Physical Sciences and Mathematics Commons^™

Tools For Prescreening The Most Active Sites On Ir And Rh Clusters Toward C−H Bond Cleavage Of Ethane: Nbo Charges And Wiberg Bond Indexes, Yingbin Ge, Anna Le, Gregory J. Marquino, Phuc Q. Nguyen, Kollin Trujillo, Morgan Schimelfenig, Ashley Noble

All Faculty Scholarship for the College of the Sciences

B3LYP calculations were carried out to study the insertion of iridium (Ir) and rhodium (Rh) clusters into a C−H bond of ethane, which is often the ratelimiting step of the catalytic cycle of oxidative dehydrogenation of ethane. Our previous research on Ir catalysis correlates the diffusivity of the lowest unoccupied molecular orbital of the Ir clusters and the relative activities of the various catalytic sites. The drawback of this research is that the molecular orbital visualization is qualitative rather than quantitative. Therefore, in this study on C−H bond activation by the Ir and Rh clusters, we conducted analyses of natural …

Soil Net Nitrogen Mineralisation Across Global Grasslands, A. C. Risch, S. Zimmerman, R. Ochoa-Hueso, M. Schütz, B. Frey, J. L. Firn, P. A. Fay, F. Hagedorn, E. T. Borer, E. W. Seabloom, W. S. Harpole, J. M. H. Knops, Rebecca L. Mcculley, A. A. D. Broadbent, C. J. Stevens, M. L. Silveria, P. B. Adler, S. Báez, L. A. Biederman, J. M. Blair

Plant and Soil Sciences Faculty Publications

Soil nitrogen mineralisation (N_min), the conversion of organic into inorganic N, is important for productivity and nutrient cycling. The balance between mineralisation and immobilisation (net N_min) varies with soil properties and climate. However, because most global-scale assessments of net N_min are laboratory-based, its regulation under field-conditions and implications for real-world soil functioning remain uncertain. Here, we explore the drivers of realised (field) and potential (laboratory) soil net N_min across 30 grasslands worldwide. We find that realised N_min is largely explained by temperature of the wettest quarter, microbial biomass, clay content and bulk density. …

Hierarchical Nanostructuring Of Porous Silicon With Electrochemical And Regenerative Electroless Etching, Ermei Mäkilä, Anne-Mari Anton Willmore, Haibo Yu, Marianna Irri, Mark Aindow, Tambet Teesalu, Leigh Trevor Canham, Kurt W. Kolasinski, Jarno Salonen

Chemistry Faculty Publications

Hierarchically nanostructured silicon was produced by regenerative electroless etching (ReEtching) of Si powder made from pulverized anodized porous silicon. This material is characterized by ∼15 nm mesopores, into the walls of which tortuous 2–4 nm pores have been introduced. The walls are sufficiently narrow that they support quantum-confined crystallites that are photoluminescent. With suitable parameters, the ReEtching process also provides control over the emission color of the photoluminescence. Ball milling and hydrosilylation of this powder with undecylenic acid produces nanoparticles with hydrodynamic diameter of ∼220 nm that exhibit robust and bright luminescence that can be excited with either one ultraviolet/visible …

From Cymatics To Sound Therapy: Their Role In Spirituality And Consciousness Research, Victor Christianto, Kasan Susilo, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

Sound is one of the types of waves that can be felt by the sense of hearing (ears). In physics, the definition of sound is something that is produced from objects that vibrate. Objects that produce sound are called sound sources. The sound source that vibrates will vibrate the molecules into the air around it. Sound is mechanical compression or longitudinal waves that propagate through the medium. This medium or intermediate agent can be liquid, solid, gas. So, sound waves can propagate for example in water, coal, or air. Most sounds are a combination of various vibratory signals composed of …

Rabies Surveillance Identifies Potential Risk Corridors And Enables Management Evaluation, Amy J. Davis, Kathleen M. Nelson, Jordana D. Kirby, Ryan M. Wallace, Xiaoyue Ma, Kim M. Pepin, Richard B. Chipman, Amy Gilbert

United States Department of Agriculture Wildlife Services: Staff Publications

Intensive efforts are being made to eliminate the raccoon variant of rabies virus (RABV) from the eastern United States and Canada. The United States Department of Agriculture (USDA) Wildlife Services National Rabies Management Program has implemented enhanced rabies surveillance (ERS) to improve case detection across the extent of the raccoon oral rabies vaccination (ORV) management area. We evaluated ERS and public health surveillance data from 2006 to 2017 in three northeastern USA states using a dynamic occupancy modeling approach. Our objectives were to examine potential risk corridors for RABV incursion from the U.S. into Canada, evaluate the effectiveness of ORV …

Evaluating The Evidence Base For Evidence-Based Instructional Practices In Chemistry Through Meta-Analysis, Md Tawabur Rahman

USF Tampa Graduate Theses and Dissertations

Investigating the effectiveness of instructional practices provides an evidence base to inform instructional decisions. Synthesizing research studies on instructional effectiveness provides an estimate of the generalizability of effectiveness across settings, along with an exploration of factors that may moderate the impact, which cannot be achieved within individual studies. This study sought to provide a synthesis of evidence- based instructional practices (EBIPs) particular to chemistry through meta-analysis. 99 studies were analyzed comprising a broader view of chemistry specific studies than past meta-analyses. The results showed that EBIPs feature a demonstrably positive impact on students’ academic performance in chemistry, although assessment topic …

Detecting Digitally Forged Faces In Online Videos, Neilesh Sambhu

USF Tampa Graduate Theses and Dissertations

We use Rossler’s FaceForensics dataset of 1004 online videos and their corresponding forged counterparts [1] to investigate the ability to distinguish digitally forged facial images from original images automatically with deep learning. The proposed convolutional neural network is much smaller than the current state-of-the-art solutions. Nevertheless, the network maintains a high level of accuracy (99.6%), all while using the entire FaceForensics dataset and not including any temporal information. We implement majority voting and show the impact on accuracy (99.67%), where only 1 video of 300 is misclassified. We examine why the model misclassified this one video. In terms of tuning …

Life History Through The Eyes Of A Hogfish: Evidence Of Trophic Growth And Differential Juvenile Habitat Use, Meaghan E. Faletti

USF Tampa Graduate Theses and Dissertations

Understanding ontogenetic linkages among fish habitats is critical for conservation of fish populations and the ecosystems on which they rely. Natural tags such as stable isotopes are an effective tool commonly used to investigate ecological questions regarding fish movement and habitat use. Here, I analyzed stable isotopes from the sequentially deposited laminae of Hogfish (Lachnolaimus maximus) eye lenses from the eastern Gulf of Mexico (eGOM) to investigate trophic and geographic changes across individual life histories. I documented evidence of entire-life scale trophic growth through increases in δ15N. I also observed depth separation at the juvenile stage, evidenced by variation in …

Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak

USF Tampa Graduate Theses and Dissertations

High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …

Deepcon-Pre: Improved Protein Contact Map Prediction Using Inverse Covariance And Deep Residual Networks, Nachammai Palaniappan

Theses

As with most domains where machine learning methods are applied, correct feature engineering is critical when developing deep learning algorithms for solving the protein folding problem. Unlike the domains such as computer vision and natural language processing, feature engineering is not rigorously studied towards solving the protein folding problem. A recent research has highlighted that input features known as precision matrix are most informative for predicting inter-residue contact map, the key for building three-dimensional models. In this work, we study the significance of the precision matrix feature when very deep residual networks are trained. Using a standard dataset of 3456 …

Nonsupereulerian Graphs With Large Size, Paul A. Catlin, Zhi-Hong Chen

Zhi-Hong Chen

No abstract provided.

On The Edge Arboricity Of A Random Graph, P. A. Catlin, Zhi-Hong Chen, E. M. Palmer

Zhi-Hong Chen

No abstract provided.

On Hamiltonian Line Graphs, Zhi-Hong Chen

Zhi-Hong Chen

No abstract provided.

Supereuleriaun Graphs And The Petersen Graph, Zhi-Hong Chen

Zhi-Hong Chen

Using a contraction method, we find some best-possible sufficient condi­tions for 3-edge-connected simple graphs such that either the graphs have spanning eulerian subgraphs or the graphs are contractible to the Petersen graph.

Now Mistakes In Keto Prime Diet That Make You Look Dumb, Diana Arris

diana arris

Near Real-Time Determination Of The Prevalence Of Cannabinoids, Cathinones, And Synthetic Opioids, Catherine O'Rourke, Bikram Subedi

Scholars Week

Unregulated new psychoactive substances (NPS) in “pure” or “preparation” forms are designed to mimic the effects of controlled substances, and are introduced and reintroduced in the market as a cheap substitute of established regulated drugs in quick succession to loophole the law enforcement efforts on combating drugs. For example, carfentanil, a synthetic opioid activates the opioid receptors similar to morphine but it is astoundingly potent compared to a typical drug of abuse (100 times more potent than fentanyl and 10,000 times more powerful than morphine). Based on the cost- and time-intensive forensic analysis, National Drug Early Warning System reported the …

Practical Planning For Successful Winter Grazing, Jim Gerrish

Kentucky Grazing Conference

Most farmers and ranchers consider feeding hay to their stock to be a fairly simple task. You go to the bale yard, pick up some hay, drive out to the stock, and feed them some hay. Simple, but very expensive. Like almost everything else in life, convenience comes at a price. It is up to you to determine what the true cost of each alternative strategy might be and then decide if you’re willing and able to pay the price for the option you choose.

Winter grazing can be as simple and as convenient as feeding hay, but much less …

Applying Kentucky Dairy Forage Research For Beef Producers, S. Ray Smith

Kentucky Grazing Conference

In 2015 the University of Kentucky and the University of Tennessee was awarded a USDA-NIFA grant that we refer to as the Southeast Organic Dairy Project. The goal of this project was to develop science-based recommendations to efficiently manage forages, herd health, and overall farm productivity on organic dairies in the Southeastern US. There are only about 40 organic dairies in Kentucky, but the over 35,000 beef cattle operations in the state will also benefit from this research. We are learning the best forage combinations for Kentucky and Tennessee soils and growing conditions. We are learning how to maximize forage …

How Good Is Our Kentucky Haylage? A Summary Of 2017-18 Farm Results, Jimmy C. Henning

Kentucky Grazing Conference

The ability to harvest moist forage as hay gives Kentucky producers many advantages, including timely harvest, higher forage quality, and less weathering loss over hay systems. The baleage system allows producers to utilize commonly available forage equipment (mowers, rakes, balers) rather than requiring choppers and silo structures or bags. Making high quality baleage requires timely access to bale wrappers.

Grazing On My Farm, Will Bowling, Debby Dulworth

Kentucky Grazing Conference

The downloadable document provides the presenters' bios only. No presentation content is available.

Summer Stockpiling, Christopher D. Teutsch

Kentucky Grazing Conference

The downloadable document includes these components:

• Stockpiling Novel Endophyte Tall Fescue for Summer Grazing
• The Yield and Nutritive Value of Tall Fescue Stockpiled for Summer Grazing
• Using a Summer Stockpiling System to Extend the Grazing Season

Hay Storage And Feeding: Avoiding Train Wrecks, Jeff Lehmkuhler

Kentucky Grazing Conference

When looking back at the Standardized Performance Analysis data collected from cow-calf operations, the data clearly illustrates that beyond the actual investment in the livestock, feed costs are the major expense in the cattle enterprise. In a report of 135 beef cow-calf operations with an average number of 80 cows/operation in the FINBIN data set, the cost of production was reported to be an average of $169.54/cwt or $847.70 for a 500 lb calf (Nordquist and Van Nurden, 2019). This includes all costs including land, labor, feed and so forth. The profit margin is narrow when all expenses are included …

The Synthesis Of Heterocycles And Carbocycles And Work Towards Kainic Acid, Mathew L. Piotrowski

Electronic Thesis and Dissertation Repository

This thesis focuses on the synthesis of a variety of heterocycles and carbocycles such as pyrrolidines, dihydrofurans, dihydropyrroles, cyclopentenes, and 2,5-dihydrooxepines. Traditional synthetic methods are discussed first, followed by the manipulation of donor-acceptor cyclopropanes towards the above-mentioned compounds. This leads to a discussion about an important pyrrolidine-containing natural product known as kainic acid. Kainic acid has been studied in the neuroscience field for its biological properties which have led to a better understanding of common human neurological disorders like epilepsy, Huntington’s disease and the after-effects of strokes.

Chapter two focuses on a common rearrangement of donor-acceptor cyclopropanes known as the …

Grazing Management 2020, Mark Harris

Kentucky Grazing Conference

Bill Gallagher Senior had the idea to use an electric shock to deter his horse Joe from rubbing on the families Essex car. After jury rigging a magneto to produce a shock, the experiment was successful enough for him to build a battery powered ticking fence unit for use on his pastoral dairy farm. Word got around and as a result Gallagher the animal management company was founded in 1938 in Hamilton New Zealand.

Most Profitable Hay Feeding Days For A Cow-Calf Farm, Gregory S. Halich

Kentucky Grazing Conference

No abstract provided.

Selecting Cattle For Optimal Production In Pasture Settings, Gordon F. Jones

Kentucky Grazing Conference

Cattle are ruminants and capable of utilizing various forages to support body maintenance and production. However, the major question that needs to be answered “is it possible to select animals that allow for optimal production per acre of land without supplying purchased feedstuffs to supplement the pasture that is provided?” As I have pondered over this issue for many years, it has become quite clear that “environmental and forage adaptability trumps every other criterion that may be used in selection”. This does NOT mean that quantitative genetic values are not available to aid in the selection process, but it is …

Why You Should Be Out Of The Hay Business, Jim Gerrish

Kentucky Grazing Conference

Winter feeding costs are typically the single greatest line-item cost in most cow-calf budgets. The irony of this is it doesn’t seem to matter whether you live in Minnesota, Missouri, or Mississippi, winter feed costs are still the highest cost. If you want to improve profitability in any resource-based production business, your first best strategy is to tackle your biggest cost items. The best way to manage a cost is to eliminate it. Shaving a little here and there does not make a big impact. Think elimination, not reduction.

Foreword And Conference Information [2019], S. Ray Smith, Jimmy C. Henning, Christopher D. Teutsch

Kentucky Grazing Conference

No abstract provided.

Are There Health Hazards Coming From The Rollout Of 5g?, David O. Carpenter

Campus Conversations in Standish

No abstract provided.

2019 Celebration Of Scholarship, Creativity, And Engagement, Beth Heldebrandt, Todd Bruns, Seth Yeakel, Matthew Eifrid

Programs

Scholarship, creativity, innovation, and the many forms of collaborative engagement that shape faculty life and student learning are central to the mission of Eastern Illinois University. For that reason, our faculty, department chairs, college deans, the Provost, and the entire campus community celebrate the achievements and outstanding contributions of our colleagues and students to their disciplines and professions every year. And, as the following pages illustrate, faculty engaged in continuing scholarly and creative activities that have provided outstanding mentoring experiences for our undergraduate and graduate students.

In addition to recognizing faculty performances, shows, publications, grants and other professional efforts, the …