Physical Sciences and Mathematics Commons^™

Detection Of Bacteria Using Antimicrobial Polymer Derived Via Ring-Opening Metathesis (Romp) Pathway, N Ceren Süer, Tüli̇n Arasoğlu, Hüsnü Cankurtaran, Mustafa Okutan, Markus Gallei, Tarik Eren

Turkish Journal of Chemistry

There is growing interest in the detection of bacteria in consumables, for example, in the food and water sectors. In this study, the aim was to produce a polymer-based bacteria biosensor via ROMP (ring opening metathesis polymerization). In the first part of the study, block and random copolymers were synthesized, and their biocidal activities were tested on the glass surface. Interdigitated electrode arrays coated with the polymers possessing the highest activity were used to screen the affinity towards different bacterial strains by monitoring impedance variations in real-time. The polymer-coated electrode could detect gram-positive and gram-negative bacteria strains at a concentration …

Impact Of Graphitic Carbon Nitrides Synthesized From Different Precursors On Schottky Junction Characteristics, Orhan Altan

Turkish Journal of Chemistry

Graphitic carbon nitride (g-CN) has gained wide interest in many areas, such as energy and the environmental remediation as a layered polymeric semiconductor that allows the formation of catalytically active Schottky junctions due to its proper electronic band structure. Interestingly, although it is known that the precursors used in the synthesis, can influence the properties of the g-CN, no detailed study on these effects on Schottky junctions could be found in the literature. In this research, the effects of g-CNs synthesized by thermal polycondensation of different precursors on the photocatalytic efficiency of Schottky junctions were investigated. For this purpose, urea, …

Adsorptive Performance Of Mwcnts For Simultaneous Cationic And Anionic Dyes Removal; Kinetics, Thermodynamics, And Isotherm Study, Zaheer Aslam, Irfan Yousaf, Abdul Zahir, Adnan Akhtar

Turkish Journal of Chemistry

Disposal of contaminated wastewater causes many serious problems especially when it gets mixed with the ground and seawater. It is, therefore, important to apply any remedial action to eradicate dangerous pollutants from the aqueous effluents and to avoid exposure of this wastewater to aquatic life. The research results discussed herein deal with the removal of Rhodamine B (RhB) and Congo Red (CR) dye from wastewater by using multi-walled carbon nanotubes (MWCNTs) as an adsorbent. Different factors like solid dosage, initial pH and concentration, time, and temperature were studied to understand the behavior and mechanism of adsorption. The maximum adsorption capacity …

Structural And Adsorption Behaviour Of Zno/Aminated Swcnt-Cooh For Malachite Green Removal: Face-Centred Central Composite Design, Zeynep Ci̇ğeroğlu

Turkish Journal of Chemistry

In this study, an effective adsorbent was synthesized to remove malachite green (MG), which is one of the toxic dyes. Firstly, single walled carbon nanotube with carboxylated acid (SWCNT-COOH) was functionalized with diethylenetriamine and a new nanocomposite was obtained using nano zinc oxide (ZnO) powder. The effects of pH (3-7), the amount of adsorbent (5-15 mg) and the initial concentration (10-50 mg L-1) of the solution on the adsorption uptake were investigated. The optimal parameters that maximize the adsorption uptake according to the specified working range are found to be 4.63 for pH, 49.94 mg L-1 for initial concentration, 5.25 …

Laccase Bound To Cryogel Functionalized With Phenylalanine For The Decolorization Oftextile Dyes, Işik Perçi̇n Demi̇rçeli̇k, Yusuf Doruk Aracagök, Nesli̇han İdi̇l, Adi̇l Deni̇zli̇, Bo Mattiasson

Turkish Journal of Chemistry

In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures, respectively. The effect of dye concentration on dye decolorization and 100% …

Optimization For Esterification Of Saturated Palm Fatty Acid Distillate By D-Optimal Design Response Surface Methodology For Biolubricant Production, Majd Jumaah, Nadia Salih, Jumat Salimon

Turkish Journal of Chemistry

This work presents a synthesis of palm fatty acid distillate (PFAD)-based esters to produce biolubricant oils through the esterification reaction between saturated palm fatty acid distillate (SFA-PFAD) with different types of high degree polyhydric alcohols such as trimethylolpropane (TMP), di-trimethylolpropane (Di-TMP), pentaerythritol (PE), and di-pentaerythritol (Di-PE) in the presence of sulfuric acid as catalyst. The chemical structures of synthesized SFA PFAD-based esters were characterized and confirmed by using FTIR, NMR (1H and 13C) spectroscopies and GC-FID chromatography. The FTIR spectra of SFA PFAD-based ester products clearly showed the peaks of C=O and C-O of ester group at 1732-1740 cm-1 and …

New Iodine-Apatites: Synthesis And Crystal Structure, Evgeny Bulanov, Sergey Petrov, Alexander Knyazev

Turkish Journal of Chemistry

The paper describes methods for the preparation of compounds with an apatite structure containing only iodine atoms in the "halogen" position. The crystal structure of the compounds was refined by the Rietveld method. The resulting apatites have a structure with a space group P63/m and have the following unit cell parameters: Ba4f 1.78(2) Ba6h 2.75(2)(PO4)3I0.04(2) (a = 10.18609(34) Å, c = 7.71113(30) Å, V = 692.889(54) Å3, R = 5.448%), Pb4f 1.82(2)Pb6h 2.75(2)(PO4)3I0.13(2) (a = 9.87882(18) Å, c = 7.43222(16) Å, V = 628.144(26) Å3, R = 8.533 %), Pb4f 1.90(2)Pb6h 2.68(2)(PO4)3I0.16(2) a = 9.87058(48) Å, c = 7.41255(46) Å, …

Investigation Of Pzt-5h And Pzt-8 Type Piezoelectric Effect On Cycling Stability On Si-Mwcnt Containing Anode Materials, Mehbare Doğrusöz, Muhammed Taha Demi̇rkan, Rezan Demi̇r Çakan

Turkish Journal of Chemistry

Silicon (Si) containing materials cannot be used in commercial lithium ion batteries due to the mechanical stress problem triggered by volume expansion during cycling. The high-volume change causes mechanical instability of Si anode materials during charging/discharging, resulting fast capacity fading. It is thought that piezoelectric materials can be a solution for the volume expansion problem because of their ability to generate electric field when pressure is applied on them. For this purpose, PZT-8 and PZT-5H type piezoelectric materials were mixed with silicon and multiwalled carbon nanotube (MWCNT) to obtain anode composites and tested electrochemically versus lithium metal. The piezoelectiric effect …

Effect Of Current Density On The Microstructure And Morphology Of The Electrodepositednickel Coatings, Amel Boukhouiete, Saliha Boumendjel, Nour-El-Houda Sobhi

Turkish Journal of Chemistry

The aim of this research work was to study the effect of deposition current density on microstructure and surface morphology of electrodeposited nickel coatings. For this purpose, nickel deposits have been synthesized by direct current from Watts bath without additive, to limit the incorporation of pollutants resulting from surface adsorption or electro-activity of these compounds. Nickel deposits have been investigated by scanning electron microscopy and X-ray diffraction. Cyclic voltammetry was also used to gain information on the general behavior of the deposition. The optimum conditions of deposition were established and the influence of current density on the grain size, surface …

Glucosamine Derived Hydrothermal Carbon Electrodes For Aqueous Electrolyte Energy Storage Systems, Burcu Ünal, Rezan Demi̇r Çakan

Turkish Journal of Chemistry

Nitrogen-doped porous hard carbons are synthesized by hydrothermal carbonization method (HTC) using glucosamine as biosource and treated at different carbonization temperatures in nitrogen environment (500, 750, 1000 °C). The electrochemical performances of hard carbons electrode materials for aqueous electrolyte sodium ion batteries are examined to observe the effect of two different voltage ranges (-0.8-0.0) V and (0.0-0.8) V in 1.0 M Na2SO4 aqueous electrolyte. The best electrochemical performances are acquired for the 1000 °C treated glucosamine (GA-1000) porous carbon sample that provides ~96 F/g capacitance value in the negative voltage range (between -0.8 and 0.0) V. The sodium diffusion coefficient …

Antiinflammatory Photodynamic Therapy Potential Of Polyoxyethylene-Substituted Perylene Diimide, Nitrocatechol, And Azo Dye, Özgül Hakli, Kasim Ocakoğlu, Furkan Ayaz

Turkish Journal of Chemistry

Photodynamic therapy (PDT) applications enable light-controlled activation of drug candidates instead of their constitutive activities to prevent undesired side effects associated with their constant activities. A specific wavelength of light is utilized to enable electron mobility in the chemical structure, which results in differential activities that may alter cell viability and cellular functions. Canonical photodynamic therapy applications mostly focus on cytotoxicity-based antimicrobial and anticancer properties of the PDT agents. In this study, we focused on subtoxic concentrations of three different molecules containing polyoxyethylene group and examined their antiinflammatory activities on stimulated mammalian macrophages. Stimulated macrophages produce proinflammatory cytokines TNF and …

Investigation Of Electrochemical Behavior Of Potassium Ferricyanide/Ferrocyanide Redox Probes On Screen Printed Carbon Electrode Through Cyclic Voltammetry And Electrochemical Impedance Spectroscopy, Yücel Koç, Uğur Morali, Sali̇m Erol, Hüseyi̇n Avci

Turkish Journal of Chemistry

Potassium ferricyanide, potassium ferrocyanide, and their combination system are widely used redox probes for electrochemical impedance spectroscopy (EIS) characterization. In this work, electrochemical behavior of K3Fe(CN)6, K4Fe(CN) 6, and K3Fe(CN)6/K4Fe(CN)6 redox probes at five different concentrations using a screen printed carbon electrode (SPCE) by cyclic voltammetry (CV) and EIS methods was analyzed. Redox potentials were observed as a result of anodic and cathodic peak with CV analysis with determination 10 mM appropriate concentration through 0.01 mM, 0.1 mM, 1 mM, and 100 mM. In addition, with EIS analysis, each redox probe was simulated according to two different Randles circuit models …

A Facile Approach For The Synthesis Of Porous Hematite And Magnetite Nanoparticles Through Sol-Gel Self-Combustion, Imene Gritli, Afrah Bardaoui, Jamila Ben Naceur, Salah Ammar, Mohammad Abu Haija, Sherif Mohamed Abdel Salam Keshk, Radhouane Chtourou

Turkish Journal of Chemistry

Porous magnetite (Fe3O4) and hematite (α-Fe2O3) nanoparticles were prepared via the sol-gel auto-combustion method. The gels were prepared by reacting ferric nitrates (as oxidants) with starch (as fuel) at an elevated temperature of 200 °C. Different ratios (Φ) of ferric nitrates to starch were used for the synthesis (Φ = fuel/oxidant). The synthesized iron oxides were characterized by Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmet-Teller (BET) and vibrating sample magnetometer (VSM) analysis techniques. The crystal structure, morphology, and specific surface area of the iron oxide nanoparticles (Fe3O4 …

Volatile Constituents Of Three Thymus Sipyleus Boiss. Subspecies From Different Sites In Turkey, Hale Gamze Ağalar, Mi̇ne Kürkçüoğlu, Kemal Hüsnü Can Başer, Kenan Turgut

Turkish Journal of Chemistry

This study was designed to reveal the chemical diversity of some Thymus sipyleus subspecies growing wild in Turkey and to compare the volatile compound profiles by using micro(hydro)distillation technique. For this purpose, volatile compounds isolated by microdistillation from nine samples (three plant samples collected from different regions in Antalya) of Thymus sipyleus Boiss. subsp. sipyleus var. sipyleus, T. sipyleus Boiss. subsp. sipyleus var. davisianus Ronniger, and T. sipyleus Boiss. subsp. rosulans (Borbas) Jalas were analyzed by GC and GC-MS systems. 1,8-Cineole, p-cymene, α-terpineol and carvacrol were identified as major compounds in T. sipyleus subsp. sipyleus var. sipyleus samples. Geranial, neral, …

A Four-Component Modified Biginelli Reaction: A Novel Approach For C-2 Functionalizeddihydropyrimidines, Harsha Narkhede, Avinash Dhake, Vaidhyanathan Balasubramaniyan

Turkish Journal of Chemistry

A novel four component modified Biginelli reaction for the synthesis of C-2 functionalized dihydropyrimidines has been established. The approach uses assembly of less explored acetyl acetone with aromatic aldehyde, thiourea, and dimethyl sulphate to construct a novel 5-acetyl 2-methylthio dihydropyrimidine system, which works as an efficient well-designed intermediate for generating C-2 modified Biginelli libraries with nitrogen nucleophiles. Phenyl hydrazine, semicarbazide, and aryl semicarbazides are successfully used as N-nucleophiles to generate C-2 functionalized dihydropyrimidine derivatives, which fulfil the demands of active pharmacophore. Time economy, step economy, and a single pot reaction with moderate to excellent yield are the major advantages of …

Lack Of Plasticity In Gopher Tortoise (Gopherus Polyphemus) Nesting Behavior And Fecundity In A Translocated Population, Jennifer N. Desha

Electronic Theses and Dissertations

Lack of Plasticity in Gopher Tortoise (Gopherus polyphemus) Nesting Behavior and Fecundity in a Translocated Population

Analysis Of The Role Of Sgs1p In Repair Of Double-Strand Dna Breaks In Saccharomyces Cerevisiae, Beth Wasserman

Senior Honors Theses and Projects

Mis-repair of DNA double-stranded breaks (DSB) can result in genomic rearrangements and cancer. Sgs1p is a helicase that unwinds DNA for DSB repair. To better understand its role in break repair, I analyzed the frequency of various types of DSB repairs in yeast cells with the mutation sgs1-FD. Given this mutation disrupts an interaction between Sgs1p and a critical protein, Rad51p, I hypothesized mutant cells would have more error-prone repair than high fidelity canonical BIR repair. Genome sequence and chromosome size were examined in sgs1-FD yeast cells that underwent DSB repair. No difference was found in the frequency of …

Building A Secure Web Application For Gamified Technical Labs, Kevin Higman

Senior Honors Theses and Projects

In order to improve upon existing online lab platforms, in an attempt to increase student motivation, gamification has been used to create a new gamified web application. Departmental research has shown gamification to provide significant improvement to student’s self-efficacy and motivation. Neuralabs, a web application created by two Eastern Michigan Honors Students, uses techniques often found in popular video games in order to create a more appealing learning experience. Building a public web application designed towards Cybersecurity students creates many technical security challenges. Neuralabs goal is to create a secure competitive learning experience where students can create and take labs …

Ligand Effects On Electronic, Magnetic, And Catalytic Properties Of Clusters And Cluster Assemblies, Dinesh Bista 9288522

Theses and Dissertations

Ligands commonly protect metallic clusters against reacting with outside reactants. However, ligands can also be used to control the redox properties enabling the formation of super donors/acceptors that can donate/accept multiple electrons. This thesis focuses on how the ligands can be used to control the electronic and magnetic features of clusters and ligand stabilized cluster-based assemblies, leading to nano pn junctions with directed transport, the possibility of light-harvesting, and catalysts for cross-coupling reactions. The thesis addresses three distinct classes of clusters and their applications. The first class of cluster “metal chalcogen clusters” is the central idea of the thesis focused …

Surficial Geology Of The Continental Shelf Off New Hampshire: Morphologic Features And Surficial Sediment, Larry G. Ward, Zachary S. Mcavoy, Maxlimer Coromoto Vallee-Anziani, Rachel C. Morrison

Center for Coastal and Ocean Mapping

The continental shelf off New Hampshire (NH) in the Western Gulf of Maine (WGOM) is extremely complex and includes extensive bedrock outcrops, marine-modified glacial deposits, marine-formed shoals, seafloor plains, and associated features that are composed of a range of sediment types from mud to gravel. Furthermore, the physiography and composition of the seafloor frequently changes dramatically over relatively short distances (tens of meters). The complexity of the WGOM seafloor results from the interplay of glaciations, sea-level fluctuations, and marine processes (waves and currents). High-resolution multibeam echosounder (MBES) bathymetry and backscatter surveys, along with ground truth consisting of archived seismic reflection …

Seasonal Changes In Sediment Grain Size Of New Hampshire Atlantic Beaches, Larry G. Ward, Nathan W. Corcoran, Zachary S. Mcavoy, Rachel C. Morrison

Center for Coastal and Ocean Mapping

The beaches along the New Hampshire Atlantic coast are essential to the local and regional economy and are one of the major attractions of the seacoast. Beyond their economic importance, the beaches also have great aesthetic and ecological value that are vital to the character and history of New Hampshire. Unfortunately, climate change and an acceleration in sea-level rise, coupled with a major reduction in sediment supply and extensive development (including engineering structures along the coast), has led to loss of elevation and narrowing of many of the beaches. The forecast is that these trends will continue and likely become …

Northeast Bathymetry And Backscatter Compilation: Western Gulf Of Maine, Southern New England, And Long Island Sound, Larry G. Ward, Paul Johnson, Michael Bogonko, Zachary S. Mcavoy, Rachel C. Morrison

Center for Coastal and Ocean Mapping

High-resolution bathymetry is critical for mapping the surficial geology of the seafloor, identifying critical habitats, and assessing marine mineral resources such as sand and gravel. In 2016, a high-resolution bathymetry map was developed for the western Gulf of Maine (WGOM) utilizing all available multibeam echosounder (MBES) surveys, as well as several older extant surveys (Western Gulf of Maine Bathymetry and Backscatter Synthesis, Ward et al., 2016). As part of that effort, a backscatter mosaic also was developed for a subset of the MBES surveys. The backscatter synthesis did not include all of the MBES surveys due to low quality of …

Analysis Of Vibracores From The New Hampshire Continental Shelf From 1984 And 1988, Larry G. Ward, Rachel C. Morrison, Zachary S. Mcavoy, Maxlimer Coromoto Vallee-Anziani

Center for Coastal and Ocean Mapping

During this study, the twenty-three vibracores taken in 1984 and 1988 were reexamined, original descriptions verified and significantly expanded, and the cores sampled to provide complete grain size data (i.e. the original sediment grain size analyses were limited). The vibracores were grouped by location with respect to major physiographic features (geoforms) or surficial sediment type including Offshore Marine-Modified Glacial Features (Drumlins and Lodgement Till Deposits), Northern Sand Body, Isles of Shoals, Nearshore Marine-Modified Glacial Features (Eskers and Drumlins), Nearshore Sheet Sand, and Offshore Seafloor Plain.

The Northern Sand Body (NSB), located near the Isles of Shoals ~10 km from shore, …

New Hampshire And Vicinity Continental Shelf: Sand And Gravel Resources, Larry G. Ward, Zachary S. Mcavoy, Maxlimer Coromoto Vallee-Anziani

Center for Coastal and Ocean Mapping

The continental shelf off New Hampshire (NH) has extensive marine-modified glacial deposits and associated shoals. These features are potential targets for sand and gravel resources for beach nourishment and other efforts to build coastal resiliency. The distribution of sand and gravel deposits was evaluated based on the synthesis of relatively recent high-resolution bathymetry, new surficial sediment and geoform maps, and an extensive data archive that includes over ~1280 km of seismic profiles, ~750 grain size analyses, and 23 vibracores. This work heavily utilizes the results of previous research on mineral resources on the NH shelf by Birch (1984) …

Erosion And Accretion Trends Of New Hampshire Beaches From December 2016 To March 2020: Results Of The Volunteer Beach Profile Monitoring Program, Larry G. Ward, Rachel C. Morrison, Alyson L. Eberhardt, Wellsley J. Costello, Zachary S. Mcavoy, Caitlin P. Mandeville

Center for Coastal and Ocean Mapping

New Hampshire Atlantic beaches were monitored from December 2016 to March 2020 to determine seasonal changes in morphology and elevation, assess the response of the beaches to storms with respect to erosion and subsequent recovery, and develop a baseline to determine long-term trends in beach size, elevation, and position. A unique aspect of this study was the involvement of community volunteers working together with the University of New Hampshire (UNH) Center for Coastal and Ocean Mapping, UNH Cooperative Extension, New Hampshire Sea Grant, and the New Hampshire Geological Survey. The monitoring network consisted of thirteen stations located at six of …

Weight Distributions, Automorphisms, And Isometries Of Cyclic Orbit Codes, Hunter Lehmann

Theses and Dissertations--Mathematics

Cyclic orbit codes are subspace codes generated by the action of the Singer subgroup Fqn* on an Fq-subspace U of Fqn. The weight distribution of a code is the vector whose ith entry is the number of codewords with distance i to a fixed reference space in the code. My dissertation investigates the structure of the weight distribution for cyclic orbit codes. We show that for full-length orbit codes with maximal possible distance the weight distribution depends only on q,n and the dimension of U. For full-length orbit codes with …

The Implementation Of A Novel Graphical Python Editor (Stremecoder) In A Rodent Discrimination Apparatus, Supraja Kalva

Senior Honors Theses and Projects

As the interest in neuroscience and the desire to perform behavioral tasks in a higher level of specificity and accuracy increases, the need to have tools and techniques to conduct experimentations in a low-cost automated manner is essential. Although such methods have been proposed previously by other researchers, they have presented their data and tools in a manner that would have been difficult to comprehend for non-programmers. In labs that do not have the accessibility to individuals who can understand the published procedures, it is very difficult for them to get started and manipulate the published procedures to their interests. …

Moving Past ‘One Size Fits All’: Developing A Trajectory Deviance Index For Dynamic Measurement Modeling, Yixiao Dong

Electronic Theses and Dissertations

Dynamic Measurement Modeling (DMM) is a recently developed measurement framework for gauging developing constructs (e.g., learning capacity) that conventional single-timepoint tests cannot assess. Like most measurement models, overall model fit indices of DMM do not indicate the measurement appropriateness for each included student. For this reason, other measurement modeling paradigms (e.g., Item-Response Theory; IRT) utilize person-fit or model appropriateness statistics to indicate whether a measurement model appropriately describes the data from each individual student. However, within the extant DMM framework, no statistical index has yet been developed for this purpose. Thus, the current project advanced a person-specific DMM Trajectory Deviance …

Evaluation Of The Effect Of The Clinical-Decision-Support Systems On Diabetes Management: A Multivariate Meta-Analysis Comparison With Univariate Meta-Analysis, Abdelfattah Elbarsha

Electronic Theses and Dissertations

The advantage of using meta-analysis lies in its ability in providing a quantitative summary of the findings from multiple studies. The aim of this dissertation was first to conduct a simulation study in order to understand what factors (sample size, between-study correlation, and percent of missing data) have a significant effect on meta-analysis estimates and whether using univariate or multivariate meta-analysis would produce different estimates.

The second goal of this study was to evaluate the effect of clinical decision support systems CDSS on diabetes care management by conducting three separate univariate meta-analyses and one multivariate meta-analysis. CDSS are health information …

Zn Orbifolds Of Vertex Operator Algebras, Daniel Graybill

Electronic Theses and Dissertations

Given a vertex algebra V and a group of automorphisms of V, the invariant subalgebra V^G is called an orbifold of V. This construction appeared first in physics and was also fundamental to the construction of the Moonshine module in the work of Borcherds. It is expected that nice properties of V such as C2-cofiniteness and rationality will be inherited by V^G if G is a finite group. It is also expected that under reasonable hypotheses, if V is strongly finitely generated and G is reductive, V^G will also be strongly finitely generated. This is an analogue …