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2023

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Articles 11941 - 11970 of 12571

Full-Text Articles in Physical Sciences and Mathematics

Vehicle-Based Disconnected Data Distribution, Aditya Singhania Jan 2023

Vehicle-Based Disconnected Data Distribution, Aditya Singhania

Master's Projects

The world today is highly connected and there is an immense dependency on this connectivity to accomplish basic everyday tasks. However much of the world lacks connectivity. Even in well-connected locations, natural disasters can cause infrastructure disruption. To combat these situations, Delay Tolerant Networks

(DTNs) employ to store and forward techniques along with intermittently connected transports to provide data connectivity. DTNs focus on intermittently connected networks however what if the regions are never connected? For example, Region A - is never connected to the internet, and Region B – has internet connectivity. Using a vehicle that travels between the two …


Ubiquitous Application Data Collection In A Disconnected Distributed System, Deepak Munagala Jan 2023

Ubiquitous Application Data Collection In A Disconnected Distributed System, Deepak Munagala

Master's Projects

Despite some incredible advancements in technology, a significant population of the world does not have internet connectivity. These people lack access to crucial information that is easily available to the rest of the world. To solve this problem, we implement a Delay Tolerant Network (DTN) that allows users in disconnected regions access to the internet. This is enabled by collecting all data requests on the users’ phones and passing them to a device that can carry them to a connected region. This device can then collect the necessary information and give it back to the users in the disconnected region. …


Codeval, Aditi Agrawal Jan 2023

Codeval, Aditi Agrawal

Master's Projects

Grading coding assignments call for a lot of work. There are numerous aspects of the code that need to be checked, such as compilation errors, runtime errors, the number of test cases passed or failed, and plagiarism. Automated grading tools for programming assignments can be used to help instructors and graders in evaluating the programming assignments quickly and easily. Creating the assignment on Canvas is again a time taking process and can be automated. We developed CodEval, which instantly grades the student assignment submitted on Canvas and provides feedback to the students. It also uploads, creates, and edits assignments, thereby …


Airport Assignment For Emergency Aircraft Using Reinforcement Learning, Saketh Kamatham Jan 2023

Airport Assignment For Emergency Aircraft Using Reinforcement Learning, Saketh Kamatham

Master's Projects

The volume of air traffic is increasing exponentially every day. The Air Traffic Control (ATC) at the airport has to handle aircraft runway assignments for landing and takeoff and airspace maintenance by directing passing aircraft through the airspace safely. If any aircraft is facing a technical issue or problem and is in a state of emergency, it requires expedited landing to respond to that emergency. The ATC gives this aircraft priority to landing and assistance. This process is very strenuous as the ATC has to deal with multiple aspects along with the emergency aircraft. It is the duty of the …


A Novel Efficient Deep Learning Framework For Facial Inpainting - Face Reconstruction From Masked Images, Akshay Ravi Jan 2023

A Novel Efficient Deep Learning Framework For Facial Inpainting - Face Reconstruction From Masked Images, Akshay Ravi

Master's Projects

The use of face masks due to the covid-19 pandemic has made surveillance of people very difficult. Since a mask covers most of the facial components, security cameras are rendered of little to no use in the identification of criminals. In order to realize what a face looks like behind a mask, we have to construct the facial features in the masked region. On a higher level, this falls under the field of image inpainting, i.e. filling missing regions of images or correcting irregularities in images. Current research on image inpainting shows promising results on images that have missing/incorrect patches …


Wikipedia Web Table Interpretation, Keyword-Based Search, And Ranking, Kartikee Dabir Jan 2023

Wikipedia Web Table Interpretation, Keyword-Based Search, And Ranking, Kartikee Dabir

Master's Projects

Information retrieval and data interpretation on the web, for the purpose of gaining knowledgeable insights, has been a widely researched topic from the onset of the world wide web or what is today popularly known as the internet. Web tables are structured tabular data present amidst unstructured, heterogenous data on the web. This makes web tables a rich source of information for a variety of tasks like data analysis, data interpretation, and information retrieval pertaining to extracting knowledge from information present on the web. Wikipedia tables which are a subset of web tables hold a huge amount of useful data, …


Untraining Gender Bias: An Eye-Tracking Study, Ripujit S. Bamrah Jan 2023

Untraining Gender Bias: An Eye-Tracking Study, Ripujit S. Bamrah

Master's Projects

In recent years, social cognitive theory has emphasized the role of cognitive processes in shaping perceptions and behavior related to gender bias. By examining the impact of targeted training interventions, this study seeks to better understand the influence of such processes on decision-making in the context of character selection. This human-computer interaction study explores the potential of intervention-based training to untraining gender bias in character selection. With an increasing need to address gender bias in various domains, understanding the impact of gender-based training becomes crucial. According to our hypothesis, exposure to masculine characters would boost people’s preference for female- intellectualized …


Driving Simulator : Driving Performance Under Distraction, Kaushik Pilligundla Jan 2023

Driving Simulator : Driving Performance Under Distraction, Kaushik Pilligundla

Master's Projects

This pilot study used a driving simulator experiment to look into how podcast consumption affects driving performance as a continuous distraction. Three volunteers conducted three trials in the study, each with a different driving scenario. Data analysis was done to compare two conditions. The first condition is the Audio, where volunteers listen to podcasts while driving. The second condition is no-audio condition.. The no-audi condition had nothing to play in the background. We used eye-tracking technology to gather gaze data. The study's findings using the post survey and eye fixation data indicate that listening to podcasts leads to continuous distraction …


Yelp Restaurant Popularity Score Calculator, Sneh Bindesh Chitalia Jan 2023

Yelp Restaurant Popularity Score Calculator, Sneh Bindesh Chitalia

Master's Projects

Yelp is a popular social media platform that has gained much traction over the last few years. The critical feature of Yelp is it has information about any small or large-scale business, as well as reviews received from customers. The reviews have both a 1 to 5 star rating, as well as text. For a particular business, any user can view the reviews, but the stars are what most users check because it is an easy and fast way to decide. Therefore, the star rating is a good metric to measure a particular business’s value. However, there are other attributes …


Malware Classification Using Api Call Information And Word Embeddings, Sahil Aggarwal Jan 2023

Malware Classification Using Api Call Information And Word Embeddings, Sahil Aggarwal

Master's Projects

Malware classification is the process of classifying malware into recognizable categories and is an integral part of implementing computer security. In recent times, machine learning has emerged as one of the most suitable techniques to perform this task. Models can be trained on various malware features such as opcodes, and API calls among many others to deduce information that would be helpful in the classification.

Word embeddings are a key part of natural language processing and can be seen as a representation of text wherein similar words will have closer representations. These embeddings can be used to discover a quantifiable …


Machine Learning-Based Anomaly Detection In Cloud Virtual Machine Resource Usage, Tarun Mourya Satveli Jan 2023

Machine Learning-Based Anomaly Detection In Cloud Virtual Machine Resource Usage, Tarun Mourya Satveli

Master's Projects

Anomaly detection is an important activity in cloud computing systems because it aids in the identification of odd behaviours or actions that may result in software glitch, security breaches, and performance difficulties. Detecting aberrant resource utilization trends in virtual machines is a typical application of anomaly detection in cloud computing (VMs). Currently, the most serious cyber threat is distributed denial-of-service attacks. The afflicted server's resources and internet traffic resources, such as bandwidth and buffer size, are slowed down by restricting the server's capacity to give resources to legitimate customers.

To recognize attacks and common occurrences, machine learning techniques such as …


Location And Environment Aware Mmwave Beam Selection Using Vision Transformer, Srajan Gupta Jan 2023

Location And Environment Aware Mmwave Beam Selection Using Vision Transformer, Srajan Gupta

Master's Projects

5G networks explore mmWave technology to achieve faster data transfer and higher network capacity. The reduced coverage area of mmWaves creates the need to deploy large antenna arrays. However, beam sweeping across a large number of antenna arrays typically involves high overhead and latency. In a vehicle-to- everything (V2X) system, beam selection becomes a frequent process in the case when vehicles are moving at high speed, leading to frequent connection delays. Modern-day vehicular systems are integrated with advanced sensors like global positioning system

(GPS), light detection and ranging (LIDAR), radio detection and ranging (RADAR), etc. Machine learning models can be …


Classification Of Darknet Traffic By Application Type, Shruti Sharma Jan 2023

Classification Of Darknet Traffic By Application Type, Shruti Sharma

Master's Projects

The darknet is frequently exploited for illegal purposes and activities, which makes darknet traffic detection an important security topic. Previous research has focused on various classification techniques for darknet traffic using machine learning and deep learning. We extend previous work by considering the effectiveness of a wide range of machine learning and deep learning technique for the classification of darknet traffic by application type. We consider the CICDarknet2020 dataset, which has been used in many previous studies, thus enabling a direct comparison of our results to previous work. We find that XGBoost performs the best among the classifiers that we …


Blue Carbon Opportunities: Seagrass Carbon Storage And Accumulation Rates At Trang, Thailand, Paul Lavery, Anna Lafratta, Rujinun Palahan, Maneewan Sanlee, Milica Stankovic, Janmanee Panyawai, Oscar Serrano, Pere Masque´ Jan 2023

Blue Carbon Opportunities: Seagrass Carbon Storage And Accumulation Rates At Trang, Thailand, Paul Lavery, Anna Lafratta, Rujinun Palahan, Maneewan Sanlee, Milica Stankovic, Janmanee Panyawai, Oscar Serrano, Pere Masque´

Research outputs 2022 to 2026

Report prepared as a contribution to the IKI Project “Conservation of biodiversity, seagrass ecosystems and their services – safeguarding food security and resilience in vulnerable coastal communities in a changing climate” funded through the International Klimate Initiative (IKI).

The IKI Project is a partnership between the CMS, Edith Cowan University, Project Seagrass, Seagrass Watch, Murdoch University, MRS, Blue Ventures, SAN, C3, ZSL, MareCet and Yapeka. The collaboration enhances the understanding of seagrass ecosystem services and the capacity to develop and deliver science-based policy solutions in seagrass conservation. It brings together scientists, policy experts, business development experts and conservation NGOs across …


Aspect Sentiment Triplet Extraction Incorporating Syntactic Constituency Parsing Tree And Commonsense Knowledge Graph, Zhenda Hu, Zhaoxia Wang, Yinglin Wang, Ah-Hwee Tan Jan 2023

Aspect Sentiment Triplet Extraction Incorporating Syntactic Constituency Parsing Tree And Commonsense Knowledge Graph, Zhenda Hu, Zhaoxia Wang, Yinglin Wang, Ah-Hwee Tan

Research Collection School Of Computing and Information Systems

The aspect sentiment triplet extraction (ASTE) task aims to extract the target term and the opinion term, and simultaneously identify the sentiment polarity of target-opinion pairs from the given sentences. While syntactic constituency information and commonsense knowledge are both important and valuable for the ASTE task, only a few studies have explored how to integrate them via flexible graph convolutional networks (GCNs) for this task. To address this gap, this paper proposes a novel end-to-end model, namely GCN-EGTS, which is an enhanced Grid Tagging Scheme (GTS) for ASTE leveraging syntactic constituency parsing tree and a commonsense knowledge graph based on …


Is A Pretrained Model The Answer To Situational Awareness Detection On Social Media?, Siaw Ling Lo, Kahhe Lee, Yuhao Zhang Jan 2023

Is A Pretrained Model The Answer To Situational Awareness Detection On Social Media?, Siaw Ling Lo, Kahhe Lee, Yuhao Zhang

Research Collection School Of Computing and Information Systems

Social media can be valuable for extracting information about an event or incident on the ground. However, the vast amount of content shared, and the linguistic variants of languages used on social media make it challenging to identify important situational awareness content to aid in decision-making for first responders. In this study, we assess whether pretrained models can be used to address the aforementioned challenges on social media. Various pretrained models, including static word embedding (such as Word2Vec and GloVe) and contextualized word embedding (such as DistilBERT) are studied in detail. According to our findings, a vanilla DistilBERT pretrained language …


Alkyd Resins Produced From Bio-Based Resources For More Sustainable And Environmentally Friendly Coating Applications, Cemi̇l Dizman, Eli̇f Cerrahoğlu Kaçakgi̇l Jan 2023

Alkyd Resins Produced From Bio-Based Resources For More Sustainable And Environmentally Friendly Coating Applications, Cemi̇l Dizman, Eli̇f Cerrahoğlu Kaçakgi̇l

Turkish Journal of Chemistry

Recently, due to the depletion of natural resources and raising environmental and economic concerns regarding petroleum derivatives, the creation of novel ecologically friendly and sustainable materials made from bio-based and renewable resources is gaining popularity. Alkyd resins are synthetic resins in which both renewable (fatty acids, glycerol, oil, etc.) and nonrenewable (maleic anhydride, pentaerythritol, phthalic anhydride, etc.) raw materials are used in their production. Due to their superior performance (good aging, greater weather resistance and high heat resistance, outstanding gloss, etc.) over other resins, easy application, low cost, and varied use, in the coating and paint industries, they are commonly …


Effect Of Okra Bast Fillers On Biodegradation Properties Of Poly(Vinyl Alcohol) Composites, Gazi Md Arifuzzaman Khan, Nazi̇re Deni̇z Yilmaz Jan 2023

Effect Of Okra Bast Fillers On Biodegradation Properties Of Poly(Vinyl Alcohol) Composites, Gazi Md Arifuzzaman Khan, Nazi̇re Deni̇z Yilmaz

Turkish Journal of Chemistry

This paper focuses on the effect of okra bast fillers on biodegradation of poly(vinyl alcohol) composites. Fibers were obtained from okra plant stems via biological degumming and subjected to different chemical treatments such as scouring, alkalizing, maleic anhydride treatment, and vinyl acetate grafting. The fibers were ground and PVA-okra bast filler composites were produced at 20 wt% fiber load via the solution casting method. The obtained composites were tested in terms of mechanical properties and exposed to biodegradation in soil. Effects of okra bast filler addition and chemical treatments on changes in mass, breaking strength, elasticity modulus, and breaking elongation …


Effect Of Carbon Fiber Reinforcement On Dimensional Variations Of 3d Printed Polyamide-6 Composites: A Simulation Study, Ans Al Rashid, Hamid Ikram, Muammer Koç Jan 2023

Effect Of Carbon Fiber Reinforcement On Dimensional Variations Of 3d Printed Polyamide-6 Composites: A Simulation Study, Ans Al Rashid, Hamid Ikram, Muammer Koç

Turkish Journal of Chemistry

Due to material design and fabrication flexibility, additive manufacturing (AM) or 3D printing (3DP) processes and polymer composites have paved their way into several industrial sectors. The quality of 3D printed polymer composites is highly dependent on the reinforcement content of polymers and 3DP process parameters. Several experimental studies are performed to optimize the reinforcement contents and process parameters; however, exploring the numerical modeling and simulation techniques is vital to lower the research and development costs. In the study, the numerical simulations for the 3DP process were performed using Digimat® software for carbon fiber-reinforced polyamide-6 (PA6) composites fabricated via the …


Effect Of Calcium Carbonate Particle Size And Content On The Thermal Properties Of Pvc Foamed Layer Used For Coated Textiles, Mouna Stambouli, Walid Chaouch, Sondes Gargoubi, Riadh Zouari, Slah Msahli Jan 2023

Effect Of Calcium Carbonate Particle Size And Content On The Thermal Properties Of Pvc Foamed Layer Used For Coated Textiles, Mouna Stambouli, Walid Chaouch, Sondes Gargoubi, Riadh Zouari, Slah Msahli

Turkish Journal of Chemistry

The goal of this research is to see how the amount and particle size of calcium carbonate (CaCO$_{3}$) used in the foamed layer in use for PVC-coated textiles affects the thermal properties of the material. Two different particle sizes were used at various concentrations. The impact of different CaCO$_{3}$ loadings and particle sizes on the PVC foamed layer's thermal properties were examined. Thermogravimetry (TGA and DTG) and differential scanning calorimetry (DSC) measurements were utilized to investigate the thermal properties of the PVC foamed layer and the samples have been also characterized by FTIR spectroscopy. According to the findings, the thermal …


Electrically Assisted Solution Blow Spinning Of Pvdf/Tpu Nanofibrous Mats For Air Filtration Applications, Andinet Kumella Eticha, Ali̇ Toptaş, Yasi̇n Akgül, Ali̇ Kiliç Jan 2023

Electrically Assisted Solution Blow Spinning Of Pvdf/Tpu Nanofibrous Mats For Air Filtration Applications, Andinet Kumella Eticha, Ali̇ Toptaş, Yasi̇n Akgül, Ali̇ Kiliç

Turkish Journal of Chemistry

In this study, pure polyvinylidene fluoride (PVDF), pure thermoplastic polyurethane (TPU), and PVDF/TPU blend nanofibers (1:3, 2:2, 3:1 ratios) were produced via electrically assisted solution blow spinning for air filtration applications. Scanning electron microscopy (SEM) analysis was conducted to investigate the diameters and morphology of nanofibers. The filtration performance of nanofibrous mats was examined by air filtration test with challenging with 0.26 ± 0.07 μm salt particles. Moreover, the flexibility and strength of the samples were determined via tensile tests. Results showed that pure TPU nanofibers had better mechanical properties, while pure PVDF nanofibers showed better filtration performance. However, 3PVDF/1TPU …


Investigating The Effect Of Poly (Ε-Caprolactone) Nanofibers Scaffolds With Random, Unidirectionally, And Radially Aligned Morphologies On The Fibroblast Cell?S Attachment And Growth Behavior, Saeed Nezari, Mohammadamin Sarli, Ahmad Hivechi, Hajir Bahrami, Peiman B. Milan, Noorahmad Latifi, Fatemeh Latifi, Tayyeb Ghadimi, S. Mohammad Amin Haramshahi, Soheila Naderi Gharahgheshlagh Jan 2023

Investigating The Effect Of Poly (Ε-Caprolactone) Nanofibers Scaffolds With Random, Unidirectionally, And Radially Aligned Morphologies On The Fibroblast Cell?S Attachment And Growth Behavior, Saeed Nezari, Mohammadamin Sarli, Ahmad Hivechi, Hajir Bahrami, Peiman B. Milan, Noorahmad Latifi, Fatemeh Latifi, Tayyeb Ghadimi, S. Mohammad Amin Haramshahi, Soheila Naderi Gharahgheshlagh

Turkish Journal of Chemistry

In the last decade, significant progress in tissue engineering, repairing, and replacing organs has been achieved. The design and production of scaffolds for tissue engineering are one of the main areas which have attracted the researcher's interest. In this regard, electrospinning is one of the most popular methods of nanoscale scaffold similar to extracellular matrix production. This paper reports the fabrication of scaffolds consisting of radially aligned PCL nanofibers by utilizing a collector composed of a central point electrode and a peripheral ring electrode. The chemical and physical properties were compared using SEM, FTIR, XRD, and DSC experiments, as well …


Surface Modification Of Polypropylene Nonwoven With Chitosan, Tio$_{2}$, And Ag Nanoparticles For The Removal Of Acid Dye From Water, Aminoddin Haji, Mohsen Hadizadeh, Masoumeh Ferdosi Jan 2023

Surface Modification Of Polypropylene Nonwoven With Chitosan, Tio$_{2}$, And Ag Nanoparticles For The Removal Of Acid Dye From Water, Aminoddin Haji, Mohsen Hadizadeh, Masoumeh Ferdosi

Turkish Journal of Chemistry

In this study, polypropylene nonwoven was coated with chitosan after being activated by oxygen/argon low-pressure plasma. The chitosan-treated sample (PP-Ch) was coated with TiO$_{2}$ nanoparticles by a pad-dry method. Silver nanoparticles were in situ synthesized on the chitosan-TiO$_{2}$-coated sample by a chemical reduction method. The morphology of each of the samples mentioned above was evaluated by FESEM. The efficiency of each sample in the removal of C.I. Acid Brown 248 from aqueous media was evaluated. The PP-Ch sample removed 90% of the dye at pH=3. Coating the PP-Ch sample with TiO$_{2}$ and silver nanoparticles improved the dye removal efficiency under …


Copper-Catalyzed Reactions Of Β-Alkoxy/Phenoxy Enones With Dimethyl Diazomalonate, Füsun Şeyma Kişkan Jan 2023

Copper-Catalyzed Reactions Of Β-Alkoxy/Phenoxy Enones With Dimethyl Diazomalonate, Füsun Şeyma Kişkan

Turkish Journal of Chemistry

2,3-dihydrofurans were synthesized from carbonyl-ylides via 1,5-electrocyclization reactions with high yields. Dimethyl diazomalonate was reacted with several β-alkoxy and/or β-phenoxy α,β-unsaturated compounds in the presence of Cu(acac)$_{2}$ as a catalyst. From the reaction of β-methoxy enone with diazo compound, dioxole, and Cα-H insertion products were also obtained as side products along with 2,3-dihydrofuran derivative. When the unsaturated compound has an ester and a ketone group, only one dihydrofuran derivative was formed, which occurred by the 1,5-ring closure of keto-carbonyl ylide. Dihydrofuran derivative from the formation of ester carbonyl ylide in the reactions was not obtained.


Catalytic Evaluation Of Cellulose Pyrolysis By Using Nanosized Metal Oxide Catalysts, Yusuf Osman Donar, Ali̇ Tolga Ünalan, Samed Ergenekon, Ali̇ Sinağ Jan 2023

Catalytic Evaluation Of Cellulose Pyrolysis By Using Nanosized Metal Oxide Catalysts, Yusuf Osman Donar, Ali̇ Tolga Ünalan, Samed Ergenekon, Ali̇ Sinağ

Turkish Journal of Chemistry

In this study, effects of TiO$_{2}$ and ZnO nanometal oxides on cellulose pyrolysis have been investigated. Both catalysts have been synthesized via hydrothermal method and characterized by using different techniques. Catalytic and catalyst-free experiments were carried out so as to identify the catalytic abilities of synthesized nanoparticles. Catalyst-free experiments were carried out at 500, 600, and 700 °C in order to determine the optimal condition for pyrolysis and it was found as 700 °C. Optimum catalyst ratio for cellulose pyrolysis was found as 5% (w/w) for both TiO$_{2}$ and ZnO catalysts. GC-MS and micro-GC analyses were conducted in order to …


Evaluation Of Photochemically Cross-Linked Collagen/Gold Nanoparticle Composites As Potential Skin Tissue Scaffolds, Evri̇m Meri̇ç Yelkuvan, Özge Erdemli̇, Bengi̇ Yilmaz, Ömer Aktürk Jan 2023

Evaluation Of Photochemically Cross-Linked Collagen/Gold Nanoparticle Composites As Potential Skin Tissue Scaffolds, Evri̇m Meri̇ç Yelkuvan, Özge Erdemli̇, Bengi̇ Yilmaz, Ömer Aktürk

Turkish Journal of Chemistry

Collagen type I is the main structural unit in skin tissue and is therefore used preferentially in skin tissue scaffolds. However, collagen-based 3D scaffolds have weak aqueous stability and degradation profiles in their uncross-linked states and chemical cross-linking reagents arise toxicity concerns, which generally restrict the spectrum of their biomedical applicability. Here, the research goal is to photochemically cross-link collagen type I with rose bengal (RB) when subjected to green laser light and to investigate the effect of silk sericin-capped gold nanoparticles (S-AuNP) when incorporated into scaffolds on the cross-linking process and thus on the scaffold properties. All the collagen …


Electrochemical Determination Of Aripiprazole Based On Aluminium Oxide Nanoparticles Modified Carbon Paste Electrode, Funda Öztürk, Eli̇f Yüksel, Pinar Esra Erden, Esma Kiliç Jan 2023

Electrochemical Determination Of Aripiprazole Based On Aluminium Oxide Nanoparticles Modified Carbon Paste Electrode, Funda Öztürk, Eli̇f Yüksel, Pinar Esra Erden, Esma Kiliç

Turkish Journal of Chemistry

The electrochemical oxidation of aripiprazole was explored at a carbon paste electrode modified with aluminium oxide nanoparticles by cyclic voltammetry and square-wave anodic adsorptive stripping voltammetry. Experimental parameters such as carbon paste composition, scan rate, buffer pH, accumulation time, and accumulation potential were optimized in order to obtain high analytical performance. The incorporation of aluminium oxide nanoparticles into the carbon paste matrix enhanced the effective surface area of the carbon paste electrode and improved the sensitivity. On the aluminium oxide nanoparticles modified carbon paste electrode, aripiprazole exhibited an irreversible anodic peak at +1.17 V in pH 1.8 BR buffer solution. …


Polymeric Nanoparticle-Based Electrochemical Sensor For The Detection Of Ca 125, Ceren Türkcan, Si̇nan Akgöl Jan 2023

Polymeric Nanoparticle-Based Electrochemical Sensor For The Detection Of Ca 125, Ceren Türkcan, Si̇nan Akgöl

Turkish Journal of Chemistry

In this paper, Cys-graft-p(HEMA) nanomaterials and a new electrochemical method were developed for determination of CA 125. Cys-graft-p(HEMA) nanomaterials were synthesized with emulsion polymerization method and modified with grafting procedure. It was determined that Cys-graft-p(HEMA) nanomaterials had 50 nm dimension and spherical morphology, and per gram polymeric material contained 0.011 mmol L-cysteine. Electrode surface was prepared step by step for electrochemical analysis with optimization process. Linear determination range was determined as 5-400 U/mL (R= 0.9935). Detection limit (LOD) was calculated as 1.87 U/mL, and quantification limit (LOQ) was determined as 5.62 U/mL. The fabricated sensor system showed good repeatability, accuracy, …


Structure-Emission Relationship Of Some Coumarin Laser Dyes And Related Molecules: Prediction Of Radiative Energy Dissipation And The Intersystem Crossing Rate Constants, Msa Abdelmottaleb Jan 2023

Structure-Emission Relationship Of Some Coumarin Laser Dyes And Related Molecules: Prediction Of Radiative Energy Dissipation And The Intersystem Crossing Rate Constants, Msa Abdelmottaleb

Turkish Journal of Chemistry

Dye lasers are commonly used in optical investigation because their solutions in organic solvents deliver tunable, coherent emissions. They exhibit intense fluorescence owing to some specific spectroscopic characteristics. One drawback of the laser dyes is that it shows excessive triplet-state losses (TSLs.) The lack of theoretical predictions of fluorescence rates, intersystem crossing (ISC), and phosphorescence in laser dyes prompted us to report on the predicted rates of radiative and nonradiative transitions of some laser dyes. Structural engineering by some substituents influencing the simulated rates of coumarin laser dye derivatives for an efficient operation was investigated. The NH$_{2}$ functional group renders …


Carbon Quantum Dots And Chitosan-Based Heterogeneous Silver Catalyst For Reduction Of Nitroaromatic Compounds, Farah Sami̇r Sali̇m, İdri̇s Sargin, Gülşi̇n Arslan Jan 2023

Carbon Quantum Dots And Chitosan-Based Heterogeneous Silver Catalyst For Reduction Of Nitroaromatic Compounds, Farah Sami̇r Sali̇m, İdri̇s Sargin, Gülşi̇n Arslan

Turkish Journal of Chemistry

Chitosan plays a crucial role in catalysis, environmental remediation, and sustainable chemistry as a renewable and cationic polysaccharide. Chitosan-based metal catalysts are used in a broad range of chemical transformations. In the study, carbon quantum dots (CQDs) were derived from Momordica charantia fruits by microwave irradiation following a green chemistry approach. Three catalysts were designed: Ag(0)-chitosan, Ag(0)-chitosan-M. charantia fruit powder, and Ag(0)-chitosan-CQDs. The catalyst supports were prepared by stabilizing CQDs or M. charantia powder within the polymeric matrix of chitosan beads. Metallic silver particles were anchored onto glutaraldehyde cross-linked chitosan beads from the aqueous solution of silver nitrate. The …