Physical Sciences and Mathematics Commons^™

Lai’S Conditions For Spanning And Dominating Closed Trails, Wei-Guo Chen, Zhi-Hong Chen, Mei Lu

Zhi-Hong Chen

No abstract provided.

Machine Learning-Based Models For Assessing Impacts Before, During And After Hurricane Events, Julie L. Harvey

Electronic Theses and Dissertations

Social media provides an abundant amount of real-time information that can be used before, during, and after extreme weather events. Government officials, emergency managers, and other decision makers can use social media data for decision-making, preparation, and assistance. Machine learning-based models can be used to analyze data collected from social media. Social media data and cloud cover temperature as physical sensor data was analyzed in this study using machine learning techniques. Data was collected from Twitter regarding Hurricane Florence from September 11, 2018 through September 20, 2018 and Hurricane Michael from October 1, 2018 through October 18, 2018. Natural language …

Mortality, Perception, And Scale: Understanding How Predation Shapes Space Use In A Wild Prey Population, Lindsey N. Messinger, Erica F. Stuber, Christopher J. Chizinski, Joseph J. Fontaine

Nebraska Cooperative Fish and Wildlife Research Unit: Staff Publications

Attempts to assess behavioral responses of prey to predation risk are often confounded by depredation of prey. Moreover, the scale at which the response of prey is assessed has important implications for discovering how predation risk alters prey behavior. Herein, we assessed space use of wild Ring-necked Pheasants (Phasianus colchicus) in response to spatial and temporal variation in recreational hunting. We radio-marked pheasants and monitored space use at two spatial scales: short-term seasonal home range, and nightly resting locations. Additionally, we considered temporal variation in predation risk by monitoring space use prior to and during the pheasant hunting season. Although …

Mapping Of A Regulatory Site Of The Escherichia Coli Adp-Glucose Pyrophosphorylase, Jaina A. Bhayani, Benjamin L. Hill, Anisha Sharma, Alberto A. Iglesias, Kenneth W. Olsen, Miguel A. Ballicora

Chemistry: Faculty Publications and Other Works

The enzyme ADP-glucose pyrophosphorylase (ADP-Glc PPase) controls the biosynthesis of glycogen in bacteria and starch in plants. It is regulated by various activators in different organisms according to their metabolic characteristics. In Escherichia coli, the major allosteric activator is fructose 1,6-bisphosphate (FBP). Other potent activator analogs include 1,6-hexanediol bisphosphate (HBP) and pyridoxal 5′-phosphate (PLP). Recently, a crystal structure with FBP bound was reported (PDB ID: 5L6S). However, it is possible that the FBP site found is not directly responsible for the activation of the enzyme. We hypothesized FBP activates by binding one of its phosphate groups to …

Tidal Variation In Cohesive Sediment Distribution And Sensitivity To Flocculation And Bed Consolidation In An Idealized, Partially Mixed Estuary, Danielle R.N. Tarpley, Courtney K. Harris, Carl Friedrichs, Christopher T. Sherwood

VIMS Articles

Particle settling velocity and erodibility are key factors that govern the transport of sediment through coastal environments including estuaries. These are difficult to parameterize in models that represent mud, whose properties can change in response to many factors, including tidally varying suspended sediment concentration (SSC) and shear stress. Using the COAWST (Coupled Ocean-Atmosphere-Wave-Sediment Transport) model framework, we implemented bed consolidation, sediment-induced stratification, and flocculation formulations within an idealized two-dimensional domain that represented the longitudinal dimension of a micro-tidal, muddy, partially mixed estuary. Within the Estuarine Turbidity Maximum (ETM), SSC and median floc diameter varied by a factor of four over …

Antibacterial Properties Of Mussel-Inspired Polydopamine Coatings Prepared By A Simple Two-Step Shaking-Assisted Method, Pegah Kord Fooroshani, Elizabeth Polega, Kevin Thomson, Mohammad Saleh Akram Bhuiyan, Rattapol Pinnaratip, Mikhail Trought, Chito E. Kendrick, Yuesheng Gao, Kathryn Perrine, Lei Pan, Bruce P. Lee

Michigan Tech Publications

A simple two-step, shaking-assisted polydopamine (PDA) coating technique was used to impart polypropylene (PP) mesh with antimicrobial properties. In this modified method, a relatively large concentration of dopamine (20 mg ml⁻¹) was first used to create a stable PDA primer layer, while the second step utilized a significantly lower concentration of dopamine (2 mg ml⁻¹) to promote the formation and deposition of large aggregates of PDA nanoparticles. Gentle shaking (70 rpm) was employed to increase the deposition of PDA nanoparticle aggregates and the formation of a thicker PDA coating with nano-scaled surface roughness (RMS = 110 …

Similarity-Based Chained Transfer Learning For Energy Forecasting With Big Data, Yifang Tian, Ljubisa Sehovac, Katarina Grolinger

Electrical and Computer Engineering Publications

Smart meter popularity has resulted in the ability to collect big energy data and has created opportunities for large-scale energy forecasting. Machine Learning (ML) techniques commonly used for forecasting, such as neural networks, involve computationally intensive training typically with data from a single building or a single aggregated load to predict future consumption for that same building or aggregated load. With hundreds of thousands of meters, it becomes impractical or even infeasible to individually train a model for each meter. Consequently, this paper proposes Similarity-Based Chained Transfer Learning (SBCTL), an approach for building neural network-based models for many meters by …

Probabilistic Modeling Of Democracy, Corruption, Hemophilia A And Prediabetes Data, A. K. M. Raquibul Bashar

USF Tampa Graduate Theses and Dissertations

Parametric analysis of any real-world data is the most powerful tool to characterize the probabilistic behavior in social, economic, medical, epidemiological, and other areas of study. In the present study, we identify the theoretical Probability Distribution Function(PDF) for Democracy Index Scores (DIS) from the Economist Intelligence Unit (EIU) database and estimate the maximum likelihood estimates of the theoretical PDFS. We also identify the individual PDFs for each of the clusters, Full Democracy, Flawed Democracy, Hybrid Regime, and Authoritarian Regime defined by the Economist Intelligence Unit (EIU).

A statistical model is a convenient instrument to predict the future value of any …

Polar Alignment Of A Protoplanetary Disc Around An Eccentric Binary – Iii. Effect Of Disc Mass, Rebecca G. Martin, Stephen H. Lubow

Physics & Astronomy Faculty Research

An initially sufficiently misaligned low-mass protoplanetary disc around an eccentric binary undergoes damped nodal oscillations of tilt angle and longitude of ascending node. Dissipation causes evolution towards a stationary state of polar alignment in which the disc lies perpendicular to the binary orbital plane with angular momentum aligned to the eccentricity vector of the binary. We use hydrodynamic simulations and analytical methods to investigate how the mass of the disc affects this process. The simulations suggest that a disc with non-zero mass settles into a stationary state in the frame of the binary, the generalized polar state, at somewhat lower …

An Engineering Geological Anatomy Of The Padma River Bank Failure And Erosion, 2018: A Case Study Of Naria Bank Section, Bangladesh, Mir Fazlul Karim, Nazrul I. Khandaker, Shahidul Haque, M. Zillur Rahman, Muhammad Qumrul Hassan, Asm Maksud Kamal, Masud Ahmed, Belal A. Sayeed

Publications and Research

The Naria town of Bangladesh is developed on the right bank of the Padma River. The bank is an old natural levee of Meghna River. The Holocene-Recent geology of Naria is actively dominated by the fluvial processes of Ganges-Brahmaputra-Meghna River system where the deltaic sediments are characterized as unconsolidated fine sand and silt, covered by thin veneer of clayey silt and loam. The annual volume of water discharge and flow dynamics are dependent on the intensity of the rainfall, runoff and the length of dry winter. Excessive river bank erosion, channel avulsion, renewed submergence of floodplains, and formation of natural …

Taking The Metabolic Pulse Of The World's Coral Reefs, Tyler Cyronak, Andreas J. Andersson, Chris Langdon, Rebecca Albright, Nicholas R. Bates, Ken Caldeira, Renee Carlton, Jorge E. Corredor, Rob B. Dunbar, Ian Enochs, Jonathan Erez, Bradley D. Eyre, Jean-Pierre Gattuso, Dwight Gledhill, Hajime Kayanne, David I. Kline, David A. Koweek, Coulson Lantz, Boaz Lazar, Derek Manzello, Ashly Mcmahon, Melissa Melendez, Heather N. Page, Isaac R. Santos, Kai G. Schulz, Emily Shaw, Jacob Silverman, Atsushi Suzuki, Lida Teneva, Atsushi Watanabe, Shoji Yamamoto

Tyler Cyronak

Worldwide, coral reef ecosystems are experiencing increasing pressure from a variety of anthropogenic perturbations including ocean warming and acidification, increased sedimentation, eutrophication, and overfishing, which could shift reefs to a condition of net calcium carbonate (CaCO3) dissolution and erosion. Herein, we determine the net calcification potential and the relative balance of net organic carbon metabolism (net community production; NCP) and net inorganic carbon metabolism (net community calcification; NCC) within 23 coral reef locations across the globe. In light of these results, we consider the suitability of using these two metrics developed from total alkalinity (TA) and dissolved inorganic carbon (DIC) …

Temperature-Induced Viral Resistance In Emiliania Huxleyi (Prymnesiophyceae), B. Jacob Kendrick, Giacomo R. Ditullio, Tyler Cyronak, James M. Fulton, Benjamin A. S. Van Mooy, Kay D. Bidle

Tyler Cyronak

Annual Emiliania huxleyi blooms (along with other coccolithophorid species) play important roles in the global carbon and sulfur cycles. E. huxleyi blooms are routinely terminated by large, host-specific dsDNA viruses, (Emiliania huxleyi Viruses; EhVs), making these host-virus interactions a driving force behind their potential impact on global biogeochemical cycles. Given projected increases in sea surface temperature due to climate change, it is imperative to understand the effects of temperature on E. huxleyi’s susceptibility to viral infection and its production of climatically active dimethylated sulfur species (DSS). Here we demonstrate that a 3°C increase in temperature induces EhV-resistant phenotypes …

Nitrous Oxide And Methane Dynamics In A Coral Reef Lagoon Driven By Pore Water Exchange: Insights From Automated High‐Frequency Observations, Chiara O'Reilly, Isaac R. Santos, Tyler Cyronak, Ashly Mcmahon, Damien T. Maher

Tyler Cyronak

Automated cavity ring down spectroscopy was used to make continuous measurements of dissolved methane, nitrous oxide, and carbon dioxide in a coral reef lagoon for 2 weeks (Heron Island, Great Barrier Reef). Radon (²²²Rn) was used to trace the influence of tidally driven pore water exchange on greenhouse gas dynamics. Clear tidal variation was observed for CH₄, which correlated to ²²²Rn in lagoon waters. N2O correlated to ²²²Rn during the day only, which appears to be a response to coupled nitrification‐denitrification in oxic sediments, fueled by nitrate derived from bird guano. The lagoon was …

Permeable Coral Reef Sediment Dissolution Driven By Elevated Pco2 And Pore Water Advection, Tyler Cyronak, Isaac R. Santos, Bradley D. Eyre

Tyler Cyronak

Ocean acidification (OA) is expected to drive the transition of coral reef ecosystems from net calcium carbonate (CaCO₃) precipitating to net dissolving within the next century. Although permeable sediments represent the largest reservoir of CaCO₃ in coral reefs, the dissolution of shallow CaCO₃ sands under future pCO₂ levels has not been measured under natural conditions. In situ, advective chamber incubations under elevated pCO₂ (~800 µatm) shifted the sediments from net precipitating to net dissolving. Pore water advection more than doubled dissolution rates (1.10 g CaCO₃ m⁻² d⁻¹) when compared to …

Hysteresis Between Coral Reef Calcification And The Seawater Aragonite Saturation State, Ashly Mcmahon, Isaac R. Santos, Tyler Cyronak, Bradley D. Eyre

Tyler Cyronak

Some predictions of how ocean acidification (OA) will affect coral reefs assume a linear functional relationship between the ambient seawater aragonite saturation state (Ω_a) and net ecosystem calcification (NEC). We quantified NEC in a healthy coral reef lagoon in the Great Barrier Reef during different times of the day. Our observations revealed a diel hysteresis pattern in the NEC versus Ω_a relationship, with peak NEC rates occurring before the Ω_a peak and relatively steady nighttime NEC in spite of variable Ω_a. Net ecosystem production had stronger correlations with NEC than light, temperature, nutrients, pH, …

Groundwater And Porewater As Major Sources Of Alkalinity To A Fringing Coral Reef Lagoon (Muri Lagoon, Cook Islands), Tyler Cyronak, Isaac R. Santos, Dirk V. Erler, Bradley D. Eyre

Tyler Cyronak

To better predict how ocean acidification will affect coral reefs, it is important to understand how biogeochemical cycles on reefs alter carbonate chemistry over various temporal and spatial scales. This study quantifies the contribution of shallow porewater exchange (as quantified from advective chamber incubations) and fresh groundwater discharge (as traced by ²²²Rn) to total alkalinity (TA) dynamics on a fringing coral reef lagoon along the southern Pacific island of Rarotonga over a tidal and diel cycle. Benthic alkalinity fluxes were affected by the advective circulation of water through permeable sediments, with net daily flux rates of carbonate alkalinity ranging …

Expanding Aquatic Observations Through Recreation, Robert J. W. Brewin, Kieran Hyder, Andreas J. Andersson, Oliver Billson, Philip J. Bresnahan, Thomas G. Brewin, Tyler Cyronak, Giorgio Dall'olmo, Lee De Mora, George Graham, Thomas Jackson, Dionysios E. Raitsos

Tyler Cyronak

Accurate observations of the Earth system are required to understand how our planet is changing and to help manage its resources. The aquatic environment—including lakes, rivers, wetlands, estuaries, coastal and open oceans—is a fundamental component of the Earth system controlling key physical, biological, and chemical processes that allow life to flourish. Yet, this environment is critically undersampled in both time and space. New and cost-effective sampling solutions are urgently needed. Here, we highlight the potential to improve aquatic sampling by tapping into recreation. We draw attention to the vast number of participants that engage in aquatic recreational activities and argue, …

Drivers Of Pco2 Variability In Two Contrasting Coral Reef Lagoons: The Influence Of Submarine Groundwater Discharge, Tyler Cyronak, Isaac R. Santos, Dirk V. Erler, Damien T. Maher, Bradley D. Eyre

Tyler Cyronak

The impact of groundwater on pCO₂ variability was assessed in two coral reef lagoons with distinct drivers of submarine groundwater discharge (SGD). Diel variability of pCO₂ in the two ecosystems was explained by a combination of biological drivers and SGD inputs. In Rarotonga, a South Pacific volcanic island, ²²²Rn‐derived SGD was driven primarily by a steep terrestrial hydraulic gradient, and the water column was influenced by the high pCO₂ (5501 µatm) of the fresh groundwater. In Heron Island, a Great Barrier Reef coral cay, SGD was dominated by seawater recirculation through the sediments …

Enhanced Acidification Of Global Coral Reefs Driven By Regional Biogeochemical Feedbacks, Tyler Cyronak, Kai G. Schulz, Isaac R. Santos, Bradley D. Eyre

Tyler Cyronak

Physical uptake of anthropogenic CO₂ is the dominant driver of ocean acidification (OA) in the open ocean. Due to expected decreases in calcification and increased dissolution of CaCO₃ framework, coral reefs are thought to be highly susceptible to OA. However, biogeochemical processes can influence the pCO₂ and pH of coastal ecosystems on diel and seasonal time scales, potentially modifying the long‐term effects of increasing atmospheric CO₂. By compiling data from the literature and removing the effects of short‐term variability, we show that the average pCO₂ of coral reefs throughout the globe has increased ~3.5‐fold …

Coral Reef Carbonate Chemistry Variability At Different Functional Scales, Yuichiro Takeshita, Tyler Cyronak, Todd R. Martz, Theodor Kindeberg, Andreas J. Andersson

Tyler Cyronak

There is a growing recognition for the need to understand how seawater carbonate chemistry over coral reef environments will change in a high-CO₂ world to better assess the impacts of ocean acidification on these valuable ecosystems. Coral reefs modify overlying water column chemistry through biogeochemical processes such as net community organic carbon production (NCP) and calcification (NCC). However, the relative importance and influence of these processes on seawater carbonate chemistry vary across multiple functional scales (defined here as space, time, and benthic community composition), and have not been fully constrained. Here, we use Bermuda as a case study to …

Comparing Chemistry And Census-Based Estimates Of Net Ecosystem Calcification On A Rim Reef In Bermuda, Travis A. Courtney, Andreas J. Andersson, Nicholas R. Bates, Andrew R. Collins, Tyler Cyronak, Samantha J. De Putron, Bradley D. Eyre, Rebecca Garley, Eric J. Hochberg, Rodney Johnson, Sylvia Musielewicz, Tim J. Noyes, Christopher L. Sabine, Adrienne J. Sutton, Jessy Toncin, Aline Tribollet

Tyler Cyronak

Coral reef net ecosystem calcification (NEC) has decreased for many Caribbean reefs over recent decades primarily due to changes in benthic community composition. Chemistry-based approaches to calculate NEC utilize the drawdown of seawater total alkalinity (TA) combined with residence time to calculate an instantaneous measurement of NEC. Census-based approaches combine annual growth rates with benthic cover and reef structural complexity to estimate NEC occurring over annual timescales. Here, NEC was calculated for Hog Reef in Bermuda using both chemistry and census-based NEC techniques to compare the mass-balance generated by the two methods and identify the dominant biocalcifiers at Hog Reef. …

Federal Protection Of Unique Environmental Interests: Endangered And Threatened Species, Ronald H. Rosenberg

Ronald H. Rosenberg

Endangered species protection has long been favored by many Americans, who watched regretfully as the numbers of American eagles, buffaloes and other species dwindled toward extinction. Only recently, however, has species protection become a matter of public controversy, subsumed in the more general "development v. environment" debate. In this Article, Professor Rosenberg surveys the federal government's role in species protection, with a special focus on the Endangered Species Act of 1973. Prompted by the much-publicized Supreme Court decision in the "snail darter case"--TVA v. Hill-Congress extensively amended the Act in 1978. After a detailed analysis of these amendments, Professor Rosenberg …

Ferrate: A Novel Water Treatment Input, Joseph Goodwill

Sustainability Seminar Series

Advanced oxidation processes (AOPs) are effective at transforming recalcitrant organic water pollutants. However, most AOPs require relatively complex and capital intensive auxiliary systems to generate radicals. Ferrate (Fe(VI)) is a strong oxidant that affords an operational simplicity that some utilities require. This presentation will provide an overview of Fe(VI) technology, and recent results of an ongoing study focused on Fe(VI) and water reuse.

Molecular Recognition Of Methionine-Terminated Peptides By Cucurbit[8]Uril, Zoheb Hirani, Hailey F. Taylor, E. F. Babcock, Andrew T. Bockus, C. D. Varnado Jr., Christopher W. Bielawski, Adam R. Urbach

Adam R Urbach

This Article describes the molecular recognition of peptides containing an N-terminal methionine (Met) by the synthetic receptor cucurbit[8]-uril (Q8) in aqueous solution and with submicromolar affinity. Prior work established that Q8 binds with high affinity to peptides containing aromatic amino acids, either by simultaneous binding of two aromatic residues, one from each of two different peptides, or by simultaneous binding of an aromatic residue and its immediate neighbor on the same peptide. The additional binding interface of two neighboring residues suggested the possibility of targeting nonaromatic peptides, which have thus far bound only weakly to synthetic receptors. A peptide library …

Antagonistic Effects Of Ocean Acidification And Rising Sea Surface Temperature On The Dissolution Of Coral Reef Carbonate Sediments, Daniel Trnovsky, Laura Stoltenberg, Tyler Cyronak, Bradley D. Eyre

Tyler Cyronak

Increasing atmospheric CO₂ is raising sea surface temperature (SST) and increasing seawater CO₂ concentrations, resulting in a lower oceanic pH (ocean acidification; OA), which is expected to reduce the accretion of coral reef ecosystems. Although sediments comprise most of the calcium carbonate (CaCO₃) within coral reefs, no in situ studies have looked at the combined effects of increased SST and OA on the dissolution of coral reef CaCO₃ sediments. In situ benthic chamber incubations were used to measure dissolution rates in permeable CaCO₃ sands under future OA and SST scenarios in a coral reef …

The Waters Of Antarctica: Do They Belong To Some States, No States, Or All States?, Linda A. Malone

Linda A. Malone

Major issues and complexities arise when one is looking at the international puzzle that is Antarctica. Despite being uninhabited year round and lacking substantial long-term international law rules for sovereignty, states still try to claim their sovereignty over various parts of Antarctica. The consortium of states under the Antarctica Treaty System (“ATS”) then further aggravates these complexities, especially when other states outside of the ATS have been arguing for different regimes and approaches to dealing with Antarctica and resource exploitation. Due to these major issues and a desperate need for a resolution in times of global climate change, this Article …

Responsibility To Protect, Libya To Japan, Linda A. Malone

Linda A. Malone

No abstract provided.

Acknowledging The Impact Of Climate Change On National Security: A Long And Winding Road, Linda A. Malone

Linda A. Malone

No abstract provided.

Shock Effects Recorded By The U-Pb Radiometric System In Zircons Of Apollo 17 Impact Breccias And By Raman Spectroscopy In Enstatite Meteorites, Bidong Zhang

Electronic Thesis and Dissertation Repository

Impact cratering processes and formations are ubiquitous on the rocky planets within the Solar System. The Earth-Moon system was formed by a massive planetary impact, and numerous impacts afterwards significantly reshaped the topography and lithology of the Moon surface. This dissertation focuses on studying some specific geochemical, geochronological, and geophysical signatures of impact processes preserved in lunar rocks and asteroidal meteorites.

The zircon U-Pb radiometric system is one of the most reliable geochronometers in measuring geological time. Recently, unsupported radiogenic Pb enrichment has been reported to compromise the accuracy and precision of zircon U-Pb geochronometer in terrestrial rocks. In Chapter …

Strategies For The Preparation Of Functional Pendant Group Polymer Materials Via Click Chemistry, Rajeshwar Vasdev

Electronic Thesis and Dissertation Repository

This thesis describes the development of a polymer via a unique masking-unmasking strategy allowing for physical and chemical modification as desired. Modifiable polymers may lead to improved applications in drug delivery, photo-patterning and emissive materials design. In recent years, these potential traits have motivated the search for efficient protocols for the synthetic modification of polymers. Accordingly, click chemistry, characterized by fast, clean and high yielding reactions represents an effective tool for the modification of polymers. To achieve this goal, an efficient methodology is created to incorporate a highly reactive strained alkyne functional group as a modification site to expand the …