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2021

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Full-Text Articles in Physical Sciences and Mathematics

The Development Of A Procedure For The Pxrf Analysis Of Soil Cation Exchange Capacity In Collaboration With Colorado Farmers, Claire E. Wineman Jan 2021

The Development Of A Procedure For The Pxrf Analysis Of Soil Cation Exchange Capacity In Collaboration With Colorado Farmers, Claire E. Wineman

Senior Independent Study Theses

Discrepancies between farmers’ and scientists’ knowledge systems and experiences have long prevented the success and mutual beneficiality of collaborative research efforts between these two groups. The development of agricultural technologies, such as portable X-ray fluorescence (PXRF) for the analysis of soil cation exchange capacity in the field, creates a promising overlap point for farmers and scientists to cooperatively study issues within their sociocultural context and with access to institutional resources. In this study, the generation of an in-field PXRF method in collaboration with Colorado farmers helps to provide a prospective model for scientists and farmers looking to use collaborative research …


Exponential Random Graphs And A Generalization Of Parking Functions, Ryan Demuse Jan 2021

Exponential Random Graphs And A Generalization Of Parking Functions, Ryan Demuse

Electronic Theses and Dissertations

Random graphs are a powerful tool in the analysis of modern networks. Exponential random graph models provide a framework that allows one to encode desirable subgraph features directly into the probability measure. Using the theory of graph limits pioneered by Borgs et. al. as a foundation, we build upon the work of Chatterjee & Diaconis and Radin & Yin. We add complexity to the previously studied models by considering exponential random graph models with edge-weights coming from a generic distribution satisfying mild assumptions. In particular, we show that a large family of two-parameter, edge-weighted exponential random graphs display a phase …


Migration Of The Tidal Marsh Range Under Sea Level Rise For Coastal Virginia, With Land Cover Data, Julie Herman, Molly Mitchell Jan 2021

Migration Of The Tidal Marsh Range Under Sea Level Rise For Coastal Virginia, With Land Cover Data, Julie Herman, Molly Mitchell

Data

The layers in this geodatabase were intended to represent the land that is encompassed by the average tidal range as sea level rises in the Virginia coastal region, including Chesapeake Bay and tributaries, the Atlantic Ocean side of the Eastern Shore, and Virginia Beach. The data layers in this geodatabase represent each two foot range of elevation incremented by 0.5 ft (e.g. 0-2 ft, 0.5-2.5 ft, 1-3 ft, etc.) with the current land cover that exists in that range.

ArcGIS metadata is included in the geodatabase.

Further details are provided in the Geodatabase Information file located from the download tab.


Upper-Sided Ewma-Based Distribution-Specific Tolerance Limits, Owen Visser Jan 2021

Upper-Sided Ewma-Based Distribution-Specific Tolerance Limits, Owen Visser

UNF Graduate Theses and Dissertations

Tolerance limits are constructed from sample data to ascertain if a proportion of a process is within specification limits. There exists multiple methods of calculating the sample size requirements for tolerance limits under various assumptions. In this research, a distribution-specific algorithm that utilizes the exponentially weighted moving average technique (EWMA), first introduced by Sa and Razaila (2004), is reconstructed. The algorithm is used to calculate the required sample sizes for continuous construction of upper-sided tolerance limits. The sample sizes and intervals constructed from them are compared to three existing methods for various distributions. The distribution-specific algorithm was observed to reduce …


Effect Of Mutation And Vaccination On Spread, Severity, And Mortality Of Covid-19 Disease, Dr Hossam Zawbaa, Hasnaa Osama, Ahmed El‐Gendy, Haitham Saeed, Hadeer S. Harb, Yasmin M. Madney, Mona Abdelrahman, Marwa Mohsen, Ahmed M.A. Ali, Mina Nicola, Marwa O. Elgendy, Ihab A. Ibrahim, Mohamed E.A. Abdelrahim Jan 2021

Effect Of Mutation And Vaccination On Spread, Severity, And Mortality Of Covid-19 Disease, Dr Hossam Zawbaa, Hasnaa Osama, Ahmed El‐Gendy, Haitham Saeed, Hadeer S. Harb, Yasmin M. Madney, Mona Abdelrahman, Marwa Mohsen, Ahmed M.A. Ali, Mina Nicola, Marwa O. Elgendy, Ihab A. Ibrahim, Mohamed E.A. Abdelrahim

Articles

Coronavirus disease 2019 (COVID-19) has had different waves within the same country. The spread rate and severity showed different properties within the COVID-19 different waves. The present work aims to compare the spread and the severity of the different waves using the available data of confirmed COVID-19 cases and death cases. Real-data sets collected from the Johns Hopkins University Center for Systems Science were used to perform a comparative study between COVID-19 different waves in 12 countries with the highest total performed tests for severe acute respiratory syndrome coronavirus 2 detection in the world (Italy, Brazil, Japan, Germany, Spain, India, …


Artificial Intelligence As Evidence, Paul W. Grimm, Maura R. Grossman, Gordon V. Cormack Jan 2021

Artificial Intelligence As Evidence, Paul W. Grimm, Maura R. Grossman, Gordon V. Cormack

Faculty Scholarship

This article explores issues that govern the admissibility of Artificial Intelligence (“AI”) applications in civil and criminal cases, from the perspective of a federal trial judge and two computer scientists, one of whom also is an experienced attorney. It provides a detailed yet intelligible discussion of what AI is and how it works, a history of its development, and a description of the wide variety of functions that it is designed to accomplish, stressing that AI applications are ubiquitous, both in the private and public sectors. Applications today include: health care, education, employment-related decision-making, finance, law enforcement, and the legal …


Founding Monsters Tales, Maggie Colangelo, Bernard Means Jan 2021

Founding Monsters Tales, Maggie Colangelo, Bernard Means

Founding Monsters

The creative team behind the Founding Monsters comic book—Maggie Colangelo and Dr. Bernard K. Means—bring you Founding Monsters Tales. Founding Monsters Tales features all-new art by Maggie and explores and expands on themes in Founding Monsters. Meet again Moses Williams, an enslaved servant of the Peale family who not only helped reconstruct the first mastodon skeleton, but was an unheralded artist in his own right. Find out whether mastodons were meat eaters, and how they differed from mammoths. Learn whether Thomas Jefferson was correct in his interpretation of what he called “the great claw.” Discover what Jefferson thought …


Founding Monsters, Maggie Colangelo, Bernard Means Jan 2021

Founding Monsters, Maggie Colangelo, Bernard Means

Founding Monsters

The Founding Monsters comic book was created as a science-friendly graphical storytelling framework that tells the story of the Founding Fathers and their obsession with prehistoric megafauna, especially mastodons and giant ground sloths. Founding Monsters combines sequential art (e.g. comic book style) with historical and scientific data. The first mastodon (Mammut americanum) fossils were found in New York in the early 18th century. Later in the 18th century, Thomas Jefferson was sent fossils from what is now West Virginia for what were eventually identified as bones from a giant ground sloth (Megalonyx jeffersoni). The founding fathers, …


The Lady Be Good: A Case Study In Radio Frequency Direction Finders, With Supplemental Material For On-Line Appendix, Gregory A. Dilisi, Kenneth Kane, Robert A. Leskovec, Alison Chaney* Jan 2021

The Lady Be Good: A Case Study In Radio Frequency Direction Finders, With Supplemental Material For On-Line Appendix, Gregory A. Dilisi, Kenneth Kane, Robert A. Leskovec, Alison Chaney*

2021 Faculty Bibliography

No abstract provided.


Conversation Among Physical Chemists: Strategies And Resources For Remote Teaching And Learning Catalyzed By A Global Pandemic, Andrea N. Giordano, David Gardner, William W. Kennedy, Chrystal D. Bruce Jan 2021

Conversation Among Physical Chemists: Strategies And Resources For Remote Teaching And Learning Catalyzed By A Global Pandemic, Andrea N. Giordano, David Gardner, William W. Kennedy, Chrystal D. Bruce

2021 Faculty Bibliography

In the midst of a global pandemic in spring 2020, physical chemistry faculty gathered to share strategies and resources for teaching remotely. During this conversation, instructors created a shared document compiling the challenges they faced in spring 2020 and ways to improve teaching and learning in the physical chemistry classroom and laboratory when institutions reopened in the fall. We present a content analysis of the shared document that provides a snapshot of physical chemists’ thoughts at that moment in June 2020. The themes that emerged from our analysis are assessment, choice of learning objectives, course management, opportunities, resources, student motivation, …


Text Classification Using Novel Term Weighting Scheme-Based Improved Tf-Idf For Internet Media Reports, Zhiying Jiang Phd, Bo Gao, Yanlin He, Yongming Han, Paul Doyle, Qunxiong Zhu Jan 2021

Text Classification Using Novel Term Weighting Scheme-Based Improved Tf-Idf For Internet Media Reports, Zhiying Jiang Phd, Bo Gao, Yanlin He, Yongming Han, Paul Doyle, Qunxiong Zhu

Other

With the rapid development of the internet technology, a large amount of internet text data can be obtained. The text classification (TC) technology plays a very important role in processing massive text data, but the accuracy of classification is directly affected by the performance of term weighting in TC. Due to the original design of information retrieval (IR), term frequency-inverse document frequency (TF-IDF) is not effective enough for TC, especially for processing text data with unbalanced distributions in internet media reports. Therefore, the variance between the DF value of a particular term and the average of all DFs , namely, …


Status Reports Of The Fisheries And Aquatic Resources Of Western Australia 2020/21, S.J. Newman, B.S. Wise, K.G. Santoro, D.J. Gaughan Jan 2021

Status Reports Of The Fisheries And Aquatic Resources Of Western Australia 2020/21, S.J. Newman, B.S. Wise, K.G. Santoro, D.J. Gaughan

Status reports of the fisheries and aquatic resources

The Status Reports of the Fisheries and Aquatic Resources of Western Australia (SRFAR) provide an annual update on the state of the fish stocks and other aquatic resources of Western Australia (WA). These reports outline the most recent assessments of the cumulative risk status for each of the aquatic resources (assets) within WA’s six Bioregions using an Ecosystem Based Fisheries Management (EBFM) approach. The Departments’ risk based EBFM framework is the State government’s basis for management of all Western Australia’s aquatic resources.


Using Nmr Spectroscopy And Computational Chemistry To Confirm The Structure Of Novel Antibiotic Nocamycin O, Stephanie Lewis Jan 2021

Using Nmr Spectroscopy And Computational Chemistry To Confirm The Structure Of Novel Antibiotic Nocamycin O, Stephanie Lewis

CMC Senior Theses

In recent years, many medically promising antibiotics have been discovered in nature, especially in insect-microbe symbioses. One of the better-studied examples of this kind of defensive relationship is that of fungus-growing ants and the antibiotic-producing Actinobacteria. These bacteria produce several defensive chemicals with myriad uses, including one antibiotic that inhibits the growth of several bacterial strains, including other Actinobacteria. This antibiotic (known as nocamycin O) is a promising candidate for medicinal use due to its similarities to bacterial RNA polymerase inhibitors tirandamycin and streptolydigin, which inhibit several human pathogens. The determination of the structure of nocamycin O will be an …


Feature Investigation For Stock Returns Prediction Using Xgboost And Deep Learning Sentiment Classification, Seungho (Samuel) Lee Jan 2021

Feature Investigation For Stock Returns Prediction Using Xgboost And Deep Learning Sentiment Classification, Seungho (Samuel) Lee

CMC Senior Theses

This paper attempts to quantify predictive power of social media sentiment and financial data in stock prediction by utilizing a comprehensive set of stock-related fundamental and technical variables and social media sentiments. For conducting sentiment analysis, this study employs a pretrained finBERT model that provides three different sentiment classifications and respective softmax scores. Hence, the significance of these variables is evaluated with XGBoost regression and Shapley Additive exPlanations (SHAP) frameworks. Through investigating feature importance, this study finds that statistical properties of sentiment variables provide a stronger predictive power than a weighted sentiment score and that it is possible to quantify …


Structural Analysis And Link Prediction Algorithm Comparison For A Local Scientific Collaboration Network, Denys Guriev Jan 2021

Structural Analysis And Link Prediction Algorithm Comparison For A Local Scientific Collaboration Network, Denys Guriev

Browse all Theses and Dissertations

Scientific collaboration between researchers is very common and much influential and ground-breaking research is performed by teams comprised of scientist from different fields and organizations. In this thesis, we analyze and model a small scientific collaboration network limited to two organizations: Wright State University and the Air Force Research Laboratory. Research paper co-authorship is used for establishing the network structure. We analyze several network properties and compare them to past results from analysis of larger and more diverse collaboration networks. We show that the two-organization network we explored exhibits properties similar to those of larger networks. Guided by advances in …


Adaptive Two-Stage Edge-Centric Architecture For Deeply-Learned Embedded Real-Time Target Classification In Aerospace Sense-And-Avoidance Applications, Nicholas A. Speranza Jan 2021

Adaptive Two-Stage Edge-Centric Architecture For Deeply-Learned Embedded Real-Time Target Classification In Aerospace Sense-And-Avoidance Applications, Nicholas A. Speranza

Browse all Theses and Dissertations

With the growing number of Unmanned Aircraft Systems, current network-centric architectures present limitations in meeting real-time and time-critical requirements. Current methods utilizing centralized off-platform processing have inherent energy inefficiencies, scalability challenges, performance concerns, and cyber vulnerabilities. In this dissertation, an adaptive, two-stage, energy-efficient, edge-centric architecture is proposed to address these limitations. A novel, edge-centric Sense-and-Avoidance architecture framework is presented, and a corresponding prototype is developed using commercial hardware to validate the proposed architecture. Instead of a network-centric approach, processing is distributed at the logical edge of the sensors, and organized as Detection and Classification Subsystems. Classical machine vision algorithms are …


Partial Facial Re-Imaging Using Generative Adversarial Networks, Derek Desentz Jan 2021

Partial Facial Re-Imaging Using Generative Adversarial Networks, Derek Desentz

Browse all Theses and Dissertations

Existing facial recognition software relies heavily on using neural networks to extract key facial features to accurately classify known individuals. Some of these key features include the shape, size, and distance between an individual’s eyes, nose, and mouth. When these key features cannot be extracted due to facial coverings, existing applications become inaccurate and unreliable. The accuracy and reliability of these technologies are growing concerns as the facial recognition market continues to grow at an exponential rate. In this thesis, we have developed a web-based application service that is able to take in a partially covered face image and generate …


Evaluating The Performance Of Using Speaker Diarization For Speech Separation Of In-Person Role-Play Dialogues, Raveendra Medaramitta Jan 2021

Evaluating The Performance Of Using Speaker Diarization For Speech Separation Of In-Person Role-Play Dialogues, Raveendra Medaramitta

Browse all Theses and Dissertations

Development of professional communication skills, such as motivational interviewing, often requires experiential learning through expert instructor-guided role-plays between the trainee and a standard patient/actor. Due to the growing demand for such skills in practices, e.g., for health care providers in the management of mental health challenges, chronic conditions, substance misuse disorders, etc., there is an urgent need to improve the efficacy and scalability of such role-play based experiential learning, which are often bottlenecked by the time-consuming performance assessment process. WSU is developing ReadMI (Real-time Assessment of Dialogue in Motivational Interviewing) to address this challenge, a mobile AI solution aiming to …


Grain-Size And Permeability Of Sediments Within The Hyporheic Zone At The Theis Environmental Monitoring And Modeling Site, Great Miami River And Buried Valley Aquifer, Southwest Ohio, Usa, Timothy Wayne Cornett Jan 2021

Grain-Size And Permeability Of Sediments Within The Hyporheic Zone At The Theis Environmental Monitoring And Modeling Site, Great Miami River And Buried Valley Aquifer, Southwest Ohio, Usa, Timothy Wayne Cornett

Browse all Theses and Dissertations

The Theis Environmental Monitoring and Modeling Site is a field research facility, located on the Great Miami River in southwest Ohio, dedicated to the study of hyporheic zone processes. The site is underlain by an aquifer on the order of 21 meters thick, comprised of fluvial deposits. The permeability of the aquifer sediments was quantified both from one large scale hydraulic test (~100 m radial distance) and from grain-size analysis of 119 small-scale core samples (~20 cm length each). The permeability determined from the large-scale hydraulic test is 98.9 Darcies. The test also gave a value for specific yield of …


Texture-Driven Image Clustering In Laser Powder Bed Fusion, Alexander H. Groeger Jan 2021

Texture-Driven Image Clustering In Laser Powder Bed Fusion, Alexander H. Groeger

Browse all Theses and Dissertations

The additive manufacturing (AM) field is striving to identify anomalies in laser powder bed fusion (LPBF) using multi-sensor in-process monitoring paired with machine learning (ML). In-process monitoring can reveal the presence of anomalies but creating a ML classifier requires labeled data. The present work approaches this problem by printing hundreds of Inconel-718 coupons with different processing parameters to capture a wide range of process monitoring imagery with multiple sensor types. Afterwards, the process monitoring images are encoded into feature vectors and clustered to isolate groups in each sensor modality. Four texture representations were learned by training two convolutional neural network …


Goal Management In Multi-Agent Systems, Venkatsampath Raja Gogineni Jan 2021

Goal Management In Multi-Agent Systems, Venkatsampath Raja Gogineni

Browse all Theses and Dissertations

Autonomous agents in a multi-agent system coordinate to achieve their goals. However, in a partially observable world, current multi-agent systems are often less effective in achieving their goals. In much part, this limitation is due to an agent's lack of reasoning about other agents and their mental states. Another factor is the agent's inability to share required knowledge with other agents and the lack of explanations in justifying the reasons behind the goal. This research addresses these problems by presenting a general approach for agent goal management in unexpected situations. In this approach, an agent applies three main concepts: goal …


Mathematical Formula Recognition And Automatic Detection And Translation Of Algorithmic Components Into Stochastic Petri Nets In Scientific Documents, Elisavet Elli Kostalia Jan 2021

Mathematical Formula Recognition And Automatic Detection And Translation Of Algorithmic Components Into Stochastic Petri Nets In Scientific Documents, Elisavet Elli Kostalia

Browse all Theses and Dissertations

A great percentage of documents in scientific and engineering disciplines include mathematical formulas and/or algorithms. Exploring the mathematical formulas in the technical documents, we focused on the mathematical operations associations, their syntactical correctness, and the association of these components into attributed graphs and Stochastic Petri Nets (SPN). We also introduce a formal language to generate mathematical formulas and evaluate their syntactical correctness. The main contribution of this work focuses on the automatic segmentation of mathematical documents for the parsing and analysis of detected algorithmic components. To achieve this, we present a synergy of methods, such as string parsing according to …


A Deep Understanding Of Structural And Functional Behavior Of Tabular And Graphical Modules In Technical Documents, Michail Alexiou Jan 2021

A Deep Understanding Of Structural And Functional Behavior Of Tabular And Graphical Modules In Technical Documents, Michail Alexiou

Browse all Theses and Dissertations

The rapid increase of published research papers in recent years has escalated the need for automated ways to process and understand them. The successful recognition of the information that is contained in technical documents, depends on the understanding of the document’s individual modalities. These modalities include tables, graphics, diagrams and etc. as defined in Bourbakis’ pioneering work. However, the depth of understanding is correlated to the efficiency of detection and recognition. In this work, a novel methodology is proposed for automatic processing of and understanding of tables and graphics images in technical document. Previous attempts on tables and graphics understanding …


Detecting Server-Side Web Applications With Unrestricted File Upload Vulnerabilities, Jin Huang Jan 2021

Detecting Server-Side Web Applications With Unrestricted File Upload Vulnerabilities, Jin Huang

Browse all Theses and Dissertations

Vulnerable web applications fundamentally undermine website security as they often expose critical infrastructures and sensitive information behind them to potential risks and threats. Web applications with unrestricted file upload vulnerabilities allow attackers to upload a file with malicious code, which can be later executed on the server by attackers to enable various attacks such as information exfiltration, spamming, phishing, and spreading malware. This dissertation presents our research in building two novel frameworks to detect server-side applications vulnerable to unrestricted file uploading attacks. We design the innovative model that holistically characterizes both data and control flows using a graphbased data structure. …


Fabricación De Morteros Reforzados Para Recubrimiento Con Fibras Extraídas Del Pseudotallo De La Planta De Plátano (Musa Paradisiaca) Mezclados Con Cenizas De Procesos Agroindustriales, Laura Natalia Galeano Sarmiento Jan 2021

Fabricación De Morteros Reforzados Para Recubrimiento Con Fibras Extraídas Del Pseudotallo De La Planta De Plátano (Musa Paradisiaca) Mezclados Con Cenizas De Procesos Agroindustriales, Laura Natalia Galeano Sarmiento

Ingeniería Civil

Debido a la alta demanda de materiales en la industria de la construcción, en este proyecto de investigación se planteó el uso de fibras vegetales como alternativa de materia prima para el reforzamiento de morteros. En este caso, se evaluó la viabilidad de añadir fibras extraídas del pseudotallo de la planta de plátano Musa Paradisiaca, y cenizas volantes. Se describieron diferentes aplicaciones de otros proyectos similares para el uso de reforzamientos con fibras vegetales en la construcción, además de referir el proceso de cultivo, extracción de la fibra y tratamiento.

Se fabricaron morteros fibroreforzados a los cuales se les realizaron …


Degradation Of Natural And Synthetic Fibers In Various Aqueous Environments, Jaylin Bryant Jan 2021

Degradation Of Natural And Synthetic Fibers In Various Aqueous Environments, Jaylin Bryant

Honors Scholars Collaborative Projects

Fabrics are one variant of polymers, macromolecules that form the foundation of our society. They consist of small subunits called monomers, which are covalently bonded together and layered over each other through intermolecular attractions. There are natural fabrics, such as cotton and silk, and synthetic fabrics like polyester and rayon. Scientists in forensic taphonomy study postmortem changes made to human remains, which can also include clothes found at the scene. In this study, the degradation rates of four white fabrics (cotton, polyester, rayon, and silk) were observed in various aqueous environments (pure, chlorinated, sea, and lake) in order to observe …


Perceptually Improved Medical Image Translations Using Conditional Generative Adversarial Networks, Anurag Vaidya Jan 2021

Perceptually Improved Medical Image Translations Using Conditional Generative Adversarial Networks, Anurag Vaidya

Honors Theses

Magnetic resonance imaging (MRI) can help visualize various brain regions. Typical MRI sequences consist of T1-weighted sequence (favorable for observing large brain structures), T2-weighted sequence (useful for pathology), and T2-FLAIR scan (useful for pathology with suppression of signal from water). While these different scans provide complementary information, acquiring them leads to acquisition times of ~1 hour and an average cost of $2,600, presenting significant barriers. To reduce these costs associated with brain MRIs, we present pTransGAN, a generative adversarial network capable of translating both healthy and unhealthy T1 scans into T2 scans. We show that the addition of non-adversarial …


Subsurface Architecture Of Alpine Icy Debris Fans: Integration Of Ground-Penetrating Radar And Surface Observations In Alaska And New Zealand, Robert W. Jacob, Jeffrey M. Trop, R. Craig Kochel Jan 2021

Subsurface Architecture Of Alpine Icy Debris Fans: Integration Of Ground-Penetrating Radar And Surface Observations In Alaska And New Zealand, Robert W. Jacob, Jeffrey M. Trop, R. Craig Kochel

Faculty Journal Articles

Icy debris fans (IDFs) are extremely dynamic supraglacial landforms at the mouths of bedrock catchments between valley glaciers and icecaps. Recent studies quantified the nature, pace, and volume of mass flow processes contributing ice and sediment to IDFs by integrating field observations, drone and time-lapse imagery, and terrestrial laser scanning. New geophysical data presented herein characterize the subsurface architecture of IDFs along the McCarthy Glacier in Alaska and the Douglas, La Perouse, and Mueller Glaciers in New Zealand. Ground Penetrating Radar (GPR) profiles and soundings from field surveys during 2013–2015 provide stratigraphic evidence of the following subsurface processes important in …


Scaling Up Exact Neural Network Compression By Relu Stability, Thiago Serra, Xin Yu, Abhinav Kumar, Srikumar Ramalingam Jan 2021

Scaling Up Exact Neural Network Compression By Relu Stability, Thiago Serra, Xin Yu, Abhinav Kumar, Srikumar Ramalingam

Faculty Conference Papers and Presentations

We can compress a rectifier network while exactly preserving its underlying functionality with respect to a given input domain if some of its neurons are stable. However, current approaches to determine the stability of neurons with Rectified Linear Unit (ReLU) activations require solving or finding a good approximation to multiple discrete optimization problems. In this work, we introduce an algorithm based on solving a single optimization problem to identify all stable neurons. Our approach is on median 183 times faster than the state-of-art method on CIFAR-10, which allows us to explore exact compression on deeper (5 x 100) and wider …


Direct Determination Of Absolute Stereochemistry Of Α-Methylselenocysteine Using The Mosher Method, Robert J. Wehrle, Douglas R. Powell, Douglas S. Masterson Jan 2021

Direct Determination Of Absolute Stereochemistry Of Α-Methylselenocysteine Using The Mosher Method, Robert J. Wehrle, Douglas R. Powell, Douglas S. Masterson

Faculty Publications

Mosher amides of α-methylselenocysteine were synthesized to determine the absolute stereochemistry of the sterically hindered α-carbon utilizing 1H, 13C, 19F, and 77Se NMR spectroscopies. After analysis of these spectra using the established Mosher method, the stereochemistry of the α-carbon was determined to be (R), which was subsequently confirmed using x-ray crystallography.