Physical Sciences and Mathematics Commons^™

In Situ Study Of Geological Fluid Inclusions Using 23na Nuclear Magnetic Resonance Spectroscopy, Stephen Pilar

Electronic Thesis and Dissertation Repository

²³Na Magic Angle Spinning Solid State Nuclear Magnetic Resonance (MAS SS NMR) spectroscopy has been used to study natural geological samples of halite, fluorite, and quartz to evaluate the efficacy of NMR spectroscopy for in situ fluid inclusion analysis. NaCl calibration standards yielded a strong linear correlation (R²=0.9919) for salinity, albeit only over a ~1 ppm breadth of chemical shift. Fluid inclusions were successfully identified in all three types of minerals studied using MAS NMR. Chemical analysis with Inductively Coupled Plasma -- Mass Spectrometry (ICP-MS) was employed to quantify elemental contaminants in halite samples. Powder X-Ray Diffraction …

Ready, Willing, And Able, Gerry Boyle

Colby Magazine

So what gives? How, after four years on Mayflower Hill, do these Colby alumni have an outsized impact in a fintech company that is focused on, for example, changing the way municipal bonds are traded? What makes them able to dive in and figure it out? “That’s part of the liberal arts education,” said Associate Professor of History John Turner, who taught Tagg Martin ’13, history major turned MarketAxess go-to analyst. “You’re always learning. … You are always going to be mastering something, as opposed to having mastered.”

Ow-Detr: Open-World Detection Transformer, Akshita Gupta, Sanath Narayan, K.J. Joseph, Salman Khan, Fahad Shahbaz Khan, Mubarak Shah

Computer Vision Faculty Publications

Open-world object detection (OWOD) is a challenging computer vision problem, where the task is to detect a known set of object categories while simultaneously identifying unknown objects. Additionally, the model must incrementally learn new classes that become known in the next training episodes. Distinct from standard object detection, the OWOD setting poses significant challenges for generating quality candidate proposals on potentially unknown objects, separating the unknown objects from the background and detecting diverse unknown objects. Here, we introduce a novel end-to-end transformer-based framework, OW-DETR, for open-world object detection. The proposed OW-DETR comprises three dedicated components namely, attention-driven pseudo-labeling, novelty classification …

Rhizobium Symbiotic Capacity Shapes Root-Associated Microbiomes In Soybean, Yuanhui Lu, Bin Ma, Wenfeng Chen, Klaus Schlaeppi, Matthias Erb, Erinne Stirling, Lingfei Hu, Entao Wang, Yunzeng Zhang, Kankan Zhao, Zhijiang Lu, Shudi Ye, Jianming Xu

Environmental Science and Geology Faculty Research Publications

Root-microbiome interactions are of central importance for plant performance and yield. A distinctive feature of legumes is that they engage in symbiosis with N₂-fixing rhizobia. If and how the rhizobial symbiotic capacity modulates root-associated microbiomes are still not yet well understood. We determined root-associated microbiomes of soybean inoculated with wild type (WT) or a noeI mutant of Bradyrhizobium diazoefficiens USDA 110 by amplicon sequencing. UPLC-MS/MS was used to analyze root exudates. The noeI gene is responsible for fucose-methylation of Nod factor secreted by USDA 110 WT strain. Soybean roots inoculated with the noeI mutant showed a significant decrease …

Single-Variable Porous Nanomaterial Series From Polymer Structure-Directing Agents, Morgan Stefik

Faculty Publications

Block polymer structure-directing agents (SDA) enable the production of porous nanoscale materials. Most strategies rely upon polymer equilibration where diverse morphologies are realized in porous functional materials. This review details how solvent selectivity determines the polymer SDA behaviors, spanning from bulk-type to solution-type. Equilibrating behavior of either type, however, obscures nanostructure cause-and-effect since the resulting sample series convolve multiple spatial variations. Solution-type SDA behaviors include both dynamic and persistent micelles. Persistent micelle templates (PMT) use high solvent selectivity for kinetic entrapment. PMTs enable independent wall thickness control with demonstrated 2 Å precision alterations. Unimodal PMT pore size distributions have spanned …

Chemical And Physical Weathering Rates Of Basaltic Volcanic Regions: Utilizing Space In Place Of Time In The Hawaiian Archipelago, Benjamin Clyde Barton

Theses and Dissertations

With large populations living in tropical regions of the world with volcanic substrates, understanding basalt weathering processes is vital. The Hawaiian Islands are an excellent natural analogue to study chemical weathering rates due to a uniform bedrock (basalt), large variations in rainfall, and varying ages across the islands. Laterite weathering profiles (LWP) develop over time through chemical weathering, where LWP thickness is influenced by many factors, including precipitation and time. Using the rapid, non-invasive horizontal-to-vertical spectral ratio (HVSR) method, LWP thicknesses can be estimated to constrain chemical weathering rates. Studying the laterite weathering profiles developed from basaltic bedrock of varying …

How Community Participation In Water And Sanitation Interventions Impacts Human Health, Wash Infrastructure And Service Longevity In Low-Income And Middle-Income Countries: A Realist Review, Sarah Nelson, Dorothy Drabarek, Aaron Jenkins, Joel Negin, Seye Abimbola

Research outputs 2014 to 2021

Objective:

To understand how, and under what circumstances community participation in water and sanitation interventions impacts the availability of safe water and sanitation, a change in health status or behaviour and the longevity of water, sanitation and hygiene (WASH) resources and services.

Design:

Realist review.

Data sources:

PubMed, Web of Science and Scopus databases were used to identify papers from low-income and middle-income countries from 2010 to 2020.

Eligibility criteria for selecting studies:

Criteria were developed for papers to be included. The contribution of each paper was assessed based on its relevance and rigour (eg, can it contribute to context, …

2021 Fall Engr333 Poster, Section B, Calvin University 2021 Engr Section B

ENGR 333

In 2020, residences used 21% of all final energy in the United States and were responsible for 20% of all U.S. carbon dioxide emissions (henceforth referred to as carbon emissions). Habitat for Humanity for Kent County is endeavoring to design homes that reduce energy consumption, energy expenditures, and carbon emissions. They have established a goal of a “low carbon footprint build” that will minimize energy consumption and carbon emissions, both during construction and across the lifetime of the house. To accomplish this goal, Habitat for Humanity for Kent County partnered with Calvin’s ENGR 333 – Thermal System Design and asked …

2021 Fall Engr333 Poster, Section A, Gerald Darkey, Jonathan Jansma, Chris Singh, Ryan Whitney, Adam Brunsting, Adam Tjoelker, Jack Van Der Molen, Cornelius Van Liere, Derrick Bittner, William Terpstra, Matthew Winkle, Kelsey Yen, Kasen Anderson, Jack Cahalane, Samantha Krupa, James Kulaga, Chukwudubem Nweke, Nathan Holwerda, Jacob Meulink, John Stehouwer, Isaac Spackman, Moses Yang

ENGR 333

Habitat for Humanity (HFH) built a low-carbon home at 726 London Street SW. Mark Ogland-hand, a representative of HFH, connected with Professor Matthew Heun to begin a carbon study of this new home with the goals of understanding the carbon footprints of a traditional HFH home, the London home, and future improvements feasible for HFH to make in reducing the carbon emissions of their houses.

An Analysis Of Comparison-Based Sorting Algorithms, Jacob M. Gomez, Edgar Aponte, Brad Isaacson

Publications and Research

Our names are Edgar Aponte and Jacob Gomez and we are Applied Mathematics students at City Tech. Our mentor is Prof. Isaacson and we conducted an analysis of comparison-based sorting algorithms, meaning that they can sort items of any type for which a “less-than” relation is defined. We implemented 24 comparison-based sorting algorithms and elaborated on 6 for our poster. We analyzed the running times of these sorting algorithms with various sets of unsorted data and found that introspective sort and timsort were the fastest and most efficient, with introspective sort being the very fastest.

Analyze And Examine Wildfire Events In California, Aleena Hoodith, Sakim Zaman, Safoan Hossain, Jiehao Huang

Publications and Research

•A wildfire is an unplanned, unwanted, uncontrolled fire in an area of combustible vegetation starting in rural areas and urban areas. •Recent studies have shown that the effect of anthropogenic climate change has fueled the wildfire events, leading to an increase in the annual burned areas and number of events. •California is one of the places having the most deadliest and destructive wildfire seasons. With the global warming effect of 1°C since 1850, the 20 largest wildfires events that have occurred in California, 8 of them were in 2017. (Center For Climate And Energy Solutions) •Climate change is primarily caused …

Evidence For Surface Effects On The Intermolecular Interactions In Fe (Ii) Spin Crossover Coordination Polymers, Thilini K. Ekanayaka, Hannah Kurz, Kayleigh A. Mcelveen, Guanhua Hao, Esha Mishra, Alpha T. N’Diaye, Rebecca Lai, Birgit Weber, Peter A. Dowben

Department of Physics and Astronomy: Faculty Publications

From X-ray absorption spectroscopy (XAS) and X-ray photoemission spectroscopy (XPS) it is evident that the spin state transition behavior of Fe(II) spin crossover coordination polymer crystallites at the surface differs from the bulk. A comparison of four different coordination polymers reveals that the observed surface properties may differ from bulk for a variety of reasons. There are Fe(II) spin crossover coordination polymers with either almost complete switching of the spin state at the surface or no switching at all. Oxidation, differences in surface packing, and changes in coordination could all contribute to making the surface very different from the bulk. …

Semantically Meaningful Sentence Embeddings, Rojina Deuja

Department of Computer Science and Engineering: Dissertations, Theses, and Student Research

Text embedding is an approach used in Natural Language Processing (NLP) to represent words, phrases, sentences, and documents. It is the process of obtaining numeric representations of text to feed into machine learning models as vectors (arrays of numbers). One of the biggest challenges in text embedding is representing longer text segments like sentences. These representations should capture the meaning of the segment and the semantic relationship between its constituents. Such representations are known as semantically meaningful embeddings. In this thesis, we seek to improve upon the quality of sentence embeddings that capture semantic information.

The current state-of-the-art models are …

Butte-Silver Bow Medical Monitoring Program Plan, Mike Mcanulty, Eric Hassler

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Measurement Of Speed Of Sound Using Smartphones, Omotolani Adelekan

Publications and Research

The goal of this experiment is to determine the speed of sound in air. To measure the speed of sound, I used two smartphones and an app called Phyphox This app uses the microphone of the smartphone to detect the time between two acoustic events The “acoustic stopwatch” tool on the app is used to measure the time between two sound signals These two signals are produced by hand clapping In this experiment, the speed of sound is determined using the time of flight method This method is based on measuring the time delay between the generation and the detection …

Fermentation And Cell Wall Degradation In Guineagrass And Italian Ryegrass Silages, Mitsuhiro Niimi, O. Kawamura

IGC Proceedings (1993-2023)

Guineagrass (Panicum maximum Jacq.) was ensiled at the room temperature and Italian ryegrass (Lolium multiflorum L.) was ensiled at the room temperature and at 30 under the laboratory conditions. As a result, the acetic acid silage was made from Guineagrass and the lactic acid silages were made from Italian ryegrass. The loss of cell wall components during ensiling was the most in hemicellulose followed by NDF, but those of cellulose and AD-lignin were slight. In the hemicellulosic monosaccharides, the loss of hexose (galactose and glucose) was relatively high and that of pentose (arabinose and xylose) was relatively low …

Evaluation Of Forage Sorghum Silages With The Addition Of Sorghum Grain, M. De León, E. Ustarroz, M. A. Brunetti, C. Boetto, M. Bulaschevich

IGC Proceedings (1993-2023)

The aim of this experiment was to evaluate the effect of additional sorghum grain and stage of maturity of forage sorghum silage on the animal performance. Two feeding trials were conducted with forage sorghum silage made at different stage of plant maturity. In trial 1, early silage was made with the crop harvested in early bloom stage. Four diets based on different ratios of silage: sorghum grain were evaluated: 100% silage (ES); 80% silage: 20% dry grain (ES20D); 60% silage: 40% dry grain (ES40D) and 60% silage: 40% wet grain silage (ES40W). In trial 2, late silage was made with …

Influence Of Additive Aiv-2000 And Pre-Wilted Big Bale On Silage Quality, Animal Performance And Rumen Metabolism, Jonas Jatkauskas, V. Vrotniakienė

IGC Proceedings (1993-2023)

Silage treatment with AIV-2000 or making of silage big bales resulted in a higher level of lactic acid and organic matter digestibilities and reduced concentrations of butyric acid and ammonia-N. Feeding AIV-2000 treated and big bale silages increased weight gains of young fattening bulls by, respectively, 5.44 and 6.77% in comparison with the ordinary made silage. AIV-2000 treated and big bale silages affected microflora activity in the rumen. Infusoria count was higher by 13.5 and 30.34% (P < 0.05), VFA concentration increased by 0.39 and 8.45%, the pH value decreased by 0.05 and 0.1 unit, the content of total nitrogen was by 14.67 and 18.73 mg/100 ml, protein nitrogen by 14.12 and 16.63 mg/100 ml and non-protein nitrogen by 0.53 and 1.39 mg/100 ml higher, respectively for AIV-2000 and big bale groups in comparison with the control group.

Effects Of Different Additives On Silage Quality Of Napiergrass, Y. K. Cheng, C. S. Chen, P. W. Peng

IGC Proceedings (1993-2023)

Objectives of this experiment were to determine the effects of different additives on silage quality of napiergrass (Pennisetum purpureum). The cultivar of TLG2 with high water soluble carbohydrates was used to making silages added with or without 5 and 10% corn meal or wheat bran, and then treated with or without enzyme. Crude protein, acid detergent fiber, neutral detergent fiber, water soluble carbohydrates and volatile fatty acid contents of silage were determined to evaluate silage quality. From the results, it showed that var.TLG2 could be making good silages without any additives but the dry matter was low. Adding …

Quality And Nutritive Value Of Mott Dwarf Elephantgrass Silage With Biological Additives, T. Clavero

IGC Proceedings (1993-2023)

This experiment was conducted to study the effects of cellulase enzymes and lactic acid bacteria on the fermentation characteristics, chemical composition and nutritive value of Pennisetum purpureum cv Mott silage. Five kinds of preparation were tested: sugar molasses (control); sugar molasses and cellulase enzymes; cellulase enzymes; concentrate of lactic acid bacteria and sugar molasses and concentrate of lactic acid bacteria. Significant differences (P< 0.05) were found in fermentation quality and chemical composition of control silage as compared to the biological additives treated silage. Addition of cellulase enzymes and lactic acid bacteria resulted in decrease of pH value, cell wall content and increased lactic acid concentration. The biological additives increased silage intake and daily live weight by growing steers.

Metal Ligand Cooperative Complexes For Acceptorless Dehydrogenation Of Amines, Matthew D. Hoffman

Electronic Thesis and Dissertation Repository

Complexes of the type [M(Cp/Cp*)(MeCN)(P^R₂N^R′₂)]PF₆ (M = Fe, Ru) were synthesized and/or tested towards acceptorless dehydrogenation (AD) of amines. The primary amine benzylamine can undergo AD to form a mixture of products, and a selection of catalysts were employed in an attempt to control product selectivity. As a result, trends in product distribution were observed by modifying the primary and secondary coordination spheres on the catalyst. A new complex, [Fe(Cp)(MeCN)(P^Ph₂N^Ph₂)]PF₆ (3a) was synthesized and characterized and was found to be a completely selective dehydrogenation …

Synergistic Broad-Spectrum Antibacterial Activity Of Hypoxis Hemerocallidea-Derived Silver Nanoparticles And Streptomycin Against Respiratory Pathobionts, Oluwole S. Aremu, T. Qwebani-Ogunleye, Lebogang Katata-Seru, Zimbili Mkhize, John F. Trant

Chemistry and Biochemistry Publications

Respiratory tract infections arise due to the introduction of microbes into the airway, disrupting the normal, healthy, complex interdependent microbiome. The selective disruption of this community can be either beneficial or dangerous. Nanoparticles are a potential tool for modifying this population. Coated silver nanoparticles (AgNPs) were synthesized using ethanolic extracts of Hypoxis hemerocallidea (EEHH), a Southern African plant used extensively in traditional medicine and the source of many bioactive secondary metabolites. The room temperature reaction between silver nitrate and EEHH forms largely spherical AgNPs with an average diameter of 6–20 nm. These nanoparticles show similar levels of antibacterial activity as …

New Isolate From Salvinia Molesta With Antioxidant And Urease Inhibitory Activity, Nadra Naheed, Saima Maher, Farooq Saleem, Ajmal Khan, Abdul Wadood, Saima Rasheed, M. Iqbal Choudhary, Matheus Froeyen, Iskandar Abdullah, Muhammad Usman Mirza, John F. Trant, Sarfraz Ahmad

Chemistry and Biochemistry Publications

Urease plays a significant role in the pathogenesis of urolithiasis pyelonephritis, urinary catheter encrustation, hepatic coma, hepatic encephalopathy, and peptic acid duodenal ulcers. Salvinia molesta was explored to identify new bioactive compounds with particular emphasis on urease inhibitors. The aqueous methanol extract was fractionated using solvents of increasing polarity. A series of column chromatography and later HPLC were performed on butanol extract. The structures of the resulting pure compounds were resolved using NMR (1D and 2D), infrared, and mass spectroscopy. The novel isolate was evaluated for antioxidant activity (using DPPH, superoxide anion radical scavenging, oxidative burst, and Fe+2 chelation assays), …

Improving E-Commerce Product Recommendation Using Semantic Context And Sequential Historical Purchases, Mahreen Nasir, C. I. Ezeife, Abdulrauf Gidado

Computer Science Publications

Collaborative Filtering (CF)-based recommendation methods suffer from (i) sparsity (have low user–item interactions) and (ii) cold start (an item cannot be recommended if no ratings exist). Systems using clustering and pattern mining (frequent and sequential) with similarity measures between clicks and purchases for next-item recommendation cannot perform well when the matrix is sparse, due to rapid increase in number of items. Additionally, they suffer from: (i) lack of personalization: patterns are not targeted for a specific customer and (ii) lack of semantics among recommended items: they can only recommend items that exist as a result of a matching rule generated …

Impurity Production And Transport In The Prototype Material Plasma Exposure Experiment, Clyde J. Beers

Doctoral Dissertations

The Prototype Material Plasma Exposure eXperiment (Proto-MPEX) is a linear pulse plasma device at Oak Ridge National Laboratory with the purpose of doing the research and development for the heating concepts on the planned full MPEX device. The goal of MPEX is to perform material studies at fusion relevant conditions. To understand the conditions at the material target for performing plasma-material interaction studies the ion temperature and density, the electron temperature and density, and the particle flux and fluence must be known. Impurities within Proto-MPEX can alter the desired conditions at the material target and need to be understood for …

Electroweak Interactions And Fundamental Symmetries In Light Nuclei With Short-Range Effective Field Theories, Zichao Yang

Doctoral Dissertations

Effective field theories(EFTs) are powerful tools to study nuclear systems that display separation of scales. In this dissertation, we present halo EFT results for the $\beta$-delayed proton emission from $^{11}$Be, and pionless EFT results for three-nucleon systems. Halo nuclei are simply described by a tightly bound core and loosely bound valence nucleons. Using the halo EFT, we calculate the rate of the rare decay $^{11}$Be, which is a well-known halo nucleus, into $^{10}\text{Be} + p +e^- + \bar{\nu}_e$. We assume a shallow $1/2 ^+$ resonance in the $^{10}$Be$-p$ system with an energy consistent with a recent experiment by Ayyad {\it …

Auto-Curation Of Large Evolving Image Datasets, Sara Mousavicheshmehkaboodi

Doctoral Dissertations

Large image collections are becoming common in many fields and offer tantalizing opportunities to transform how research, work, and education are conducted if the information and associated insights could be extracted from them. However, major obstacles to this vision exist. First, image datasets with associated metadata contain errors and need to be cleaned and organized to be easily explored and utilized. Second, such collections typically lack the necessary context or may have missing attributes that need to be recovered. Third, such datasets are domain-specific and require human expert involvement to make the right interpretation of the image content. Fourth, the …

Total Internal Reflection: Applications In Nonlinear Microscopy And Fluorescence Anisotropy, Brandon Colon

Doctoral Dissertations

As technology advances to harness new energies and to create new cures, the sophistication of analysis grows not only in depth but in efficiency. Total internal reflection (TIR) has been coupled to microscopy leveraging its unique optical phenomenon on a breadth of topics. In this dissertation, the work presented will show how TIR was applied in two different instrumental analyses to evaluate two unique and complex systems. The first project features TIR paired with the transient absorption microscopy (TAM), a nonlinear optical technique, to gauge solvent mixing and diffusion in microreactors. Microreactors gained acclaim for their ability to produce high …

Instrument Development For High Sensitivity Size Characterization Of Lipid Vesicles And Other Biological Macromolecules Via Taylor Dispersion Analysis, Meagan Moser

Doctoral Dissertations

Just as humans communicate with other humans, the cells in our bodies communicate with each other through various, often complex, mechanisms. Cell-to-cell transmission of small molecules, lipids, proteins, peptides, or nucleic acids can be mediated by extracellular lipid vesicles called exosomes. Exosomes have been found to play a role in the delivery of regulatory molecules from one cell to another, serving as a universal communication mechanism. Currently, there is an emerging focus on characterizing exosome communication dynamics. Understanding exosome mechanisms of cell-to-cell communication requires accurate measurements of the spatiotemporal and chemical dynamics of exosome secretion. No current analytical approach offers …

Search For New Physics In Rare Higgs Boson Decays With The Cms Detector At The Large Hadron Collider, Himal Acharya

Doctoral Dissertations

A new boson with a mass of 125 GeV was discovered at the large hadron collider (LHC) in July 2012. The properties of this particle are so far consistent with the standard model (SM) expectation. Differences in the Higgs boson decay rates and predicted by the SM might indicate the presence of new particles and forces between them. Particularly, rare exclusive decays of the Higgs boson are a promising laboratory to study physics beyond the standard model. Searches for decays of the Higgs boson into a Z boson and a J/ψ meson or into pairs of J/ψ or Υ mesons …