficult. Here I expand on three yellow cedar chronologies on the west slopes of the North Cascades and build chronologies for two co-dominant species at one of the sites. I used the VIC hydrologic model to include biologically relevant proxies for water stress, including evapotranspiration deficit, and snow cover in a climate-growth analysis. The co-dominant species, specifically mountain hemlock, showed a climate response reminiscent of a high-elevation, energy-limited environment with an interaction between …

Assessing Coastal Vulnerability To Storm Surge And Wave Impacts With Projected Sea Level Rise Within The Salish Sea, Nathan R. Vanarendonk

WWU Graduate School Collection

Sea level rise (SLR) in the Salish Sea, a large inland waterway shared between Canada and the United States, is expected to be 0.3 to 1.8 m by the year 2100. Uncertainty in greenhouse gas emissions, global ice sheet loss, and other controls such as vertical land movement all contribute to this range. Valuable property, infrastructure, and critical habitats for shellfish and threatened salmon populations are at risk to coastal changes associated with SLR. Additionally, development in Washington State is expected to accelerate through the end of the 21st century adding extra pressure on protecting ecosystems and people from natural …

Springtime Benthic Fluxes In The Salish Sea: Environmental Parameters Driving Spatial Variation In The Exchange Of Dissolved Oxygen, Inorganic Carbon, Nutrients, And Alkalinity Between The Sediments And Overlying Water, Emma I. Rigby

WWU Graduate School Collection

Recent decades have seen changes to biogeochemical cycles in the Salish Sea, including alterations in water column nutrients, an expansion of hypoxic zones, and bottom water acidification. Marine sediments can be a major contributor to these biogeochemical cycles by exchanging solutes with bottom water. In an effort to understand the sediment biogeochemistry of the Salish Sea further, benthic fluxes of dissolved oxygen (DO), dissolved inorganic carbon (DIC), pH, total alkalinity (TA), and nutrients (ammonium, nitrate+nitrite, phosphate, silicate) between the sediment and the overlying water were directly measured using incubated flux cores at 42 sites in April and early May 2018. …

Under What Conditions Could Eelgrass Measurably Drawdown Carbon? Relating Carbon Drawdown To Pco2, Irradiance, And Leaf Area Index Of Zostera Marina, Tyler Tran

WWU Graduate School Collection

Seagrass meadows, common to coastal habitats, have been identified as potential short-term refugia for calcifying organisms from ocean acidification (OA). In nearshore, soft-sediment habitats of the Salish Sea, eelgrass (Zostera marina L.) is the dominant seagrass species, and several studies have found that eelgrass is effective at taking up inorganic carbon and may be carbon-limited, potentially increasing uptake potential in the future. However, irradiance levels vary throughout a day and can therefore influence rates of carbon uptake and release through the relative rates of photosynthesis and respiration. Eelgrass meadows vary in terms of meadow size, shoot density and morphology, …

Surface Modified Gold Nanorods Based Mercury Sensor, Tianqi Luan

WWU Graduate School Collection

The high toxicity of mercury in the form of inorganic vapor and organic compounds has become a major concern leading scientists to investigate more accurate and effective methods for the quantification of residue mercury in drinking water, aquaculture products and industrial wastes. In this research, we designed a mercury sensor based on the amalgamation between mercury and gold nanorods (AuNRs) which relate the longitudinal surface plasmon resonance (LSPR) peak shift induced by aspect ratio (AR) change after amalgamation. However, most of AuNRs synthesized based on seed mediated methods use either citrate or hexadecyl trimethyl ammonium bromide (CTAB) as surface stabilizing …

Development Of A Rangeland Degradation Risk Model For The Peruvian Andes, Colin Schmidt

WWU Graduate School Collection

This study developed a Rangeland Degradation Risk Model for the Peruvian Andes based on the Unit Stream Powered Erosion Deposition Model using globally available datasets. A supervised land cover classification was conducted to identify suitable grazing areas and to conduct a regional analysis of susceptibility to erosion. Field data were collected from two different study sites, Huascaran National Park and Nor Yauyos Cochas Landscape Reserve, and were used to assess the model’s accuracy in different ecosystems and land use types. Field data were also leveraged to identify additional data needs and other potential drivers of degradation not taken into account …

Slip And Strain Accumulation Along The Sadie Creek Fault, Olympic Peninsula, Washington, Cody Duckworth

WWU Graduate School Collection

Upper-plate faulting in the Olympic Peninsula of Washington State reflects the interaction of crustal blocks within the Cascadia forearc as well as contributions from various earthquake cycle processes along the Cascadia subduction zone (CSZ). These processes include interseismic coupling, megathrust earthquakes, and aseismic slow slip events. In this study I utilize high resolution airborne lidar, field mapping of deformed surficial deposits and landforms, optically stimulated luminescence (OSL) dating and radiocarbon dating to reconstruct fault slip rates since Late Pleistocene deglaciation on the Sadie Creek fault (SCF), located north of the Olympic Mountains. This mapping reveals the SCF as a ~14 …

Isopeptide Ligations Catalyzed By Streptococcus Suis Sortase A, Sarah Bowersox

WWU Graduate School Collection

Chemically modified proteins are critical components of modern therapeutics and basic research. To generate non-natural protein derivatives, bacterial sortase enzymes have been effective due to their ability to catalyze selective ligations between protein targets and functional groups that are uncommon in nature. Thus far, the enzymatic approach using sortase has been limited to modifications at the termini of peptide chains. Here we describe efforts to develop a sortase-mediated strategy for the formation of isopeptide bonds at the side chains of internal lysine residues. To this end, we have identified a sortase A homolog from Streptococcus suis (SrtA_suis) that …